Photomechanics is a crucial branch of solid mechanics.The localization of point targets constitutes a fundamental problem in optical experimental mechanics,with extensive applications in various missions of unmanned a...Photomechanics is a crucial branch of solid mechanics.The localization of point targets constitutes a fundamental problem in optical experimental mechanics,with extensive applications in various missions of unmanned aerial vehicles.Localizing moving targets is crucial for analyzing their motion characteristics and dynamic properties.Reconstructing the trajectories of points from asynchronous cameras is a significant challenge.It encompasses two coupled sub-problems:Trajectory reconstruction and camera synchronization.Present methods typically address only one of these sub-problems individually.This paper proposes a 3D trajectory reconstruction method for point targets based on asynchronous cameras,simultaneously solving both sub-problems.Firstly,we extend the trajectory intersection method to asynchronous cameras to resolve the limitation of traditional triangulation that requires camera synchronization.Secondly,we develop models for camera temporal information and target motion,based on imaging mechanisms and target dynamics characteristics.The parameters are optimized simultaneously to achieve trajectory reconstruction without accurate time parameters.Thirdly,we optimize the camera rotations alongside the camera time information and target motion parameters,using tighter and more continuous constraints on moving points.The reconstruction accuracy is significantly improved,especially when the camera rotations are inaccurate.Finally,the simulated and real-world experimental results demonstrate the feasibility and accuracy of the proposed method.The real-world results indicate that the proposed algorithm achieved a localization error of 112.95 m at an observation distance range of 15-20 km.展开更多
Flexible circuit switches have been widely used in electronic devices due to their outstanding flexibility and operability.In order to expand the types of flexible circuit switch materials,we develop a unique composit...Flexible circuit switches have been widely used in electronic devices due to their outstanding flexibility and operability.In order to expand the types of flexible circuit switch materials,we develop a unique composite material,which integrates a photoresponsive flexible substrate derived from a photoreactive coordination polymer(CP)with an elastic conductive adhesive tape(CAT)in this work.The photoreactive CP{[Cd(2,6-bpvn)(3,5-DBB)_(2)]·DMF}_(n)(1)is prepared through solvothermal reaction of Cd(NO_(3))_(2)·4H_(2)O with 2,6-bis((E)-2-(pyridin-4-yl)vinyl)naphthalene(2,6-bpvn)and 3,5-dibromobenzoic acid(3,5-HDBB).Upon irradiation with UV light,crystals of 1 can undergo[2+2]photocycloaddition reaction and exhibit photomechanical movements.The crystalline powder of 1 can be uniformly distributed in polyvinyl alcohol(PVA)to generate the composite film 1-PVA.After pasting a piece of CAT on the surface of a 1-PVA film,a conductive two-layer film of 1-PVA/CAT can be fabricated.This film bends rapidly upon UV light exposure,connecting the circuit and causing the bulb to light up.When the light source is removed,it reverts to its initial state and the circuit is disconnected and the bulb is extinguished.This process can be cycled at least 100 times,achieving precise turn-on and turn-off performances of the photocontrollable circuit switch.展开更多
In this review, acritical look at the research progress ofexperimentalsolid mechanics in China for the past years is presented. Issues are discussed of the discovery and development of new fundamental methods and tech...In this review, acritical look at the research progress ofexperimentalsolid mechanics in China for the past years is presented. Issues are discussed of the discovery and development of new fundamental methods and techniques versus performance benchmarking for many of their applications. Included herein are photoelasticity and various forms of modern photomechanics, acoustical techniques, image processing and videometrics, radial and spectrum techniques, and experimental mechanics on micro/nano scale. It is also noticed that both the ever developed instrumentation and specialized synthetical techniques have played important roles in advancing experimental mechanics in scientific researches and industrial applications. Finally, an attempt is made to look into the future of experimental solid mechanics with personal opinions offered on what the future trends will be for the researches in the field.展开更多
This paper presents the principle of phase modulation of the optical wave,that is using a dense fringe family to modulate another fringe pattern,and its applicationin fringe multiplication.It is of universal significa...This paper presents the principle of phase modulation of the optical wave,that is using a dense fringe family to modulate another fringe pattern,and its applicationin fringe multiplication.It is of universal significance in optically experimental mechanics.展开更多
Photomechanical crystals are capable of converting light energy into mechanical energy, making them as potential candidates for a wide range of applications in areas such as actuators, artificial muscles, and optical ...Photomechanical crystals are capable of converting light energy into mechanical energy, making them as potential candidates for a wide range of applications in areas such as actuators, artificial muscles, and optical switches. In this work, we successfully synthesized a tridentate cyano styrene derivative molecule, (2Z,2′Z,2′Z)-3,3′,3′-(benzene-1,3,5-triyl)tris-(2-(4-(trifluoromethoxyl)ph-enyl)acrylonitrile) (C3-CF3), along with its three different polymorphs. Both blocky Form I and sheet-like Form II, exhibit photosalient effects (ballistic splitting, moving, and jumping) under both ultraviolet and visible lasers. More importantly, they could even respond to sunlight and light-emitting diode white light with a subdued photomechanical response. 1H nuclear magnetic resonance indicates that Form I and Form II undergo photo-induced [2 + 2] cycloaddition reactions under various light sources. The kinetic analysis of the photoreactions reveals that both polymorphs demonstrate rapid reaction kinetics and high photodimerization conversion when exposed to 420 nm visible laser, with conversions reaching 97.6% and 95.26% after 300 s of irradiation, respectively. Additionally, although the needle-shaped Form III of C3-CF3 lacks photomechanical activity, it possesses notable mechanical flexibility. Finally, films composed of powders from Form I or Form II with poly(vinyl alcohol) were created, which were capable of controllable photo-induced bending.展开更多
Two azobenzene compounds,Disperse Red 1(DR1)and 4-aminoazobenzene(Aazo),were separately linked to poly(acrylic acid)(PAA)side chains to form PAA-DR1 and PAA-Aazo,which were then associated with poly(ethylene oxide)(PE...Two azobenzene compounds,Disperse Red 1(DR1)and 4-aminoazobenzene(Aazo),were separately linked to poly(acrylic acid)(PAA)side chains to form PAA-DR1 and PAA-Aazo,which were then associated with poly(ethylene oxide)(PEO)to produce hydrogen-bonded polymer complex fibers.After UV irradiation,the initial modulus and yielding strength of PAA-Aazo/PEO fiber were both increased tremendously,while the mechanical properties of PAA-DR1/PEO fiber only slightly changed.After drawn and dried in vacuum,PAA-DR1/PEO and PAA-Aazo/PEO fibers with an extended length exhibited a contraction of 20%and 25%under UV irradiation,showing potential for photo-actuation.展开更多
Real-time terahertz(THz)imaging offers remarkable application possibilities,especially in the security and medical fields.However,most THz detectors work with scanners,and a long image acquisition time is required.Som...Real-time terahertz(THz)imaging offers remarkable application possibilities,especially in the security and medical fields.However,most THz detectors work with scanners,and a long image acquisition time is required.Some thermal detectors can achieve realtime imaging by using a focal plane array but have the drawbacks of low sensitivity due to a lack of suitable absorbing materials.In this study,we propose a novel photomechanical meta-molecule array by conveniently assembling THz meta-atom absorbers and bi-material cantilevers together,which can couple THz radiation to a mechanical deflection of the meta-molecules with high efficiency.By optically reading out the mechanical deflections of all of the meta-molecules simultaneously,real-time THz imaging can be achieved.A polyimide sacrificial layer technique was developed to fabricate the device on a glass wafer,which facilitates the transmission of a readout light while the THz wave radiates onto the meta-molecule array directly from the front side.THz images and video of various objects as well as infrared images of the human body were captured successfully with the fabricated metamolecule array.The proposed photomechanical device holds promise in applications in single and broadband THz as well as infrared imaging.展开更多
Photoresponsive materials are considered as promising systems for intelligent technology applications owing to the contactless spatial and temporal control.Herein,controllable multi-photoresponsive behaviors are reali...Photoresponsive materials are considered as promising systems for intelligent technology applications owing to the contactless spatial and temporal control.Herein,controllable multi-photoresponsive behaviors are realized in benzo[b]thiophene derivatives(o-DMP-S,o-DMP-SO,and o-DMP-SO_(2))by modulating the sulfur oxidation state.Among them,o-DMP-S is photo-unreactive but possesses denser molecular packing upon ultraviolet(UV)light irradiation,exhibiting photoenhanced room-temperature phosphorescence properties.Through stoichiometric oxidation of the sulfur atom in o-DMP-S,the resulting sulfoxide compound o-DMP-SO undergoes a radical photolysis reaction involving photodeoxygenation and photochemical rearrangement,thereby leading to the photomechanical effect.The sulfone compound o-DMP-SO_(2)displays prominent reversible photochromism,resulting from the radical photocyclization under 365 nm UV light irradiation.Based on comprehensive experimental and computational investigations,the diverse photoresponsive behaviors of these benzo[b]thiophene derivatives are demonstrated to depend on the intersystem crossing efficiency and radical-mediated photochemical reaction activity in excited states due to the different sulfur oxidation states.This work provides an insightful understanding of the relationship between molecular structure and photoresponsive behavior and opens up the opportunity for the development of photoresponsive materials with potential applications.展开更多
Herein,a series of molecular actuators based on the crystals of(E)-2-(4-fluorostyryl)benzo[d]oxazole(BOAF4),(E)-2-(2,4-difluorostyryl)benzo[d]oxazole(BOAF24),(E)-2-(4-fluorostyryl)benzo[d]thiazole(BTAF4),and(E)-2-(2,4...Herein,a series of molecular actuators based on the crystals of(E)-2-(4-fluorostyryl)benzo[d]oxazole(BOAF4),(E)-2-(2,4-difluorostyryl)benzo[d]oxazole(BOAF24),(E)-2-(4-fluorostyryl)benzo[d]thiazole(BTAF4),and(E)-2-(2,4-difluorostyryl)benzo[d]thiazole(BTAF24)showed unique bending behavior under UV irradiation.The one-dimensional(1D)crystals of BOAF4 and BTAF4 bent toward light,whereas those of BOAF24 and BTAF24 bent away from light.Although the chemical structures of these compounds are similar,the authors found that F···H–C interaction played a key role in the different molecular packing in structures crystals,which led to the positive/negative phototropism of the actuators.Moreover,theoretical calculations were carried out to reveal the mechanical properties of the crystals.Taking advantage of these photomechanical properties,the authors achieved the potential application in pushing objects,as well as enriching and removing pollutants.Hence,the molecular actuators with different bending behavior could be fabricated by introducing different number of F atom,which may open a novel gate for crystal engineering.展开更多
基金supported by the Hunan Provin〓〓cial Natural Science Foundation for Excellent Young Scholars(Grant No.2023JJ20045)the National Natural Science Foundation of China(Grant No.12372189)。
文摘Photomechanics is a crucial branch of solid mechanics.The localization of point targets constitutes a fundamental problem in optical experimental mechanics,with extensive applications in various missions of unmanned aerial vehicles.Localizing moving targets is crucial for analyzing their motion characteristics and dynamic properties.Reconstructing the trajectories of points from asynchronous cameras is a significant challenge.It encompasses two coupled sub-problems:Trajectory reconstruction and camera synchronization.Present methods typically address only one of these sub-problems individually.This paper proposes a 3D trajectory reconstruction method for point targets based on asynchronous cameras,simultaneously solving both sub-problems.Firstly,we extend the trajectory intersection method to asynchronous cameras to resolve the limitation of traditional triangulation that requires camera synchronization.Secondly,we develop models for camera temporal information and target motion,based on imaging mechanisms and target dynamics characteristics.The parameters are optimized simultaneously to achieve trajectory reconstruction without accurate time parameters.Thirdly,we optimize the camera rotations alongside the camera time information and target motion parameters,using tighter and more continuous constraints on moving points.The reconstruction accuracy is significantly improved,especially when the camera rotations are inaccurate.Finally,the simulated and real-world experimental results demonstrate the feasibility and accuracy of the proposed method.The real-world results indicate that the proposed algorithm achieved a localization error of 112.95 m at an observation distance range of 15-20 km.
基金support from the National Natural Science Foundation of China(No.U24A20507,22271203)the State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences(No.2024KF005)Open Research Fund of State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering of Nanjing University and the Collaborative Innovation Centre of Suzhou Nano Science and Technology.
文摘Flexible circuit switches have been widely used in electronic devices due to their outstanding flexibility and operability.In order to expand the types of flexible circuit switch materials,we develop a unique composite material,which integrates a photoresponsive flexible substrate derived from a photoreactive coordination polymer(CP)with an elastic conductive adhesive tape(CAT)in this work.The photoreactive CP{[Cd(2,6-bpvn)(3,5-DBB)_(2)]·DMF}_(n)(1)is prepared through solvothermal reaction of Cd(NO_(3))_(2)·4H_(2)O with 2,6-bis((E)-2-(pyridin-4-yl)vinyl)naphthalene(2,6-bpvn)and 3,5-dibromobenzoic acid(3,5-HDBB).Upon irradiation with UV light,crystals of 1 can undergo[2+2]photocycloaddition reaction and exhibit photomechanical movements.The crystalline powder of 1 can be uniformly distributed in polyvinyl alcohol(PVA)to generate the composite film 1-PVA.After pasting a piece of CAT on the surface of a 1-PVA film,a conductive two-layer film of 1-PVA/CAT can be fabricated.This film bends rapidly upon UV light exposure,connecting the circuit and causing the bulb to light up.When the light source is removed,it reverts to its initial state and the circuit is disconnected and the bulb is extinguished.This process can be cycled at least 100 times,achieving precise turn-on and turn-off performances of the photocontrollable circuit switch.
基金Project supported by the NSFC (Nos.10472112,19232020,10627201,10972113, 90916010 and 10732080)the National Basic Research Program of China (Nos.2007CB936803 and 2010CB631005)SRFDP (Nos.20070003053 and 20090002110048)
文摘In this review, acritical look at the research progress ofexperimentalsolid mechanics in China for the past years is presented. Issues are discussed of the discovery and development of new fundamental methods and techniques versus performance benchmarking for many of their applications. Included herein are photoelasticity and various forms of modern photomechanics, acoustical techniques, image processing and videometrics, radial and spectrum techniques, and experimental mechanics on micro/nano scale. It is also noticed that both the ever developed instrumentation and specialized synthetical techniques have played important roles in advancing experimental mechanics in scientific researches and industrial applications. Finally, an attempt is made to look into the future of experimental solid mechanics with personal opinions offered on what the future trends will be for the researches in the field.
文摘This paper presents the principle of phase modulation of the optical wave,that is using a dense fringe family to modulate another fringe pattern,and its applicationin fringe multiplication.It is of universal significance in optically experimental mechanics.
基金supported by the National Natural Science Foundation of China(22208237)。
文摘Photomechanical crystals are capable of converting light energy into mechanical energy, making them as potential candidates for a wide range of applications in areas such as actuators, artificial muscles, and optical switches. In this work, we successfully synthesized a tridentate cyano styrene derivative molecule, (2Z,2′Z,2′Z)-3,3′,3′-(benzene-1,3,5-triyl)tris-(2-(4-(trifluoromethoxyl)ph-enyl)acrylonitrile) (C3-CF3), along with its three different polymorphs. Both blocky Form I and sheet-like Form II, exhibit photosalient effects (ballistic splitting, moving, and jumping) under both ultraviolet and visible lasers. More importantly, they could even respond to sunlight and light-emitting diode white light with a subdued photomechanical response. 1H nuclear magnetic resonance indicates that Form I and Form II undergo photo-induced [2 + 2] cycloaddition reactions under various light sources. The kinetic analysis of the photoreactions reveals that both polymorphs demonstrate rapid reaction kinetics and high photodimerization conversion when exposed to 420 nm visible laser, with conversions reaching 97.6% and 95.26% after 300 s of irradiation, respectively. Additionally, although the needle-shaped Form III of C3-CF3 lacks photomechanical activity, it possesses notable mechanical flexibility. Finally, films composed of powders from Form I or Form II with poly(vinyl alcohol) were created, which were capable of controllable photo-induced bending.
基金National Natural Science Foundation of China(No.51973029)Science and Technology Commission of Shanghai Municipality(No.20JC1414900).
文摘Two azobenzene compounds,Disperse Red 1(DR1)and 4-aminoazobenzene(Aazo),were separately linked to poly(acrylic acid)(PAA)side chains to form PAA-DR1 and PAA-Aazo,which were then associated with poly(ethylene oxide)(PEO)to produce hydrogen-bonded polymer complex fibers.After UV irradiation,the initial modulus and yielding strength of PAA-Aazo/PEO fiber were both increased tremendously,while the mechanical properties of PAA-DR1/PEO fiber only slightly changed.After drawn and dried in vacuum,PAA-DR1/PEO and PAA-Aazo/PEO fibers with an extended length exhibited a contraction of 20%and 25%under UV irradiation,showing potential for photo-actuation.
基金This study was funded by the National Natural Science Foundation of China(Grants No.61575003)the China Postdoctoral Science Foundation(Grants Nos.2015M580096 and 2017T100074).
文摘Real-time terahertz(THz)imaging offers remarkable application possibilities,especially in the security and medical fields.However,most THz detectors work with scanners,and a long image acquisition time is required.Some thermal detectors can achieve realtime imaging by using a focal plane array but have the drawbacks of low sensitivity due to a lack of suitable absorbing materials.In this study,we propose a novel photomechanical meta-molecule array by conveniently assembling THz meta-atom absorbers and bi-material cantilevers together,which can couple THz radiation to a mechanical deflection of the meta-molecules with high efficiency.By optically reading out the mechanical deflections of all of the meta-molecules simultaneously,real-time THz imaging can be achieved.A polyimide sacrificial layer technique was developed to fabricate the device on a glass wafer,which facilitates the transmission of a readout light while the THz wave radiates onto the meta-molecule array directly from the front side.THz images and video of various objects as well as infrared images of the human body were captured successfully with the fabricated metamolecule array.The proposed photomechanical device holds promise in applications in single and broadband THz as well as infrared imaging.
基金supported by the Agency for Science,Technology and Research Singapore through its Manufacturing,Trade and Connectivity Individual Research Grant(grant no.M22K2c0077)the National Natural Science Foundation of China(grant nos.21788102,22375066,21874121,and 21974128)the Guangdong Basic and Applied Basic Research Foundation(grant nos.2023B1515040003 and 2022A1515010315).
文摘Photoresponsive materials are considered as promising systems for intelligent technology applications owing to the contactless spatial and temporal control.Herein,controllable multi-photoresponsive behaviors are realized in benzo[b]thiophene derivatives(o-DMP-S,o-DMP-SO,and o-DMP-SO_(2))by modulating the sulfur oxidation state.Among them,o-DMP-S is photo-unreactive but possesses denser molecular packing upon ultraviolet(UV)light irradiation,exhibiting photoenhanced room-temperature phosphorescence properties.Through stoichiometric oxidation of the sulfur atom in o-DMP-S,the resulting sulfoxide compound o-DMP-SO undergoes a radical photolysis reaction involving photodeoxygenation and photochemical rearrangement,thereby leading to the photomechanical effect.The sulfone compound o-DMP-SO_(2)displays prominent reversible photochromism,resulting from the radical photocyclization under 365 nm UV light irradiation.Based on comprehensive experimental and computational investigations,the diverse photoresponsive behaviors of these benzo[b]thiophene derivatives are demonstrated to depend on the intersystem crossing efficiency and radical-mediated photochemical reaction activity in excited states due to the different sulfur oxidation states.This work provides an insightful understanding of the relationship between molecular structure and photoresponsive behavior and opens up the opportunity for the development of photoresponsive materials with potential applications.
基金The authors are grateful for financial support from the National Science Foundation of China(nos.51773067 and 21788102)the Open Project of State Key Laboratory of Supramolecular Structure and Materials(no.sklssm202019)+2 种基金the Research Grants Council of Hong Kong(no.C6009-17G)the Innovation of Technology Commission(no.ITC-CNERC14SC01)the National Key Research and Development Program of China(no.2018YFE0190200).
文摘Herein,a series of molecular actuators based on the crystals of(E)-2-(4-fluorostyryl)benzo[d]oxazole(BOAF4),(E)-2-(2,4-difluorostyryl)benzo[d]oxazole(BOAF24),(E)-2-(4-fluorostyryl)benzo[d]thiazole(BTAF4),and(E)-2-(2,4-difluorostyryl)benzo[d]thiazole(BTAF24)showed unique bending behavior under UV irradiation.The one-dimensional(1D)crystals of BOAF4 and BTAF4 bent toward light,whereas those of BOAF24 and BTAF24 bent away from light.Although the chemical structures of these compounds are similar,the authors found that F···H–C interaction played a key role in the different molecular packing in structures crystals,which led to the positive/negative phototropism of the actuators.Moreover,theoretical calculations were carried out to reveal the mechanical properties of the crystals.Taking advantage of these photomechanical properties,the authors achieved the potential application in pushing objects,as well as enriching and removing pollutants.Hence,the molecular actuators with different bending behavior could be fabricated by introducing different number of F atom,which may open a novel gate for crystal engineering.
