Two-dimensional(2D)transition metal dichalcogenides(TMDs),which allow atomic-scale manipulation,have supe-rior electrical and optical properties that challenge the limits of traditional bulk semiconductors like silico...Two-dimensional(2D)transition metal dichalcogenides(TMDs),which allow atomic-scale manipulation,have supe-rior electrical and optical properties that challenge the limits of traditional bulk semiconductors like silicon^([1,2]).As a repre-sentative TMD and a promising 2D channel material for high-performance,scalable p-type transistors,tungsten diselenide(WSe_(2))has attracted considerable academic and industrial interest for its potential in advanced complementary metal−oxide−semiconductor(CMOS)logic technology and in extending Moore’s Law^([3−7]).展开更多
文摘Two-dimensional(2D)transition metal dichalcogenides(TMDs),which allow atomic-scale manipulation,have supe-rior electrical and optical properties that challenge the limits of traditional bulk semiconductors like silicon^([1,2]).As a repre-sentative TMD and a promising 2D channel material for high-performance,scalable p-type transistors,tungsten diselenide(WSe_(2))has attracted considerable academic and industrial interest for its potential in advanced complementary metal−oxide−semiconductor(CMOS)logic technology and in extending Moore’s Law^([3−7]).
文摘以磷钼钒杂多酸H4PMo11V1O40为催化剂、乙酸为溶剂,用双氧水氧化2-甲基萘制备2-甲基萘醌.实验表明：H4PMo11V1O40具有一定的催化活性.通过正交试验和单因素试验考察了催化剂用量、乙酸用量、双氧水用量、反应时间、反应温度等对收率的影响,获得较佳的合成条件：杂多酸∶2-MN（质量比）=7%,乙酸∶2-MN（质量比）=10.5∶1,双氧水∶2-甲基萘（摩尔比）=4.2∶1,较适宜的温度为40~50℃,反应时间为30 min.
