In this study,using 3,5‑di(3′,5′‑dicarboxylphenyl)‑1H‑1,2,4‑triazole(H4L)as ligands,a gadolinia‑based organic framework complex{[GdNa(L)(H_(2)O)3]·2H_(2)O}_(n)(Gd‑Na‑MOF)was successfully designed and synthesize...In this study,using 3,5‑di(3′,5′‑dicarboxylphenyl)‑1H‑1,2,4‑triazole(H4L)as ligands,a gadolinia‑based organic framework complex{[GdNa(L)(H_(2)O)3]·2H_(2)O}_(n)(Gd‑Na‑MOF)was successfully designed and synthesized by hydrothermal method.The structure and properties were systematically characterized and tested by techniques such as single‑crystal X‑ray diffraction,powder X‑ray diffraction,thermogravimetric analysis,infrared spectroscopy,and fluorescence spectroscopy.The results indicate that this complex has a unique 3D structure,excellent thermal stability,and outstanding luminescent performance.Based on its luminescent properties,a polymer‑embedding method was employed to fabricate the Gd‑Na‑MOF into a flexible,washable composite fluorescent film,Gd‑Na‑MOF@PMMA/BMA(PMMA=polymethyl methacrylate,BMA=butyl methacrylate).This fluorescent film exhibited highly sensitive recognition capability for tyramine,with a low detection limit of 1.66μmol·L^(-1).It was used for the detection of tyramine in bananas,with a recovery rate of 96.92%‑100.26%.CCDC:2466949.展开更多
Polymethyl methacrylate(PMMA)has the advantages of good transparency,corrosion resistance and light weight and can be used as the preferred material for pressure-resistant cabins of fully transparent submersibles.In t...Polymethyl methacrylate(PMMA)has the advantages of good transparency,corrosion resistance and light weight and can be used as the preferred material for pressure-resistant cabins of fully transparent submersibles.In this study,based on the fracture mechanics method,a calculation method for estimating the residual fatigue life of a PMMA manned cabin is proposed by improving the small-time scale fatigue crack growth rate model.This improved model is verified by the experimental data of the PMMA material.Then,through the Weibull and Gumbel combined distribution functions,the fatigue load spectrum suitable for the fully transparent manned cabin is fitted according to the dive data.A parametric analysis of the residual fatigue life of the fully transparent manned cabin under various initial crack sizes and dwell time is conducted,yielding valuable results.This study aims to increase the safety of fully transparent pressure-resistant cabins and offer insights for fatigue analysis of underwater structures utilizing PMMA materials.展开更多
文摘In this study,using 3,5‑di(3′,5′‑dicarboxylphenyl)‑1H‑1,2,4‑triazole(H4L)as ligands,a gadolinia‑based organic framework complex{[GdNa(L)(H_(2)O)3]·2H_(2)O}_(n)(Gd‑Na‑MOF)was successfully designed and synthesized by hydrothermal method.The structure and properties were systematically characterized and tested by techniques such as single‑crystal X‑ray diffraction,powder X‑ray diffraction,thermogravimetric analysis,infrared spectroscopy,and fluorescence spectroscopy.The results indicate that this complex has a unique 3D structure,excellent thermal stability,and outstanding luminescent performance.Based on its luminescent properties,a polymer‑embedding method was employed to fabricate the Gd‑Na‑MOF into a flexible,washable composite fluorescent film,Gd‑Na‑MOF@PMMA/BMA(PMMA=polymethyl methacrylate,BMA=butyl methacrylate).This fluorescent film exhibited highly sensitive recognition capability for tyramine,with a low detection limit of 1.66μmol·L^(-1).It was used for the detection of tyramine in bananas,with a recovery rate of 96.92%‑100.26%.CCDC:2466949.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFC2800600)the National Natural Science Foundation of China(Grant No.52071203).
文摘Polymethyl methacrylate(PMMA)has the advantages of good transparency,corrosion resistance and light weight and can be used as the preferred material for pressure-resistant cabins of fully transparent submersibles.In this study,based on the fracture mechanics method,a calculation method for estimating the residual fatigue life of a PMMA manned cabin is proposed by improving the small-time scale fatigue crack growth rate model.This improved model is verified by the experimental data of the PMMA material.Then,through the Weibull and Gumbel combined distribution functions,the fatigue load spectrum suitable for the fully transparent manned cabin is fitted according to the dive data.A parametric analysis of the residual fatigue life of the fully transparent manned cabin under various initial crack sizes and dwell time is conducted,yielding valuable results.This study aims to increase the safety of fully transparent pressure-resistant cabins and offer insights for fatigue analysis of underwater structures utilizing PMMA materials.
