The quantification of hydrogen peroxide(H_(2)O_(2))generated in the plasma-liquid interactions is of great importance,since the H_(2)O_(2)species is vital for the applications of the plasma-liquid system.Herein,we rep...The quantification of hydrogen peroxide(H_(2)O_(2))generated in the plasma-liquid interactions is of great importance,since the H_(2)O_(2)species is vital for the applications of the plasma-liquid system.Herein,we report on in situ quantification of the aqueous H_(2)O_(2)(H_(2)O_(2)aq)using a colorimetric method for the DC plasma-liquid systems with liquid as either a cathode or an anode.The results show that the H_(2)O_(2)aqyield is 8-12 times larger when the liquid acts as a cathode than when the liquid acts as an anode.The conversion rate of the gaseous OH radicals to H_(2)O_(2)aqis 4-6 times greater in the former case.However,the concentrations of dissolved OH radicals for both liquid as cathode and anode are of the same order of tens of n M.展开更多
Atmospheric pressure plasma-liquid interactions exist in a variety of applications,including wastewater treatment,wound sterilization,and disinfection.In practice,the phenomenon of liquid surface depression will inevi...Atmospheric pressure plasma-liquid interactions exist in a variety of applications,including wastewater treatment,wound sterilization,and disinfection.In practice,the phenomenon of liquid surface depression will inevitably appear.The applied gas will cause a depression on the liquid surface,which will undoubtedly affect the plasma generation and further affect the application performance.However,the effect of liquid surface deformation on the plasma is still unclear.In this work,numerical models are developed to reveal the mechanism of liquid surface depressions affecting plasma discharge characteristics and the consequential distribution of plasma species,and further study the influence of liquid surface depressions of different sizes generated by different helium flow rates on the plasma.Results show that the liquid surface deformation changes the initial spatial electric field,resulting in the rearrangement of electrons on the liquid surface.The charges deposited on the liquid surface further increase the degree of distortion of the electric field.Moreover,the electric field and electron distribution affected by the liquid surface depression significantly influence the generation and distribution of active species,which determines the practical effectiveness of the relevant applications.This work explores the phenomenon of liquid surface depression,which has been neglected in previous related work,and contributes to further understanding of plasma-liquid interactions,providing better theoretical guidance for related applications and technologies.展开更多
The plasma liquid phase oxidation of n-heptane was investigated. The selectivity of product formation is far superior to plasma oxidation in the gas phase.
A few factors affecting plasma oxidation desulfurization of isobutyl mercaptan were investigated. Under the reasonable condition, the conversion and degree of desulfurization of isobutyl mercaptan can be achieved up t...A few factors affecting plasma oxidation desulfurization of isobutyl mercaptan were investigated. Under the reasonable condition, the conversion and degree of desulfurization of isobutyl mercaptan can be achieved up to over 95% and 94％ respectively.展开更多
This research investigates the possibility of convergent acoustic waves generation in the liquid by means of the sotmd waves reflection from the solid cylindrical surface, emerged in the pulsed electric discharge. The...This research investigates the possibility of convergent acoustic waves generation in the liquid by means of the sotmd waves reflection from the solid cylindrical surface, emerged in the pulsed electric discharge. The spectra of pulse discharge plasma emission in the water and in the air-water mixture were obtained. The temperature of cuprum and oxygen atoms electronic excitation levels and the temperature tendencies during the discharge current existence were calculated.展开更多
目的建立一种液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry,LC-MS/MS)方法快速、灵敏地测定大鼠血浆中Hu7691的浓度。方法大鼠血浆样本以乙腈沉淀蛋白后,选用三键键合烷基色谱柱,以0.1%甲酸水-乙腈作为流动相进...目的建立一种液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry,LC-MS/MS)方法快速、灵敏地测定大鼠血浆中Hu7691的浓度。方法大鼠血浆样本以乙腈沉淀蛋白后,选用三键键合烷基色谱柱,以0.1%甲酸水-乙腈作为流动相进行梯度洗脱,选用多重反应监测扫描方式进行监测。将经验证的方法应用于Hu7691在SD大鼠体内的药动学研究。结果大鼠口服5、10、20 mg·kg^(-1)Hu7691以及静脉注射5 mg·kg^(-1)的Hu7691后,大鼠血浆中Hu7691的AUC和C_(max)随剂量的增大而增加,生物利用度分别为50.2%、62.0%、75.7%。结论表明Hu7691在大鼠体内具有较高的胃肠吸收率和稳定的药动学特性。展开更多
基金National Natural Science Foundation of China(No.52077185)the Basic Research Program of Science and Technology of Shenzhen,China(No.JCYJ20190809162617137)for partial financial support+6 种基金the financial supports from the Basic Ability Promotion Project for Young and Middle-Aged Teachers in Universities of Guangxi(No.2018KY0083)Doctoral Scientific Research Fund of Guangxi Normal University(No.2017BQ019)the financial supports from National Natural Science Foundation of China(No.11975061)the Technology Innovation and Application Development Project of Chongqing(No.cstc2019jscxmsxm X0041)the Construction Committee Project of Chongqing(No.2018-1-3-6)the Fundamental Research Funds for the Central Universities(No.2019CDQYDQ034)the Australian Research Council(ARC)for partial support。
文摘The quantification of hydrogen peroxide(H_(2)O_(2))generated in the plasma-liquid interactions is of great importance,since the H_(2)O_(2)species is vital for the applications of the plasma-liquid system.Herein,we report on in situ quantification of the aqueous H_(2)O_(2)(H_(2)O_(2)aq)using a colorimetric method for the DC plasma-liquid systems with liquid as either a cathode or an anode.The results show that the H_(2)O_(2)aqyield is 8-12 times larger when the liquid acts as a cathode than when the liquid acts as an anode.The conversion rate of the gaseous OH radicals to H_(2)O_(2)aqis 4-6 times greater in the former case.However,the concentrations of dissolved OH radicals for both liquid as cathode and anode are of the same order of tens of n M.
基金supported by National Natural Science Foundation of China(No.52377145).
文摘Atmospheric pressure plasma-liquid interactions exist in a variety of applications,including wastewater treatment,wound sterilization,and disinfection.In practice,the phenomenon of liquid surface depression will inevitably appear.The applied gas will cause a depression on the liquid surface,which will undoubtedly affect the plasma generation and further affect the application performance.However,the effect of liquid surface deformation on the plasma is still unclear.In this work,numerical models are developed to reveal the mechanism of liquid surface depressions affecting plasma discharge characteristics and the consequential distribution of plasma species,and further study the influence of liquid surface depressions of different sizes generated by different helium flow rates on the plasma.Results show that the liquid surface deformation changes the initial spatial electric field,resulting in the rearrangement of electrons on the liquid surface.The charges deposited on the liquid surface further increase the degree of distortion of the electric field.Moreover,the electric field and electron distribution affected by the liquid surface depression significantly influence the generation and distribution of active species,which determines the practical effectiveness of the relevant applications.This work explores the phenomenon of liquid surface depression,which has been neglected in previous related work,and contributes to further understanding of plasma-liquid interactions,providing better theoretical guidance for related applications and technologies.
基金The project was supported by National Natural Science Foundation of China.
文摘The plasma liquid phase oxidation of n-heptane was investigated. The selectivity of product formation is far superior to plasma oxidation in the gas phase.
基金The project was supported by National Natural Science Foundation of China.
文摘A few factors affecting plasma oxidation desulfurization of isobutyl mercaptan were investigated. Under the reasonable condition, the conversion and degree of desulfurization of isobutyl mercaptan can be achieved up to over 95% and 94％ respectively.
文摘This research investigates the possibility of convergent acoustic waves generation in the liquid by means of the sotmd waves reflection from the solid cylindrical surface, emerged in the pulsed electric discharge. The spectra of pulse discharge plasma emission in the water and in the air-water mixture were obtained. The temperature of cuprum and oxygen atoms electronic excitation levels and the temperature tendencies during the discharge current existence were calculated.
