目的:通过航天诱变选育优良的知母突变体,定向培育成药用部分品质提升的优良种质资源。方法:利用我国发射的神舟三号宇宙飞船搭载知母种子,回收后在地面上筛选繁育,并对枝叶和产量等方面占优势的第4代太空组及地面组知母药用部分中多种...目的:通过航天诱变选育优良的知母突变体,定向培育成药用部分品质提升的优良种质资源。方法:利用我国发射的神舟三号宇宙飞船搭载知母种子,回收后在地面上筛选繁育,并对枝叶和产量等方面占优势的第4代太空组及地面组知母药用部分中多种元素含量用 X 射线荧光光谱(XRF)和粉末 X 射线衍射(PXRD)法测定并对比分析。结果:太空知母元素种类无改变,但 Zn、Sr 元素含量比地面组知母分别提高到2.7和1.7倍,Al 元素含量降低66.7%;并首次用 PXRD 技术在知母中鉴别出一水草酸钙晶体,太空知母中该晶体含量和晶粒尺寸比地面组明显减小。结论:航天诱变第4代知母中一水草酸钙晶体的含量明显减少,微量元素指标明显优化。通过航天诱变育种可以筛选出品质优化的知母新品种。展开更多
Objective: To develop the characterization of the polymorphs and the best preparation method of two forms of the title compound (SU2162). After SU2162 was prepared in accordance with the patent process, the crystal fo...Objective: To develop the characterization of the polymorphs and the best preparation method of two forms of the title compound (SU2162). After SU2162 was prepared in accordance with the patent process, the crystal form I was recrystallized by ethyl acetate and the crystal form II was obtained by the recrystal in acetone. And the two crystal forms were characterized with differential scanning calorimetry (DSC) and X-ray powder diffraction (PXRD). The melting point of crystal form I (triclinic) is at 158°C, and the melting point of crystal form II (monoclinic) is at 163°C. The PXRD studies of the two crystalline samples indicate that they have the distinct diffraction patterns. The method herein can be stably prepared for the two crystal forms of the title compound.展开更多
Study on the microscopic structure of clathrate hydrate has made significant progress in the past decades.This review aims to summarize the state of the art of the experimental characterization of vip molecular occu...Study on the microscopic structure of clathrate hydrate has made significant progress in the past decades.This review aims to summarize the state of the art of the experimental characterization of vip molecular occupancy in clathrate hydrate cages,which is an important area of the microscopic structures.The characterizing method and features of different vip molecular,such as hydrocarbon,carbon dioxide,hydrogen and inhibitor/promoter,in different hydrate cages have been extensively reviewed.A comprehensive use of advanced technologies such as X-ray diffraction,Raman spectroscopy and nuclear magnetic resonance may provide better understanding on the compositions and microscopic mechanisms of clathrate hydrate.展开更多
The title compound, tetramethylammonium nickel nitrite [（CH3）4N][Ni（NO2）3], has a hexagonal perovskite-type structure with formula ABX3. It undergoes two reversible phase transitions occurring at about 409.1 and 4...The title compound, tetramethylammonium nickel nitrite [（CH3）4N][Ni（NO2）3], has a hexagonal perovskite-type structure with formula ABX3. It undergoes two reversible phase transitions occurring at about 409.1 and 428.4 K, associated with dielectric transitions. DSC measurement and dielectric measurement confirm the transition. The variable-temperature X-ray structural determinations and the powder X-ray diffraction （PXRD） experiments reveal that this compound has the same space group P3ml （No. 164） at 293 K, 413 K and 438 K. The phase transitions are caused by the rotation of the [（CH3）4N]＋ cation.展开更多
A chiral supramolecular coordination polymer, [Co（HL）·（DMF）]n（1）, with helical chains from a flexible ligand 5-（imidazol-1-ylmethyl）isophthalic acid（H2L） has been obtained under hydrothermal conditions ...A chiral supramolecular coordination polymer, [Co（HL）·（DMF）]n（1）, with helical chains from a flexible ligand 5-（imidazol-1-ylmethyl）isophthalic acid（H2L） has been obtained under hydrothermal conditions and characterized by elemental analysis, powder X-ray diffraction（PXRD）, IR, Uv/vis spectra, thermal gravimetric analyses（TGA） and also by single-crystal X-ray diffraction. It crystallizes in hexagonal, space group P6522 with a = 8.8109（3）, b = 8.8109（3）, c = 71.771（3） , γ = 120°, V = 4825.3（3） -3, Z = 6, Mr = 695.55, Dc = 1.436 g/cm-3, Rint = 0.0684, F（000） = 2166, the final R = 0.0923 and w R = 0.2697 for 3056 observed reflections（I 2σ（I））. The title coordination polymer 1 shows a chiral layered structure based on right-handed helix chains. Such layers are associated together through hydrogen-bonding interactions to form a 3D supramolecular framework.展开更多
文摘目的:通过航天诱变选育优良的知母突变体,定向培育成药用部分品质提升的优良种质资源。方法:利用我国发射的神舟三号宇宙飞船搭载知母种子,回收后在地面上筛选繁育,并对枝叶和产量等方面占优势的第4代太空组及地面组知母药用部分中多种元素含量用 X 射线荧光光谱(XRF)和粉末 X 射线衍射(PXRD)法测定并对比分析。结果:太空知母元素种类无改变,但 Zn、Sr 元素含量比地面组知母分别提高到2.7和1.7倍,Al 元素含量降低66.7%;并首次用 PXRD 技术在知母中鉴别出一水草酸钙晶体,太空知母中该晶体含量和晶粒尺寸比地面组明显减小。结论:航天诱变第4代知母中一水草酸钙晶体的含量明显减少,微量元素指标明显优化。通过航天诱变育种可以筛选出品质优化的知母新品种。
文摘Objective: To develop the characterization of the polymorphs and the best preparation method of two forms of the title compound (SU2162). After SU2162 was prepared in accordance with the patent process, the crystal form I was recrystallized by ethyl acetate and the crystal form II was obtained by the recrystal in acetone. And the two crystal forms were characterized with differential scanning calorimetry (DSC) and X-ray powder diffraction (PXRD). The melting point of crystal form I (triclinic) is at 158°C, and the melting point of crystal form II (monoclinic) is at 163°C. The PXRD studies of the two crystalline samples indicate that they have the distinct diffraction patterns. The method herein can be stably prepared for the two crystal forms of the title compound.
基金Supported by the National Natural Science Foundation of China(51706248,51876222)National Key R&D Program of China(2017YFC0307304)
文摘Study on the microscopic structure of clathrate hydrate has made significant progress in the past decades.This review aims to summarize the state of the art of the experimental characterization of vip molecular occupancy in clathrate hydrate cages,which is an important area of the microscopic structures.The characterizing method and features of different vip molecular,such as hydrocarbon,carbon dioxide,hydrogen and inhibitor/promoter,in different hydrate cages have been extensively reviewed.A comprehensive use of advanced technologies such as X-ray diffraction,Raman spectroscopy and nuclear magnetic resonance may provide better understanding on the compositions and microscopic mechanisms of clathrate hydrate.
基金supported by the Project 973(No. 2014CB848800)National Natural Science Foundation of China (Nos.91022003 and 21301029)+1 种基金Jiangsu Province NSF(No. BK20130600)Program for NCET and Ph.D.Programs Foundation of Ministry of Education of China(No.20130092120013)
文摘The title compound, tetramethylammonium nickel nitrite [（CH3）4N][Ni（NO2）3], has a hexagonal perovskite-type structure with formula ABX3. It undergoes two reversible phase transitions occurring at about 409.1 and 428.4 K, associated with dielectric transitions. DSC measurement and dielectric measurement confirm the transition. The variable-temperature X-ray structural determinations and the powder X-ray diffraction （PXRD） experiments reveal that this compound has the same space group P3ml （No. 164） at 293 K, 413 K and 438 K. The phase transitions are caused by the rotation of the [（CH3）4N]＋ cation.
基金supported by Education Chamber of Henan Province(No.15A150068)
文摘A chiral supramolecular coordination polymer, [Co（HL）·（DMF）]n（1）, with helical chains from a flexible ligand 5-（imidazol-1-ylmethyl）isophthalic acid（H2L） has been obtained under hydrothermal conditions and characterized by elemental analysis, powder X-ray diffraction（PXRD）, IR, Uv/vis spectra, thermal gravimetric analyses（TGA） and also by single-crystal X-ray diffraction. It crystallizes in hexagonal, space group P6522 with a = 8.8109（3）, b = 8.8109（3）, c = 71.771（3） , γ = 120°, V = 4825.3（3） -3, Z = 6, Mr = 695.55, Dc = 1.436 g/cm-3, Rint = 0.0684, F（000） = 2166, the final R = 0.0923 and w R = 0.2697 for 3056 observed reflections（I 2σ（I））. The title coordination polymer 1 shows a chiral layered structure based on right-handed helix chains. Such layers are associated together through hydrogen-bonding interactions to form a 3D supramolecular framework.
