Evaluation of water richness in sandstone is an important research topic in the prevention and control of mine water disasters,and the water richness in sandstone is closely related to its porosity.The refl ection sei...Evaluation of water richness in sandstone is an important research topic in the prevention and control of mine water disasters,and the water richness in sandstone is closely related to its porosity.The refl ection seismic exploration data have high-density spatial sampling information,which provides an important data basis for the prediction of sandstone porosity in coal seam roofs by using refl ection seismic data.First,the basic principles of the variational mode decomposition(VMD)method and the random forest method are introduced.Then,the geological model of coal seam roof sandstone is constructed,seismic forward modeling is conducted,and random noise is added.The decomposition eff ects of the empirical mode decomposition(EMD)method and VMD method on noisy signals are compared and analyzed.The test results show that the firstorder intrinsic mode functions(IMF1)and IMF2 decomposed by the VMD method contain the main eff ective components of seismic signals.A prediction process of sandstone porosity in coal seam roofs based on the combination of VMD and random forest method is proposed.The feasibility and eff ectiveness of the method are verified by trial calculation in the porosity prediction of model data.Taking the actual coalfield refl ection seismic data as an example,the sandstone porosity of the 8 coal seam roof is predicted.The application results show the potential application value of the new porosity prediction method proposed in this study.This method has important theoretical guiding significance for evaluating water richness in coal seam roof sandstone and the prevention and control of mine water disasters.展开更多
Attributing to the noteworthy volume change of silicon active particles upon cycling,the porosity of the coated silicon composite electrode can vary significantly and therefore be expected to affect the apparent mecha...Attributing to the noteworthy volume change of silicon active particles upon cycling,the porosity of the coated silicon composite electrode can vary significantly and therefore be expected to affect the apparent mechanical response of the composite electrode.However,direct experimental evidence is still lacking.By stripping the active layer from the current collector and performing quasi-static stretching tests,this work shows a direct correlation between the variation of tensile properties and related coating porosity of the silicon composite electrode during lithiation.Although silicon particles soften when lithiated,it is found that the increased particle volume can significantly lower the porosity of the coating,resulting in the densification of the silicon composite electrode and thus reducing the toughness of the silicon composite electrode and making the electrode more prone to lose its mechanical integrity under small strain in service.Based on finite element simulation and experimental data analysis,analytical expressions of equivalent modulus and strength of the porous silicon composite electrode were also constructed and are in good agreement with the experimental values.Moreover,the maximum tensile stress of the electrode was found to be amplified by at least 1.8 times when the coating-dependent porosity is considered,indicating the necessity in the design of electrode structural integrity and optimization in service.The results of work are expected to provide important experimental data and model basis for the mechanical design of silicon composite electrodes upon usage.展开更多
This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were perfor...This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were performed on sand samples with various porosities at different temperatures and centrifugal accelerations.The objectives were to qualitatively and quantitatively investigate the effects of temperature,porosity,and centrifugal acceleration on the hydraulic conductivity of sand and to study the applicability of the Kozeny-Carman equation for the centrifugal environment.Test results showed that in a similar temperature range and under the same porosity,the hydraulic conductivity of the sand is linearly correlated with centrifugal acceleration.When subjected to the same centrifugal acceleration and in a similar temperature range,the hydraulic conductivity of the sand exhibits an almost linear increase in relation to its porosity function(s^(3)/(1−s)^(2));the functional relationships between the hydraulic conductivity of the sand and temperature,centrifugal acceleration level,and porosity were established using two pathways.When the centrifugal acceleration is less than 50g,the Kozeny-Carman equation is effectively accurate in predicting the hydraulic conductivity of sand;however,when the centrifugal acceleration exceeds 50g,it is important to consider a significant error.展开更多
The recently reported silicon/graphite(Si/Gr)composite electrode with a layered structure is a promising approach to achieve high capacity and stable cycling of Si-based electrodes in lithium-ion batteries.However,the...The recently reported silicon/graphite(Si/Gr)composite electrode with a layered structure is a promising approach to achieve high capacity and stable cycling of Si-based electrodes in lithium-ion batteries.However,there is still a need to clarify why particular layered structures are effective and why others are ineffective or even detrimental.In this work,an unreported mechanism dominated by the porosity evolution of electrodes is proposed for the degradation behavior of layered Si/Gr electrodes.First,the effect of layering sequence on the overall electrode performance is investigated experimentally,and the results suggest that the cycling performance of the silicon-on-graphite(SG)electrode is much superior to that of the graphite-on-silicon electrode.To explain this phenomenon,a coupled mechanical-electrochemical porous electrode model is developed,in which the porosity is affected by the silicon expansion and the local constraints.The modeling results suggest that the weaker constraint of the silicon layer in the SG electrode leads to a more insignificant decrease in porosity,and consequently,the more stable cycling performance.The findings of this work provide new insights into the structural design of Si-based electrodes.展开更多
Novel neutral electrolytes were designed to substantially decrease porosity and increase barrier property of plasma electrolytic oxidation(PEO)coating on AM50 Mg surface.Presence of additives was effective in tuning c...Novel neutral electrolytes were designed to substantially decrease porosity and increase barrier property of plasma electrolytic oxidation(PEO)coating on AM50 Mg surface.Presence of additives was effective in tuning coating microstructure and composition,leading to significantly enhanced corrosion and wear properties.50%improvement in fatigue limit was detected for the optimized coating compared to conventional PEO coating.The low-porosity coating remained uncorroded after performing salt spray test for 1 month,and exposure 1 year in harsh South China Sea environment.This can be new strategy to evaluate coating lifespan and promote wide range of applications for Mg alloy.展开更多
Porosity is an important attribute for evaluating the petrophysical properties of reservoirs, and has guiding significance for the exploration and development of oil and gas. The seismic inversion is a key method for ...Porosity is an important attribute for evaluating the petrophysical properties of reservoirs, and has guiding significance for the exploration and development of oil and gas. The seismic inversion is a key method for comprehensively obtaining the porosity. Deep learning methods provide an intelligent approach to suppress the ambiguity of the conventional inversion method. However, under the trace-bytrace inversion strategy, there is a lack of constraints from geological structural information, resulting in poor lateral continuity of prediction results. In addition, the heterogeneity and the sedimentary variability of subsurface media also lead to uncertainty in intelligent prediction. To achieve fine prediction of porosity, we consider the lateral continuity and variability and propose an improved structural modeling deep learning porosity prediction method. First, we combine well data, waveform attributes, and structural information as constraints to model geophysical parameters, constructing a high-quality training dataset with sedimentary facies-controlled significance. Subsequently, we introduce a gated axial attention mechanism to enhance the features of dataset and design a bidirectional closed-loop network system constrained by inversion and forward processes. The constraint coefficient is adaptively adjusted by the petrophysical information contained between the porosity and impedance in the study area. We demonstrate the effectiveness of the adaptive coefficient through numerical experiments.Finally, we compare the performance differences between the proposed method and conventional deep learning methods using data from two study areas. The proposed method achieves better consistency with the logging porosity, demonstrating the superiority of the proposed method.展开更多
The application of a controllable neutron source for measuring formation porosity in the advancement of nuclear logging has garnered increased attention.The existing porosity algorithm,which is based on the thermal ne...The application of a controllable neutron source for measuring formation porosity in the advancement of nuclear logging has garnered increased attention.The existing porosity algorithm,which is based on the thermal neutron counting ratio,exhibits lower sensitivity in high-porosity regions.To enhance the sensitivity,the effects of elastic and inelastic scattering,which influence the slowing-down of fast neutrons,were theoretically analyzed,and a slowing-down model of fast neutrons was created.Based on this model,a density correction porosity algorithm was proposed based on the relationship between density,thermal neutron counting ratio,and porosity.Finally,the super multifunctional calculation program for nuclear design and safety evaluation(TopMC/SuperMC)was used to create a simulation model for porosity logging,and its applicability was examined.The results demonstrated that the relative error between the calculated and actual porosities was less than 1%,and the influence of deviation in the density measurement was less than 2%.Therefore,the proposed density correction algorithm based on the slowing-down model of fast neutrons can effectively improve the sensitivity in the high-porosity region.This study is expected to serve as a reference for the application of neutron porosity measurements with D–T neutron sources.展开更多
The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron mi...The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM)and laboratory computed tomography(CT).Results showed that the newly developed AlSi9MnMoV alloy exhibited improved mechanical properties when compared to the AlSi10MnMg alloy.The AlSi9MnMoV alloy,which was designed with trace multicomponent additions,displays a notable grain refining effect in comparison to the AlSi10MnMg alloy.Refining elements Ti,Zr,V,Nb,B promote heterogeneous nucleation and reduce the grain size of primaryα-Al.At a lower slow shot speed,the large ESCs are easier to form and gather,developing into the dendrite net and net-shrinkage.With an increase in slow shot speed,the size and number of ESCs and porosities significantly reduce.In addition,the distribution of ESCs is more dispersed and the net-shrinkage disappears.The tensile property is greatly improved by adopting a higher slow shot speed.The ultimate tensile strength is enhanced from 260.31 MPa to 290.31 MPa(increased by 11.52%),and the elongation is enhanced from 3.72%to 6.34%(increased by 70.52%).展开更多
This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin,Pakistan.Multiple data sets including outcrop,petrography,cathodolumin...This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin,Pakistan.Multiple data sets including outcrop,petrography,cathodoluminescence,scanning electron microscopy(SEM),mineralogy,and geochemical isotopic compositions were integrated to establish a link between porosity evolution and diagenesis.The spatial thickness and facies variations of the strata at outcrop scale are inherently controlled by the underlying bathymetry of the basin with deepening westward trend.The low values ofδ^(18)O of the target strata,relative to average values of the Permian carbonate,hints to diagenetic alteration in the strata.The data sets used in this study reveal modification of the strata in four environments,that is,i)early marine diagenesis indicated by micritization,pervasive dolomitization and isopachous fibrous cements,followed by ii)meteoric dissolution,and iii)shallow burial diagenetic processes including the precipitation of blocky cement,compaction of skeletal and non-skeletal allochems,and stylolites,and iv)a deep burial environment,characterized by pressure solution,and micro-fractures.The clastic intervals host subangular to subrounded quartz grains,floating textures,and almost complete absence of deleterious clay minerals,consequently resulting in the preservation of primary porosity.The primary porosity of carbonate intervals is preserved in the form of intercrystalline and intracrystalline porosity.The secondary porosity evolved through various diagenetic phases in the form of fractures and dissolution.The diagenetic solution mediated by organic matter in carbonates may have experienced both bacterial decomposition and thermochemical sulfate reduction,precipitating sulfides within the pores.The plug porosity/permeability analyses generally suggest high porosity in the siliciclastic unit,and carbonates with wackestone fabric while lower values were observed for the inner shelf pure carbonate facies.However,both intervals show very low permeability values probably due to isolated moldic pores and intense micritization.Therefore,clastic intervals may provide an opportunity to serve as a moderate reservoir;however,the carbonate intervals possess very low permeability values and could generally be considered as low-moderate reservoir potential.展开更多
We apply stochastic seismic inversion and Bayesian facies classification for porosity modeling and igneous rock identification in the presalt interval of the Santos Basin. This integration of seismic and well-derived ...We apply stochastic seismic inversion and Bayesian facies classification for porosity modeling and igneous rock identification in the presalt interval of the Santos Basin. This integration of seismic and well-derived information enhances reservoir characterization. Stochastic inversion and Bayesian classification are powerful tools because they permit addressing the uncertainties in the model. We used the ES-MDA algorithm to achieve the realizations equivalent to the percentiles P10, P50, and P90 of acoustic impedance, a novel method for acoustic inversion in presalt. The facies were divided into five: reservoir 1,reservoir 2, tight carbonates, clayey rocks, and igneous rocks. To deal with the overlaps in acoustic impedance values of facies, we included geological information using a priori probability, indicating that structural highs are reservoir-dominated. To illustrate our approach, we conducted porosity modeling using facies-related rock-physics models for rock-physics inversion in an area with a well drilled in a coquina bank and evaluated the thickness and extension of an igneous intrusion near the carbonate-salt interface. The modeled porosity and the classified seismic facies are in good agreement with the ones observed in the wells. Notably, the coquinas bank presents an improvement in the porosity towards the top. The a priori probability model was crucial for limiting the clayey rocks to the structural lows. In Well B, the hit rate of the igneous rock in the three scenarios is higher than 60%, showing an excellent thickness-prediction capability.展开更多
Reducing coke use is an effective measure to reduce carbon emission and energy consumption in the blast furnace(BF)ironmaking.Essentially,BF is a high-temperature moving bed reactor,where complex physical transformati...Reducing coke use is an effective measure to reduce carbon emission and energy consumption in the blast furnace(BF)ironmaking.Essentially,BF is a high-temperature moving bed reactor,where complex physical transformations coupled with complicated reactions occur.This makes it challenging to investigate the factors determining BF performance with the conventional method.A multi-physical field coupling mathematical model of BF was thus developed to describe its mass and heat transfer as well as its intrinsic reactions.Then,the proposed model was validated with the production data.Under coupling conditions,influences of dominating reactions on BF performance(temperature distribution,gas distribution,iron formation reaction,and direct reduction degree)were revealed.The results indicated that coke combustion,indirect reduction,and direct reduction of iron ore mainly took place nearby the shaft tuyere,cohesive zone,and dripping zone,respectively.Besides,the rate of coke solution loss reaction was increased with the rising coke porosity in the cohesive zone.Considering the effect of coke porosity on the efficiency and stability of BF,the coke porosity of 0.42 was regarded as a reasonable value.展开更多
The measurement of nuclear magnetic resonance(NMR)porosity is affected by temperature.Without considering the impact of NMR logging tools,this phenomenon is mainly caused by variations in magnetization intensity of th...The measurement of nuclear magnetic resonance(NMR)porosity is affected by temperature.Without considering the impact of NMR logging tools,this phenomenon is mainly caused by variations in magnetization intensity of the measured system due to temperature fluctuations and difference between the temperature of the porous medium and calibration sample.In this study,the effect of temperature was explained based on the thermodynamic theory,and the rules of NMR porosity responses to temperature changes were identified through core physics experiments.In addition,a method for correcting the influence of temperature on NMR porosity measurement was proposed,and the possible factors that may affect its application were also discussed.展开更多
The real-time detection of porosity in welding process is an important problem to be solved in intelligent welding manufacturing.A new on-line detection method for porosity of aluminum alloy in robotic arc welding bas...The real-time detection of porosity in welding process is an important problem to be solved in intelligent welding manufacturing.A new on-line detection method for porosity of aluminum alloy in robotic arc welding based on arc spectrum is proposed in this paper.First,k-shape and the improved k-means were used for the initial feature selection of the preprocessed arc spectrum to reduce the data dimension.Second,the secondary feature selection was carried out based on the importance of features to further reduce feature redundancy.Then,the optimal sample label library was established by combining the final characteristic parameters and the X-ray pictures of welds.Finally,an on-line detection method of porosity in gas tungsten arc welding of aluminum alloy based on light gradient boosting machine(LightGBM)was proposed.Compared with extreme gradient boosting(XGBoost)and categorical boosting(CatBoost),this method can achieve better detection performance.The new method proposed in this paper can be used to detect other welding defects,which is helpful to the development of intelligent welding technology.展开更多
In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not...In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not just at predicting geophysical logging curve values but also innovatively mitigate hydrocarbon depletion observed in geochemical logging.Through a rigorous assessment,we explore the efficacy of eight regression models,bifurcated into linear and nonlinear groups,to accommodate the multifaceted nature of geological datasets.Our linear model suite encompasses the Standard Equation,Ridge Regression,Least Absolute Shrinkage and Selection Operator,and Elastic Net,each presenting distinct advantages.The Standard Equation serves as a foundational benchmark,whereas Ridge Regression implements penalty terms to counteract overfitting,thus bolstering model robustness in the presence of multicollinearity.The Least Absolute Shrinkage and Selection Operator for variable selection functions to streamline models,enhancing their interpretability,while Elastic Net amalgamates the merits of Ridge Regression and Least Absolute Shrinkage and Selection Operator,offering a harmonized solution to model complexity and comprehensibility.On the nonlinear front,Gradient Descent,Kernel Ridge Regression,Support Vector Regression,and Piecewise Function-Fitting methods introduce innovative approaches.Gradient Descent assures computational efficiency in optimizing solutions,Kernel Ridge Regression leverages the kernel trick to navigate nonlinear patterns,and Support Vector Regression is proficient in forecasting extremities,pivotal for exploration risk assessment.The Piecewise Function-Fitting approach,tailored for geological data,facilitates adaptable modeling of variable interrelations,accommodating abrupt data trend shifts.Our analysis identifies Ridge Regression,particularly when augmented by Piecewise Function-Fitting,as superior in recouping hydrocarbon losses,and underscoring its utility in resource quantification refinement.Meanwhile,Kernel Ridge Regression emerges as a noteworthy strategy in ameliorating porosity-logging curve prediction for well A,evidencing its aptness for intricate geological structures.This research attests to the scientific ascendancy and broad-spectrum relevance of these regression techniques over conventional methods while heralding new horizons for their deployment in the oil and gas sector.The insights garnered from these advanced modeling strategies are set to transform geological and engineering practices in hydrocarbon prediction,evaluation,and recovery.展开更多
Wire arc additive manufacturing(WAAM)technique is a promising approach to producing large-scale metal components due to high deposition efficiency and low production cost.However,fundamental research about WAAM-proces...Wire arc additive manufacturing(WAAM)technique is a promising approach to producing large-scale metal components due to high deposition efficiency and low production cost.However,fundamental research about WAAM-processed Al-Mg-Sc-Zr alloy was still fewer.In this study,Al-6.54Mg-0.36Sc-0.11Zr(wt%)components were successfully manufactured by WAAM with an interlayer temperature at 100℃(named IW)and continuous printing(named CP),and the corresponding porosity,microstructure,and mechanical properties of components were studied in detail.The porosity of components as-deposited was relatively low,about 0.385%and 0.116%,respectively.The microstructures of the two components exhibited the same distribution characteristics in XZ and YZ planes:fine equiaxed grains(FEG)at remelted zone+FEG and coarse equiaxed grain(CEG)alternative distribution at middle zone+FEG at the top zone of the molten pool.The average grain size of component IW was about 10.51±6.01μm,and that of component CP significantly increased,to about 11.85±5.86μm.The short-circuit transition mode of cold metal transfer technology and the heterogeneous nucleation effect of primary Al3(Sc,Zr)and Al3(Sc,Zr,Ti)phases together promoted the formation of equiaxed grains and refined the microstructures.After heat treatment at 325℃and 6 h,nano-Al3Sc precipitated with a size of about 15-50 nm.The yield strength(YS)of components IW and CP increased from 171±3 to 261±1 MPa and 168±7 to 240±17 MPa,respectively.Component IW had the highest ultimate tensile strength,about 400±1 MPa.For WAAMprocessed Al-Mg-Sc-Zr alloys,the contribution of the strengthening mechanism to YS was solid solution strengthening>precipitation strengthening>fine grain strengthening>dislocation strengthening.展开更多
A three-dimensional finite element model coupled with heat transfer,shrinkage accumulation and high temperature deformation was established forϕ690 mm round bloom in continuous casting,and it was verified by surface t...A three-dimensional finite element model coupled with heat transfer,shrinkage accumulation and high temperature deformation was established forϕ690 mm round bloom in continuous casting,and it was verified by surface temperature,shell thickness,contour shape and porosity size by measurement.The compensation area of the shrinkage zone increases as the reduction amount increases.The compensation effect by the reduction of the unit with liquid core is about two times higher than others with fully solid matrix at a given reduction amount.A mathematical method to determine the reduction parameters for large-sized round bloom during continuous casting was proposed by the multi-rollers strategy.For theϕ690 mm round bloom,the suitable reduction parameters for Nos.2–6 units are suggested as 15,15,10,10,10 mm with a casting speed of 0.26 m min^(-1)to close the shrinkage with a diameter of about 17.5 mm in average.The industrial test on the reduction of large-sized round bloom for LZ50 steel was carried out.A total amount of 65–70 mm reduction was realized in the bloom for different casting speeds.The maximum diameter of the central porosity is about 16.3 mm in the longitudinal section at the casting speed of 0.24 m min^(-1),and it decreases to 7.3 mm after 65 mm reduction.Meanwhile,the maximum diameter of the central porosity is about 18.7 mm at 0.26 m min^(-1),while it decreases to 4.1 mm by a reduction of 70 mm.Finally,the difference of the solidification end reduction on round bloom and rectangular or square bloom is theoretically compared.Low deformation resistance and high bulge effect were found in round bloom compared to rectangular bloom.According to the results about solidification contraction accumulation and reduction efficiency in round bloom,the suitable reduction zone to control the central porosity during continuous casting is suggested to be 0.5–1.0.展开更多
We consider a generalized form of the porous medium equation where the porosity ϕis a function of time t: ϕ=ϕ(x,t): ∂(ϕS)∂t−∇⋅(k(S)∇S)=Q(S).In many works, the porosity ϕis either assumed to be independent of (or to de...We consider a generalized form of the porous medium equation where the porosity ϕis a function of time t: ϕ=ϕ(x,t): ∂(ϕS)∂t−∇⋅(k(S)∇S)=Q(S).In many works, the porosity ϕis either assumed to be independent of (or to depend very little of) the time variable t. In this work, we want to study the case where it does depend on t(and xas well). For this purpose, we make a change of unknown function V=ϕSin order to obtain a saturation-like (advection-diffusion) equation. A priori estimates and regularity results are established for the new equation based in part on what is known from the saturation equation, when ϕis independent of the time t. These results are then extended to the full saturation equation with time-dependent porosity ϕ=ϕ(x,t). In this analysis, we make explicitly the dependence of the various constants in the estimates on the porosity ϕby the introduced transport vector w, through the change of unknown function. Also we do not assume zero-flux boundary, but we carry the analysis for the case Q≡0.展开更多
The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, ...The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, cementation and dissolution — affect reservoir properties most intensively. An average porosity loss due to compaction is 0.78% per 100 meters, slightly higher in the central and southern parts and lower in the northern. Cementation has resulted in the porosity loss from 8% to 20% at a depth below 1,500 meters. Dissolution, which in most cases is the dissolution of feldspar and of carbonate cement, primarily occurs in two depth intervals, from 1,400 to 2,500 meters and 2,700 to 4,000 meters respectively. New porosity is created through dissolution from 4% to 14%. The sandstones experienced stage A and stage B of early diagenesis and stage A of late diagenesis. At present, most of them are experiencing Phase A2 of late diagenesis. The types of pores in the sand reservoir can be grouped into primary and secondary ones.展开更多
Activated carbons (ACs) calcined at 400˚C, 500˚C, and 600˚C (AC-400, AC-500, and AC-600) were prepared using palm nut shells from Gabon as raw material and zinc chloride (ZnCl2) as a chemical activating agent. Prepare...Activated carbons (ACs) calcined at 400˚C, 500˚C, and 600˚C (AC-400, AC-500, and AC-600) were prepared using palm nut shells from Gabon as raw material and zinc chloride (ZnCl2) as a chemical activating agent. Prepared ACs were characterized by physisorption of nitrogen (N2), determination of diode and methylene blue numbers for studies of porosity and by quantification and determination of surface functional groups and pH at point of zero charge (pHpzc) respectively, for studies of chemical properties of prepared ACs. Then, effects of calcination temperature (Tcal) on porosity and chemical properties of prepared ACs were studied. The results obtained showed that when the calcination temperature increases from 500˚C to 600˚C, the porosity and chemical properties of prepared ACs are modified. Indeed, the methylene blue and iodine numbers determined for activated carbons AC-400 (460 and 7.94 mg·g−1, respectively) and AC-500 (680 and 8.90 mg·g−1, respectively) are higher than those obtained for AC-600 (360 and 5.75 mg·g−1, respectively). Compared to the AC-500 adsorbent, specific surface areas (SBET) and microporous volume losses for AC-600 were estimated to 44.7% and 45.8%, respectively. Moreover, in our experimental conditions, the effect of Tcal on the quantities of acidic and basic functional groups on the surface of the ACs appears negligible. In addition, results of the pHpzc of prepared ACs showed that as Tcal increases, the pH of the adsorbents increases and tends towards neutrality. Indeed, a stronger acidity was determined on AC-400 (pHpzc = 5.60) compared to those on AC-500 and AC-600 (pHpzc = 6.85 and 6.70, respectively). Also according to the results of porosity and chemical characterizations, adsorption being a surface phenomenon, 500˚C appears to be the optimal calcination temperature for the preparation of activated carbons from palm nut shells in our experimental conditions.展开更多
A critical porosity model is often used to calculate the dry frame elastic modulus by the rock critical porosity value which is affected by many factors. In practice it is hard for us to obtain an accurate critical po...A critical porosity model is often used to calculate the dry frame elastic modulus by the rock critical porosity value which is affected by many factors. In practice it is hard for us to obtain an accurate critical porosity value and we can generally take only an empirical critical porosity value which often causes errors. In this paper, we propose a method to obtain the rock critical porosity value by inverting P-wave velocity and applying it to predict S-wave velocity. The applications of experiment and log data both show that the critical porosity inversion method can reduce the uncertainty resulting from using an empirical value in the past and provide the accurate critical porosity value for predicting S-wave velocity which significantly improves the prediction accuracy.展开更多
基金National Natural Science Foundation of China(Grant No.42274180)National Key Research and Development Program of China(2021YFC2902003).
文摘Evaluation of water richness in sandstone is an important research topic in the prevention and control of mine water disasters,and the water richness in sandstone is closely related to its porosity.The refl ection seismic exploration data have high-density spatial sampling information,which provides an important data basis for the prediction of sandstone porosity in coal seam roofs by using refl ection seismic data.First,the basic principles of the variational mode decomposition(VMD)method and the random forest method are introduced.Then,the geological model of coal seam roof sandstone is constructed,seismic forward modeling is conducted,and random noise is added.The decomposition eff ects of the empirical mode decomposition(EMD)method and VMD method on noisy signals are compared and analyzed.The test results show that the firstorder intrinsic mode functions(IMF1)and IMF2 decomposed by the VMD method contain the main eff ective components of seismic signals.A prediction process of sandstone porosity in coal seam roofs based on the combination of VMD and random forest method is proposed.The feasibility and eff ectiveness of the method are verified by trial calculation in the porosity prediction of model data.Taking the actual coalfield refl ection seismic data as an example,the sandstone porosity of the 8 coal seam roof is predicted.The application results show the potential application value of the new porosity prediction method proposed in this study.This method has important theoretical guiding significance for evaluating water richness in coal seam roof sandstone and the prevention and control of mine water disasters.
基金the Natural Science Foundation of Shanghai(Grant No.23ZR1421800)the National Natural Science Foundation of China(Grant Nos.12272213 and 11872235).
文摘Attributing to the noteworthy volume change of silicon active particles upon cycling,the porosity of the coated silicon composite electrode can vary significantly and therefore be expected to affect the apparent mechanical response of the composite electrode.However,direct experimental evidence is still lacking.By stripping the active layer from the current collector and performing quasi-static stretching tests,this work shows a direct correlation between the variation of tensile properties and related coating porosity of the silicon composite electrode during lithiation.Although silicon particles soften when lithiated,it is found that the increased particle volume can significantly lower the porosity of the coating,resulting in the densification of the silicon composite electrode and thus reducing the toughness of the silicon composite electrode and making the electrode more prone to lose its mechanical integrity under small strain in service.Based on finite element simulation and experimental data analysis,analytical expressions of equivalent modulus and strength of the porous silicon composite electrode were also constructed and are in good agreement with the experimental values.Moreover,the maximum tensile stress of the electrode was found to be amplified by at least 1.8 times when the coating-dependent porosity is considered,indicating the necessity in the design of electrode structural integrity and optimization in service.The results of work are expected to provide important experimental data and model basis for the mechanical design of silicon composite electrodes upon usage.
基金supported by the Basic Science Center Program for Multiphase Media Evolution in Hypergravity of the National Natural Science Foundation of China(No.51988101)。
文摘This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were performed on sand samples with various porosities at different temperatures and centrifugal accelerations.The objectives were to qualitatively and quantitatively investigate the effects of temperature,porosity,and centrifugal acceleration on the hydraulic conductivity of sand and to study the applicability of the Kozeny-Carman equation for the centrifugal environment.Test results showed that in a similar temperature range and under the same porosity,the hydraulic conductivity of the sand is linearly correlated with centrifugal acceleration.When subjected to the same centrifugal acceleration and in a similar temperature range,the hydraulic conductivity of the sand exhibits an almost linear increase in relation to its porosity function(s^(3)/(1−s)^(2));the functional relationships between the hydraulic conductivity of the sand and temperature,centrifugal acceleration level,and porosity were established using two pathways.When the centrifugal acceleration is less than 50g,the Kozeny-Carman equation is effectively accurate in predicting the hydraulic conductivity of sand;however,when the centrifugal acceleration exceeds 50g,it is important to consider a significant error.
基金supported by the National Natural Science Foundation of China(Grant Nos.12072183,12472174,and 12421002).
文摘The recently reported silicon/graphite(Si/Gr)composite electrode with a layered structure is a promising approach to achieve high capacity and stable cycling of Si-based electrodes in lithium-ion batteries.However,there is still a need to clarify why particular layered structures are effective and why others are ineffective or even detrimental.In this work,an unreported mechanism dominated by the porosity evolution of electrodes is proposed for the degradation behavior of layered Si/Gr electrodes.First,the effect of layering sequence on the overall electrode performance is investigated experimentally,and the results suggest that the cycling performance of the silicon-on-graphite(SG)electrode is much superior to that of the graphite-on-silicon electrode.To explain this phenomenon,a coupled mechanical-electrochemical porous electrode model is developed,in which the porosity is affected by the silicon expansion and the local constraints.The modeling results suggest that the weaker constraint of the silicon layer in the SG electrode leads to a more insignificant decrease in porosity,and consequently,the more stable cycling performance.The findings of this work provide new insights into the structural design of Si-based electrodes.
基金supported by LiaoNing Revitalization Talents Program(XLYC2403026)Shenyang Young and Middle-aged Science and Technology Innovation Talent Support Program(No.RC231178)the Fundamental Research Funds for the Central Universities(No.N2302019).
文摘Novel neutral electrolytes were designed to substantially decrease porosity and increase barrier property of plasma electrolytic oxidation(PEO)coating on AM50 Mg surface.Presence of additives was effective in tuning coating microstructure and composition,leading to significantly enhanced corrosion and wear properties.50%improvement in fatigue limit was detected for the optimized coating compared to conventional PEO coating.The low-porosity coating remained uncorroded after performing salt spray test for 1 month,and exposure 1 year in harsh South China Sea environment.This can be new strategy to evaluate coating lifespan and promote wide range of applications for Mg alloy.
基金the support of Research Program of Fine Exploration and Surrounding Rock Classification Technology for Deep Buried Long Tunnels Driven by Horizontal Directional Drilling and Magnetotelluric Methods Based on Deep Learning under Grant E202408010the Sichuan Science and Technology Program under Grant 2024NSFSC1984 and Grant 2024NSFSC1990。
文摘Porosity is an important attribute for evaluating the petrophysical properties of reservoirs, and has guiding significance for the exploration and development of oil and gas. The seismic inversion is a key method for comprehensively obtaining the porosity. Deep learning methods provide an intelligent approach to suppress the ambiguity of the conventional inversion method. However, under the trace-bytrace inversion strategy, there is a lack of constraints from geological structural information, resulting in poor lateral continuity of prediction results. In addition, the heterogeneity and the sedimentary variability of subsurface media also lead to uncertainty in intelligent prediction. To achieve fine prediction of porosity, we consider the lateral continuity and variability and propose an improved structural modeling deep learning porosity prediction method. First, we combine well data, waveform attributes, and structural information as constraints to model geophysical parameters, constructing a high-quality training dataset with sedimentary facies-controlled significance. Subsequently, we introduce a gated axial attention mechanism to enhance the features of dataset and design a bidirectional closed-loop network system constrained by inversion and forward processes. The constraint coefficient is adaptively adjusted by the petrophysical information contained between the porosity and impedance in the study area. We demonstrate the effectiveness of the adaptive coefficient through numerical experiments.Finally, we compare the performance differences between the proposed method and conventional deep learning methods using data from two study areas. The proposed method achieves better consistency with the logging porosity, demonstrating the superiority of the proposed method.
基金supported by the Anhui Provincial Major Science and Technology Project(No.201903c08020003)the Taishan industrial Experts Program。
文摘The application of a controllable neutron source for measuring formation porosity in the advancement of nuclear logging has garnered increased attention.The existing porosity algorithm,which is based on the thermal neutron counting ratio,exhibits lower sensitivity in high-porosity regions.To enhance the sensitivity,the effects of elastic and inelastic scattering,which influence the slowing-down of fast neutrons,were theoretically analyzed,and a slowing-down model of fast neutrons was created.Based on this model,a density correction porosity algorithm was proposed based on the relationship between density,thermal neutron counting ratio,and porosity.Finally,the super multifunctional calculation program for nuclear design and safety evaluation(TopMC/SuperMC)was used to create a simulation model for porosity logging,and its applicability was examined.The results demonstrated that the relative error between the calculated and actual porosities was less than 1%,and the influence of deviation in the density measurement was less than 2%.Therefore,the proposed density correction algorithm based on the slowing-down model of fast neutrons can effectively improve the sensitivity in the high-porosity region.This study is expected to serve as a reference for the application of neutron porosity measurements with D–T neutron sources.
基金financially supported by the National Key Research and Development Program of China(2022YFB3404201)the Major Science and Technology Project of Changchun City,Jilin Province(Grant No.20210301024GX)。
文摘The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM)and laboratory computed tomography(CT).Results showed that the newly developed AlSi9MnMoV alloy exhibited improved mechanical properties when compared to the AlSi10MnMg alloy.The AlSi9MnMoV alloy,which was designed with trace multicomponent additions,displays a notable grain refining effect in comparison to the AlSi10MnMg alloy.Refining elements Ti,Zr,V,Nb,B promote heterogeneous nucleation and reduce the grain size of primaryα-Al.At a lower slow shot speed,the large ESCs are easier to form and gather,developing into the dendrite net and net-shrinkage.With an increase in slow shot speed,the size and number of ESCs and porosities significantly reduce.In addition,the distribution of ESCs is more dispersed and the net-shrinkage disappears.The tensile property is greatly improved by adopting a higher slow shot speed.The ultimate tensile strength is enhanced from 260.31 MPa to 290.31 MPa(increased by 11.52%),and the elongation is enhanced from 3.72%to 6.34%(increased by 70.52%).
基金funded by the National Natural Science Foundation of China(Grant/Award Numbers:41272115,41572086)OeAD(Austria's Agency for Education and Internationalization).
文摘This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin,Pakistan.Multiple data sets including outcrop,petrography,cathodoluminescence,scanning electron microscopy(SEM),mineralogy,and geochemical isotopic compositions were integrated to establish a link between porosity evolution and diagenesis.The spatial thickness and facies variations of the strata at outcrop scale are inherently controlled by the underlying bathymetry of the basin with deepening westward trend.The low values ofδ^(18)O of the target strata,relative to average values of the Permian carbonate,hints to diagenetic alteration in the strata.The data sets used in this study reveal modification of the strata in four environments,that is,i)early marine diagenesis indicated by micritization,pervasive dolomitization and isopachous fibrous cements,followed by ii)meteoric dissolution,and iii)shallow burial diagenetic processes including the precipitation of blocky cement,compaction of skeletal and non-skeletal allochems,and stylolites,and iv)a deep burial environment,characterized by pressure solution,and micro-fractures.The clastic intervals host subangular to subrounded quartz grains,floating textures,and almost complete absence of deleterious clay minerals,consequently resulting in the preservation of primary porosity.The primary porosity of carbonate intervals is preserved in the form of intercrystalline and intracrystalline porosity.The secondary porosity evolved through various diagenetic phases in the form of fractures and dissolution.The diagenetic solution mediated by organic matter in carbonates may have experienced both bacterial decomposition and thermochemical sulfate reduction,precipitating sulfides within the pores.The plug porosity/permeability analyses generally suggest high porosity in the siliciclastic unit,and carbonates with wackestone fabric while lower values were observed for the inner shelf pure carbonate facies.However,both intervals show very low permeability values probably due to isolated moldic pores and intense micritization.Therefore,clastic intervals may provide an opportunity to serve as a moderate reservoir;however,the carbonate intervals possess very low permeability values and could generally be considered as low-moderate reservoir potential.
基金Equinor for financing the R&D projectthe Institute of Science and Technology of Petroleum Geophysics of Brazil for supporting this research。
文摘We apply stochastic seismic inversion and Bayesian facies classification for porosity modeling and igneous rock identification in the presalt interval of the Santos Basin. This integration of seismic and well-derived information enhances reservoir characterization. Stochastic inversion and Bayesian classification are powerful tools because they permit addressing the uncertainties in the model. We used the ES-MDA algorithm to achieve the realizations equivalent to the percentiles P10, P50, and P90 of acoustic impedance, a novel method for acoustic inversion in presalt. The facies were divided into five: reservoir 1,reservoir 2, tight carbonates, clayey rocks, and igneous rocks. To deal with the overlaps in acoustic impedance values of facies, we included geological information using a priori probability, indicating that structural highs are reservoir-dominated. To illustrate our approach, we conducted porosity modeling using facies-related rock-physics models for rock-physics inversion in an area with a well drilled in a coquina bank and evaluated the thickness and extension of an igneous intrusion near the carbonate-salt interface. The modeled porosity and the classified seismic facies are in good agreement with the ones observed in the wells. Notably, the coquinas bank presents an improvement in the porosity towards the top. The a priori probability model was crucial for limiting the clayey rocks to the structural lows. In Well B, the hit rate of the igneous rock in the three scenarios is higher than 60%, showing an excellent thickness-prediction capability.
基金supported by the National Natural Science Foundation of China(Grant Nos.22278001 and 21776002)the Natural Science Foundation of Anhui Provincial Education Department(No.KJ2021A0407)+1 种基金the Natural Science Foundation of Anhui Province(Grant No.2008085QB87)Anhui Provincial Postdoctoral Science Foundation(No.2021B538).
文摘Reducing coke use is an effective measure to reduce carbon emission and energy consumption in the blast furnace(BF)ironmaking.Essentially,BF is a high-temperature moving bed reactor,where complex physical transformations coupled with complicated reactions occur.This makes it challenging to investigate the factors determining BF performance with the conventional method.A multi-physical field coupling mathematical model of BF was thus developed to describe its mass and heat transfer as well as its intrinsic reactions.Then,the proposed model was validated with the production data.Under coupling conditions,influences of dominating reactions on BF performance(temperature distribution,gas distribution,iron formation reaction,and direct reduction degree)were revealed.The results indicated that coke combustion,indirect reduction,and direct reduction of iron ore mainly took place nearby the shaft tuyere,cohesive zone,and dripping zone,respectively.Besides,the rate of coke solution loss reaction was increased with the rising coke porosity in the cohesive zone.Considering the effect of coke porosity on the efficiency and stability of BF,the coke porosity of 0.42 was regarded as a reasonable value.
基金This paper is supported by“National Natural Science Foundation of China(Grant No.42204106)”.
文摘The measurement of nuclear magnetic resonance(NMR)porosity is affected by temperature.Without considering the impact of NMR logging tools,this phenomenon is mainly caused by variations in magnetization intensity of the measured system due to temperature fluctuations and difference between the temperature of the porous medium and calibration sample.In this study,the effect of temperature was explained based on the thermodynamic theory,and the rules of NMR porosity responses to temperature changes were identified through core physics experiments.In addition,a method for correcting the influence of temperature on NMR porosity measurement was proposed,and the possible factors that may affect its application were also discussed.
基金the National Natural Science Foundation of China(Nos.61873164 and 51575349)。
文摘The real-time detection of porosity in welding process is an important problem to be solved in intelligent welding manufacturing.A new on-line detection method for porosity of aluminum alloy in robotic arc welding based on arc spectrum is proposed in this paper.First,k-shape and the improved k-means were used for the initial feature selection of the preprocessed arc spectrum to reduce the data dimension.Second,the secondary feature selection was carried out based on the importance of features to further reduce feature redundancy.Then,the optimal sample label library was established by combining the final characteristic parameters and the X-ray pictures of welds.Finally,an on-line detection method of porosity in gas tungsten arc welding of aluminum alloy based on light gradient boosting machine(LightGBM)was proposed.Compared with extreme gradient boosting(XGBoost)and categorical boosting(CatBoost),this method can achieve better detection performance.The new method proposed in this paper can be used to detect other welding defects,which is helpful to the development of intelligent welding technology.
文摘In oil and gas exploration,elucidating the complex interdependencies among geological variables is paramount.Our study introduces the application of sophisticated regression analysis method at the forefront,aiming not just at predicting geophysical logging curve values but also innovatively mitigate hydrocarbon depletion observed in geochemical logging.Through a rigorous assessment,we explore the efficacy of eight regression models,bifurcated into linear and nonlinear groups,to accommodate the multifaceted nature of geological datasets.Our linear model suite encompasses the Standard Equation,Ridge Regression,Least Absolute Shrinkage and Selection Operator,and Elastic Net,each presenting distinct advantages.The Standard Equation serves as a foundational benchmark,whereas Ridge Regression implements penalty terms to counteract overfitting,thus bolstering model robustness in the presence of multicollinearity.The Least Absolute Shrinkage and Selection Operator for variable selection functions to streamline models,enhancing their interpretability,while Elastic Net amalgamates the merits of Ridge Regression and Least Absolute Shrinkage and Selection Operator,offering a harmonized solution to model complexity and comprehensibility.On the nonlinear front,Gradient Descent,Kernel Ridge Regression,Support Vector Regression,and Piecewise Function-Fitting methods introduce innovative approaches.Gradient Descent assures computational efficiency in optimizing solutions,Kernel Ridge Regression leverages the kernel trick to navigate nonlinear patterns,and Support Vector Regression is proficient in forecasting extremities,pivotal for exploration risk assessment.The Piecewise Function-Fitting approach,tailored for geological data,facilitates adaptable modeling of variable interrelations,accommodating abrupt data trend shifts.Our analysis identifies Ridge Regression,particularly when augmented by Piecewise Function-Fitting,as superior in recouping hydrocarbon losses,and underscoring its utility in resource quantification refinement.Meanwhile,Kernel Ridge Regression emerges as a noteworthy strategy in ameliorating porosity-logging curve prediction for well A,evidencing its aptness for intricate geological structures.This research attests to the scientific ascendancy and broad-spectrum relevance of these regression techniques over conventional methods while heralding new horizons for their deployment in the oil and gas sector.The insights garnered from these advanced modeling strategies are set to transform geological and engineering practices in hydrocarbon prediction,evaluation,and recovery.
基金supported by the Basic Key Research Program of Basic Strengthening Plan(No.2021-JCJQ-ZD-075-11)the CISRI Independent Research and Development Programs(Nos.21H62580Z and No.23H60450Z)the National Natural Science Foundation of China(Grant No.52374365).
文摘Wire arc additive manufacturing(WAAM)technique is a promising approach to producing large-scale metal components due to high deposition efficiency and low production cost.However,fundamental research about WAAM-processed Al-Mg-Sc-Zr alloy was still fewer.In this study,Al-6.54Mg-0.36Sc-0.11Zr(wt%)components were successfully manufactured by WAAM with an interlayer temperature at 100℃(named IW)and continuous printing(named CP),and the corresponding porosity,microstructure,and mechanical properties of components were studied in detail.The porosity of components as-deposited was relatively low,about 0.385%and 0.116%,respectively.The microstructures of the two components exhibited the same distribution characteristics in XZ and YZ planes:fine equiaxed grains(FEG)at remelted zone+FEG and coarse equiaxed grain(CEG)alternative distribution at middle zone+FEG at the top zone of the molten pool.The average grain size of component IW was about 10.51±6.01μm,and that of component CP significantly increased,to about 11.85±5.86μm.The short-circuit transition mode of cold metal transfer technology and the heterogeneous nucleation effect of primary Al3(Sc,Zr)and Al3(Sc,Zr,Ti)phases together promoted the formation of equiaxed grains and refined the microstructures.After heat treatment at 325℃and 6 h,nano-Al3Sc precipitated with a size of about 15-50 nm.The yield strength(YS)of components IW and CP increased from 171±3 to 261±1 MPa and 168±7 to 240±17 MPa,respectively.Component IW had the highest ultimate tensile strength,about 400±1 MPa.For WAAMprocessed Al-Mg-Sc-Zr alloys,the contribution of the strengthening mechanism to YS was solid solution strengthening>precipitation strengthening>fine grain strengthening>dislocation strengthening.
基金This work is financially supported by the Fundamental Research Funds for the Central Universities(No.FRF-TP-19-017A3)National Natural Science Foundation of China(No.51874026).
文摘A three-dimensional finite element model coupled with heat transfer,shrinkage accumulation and high temperature deformation was established forϕ690 mm round bloom in continuous casting,and it was verified by surface temperature,shell thickness,contour shape and porosity size by measurement.The compensation area of the shrinkage zone increases as the reduction amount increases.The compensation effect by the reduction of the unit with liquid core is about two times higher than others with fully solid matrix at a given reduction amount.A mathematical method to determine the reduction parameters for large-sized round bloom during continuous casting was proposed by the multi-rollers strategy.For theϕ690 mm round bloom,the suitable reduction parameters for Nos.2–6 units are suggested as 15,15,10,10,10 mm with a casting speed of 0.26 m min^(-1)to close the shrinkage with a diameter of about 17.5 mm in average.The industrial test on the reduction of large-sized round bloom for LZ50 steel was carried out.A total amount of 65–70 mm reduction was realized in the bloom for different casting speeds.The maximum diameter of the central porosity is about 16.3 mm in the longitudinal section at the casting speed of 0.24 m min^(-1),and it decreases to 7.3 mm after 65 mm reduction.Meanwhile,the maximum diameter of the central porosity is about 18.7 mm at 0.26 m min^(-1),while it decreases to 4.1 mm by a reduction of 70 mm.Finally,the difference of the solidification end reduction on round bloom and rectangular or square bloom is theoretically compared.Low deformation resistance and high bulge effect were found in round bloom compared to rectangular bloom.According to the results about solidification contraction accumulation and reduction efficiency in round bloom,the suitable reduction zone to control the central porosity during continuous casting is suggested to be 0.5–1.0.
文摘We consider a generalized form of the porous medium equation where the porosity ϕis a function of time t: ϕ=ϕ(x,t): ∂(ϕS)∂t−∇⋅(k(S)∇S)=Q(S).In many works, the porosity ϕis either assumed to be independent of (or to depend very little of) the time variable t. In this work, we want to study the case where it does depend on t(and xas well). For this purpose, we make a change of unknown function V=ϕSin order to obtain a saturation-like (advection-diffusion) equation. A priori estimates and regularity results are established for the new equation based in part on what is known from the saturation equation, when ϕis independent of the time t. These results are then extended to the full saturation equation with time-dependent porosity ϕ=ϕ(x,t). In this analysis, we make explicitly the dependence of the various constants in the estimates on the porosity ϕby the introduced transport vector w, through the change of unknown function. Also we do not assume zero-flux boundary, but we carry the analysis for the case Q≡0.
文摘The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, cementation and dissolution — affect reservoir properties most intensively. An average porosity loss due to compaction is 0.78% per 100 meters, slightly higher in the central and southern parts and lower in the northern. Cementation has resulted in the porosity loss from 8% to 20% at a depth below 1,500 meters. Dissolution, which in most cases is the dissolution of feldspar and of carbonate cement, primarily occurs in two depth intervals, from 1,400 to 2,500 meters and 2,700 to 4,000 meters respectively. New porosity is created through dissolution from 4% to 14%. The sandstones experienced stage A and stage B of early diagenesis and stage A of late diagenesis. At present, most of them are experiencing Phase A2 of late diagenesis. The types of pores in the sand reservoir can be grouped into primary and secondary ones.
文摘Activated carbons (ACs) calcined at 400˚C, 500˚C, and 600˚C (AC-400, AC-500, and AC-600) were prepared using palm nut shells from Gabon as raw material and zinc chloride (ZnCl2) as a chemical activating agent. Prepared ACs were characterized by physisorption of nitrogen (N2), determination of diode and methylene blue numbers for studies of porosity and by quantification and determination of surface functional groups and pH at point of zero charge (pHpzc) respectively, for studies of chemical properties of prepared ACs. Then, effects of calcination temperature (Tcal) on porosity and chemical properties of prepared ACs were studied. The results obtained showed that when the calcination temperature increases from 500˚C to 600˚C, the porosity and chemical properties of prepared ACs are modified. Indeed, the methylene blue and iodine numbers determined for activated carbons AC-400 (460 and 7.94 mg·g−1, respectively) and AC-500 (680 and 8.90 mg·g−1, respectively) are higher than those obtained for AC-600 (360 and 5.75 mg·g−1, respectively). Compared to the AC-500 adsorbent, specific surface areas (SBET) and microporous volume losses for AC-600 were estimated to 44.7% and 45.8%, respectively. Moreover, in our experimental conditions, the effect of Tcal on the quantities of acidic and basic functional groups on the surface of the ACs appears negligible. In addition, results of the pHpzc of prepared ACs showed that as Tcal increases, the pH of the adsorbents increases and tends towards neutrality. Indeed, a stronger acidity was determined on AC-400 (pHpzc = 5.60) compared to those on AC-500 and AC-600 (pHpzc = 6.85 and 6.70, respectively). Also according to the results of porosity and chemical characterizations, adsorption being a surface phenomenon, 500˚C appears to be the optimal calcination temperature for the preparation of activated carbons from palm nut shells in our experimental conditions.
基金sponsored by Important National Science and Technology Specifi c Projects of China (No.2011ZX05001)
文摘A critical porosity model is often used to calculate the dry frame elastic modulus by the rock critical porosity value which is affected by many factors. In practice it is hard for us to obtain an accurate critical porosity value and we can generally take only an empirical critical porosity value which often causes errors. In this paper, we propose a method to obtain the rock critical porosity value by inverting P-wave velocity and applying it to predict S-wave velocity. The applications of experiment and log data both show that the critical porosity inversion method can reduce the uncertainty resulting from using an empirical value in the past and provide the accurate critical porosity value for predicting S-wave velocity which significantly improves the prediction accuracy.
