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非对称烷烃体系气液相平衡预测模型的改进
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作者 黄辉荣 王丹 +4 位作者 杨居衡 杜培恩 李欣泽 彭泽桓 宫敬 《油气储运》 CAS 北大核心 2017年第3期267-273,共7页
针对高度非对称烷烃体系,对EOS-G^E气液相平衡预测模型加以改进,其中,状态方程采用考虑体积平移参数的PR-EOS,G^E通过UNIFAC溶液模型计算。针对基团贡献法中假设"溶液中所有基团各向同性"的不足,采用体积参数非线性加和的方式... 针对高度非对称烷烃体系,对EOS-G^E气液相平衡预测模型加以改进,其中,状态方程采用考虑体积平移参数的PR-EOS,G^E通过UNIFAC溶液模型计算。针对基团贡献法中假设"溶液中所有基团各向同性"的不足,采用体积参数非线性加和的方式对UNIFAC模型中组合活度系数加以改进。通过对比原始UNIFAC模型和改进UNIFAC模型的预测误差发现,当体系中轻组分含量较低时,原始UNIFAC模型和改进UNIFAC模型对体系泡点预测精度相当;当体系中轻组分含量较高时,原始UNIFAC模型泡点预测值远远低于实验值,而改进UNIFAC模型泡点预测值与实验值高度吻合。模型的改进不仅提高了非对称烷烃体系气液相平衡的预测精度,而且拓展了EOS-G^E模型的应用范围。 展开更多
关键词 气液相平衡 非对称烷烃体系 EOS-G E pr-eos UNIFAC
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Phase behavior of heavy oil-solvent mixture systems under reservoir conditions 被引量:2
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作者 Xiao-Fei Sun Zhao-Yao Song +2 位作者 Lin-Feng Cai Yan-Yu Zhang Peng Li 《Petroleum Science》 SCIE CAS CSCD 2020年第6期1683-1698,共16页
A novel experimental procedure was proposed to investigate the phase behavior of a solvent mixture(SM)(64 mol%CH4,8 mol%CO2,and 28 mol%C3 H8)with heavy oil.Then,a theoretical methodology was employed to estimate the p... A novel experimental procedure was proposed to investigate the phase behavior of a solvent mixture(SM)(64 mol%CH4,8 mol%CO2,and 28 mol%C3 H8)with heavy oil.Then,a theoretical methodology was employed to estimate the phase behavior of the heavy oil-solvent mixture(HO-SM)systems with various mole fractions of SM.The experimental results show that as the mole fraction of SM increases,the saturation pressures and swelling factors of the HO-SM systems considerably increase,and the viscosities and densities of the HO-SM systems decrease.The heavy oil is upgraded in situ via asphaltene precipitation and SM dissolution.Therefore,the solvent-enriched oil phase at the top layer of reservoirs can easily be produced from the reservoir.The aforementioned results indicate that the SM has promising application potential for enhanced heavy oil recovery via solvent-based processes.The theoretical methodology can accurately predict the saturation pressures,swelling factors,and densities of HO-SM systems with various mole fractions of SM,with average error percentages of1.77%for saturation pressures,0.07%for swelling factors,and 0.07%for densities. 展开更多
关键词 Heavy oil Solvent mixture pr-eos Phase behavior Pressure-volume-temperature(PVT)
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