In recent years,FeCl_(3)-photocatalyzed direct C–H/Si–H bond functionalization reactions have attracted huge attention.In those transformations,chlorine radical(Cl·)could be generated from FeCl_(3)via a ligandt...In recent years,FeCl_(3)-photocatalyzed direct C–H/Si–H bond functionalization reactions have attracted huge attention.In those transformations,chlorine radical(Cl·)could be generated from FeCl_(3)via a ligandto-metal charge transfer(LMCT)/homolysis process under light irradiation.The resulting chlorine radical subsequently acts as a hydrogen atom transfer(HAT)agent to abstract the hydrogen atom of aliphatic C–H,O–H,or Si–H bonds to give the corresponding C/Si/O-centered radicals for various organic transformations.In this review,we summarized the recent advances in the application of FeCl_(3)as a HAT photocatalyst for the C/Si–H functionalization to construct C–C,C–N,C–Si,C–S,C–B,and C-P bonds.展开更多
基金the National Natural Science Foundation of China(Nos.21971224,22171249)Program for Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003).
文摘In recent years,FeCl_(3)-photocatalyzed direct C–H/Si–H bond functionalization reactions have attracted huge attention.In those transformations,chlorine radical(Cl·)could be generated from FeCl_(3)via a ligandto-metal charge transfer(LMCT)/homolysis process under light irradiation.The resulting chlorine radical subsequently acts as a hydrogen atom transfer(HAT)agent to abstract the hydrogen atom of aliphatic C–H,O–H,or Si–H bonds to give the corresponding C/Si/O-centered radicals for various organic transformations.In this review,we summarized the recent advances in the application of FeCl_(3)as a HAT photocatalyst for the C/Si–H functionalization to construct C–C,C–N,C–Si,C–S,C–B,and C-P bonds.
