Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,viole...Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.展开更多
Heat-induced emission peak shift(HIEPS),encompassing both redshift and blueshift,remains mechanistically unresolved in phosphor materials.Using state-of-the-art first-principles calculations of M_(2)SiO_(4):Eu^(2+)(M=...Heat-induced emission peak shift(HIEPS),encompassing both redshift and blueshift,remains mechanistically unresolved in phosphor materials.Using state-of-the-art first-principles calculations of M_(2)SiO_(4):Eu^(2+)(M=Sr,Ba,Ca),we reveal that conventional thermal expansion theory cannot adequately explain these phenomena.Instead,our frozen phonon analysis identifies local electron-phonon coupling as the dominant mechanism,where anisotropic thermal vibrations selectively distort the asymmetric Eu-5d potential well that arises from the dopant’s coordination environment.This distortion manifests through the temperature-sensitiveΔ_(f−d) parameter governing the 5d→4f transition energy,directly controlling spectral shifts.Our findings establish a universal framework for HIEPS in rare-earth phosphors and enable a Δ_(f−d)-guided strategy for designing thermally stable phosphors.展开更多
Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic k...Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic kinetic model was applied to identify three characteristic processes:nucleation and growth(NG),phase boundary interaction(I),and diffusion(D).Control mixtures containing inert quartz powder with comparable particle size distributions were prepared for comparison.Pore characteristics of hardened PS pastes at different temperatures were analyzed via mercury intrusion porosimetry,while hydration products were characterized using X-ray diffraction(XRD)and thermogravimetric analysis(TG-DTG).The experimental results indicate that the retarding effect of PS on early cement hydration outweighs its accelerating effect,attributed to the combined influence of nucleation and dilution,with retardation decreasing as temperature increases.PS exhibits early reactivity and continuously consumes calcium hydroxide through the pozzolanic reaction,as evidenced by stable phase assemblages accompanied by reduced CH content in XRD and TG-DTG analyses.At 20℃,increasing PS content maintains the NG→I→D mechanism but slows reaction rates across all stages.Elevated temperatures significantly accelerate the NG process,shifting the dominant mechanism from NG toward D.Simultaneously,enhanced PS reactivity contributes to a refined pore structure and improved compressive strength.展开更多
High phosphorous oolitic hematite ore is one of typical intractable iron ores in China, and the conventional beneficiation methods are found to be impracticable to , remove phosphorus from the ore effectively. Better ...High phosphorous oolitic hematite ore is one of typical intractable iron ores in China, and the conventional beneficiation methods are found to be impracticable to , remove phosphorus from the ore effectively. Better beneficiation index were gotten by direct reduction roasting with dephosphorization agent followed by two stages of grinding and magnetic separation. P content decreases from 0.82% in the raw ore to 0.06% in the magnetic concentrate, and the total iron grade increases from 43.65% to 90.23%, the recovery of iron can reach 87%. Mechanisms of phosphorus removal in the beneficiation of high phosphorous oolitic hematite ore by direct reduction roasting with dephosphorization agent were studied using XRD, SEM and EPMA. The results showed that about 20% of the apatite in the raw ore transferred into phosphorus and volatilized with the gas in the process of reduction roasting, while the rest 80% apatite was not involved in the reaction of generation of phosphorus, and remained as apatite in the roasted products, which was removed to tailings by grinding and magnetic separation. A small amount of phosphorus existed in the magnetic concentrate as apatite. The oolitic texture of raw ore was partly changed during roasting, resulting in the formation of nepheline in the reaction between the dephosphorization agent, SiO2 and Al2O3 in the raw ore, which greatly improved the liberation degree of minerals in the roasted products, and it was beneficial to the subsequent grinding and magnetic separation.展开更多
All-inorganic reflective phosphor-in-glass film(PiGF) converter has garnered widespread attentions for high brightness laser-driven white lighting,while its poor color quality and low luminescence stability have been ...All-inorganic reflective phosphor-in-glass film(PiGF) converter has garnered widespread attentions for high brightness laser-driven white lighting,while its poor color quality and low luminescence stability have been inevitable roadblocks.Herein,the bicolor PiGF containing green-emitting Y3Al3.08Ga1.92O12:Ce3+(YAGG) and red-emitting CaAlSiN_(3):Eu^(2+)(CASN) phosphors bonded on Al2O3substrate was prepared for enabling high color quality laser-driven white lighting in reflective configuration.The bicolor PiGF has high quantum efficiency and good structure stability.By optimizing the CASN content,PiGF thickness and Al_(2)O_(3) content,the reflective bicolor PiGF based white laser diode(LD)displays good luminescence performance with a luminous flux of 451.5 lm and a luminous efficacy of142.3 lm/W and high color quality with a color rendering index(CRI) of 85.3 and a correlated color temperature(CCT) of 5177 K under the incident laser power of 3.15 W,and still has excellent luminescence and color stabilities(CRI and CCT) under the continuous laser excitation of 5.61 W,attributed to the good thermal conductivity and high reflectivity of Al_(2)O_(3) substrate and scattering enhancement effect of Al_(2)O_(3) particles.It can be foreseen that the reflective bicolor PiGF converter provides a promising strategy for enabling high quality laser-driven white lighting.展开更多
Sodium-ion batteries(SIBs) are promising electrochemical energy storage systems as lithium-ion batteries by virtue of their similar chemical properties and natural abundance and availability.However,the ionic radius o...Sodium-ion batteries(SIBs) are promising electrochemical energy storage systems as lithium-ion batteries by virtue of their similar chemical properties and natural abundance and availability.However,the ionic radius of Na^(+)is larger than that of Li^(+),leading to challenges in its insertion/extraction at anode side.As a class of anode materials,phosphorus allotropes(PAs,red,and black) and metal phosphides(MPs) have shown great prospects because of high theoretical gravimetric/volumetric capacity,high carrier mobility,and suitable redox potential.In this review,recent developments in the studies of PAs and MPs with particular emphasis on understanding sodium storage mechanisms,developing novel synthesis strategies,and performance validations have been manifested valuable solutions to address these challenges.We begin with the introduction and classification of the macroscopic sodiation mechanisms of PAs and MPs,and the various fabrication strategies of PAs and MPs are comprehensively summarized in second section.The third section thoroughly reviews the progresses on PAs and MPs-based advanced materials for their application in SIBs.Finally,we also discuss the significant challenges and outline a roadmap for future research directions.展开更多
To completely recover valuable elements and reduce the amount of waste,the impact of phosphoric acid on the decomposition of rare earth,fluorine and phosphorus during cyclic leaching was studied based on the character...To completely recover valuable elements and reduce the amount of waste,the impact of phosphoric acid on the decomposition of rare earth,fluorine and phosphorus during cyclic leaching was studied based on the characteristics of low-tempe rature sulfuric acid deco mposition.When a single monazite was leached using 75 wt% H_(2)SO_(4) solution with phosphoric acid,the size and number of monazite particles in the washing slag gradually decrease with the increase in phosphoric acid content in the leaching solution.The monazite phase can hardly be found in the slag when the phosphoric acid content reaches 70 g/L,which indicates that phosphoric acid is favorable for monazite decomposition.The mixed rare earth concentrate was leached by 75 wt% H_(2)SO_(4) containing 70 g/L phosphoric acid,the mineral compositions of the washing slag are only gypsum and unwashed rare earth sulfuric acid.After cyclic leaching of75 wt% H_(2)SO_(4),the mineral compositions of the primary leaching washing slag are mainly undecomposed monazite,rare earth sulfate and calcium sulfate.However,monazite is not found in the mineral phase of the second and third leaching washing slag.The leaching rates of rare earth and phosphorus gradually increase with the increase in cyclic leaching times.In addition,the phosphoric acid content in the leaching solution increases with the increase in the number of cyclic leaching time.However,the rising trend decreases when the phosphoric acid content reaches 50 g/L by adsorption and crystallization of phosphoric acid.A small amount of water can be used to clean the leaching residue before washing to recover the more soluble phosphorus acid according to the difference of dissolution between phosphoric acid and rare earth sulfuric acid.展开更多
Different reactive flame retardants have been extensively developed for vinyl ester resins(VERs),but very few of them can yield a flame-retardant resin that meets defined standards(e.g.UL-94 V-0 rating).In this work,p...Different reactive flame retardants have been extensively developed for vinyl ester resins(VERs),but very few of them can yield a flame-retardant resin that meets defined standards(e.g.UL-94 V-0 rating).In this work,phosphorous-containing 1-vinylimidazole salts(called VIDHP and VIDPP)were synthesized through the facile neutralization of the acid and 1-vinylimidazole.VIDHP and VIDPP were then applied as flame-retardant crosslinking agents of VERs,by which phosphorus-containing groups could be incorporated into the resin chain via ionic bonds.VIDHP/VER and VIDPP/VER showed a high curing activity and can be well cured in moderate temperatures.With 20 wt.%additions of VIDHP and VIDPP,VIDHP20/VER,and VIDPP20/VER presented a limiting oxygen index value of 29.7%and 28.4%,respectively,with the latter achieving a UL 94 V0 rating.In the cone calorimetric test,compared to the unmodified VERs,VIDPP20/VER exhibited large reductions in the peak heat release rate,total heat release rate,and total smoke release rate while VIDHP20/VER demonstrated comparatively inferior performance in terms of the heat release.VIDHP20/VER and VIDPP20/VER showed good thermal stability and presented a little lower glass transition temperature than the control sample.VIDPP with a low phosphorus oxidation state(+1)demonstrated high flame-retardant activities in the gaseous phase,whereas VIDHP with a high phosphorus oxidation state(+5)primarily exhibited efficacy in the condensed phase.展开更多
The catalytic enantioselective electrophilic amination reaction has emerged as a highly efficient method for synthesizing diverse nitrogen-containing chiral molecules,with the development of various asymmetric catalys...The catalytic enantioselective electrophilic amination reaction has emerged as a highly efficient method for synthesizing diverse nitrogen-containing chiral molecules,with the development of various asymmetric catalysis systems.Chiral phosphoric acids(CPA)have been widely acknowledged as versatile chiral organocatalysts since it was first discovered in 2004,finding application in catalyzing diverse asymmetric reactions.A comprehensive overview of recent advances in CPA-catalyzed asymmetric electrophilic amination reactions using different N-electrophilic reagents,including azo reagents,aryldiazonium salts,and imine derivatives,is presented.Furthermore,insights into future developments in this field are offered.展开更多
Broadband near-infrared(NIR)phosphor-conve rted light-emitting diode(pc-LED)is a new generation of light source for spectroscopy applications.Current studies generate a broad continuous NIR spectrum to promise the det...Broadband near-infrared(NIR)phosphor-conve rted light-emitting diode(pc-LED)is a new generation of light source for spectroscopy applications.Current studies generate a broad continuous NIR spectrum to promise the detection of a wide range of substances.This paper reports a discontinuous NIR spectral distribution peaking at 760 and 1400 nm,respectively,by co-doping Cr^(3+)and Ni^(2+)ions into CaLu_(2)Mg_(2)Si_(3)O_(12)garnet.The benefit of such a discontinuous spectrum is its ability to prevent energy waste in specific applications,such as moisture(freshness)and hemoglobin detection,where only spectral bands near 750 and 1500 nm are required.The discontinuous spectrum is attributed to the ene rgy transfer from Cr^(3+)to Ni^(2+)ions.The NIR pc-LED fabricated by the new phosphor shows photoelectric efficiency of 9.12%@10 mA and NIR output power of 11.44 mW@100 mA.The NIR pc-LED also performs well when measuring alcohol solution where only a discontinuous spectrum is needed.These results highlight the potential of NIR phosphors with a discontinuous spectrum across a broad 700-1600 nm range.展开更多
Bifunctional applications in solid state lighting and optical thermometry are attractive in the optical field.Despite Eu^(3+)doped phosphors are widely used in white-LEDs,phosphors with high temperature sensitivity re...Bifunctional applications in solid state lighting and optical thermometry are attractive in the optical field.Despite Eu^(3+)doped phosphors are widely used in white-LEDs,phosphors with high temperature sensitivity remain rare.Herein,NaLnTe_(2)O_(7):Eu^(3+)(Ln=Y and Gd)phosphors were synthesized using a rapid microwave-assisted solidstate(MASS)method to fulfill these applications.Under 395 nm excitation,NaLnTe_(2)O_(7):Eu^(3+)exhibit the characteristic ^(5)D_(0)→^(7)F_(J)(J=1–4)transitions of Eu^(3+).Substituting Gd^(3+) for Y^(3+) enhances the luminescence by approximately 2.42 times.Structural analyses reveal that the improved luminescent properties are attributed to the more distorted and appropriate coordination environment in NaGdTe_(2)O_(7):Eu^(3+).Finally,white-LEDs using NaGdTe_(2)O_(7):Eu^(3+)as the red-component produce white light with high Ra of 89.Furthermore,the distinct thermal responses of the ^(5)D_(0)→^(7)F_(J) transitions enable NaLnTe_(2)O_(7):Eu^(3+)to function as temperature sensors via fluorescence intensity ratio(FIR)strategy.NaYTe_(2)O_(7):Eu^(3+)possesses the maximum relative/absolute sensitivity of 1.45%/15.93%K^(-1),whereas NaGdTe_(2)O_(7):Eu^(3+)achieves the maximum relative/absolute sensitivity of 1.53%/30.24% K^(-1).This work highlights the significance of cationic substitution in enhancing luminescent properties for multifunctional applications.展开更多
Er^(3+)-doped BaLaGaO_(4)green phosphors was synthesized through a high-temperature solid-state reaction technique.The phase structure and morphology test results of the phosphor indicate that the BaLaGaO_(4)material ...Er^(3+)-doped BaLaGaO_(4)green phosphors was synthesized through a high-temperature solid-state reaction technique.The phase structure and morphology test results of the phosphor indicate that the BaLaGaO_(4)material was successfully synthesized and Er^(3+)ions were successfully doped into the main lattice.This doping does change the basic structure of the crystal.BaLaGaO_(4):Er^(3+)phosphor exhibits bright green emission centered at 545 nm when excited by 381 nm ultraviolet light or 980 nm near-infrared light.The optimal doping concentration is found to be x=0.04.To quantify the temperature sensitivity of the phosphor,the fluorescence intensity ratio method was used.Within the temperature range of 298-473 K,the maximum relative sensitivities are 1.35%/K(298 K,381 nm)and 1.45%/K(298 K,980 nm),respectively.The maximum absolute sensitivities are 0.67%/K(473 K,381 nm)and 0.69%/K(473 K,980 nm),respectively.Finally,white light-emitting diodes(WLEDs)with a high colour index of Ra=82and a relatively low correlated colour temperature of CCT=5064 K are obtained by integrating the synthesized BaLaGaO_(4):0.04Er^(3+)green phosphor into warm WLEDs devices.These results suggest that Er^(3+)-activated BaLaGaO_(4)multifunctional phosphors hold considerable promise in the areas of optical temperature sensing and WLEDs phosphor conversion.展开更多
We demonstrate a case study of Ce-doped yttrium aluminum garnet(YAG)phosphor to illustrate a novel plasma route for the synthesis of multicomponent materials with addressing morphology and structural control.The prese...We demonstrate a case study of Ce-doped yttrium aluminum garnet(YAG)phosphor to illustrate a novel plasma route for the synthesis of multicomponent materials with addressing morphology and structural control.The presented strategy was started directly from liquid precursors without any precipitating agents,and an innovative growth mechanism was proposed to explain the formation of monodispersed spherical particles with an adjusted size distribution.Homogeneous elemental distribution close to that of liquid precursors was also achieved due to the thermal nonequilibrium effect in plasma.Benefiting from the structural feature of the obtained product,a low transformation temperature of 1100℃for YAG phase was obtained and final products exhibit the highest photoluminescence intensity with rather low Ce doping of 0.5 wt.%,together with excellent thermal stability of 92%preservation of initial emission at 473 K.This work well illustrates the advance of plasma strategy in formation of multicomponent com-pounds with excellent performances,and its potential for large-scale production due to the transient and in-flight synthesis process.展开更多
A blue-red dual-emitting phosphor,Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+),Mn^(2+)was developed in this study.Eu^(2+)acts as a sensitizer ion in Na_(3)KMg_(7)(PO_(4))_(6):Mn^(2+),which significantly improves the undesirable ...A blue-red dual-emitting phosphor,Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+),Mn^(2+)was developed in this study.Eu^(2+)acts as a sensitizer ion in Na_(3)KMg_(7)(PO_(4))_(6):Mn^(2+),which significantly improves the undesirable luminous efficiency of Mn^(2+).The energy transfer between Eu^(2+)and Mn^(2+)significantly boosts both internal quantum efficiency(IQE)and external quantum efficiency(EQE)of the phosphor,achieving values of 72.5%and 42.6%,respectively.Additionally,the phosphor demonstrates exceptional thermal stability,at150℃.maintaining 71.49%of its initial emission intensity.The emission spectrum of the phosphor closely matches the chlorophyll's absorption spectra,with similarities of 75.06%and 94.52%,respectively.This was further confirmed through a fabricated LED with a n-UV chip(395 nm).To further assess the potential for agritech applications,a light-conversion film incorporating the developed phosphor in PDMS glue was prepared.An outdoor cultivation trial with Chlorella showed that the algae's growth rate improves by 27.3%relative to a control group.These results reveal the significant potential of the Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+),Mn^(2+)phosphor for enhancing plant growth in practical applications.展开更多
The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples w...The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples with the oxide demonstrate a long-lasting photoluminescence(PL)under sunlight and ultra-violet(UV)illumination.Room-temperature the PL spectra reveal a wide multicomponent band spreading over all the visible spectral regions.The short-wavelength part of the band is ascribed to the cellulose-related luminescence,while the long-wavelength PL component with maxima near 540 nm corresponds to the luminescence of the SrAl_(2)O_(4):Eu,Dy phosphor.The dependency of the PL intensity on oxide concentration suggests the reabsorption of cellulose emission by the oxide and vice versa.The study of the dielectric properties of composite papers shows the presence of dielectric relaxations at low temperatures(T~−50℃).Similar cellulose materials to those studied can be considered as alternatives for artificial petroleum-based polymers.Low cost,eco-friendliness,biocompatibility,and the simplicity of recycling are among the main advantages of these materials.They are produced from the cellulose which is one of the most abundant renewable materials in nature.The data on the mechanical,dielectric,and optical properties indicate that the papers studied can be used in flexible lighting devices,WLEDs,coating,markers,labels,etc.展开更多
Phosphoric acid is a key ingredient in fertilizer production and contains many rare earth elements(REEs).Recovering REEs from phosphoric acid can prevent the accumulation of these elements in the soil and help bridge ...Phosphoric acid is a key ingredient in fertilizer production and contains many rare earth elements(REEs).Recovering REEs from phosphoric acid can prevent the accumulation of these elements in the soil and help bridge the gap between supply and demand.In this concern,a new material called Si-6G PAMAMPPAAM dendrimers modified silica gel terminated with phenylphosphonic acid-amide moieties was developed and its ability to adsorb Nd(Ⅲ)and Er(Ⅲ)from the phosphoric acid solution was investigated.K inetics and isotherm of the uptake process were investigated to explo re the so rption characte ristics.The attained results show that both metal ions exhibit the same adsorption performance,and the uptake process is depicted as a chemisorption,monolayer,uniform,and homogeneous process.The equilibrium state is achieved within 120 min,and the maximum uptake capacity is 16.7 mg Nd(Ⅲ)/g,and 14.0 mg Er(Ⅲ)/g.Sorption thermodynamics is an endothermic,spontaneous,and feasible uptake process.Nitric acid(1.0 mol/L)is found to be efficient for adsorbing about 94.3%and 92.5%of neodymium(Ⅲ)and erbium(Ⅲ)respectively,and the prepared Si-6G PAMAM-PPAAM demonstrates excellent stability over five consecutive sorption/desorption cycles.Preliminary tests on commercial phosphoric acid demonstrate that Si-6G PAMAM-PPAAM retains its effective REEs uptake from a complex comm ercial phosph oric acid solution.展开更多
This investigation evaluated the impact of as-is biochar(BC)and phosphorous(P)-loaded biochar(PBC)(3%)on the growth and biochemical characteristics of rice under exposure to vanadium(V)(60 mg L^(-1)).The results indic...This investigation evaluated the impact of as-is biochar(BC)and phosphorous(P)-loaded biochar(PBC)(3%)on the growth and biochemical characteristics of rice under exposure to vanadium(V)(60 mg L^(-1)).The results indicate that rice plants exposed to a V-only treatment experienced declines in several growth parameters.Conversely,the inclusion of BC and PBC caused noteworthy increases in physiological traits.PBC performed well in stress environments.Specifically,the shoot and root fresh weights increased by 82.86 and 53.33%,respectively,when compared to the V-only treatment.In addition,the SPAD chlorophyll of the shoot increased by 13.05%relative to the V-amended plants.Moreover,including BC and PBC improved the antioxidant enzyme traits of plant shoot and root,such as significant increases in superoxide dismutase(SOD by 56.11 and 117.35%),catalase(CAT by 34.19 and 35.77%),and peroxidase(POD by 25.90 and 18.74%)when compared to V-only amended plants,respectively.These findings strongly suggest that the application of BC and PBC can trigger biochemical pathways that facilitate biomass accumulation in meristematic cells.However,further investigations are required to elucidate the underlying mechanisms responsible for this growth promotion.展开更多
Eu^(3+)-activated red phosphors are popular for their classic^(5)D_(0)→^(7)F_(J)(J=0,1,2,3,4)emission characteristics.However,the weak emission of the^(5)D_(0)→^(7)F_(4)transition and the concentration quenching cau...Eu^(3+)-activated red phosphors are popular for their classic^(5)D_(0)→^(7)F_(J)(J=0,1,2,3,4)emission characteristics.However,the weak emission of the^(5)D_(0)→^(7)F_(4)transition and the concentration quenching caused by energy migration have become the main obstacles to achieving strong far-red emission.Herein,we report a novel Ba_(3)Sc_(1-x)(BO_(2))9:xEu^(3+)phosphor that simultaneously enhances 5D0→7F4 emission and suppresses quenching through size confinement and low phonon energy.A Sr^(2+)→Ba^(2+)substitution strategy optimizes luminescence,achieving 1.56-fold intensity enhancement and improved quantum efficiency(IQE:83%→92%;EQE:38%→40%).The improvement mechanism was revealed through the local coordination distortion of Eu^(3+)and the change of the band gap when Sr and Ba coexist.Structural analysis reveals enhanced thermal stability(423 K:86%→97%;483 K:78%→95%)originates from increased lattice rigidity.Abnormal thermal quenching(303-363 K)is white light-emitting diodes(WLEDs)device prepared based on Ba_(2.80)Sr_(0.20)Eu(BO_(2))_(9)phosphor shows a color temperature of 4532 K and a color rendering index of 91.6.This article also explores three applications of plant growth,latent fingerprint visualization,and anticounterfeiting QR code.This finding provides a reference for further exploring the design of high concentration quenching and efficient far-red emitting phosphors.展开更多
The significance of axial chiral compounds in asymmetric organic catalysis,functional materials,and pharmaceutical useful molecules has encouraged advancements in the atroposelective synthesis of such compounds.Herein...The significance of axial chiral compounds in asymmetric organic catalysis,functional materials,and pharmaceutical useful molecules has encouraged advancements in the atroposelective synthesis of such compounds.Herein,we report the first atroposelective construction of axially chiral N-aryl benzimidazoles catalyzed by a polymer-supported chiral phosphoric acid.A varied library of atropisomers has been synthesized in 30%-96%yield with 58%-98%enantiomeric excess(ee)under a straightforward reaction setup(without the use of molecular sieves).Notably,even after 12 cycles,the immobilized catalyst maintained its reactivity and selectivity(TON>540).展开更多
To develop new up-conversion luminescent materials for non-contact optical thermometer with high sensitivity and temperature re solution,a battery of KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphors were fabricated through...To develop new up-conversion luminescent materials for non-contact optical thermometer with high sensitivity and temperature re solution,a battery of KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphors were fabricated through solid reaction process.The crystal structure,up-conversion luminescence,energy transfer,thermal stability and optical temperature sensing performances were studied in detail.Under 980 nm laser excitation,the KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphor exhibits distinctive emission bands of Ho^(3+)at545,660,and 755 nm,and excellent illuminant performance.Based on the thermally coupled levels(TCLs)of Ho^(3+),both the relative sensitivity(S_(r))and absolute sensitivity(S_(a))display similar change trends,with the highest values of 6.73%/K(@298 K)and 5.69%/K(@298 K),respectively.Furthermore,the highest Saof 13.90%/K(@623 K)and the ultimate Srof 0.62%/K(@298 K)are achieved based on non-TCLs of Ho^(3+).Therefore,KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphor is a promising candidate for self-referenced optical thermometry.展开更多
基金National Key Research and Development Program of China(2021YFB3500501)。
文摘Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.
基金supported by the National Natural Science Foundation(NSF)of China(62475265,22031009,22075282,12404064)the National Key Research and Development Program of China(2021YFB3601501)+1 种基金Strategic Priority Research Program of the Chinese Academy of Sciences(XDB1170000)NSF of Fujian Province(2023J01212,2024J08106).
文摘Heat-induced emission peak shift(HIEPS),encompassing both redshift and blueshift,remains mechanistically unresolved in phosphor materials.Using state-of-the-art first-principles calculations of M_(2)SiO_(4):Eu^(2+)(M=Sr,Ba,Ca),we reveal that conventional thermal expansion theory cannot adequately explain these phenomena.Instead,our frozen phonon analysis identifies local electron-phonon coupling as the dominant mechanism,where anisotropic thermal vibrations selectively distort the asymmetric Eu-5d potential well that arises from the dopant’s coordination environment.This distortion manifests through the temperature-sensitiveΔ_(f−d) parameter governing the 5d→4f transition energy,directly controlling spectral shifts.Our findings establish a universal framework for HIEPS in rare-earth phosphors and enable a Δ_(f−d)-guided strategy for designing thermally stable phosphors.
基金Funded by the Sichuan Province Science and Technology Support Program(No.2025YFNZH0022)the Chengdu Municipal Science and Technology Program(No.2025-YF11-00003-HZ)。
文摘Curing temperature significantly affects the pozzolanic reaction kinetics of phosphorous slag(PS),thereby governing the early-age(7 d)hydration behavior of PS composite binders at 20,30,and 60℃.The Krstulovic-Dabic kinetic model was applied to identify three characteristic processes:nucleation and growth(NG),phase boundary interaction(I),and diffusion(D).Control mixtures containing inert quartz powder with comparable particle size distributions were prepared for comparison.Pore characteristics of hardened PS pastes at different temperatures were analyzed via mercury intrusion porosimetry,while hydration products were characterized using X-ray diffraction(XRD)and thermogravimetric analysis(TG-DTG).The experimental results indicate that the retarding effect of PS on early cement hydration outweighs its accelerating effect,attributed to the combined influence of nucleation and dilution,with retardation decreasing as temperature increases.PS exhibits early reactivity and continuously consumes calcium hydroxide through the pozzolanic reaction,as evidenced by stable phase assemblages accompanied by reduced CH content in XRD and TG-DTG analyses.At 20℃,increasing PS content maintains the NG→I→D mechanism but slows reaction rates across all stages.Elevated temperatures significantly accelerate the NG process,shifting the dominant mechanism from NG toward D.Simultaneously,enhanced PS reactivity contributes to a refined pore structure and improved compressive strength.
基金Project (51074016) support by the National Natural Science Foundation of China
文摘High phosphorous oolitic hematite ore is one of typical intractable iron ores in China, and the conventional beneficiation methods are found to be impracticable to , remove phosphorus from the ore effectively. Better beneficiation index were gotten by direct reduction roasting with dephosphorization agent followed by two stages of grinding and magnetic separation. P content decreases from 0.82% in the raw ore to 0.06% in the magnetic concentrate, and the total iron grade increases from 43.65% to 90.23%, the recovery of iron can reach 87%. Mechanisms of phosphorus removal in the beneficiation of high phosphorous oolitic hematite ore by direct reduction roasting with dephosphorization agent were studied using XRD, SEM and EPMA. The results showed that about 20% of the apatite in the raw ore transferred into phosphorus and volatilized with the gas in the process of reduction roasting, while the rest 80% apatite was not involved in the reaction of generation of phosphorus, and remained as apatite in the roasted products, which was removed to tailings by grinding and magnetic separation. A small amount of phosphorus existed in the magnetic concentrate as apatite. The oolitic texture of raw ore was partly changed during roasting, resulting in the formation of nepheline in the reaction between the dephosphorization agent, SiO2 and Al2O3 in the raw ore, which greatly improved the liberation degree of minerals in the roasted products, and it was beneficial to the subsequent grinding and magnetic separation.
基金Project supported by the Science and Technology Project of Shenzhen City (JSGG20210802154213040)the Guangdong Basic and Applied Basic Research Foundation (2024A1515010001)the Shenzhen Postdoctoral Research Funding Project。
文摘All-inorganic reflective phosphor-in-glass film(PiGF) converter has garnered widespread attentions for high brightness laser-driven white lighting,while its poor color quality and low luminescence stability have been inevitable roadblocks.Herein,the bicolor PiGF containing green-emitting Y3Al3.08Ga1.92O12:Ce3+(YAGG) and red-emitting CaAlSiN_(3):Eu^(2+)(CASN) phosphors bonded on Al2O3substrate was prepared for enabling high color quality laser-driven white lighting in reflective configuration.The bicolor PiGF has high quantum efficiency and good structure stability.By optimizing the CASN content,PiGF thickness and Al_(2)O_(3) content,the reflective bicolor PiGF based white laser diode(LD)displays good luminescence performance with a luminous flux of 451.5 lm and a luminous efficacy of142.3 lm/W and high color quality with a color rendering index(CRI) of 85.3 and a correlated color temperature(CCT) of 5177 K under the incident laser power of 3.15 W,and still has excellent luminescence and color stabilities(CRI and CCT) under the continuous laser excitation of 5.61 W,attributed to the good thermal conductivity and high reflectivity of Al_(2)O_(3) substrate and scattering enhancement effect of Al_(2)O_(3) particles.It can be foreseen that the reflective bicolor PiGF converter provides a promising strategy for enabling high quality laser-driven white lighting.
基金financially supported by the Natural Science Foundation of China(Nos.22208214,22005190,and 21938005)the Science&Technology Commission of Shanghai Municipality(Nos.20QB1405700,and 19DZ1205500)Zhejiang Key Research and Development Program(No.2020C01128)
文摘Sodium-ion batteries(SIBs) are promising electrochemical energy storage systems as lithium-ion batteries by virtue of their similar chemical properties and natural abundance and availability.However,the ionic radius of Na^(+)is larger than that of Li^(+),leading to challenges in its insertion/extraction at anode side.As a class of anode materials,phosphorus allotropes(PAs,red,and black) and metal phosphides(MPs) have shown great prospects because of high theoretical gravimetric/volumetric capacity,high carrier mobility,and suitable redox potential.In this review,recent developments in the studies of PAs and MPs with particular emphasis on understanding sodium storage mechanisms,developing novel synthesis strategies,and performance validations have been manifested valuable solutions to address these challenges.We begin with the introduction and classification of the macroscopic sodiation mechanisms of PAs and MPs,and the various fabrication strategies of PAs and MPs are comprehensively summarized in second section.The third section thoroughly reviews the progresses on PAs and MPs-based advanced materials for their application in SIBs.Finally,we also discuss the significant challenges and outline a roadmap for future research directions.
基金support by the National Natural Science Foundation of Inner Mongolia (2022SHZR1885)Natural Science Foundation of Hebei province (E2022402101,E2022402105)。
文摘To completely recover valuable elements and reduce the amount of waste,the impact of phosphoric acid on the decomposition of rare earth,fluorine and phosphorus during cyclic leaching was studied based on the characteristics of low-tempe rature sulfuric acid deco mposition.When a single monazite was leached using 75 wt% H_(2)SO_(4) solution with phosphoric acid,the size and number of monazite particles in the washing slag gradually decrease with the increase in phosphoric acid content in the leaching solution.The monazite phase can hardly be found in the slag when the phosphoric acid content reaches 70 g/L,which indicates that phosphoric acid is favorable for monazite decomposition.The mixed rare earth concentrate was leached by 75 wt% H_(2)SO_(4) containing 70 g/L phosphoric acid,the mineral compositions of the washing slag are only gypsum and unwashed rare earth sulfuric acid.After cyclic leaching of75 wt% H_(2)SO_(4),the mineral compositions of the primary leaching washing slag are mainly undecomposed monazite,rare earth sulfate and calcium sulfate.However,monazite is not found in the mineral phase of the second and third leaching washing slag.The leaching rates of rare earth and phosphorus gradually increase with the increase in cyclic leaching times.In addition,the phosphoric acid content in the leaching solution increases with the increase in the number of cyclic leaching time.However,the rising trend decreases when the phosphoric acid content reaches 50 g/L by adsorption and crystallization of phosphoric acid.A small amount of water can be used to clean the leaching residue before washing to recover the more soluble phosphorus acid according to the difference of dissolution between phosphoric acid and rare earth sulfuric acid.
基金supported by the National Natural Science Foundation of China(Grant Nos.51991351 and51903132)the Young Elite Scientist Sponsorship Program by CAST(No.2022QNRC001).
文摘Different reactive flame retardants have been extensively developed for vinyl ester resins(VERs),but very few of them can yield a flame-retardant resin that meets defined standards(e.g.UL-94 V-0 rating).In this work,phosphorous-containing 1-vinylimidazole salts(called VIDHP and VIDPP)were synthesized through the facile neutralization of the acid and 1-vinylimidazole.VIDHP and VIDPP were then applied as flame-retardant crosslinking agents of VERs,by which phosphorus-containing groups could be incorporated into the resin chain via ionic bonds.VIDHP/VER and VIDPP/VER showed a high curing activity and can be well cured in moderate temperatures.With 20 wt.%additions of VIDHP and VIDPP,VIDHP20/VER,and VIDPP20/VER presented a limiting oxygen index value of 29.7%and 28.4%,respectively,with the latter achieving a UL 94 V0 rating.In the cone calorimetric test,compared to the unmodified VERs,VIDPP20/VER exhibited large reductions in the peak heat release rate,total heat release rate,and total smoke release rate while VIDHP20/VER demonstrated comparatively inferior performance in terms of the heat release.VIDHP20/VER and VIDPP20/VER showed good thermal stability and presented a little lower glass transition temperature than the control sample.VIDPP with a low phosphorus oxidation state(+1)demonstrated high flame-retardant activities in the gaseous phase,whereas VIDHP with a high phosphorus oxidation state(+5)primarily exhibited efficacy in the condensed phase.
文摘The catalytic enantioselective electrophilic amination reaction has emerged as a highly efficient method for synthesizing diverse nitrogen-containing chiral molecules,with the development of various asymmetric catalysis systems.Chiral phosphoric acids(CPA)have been widely acknowledged as versatile chiral organocatalysts since it was first discovered in 2004,finding application in catalyzing diverse asymmetric reactions.A comprehensive overview of recent advances in CPA-catalyzed asymmetric electrophilic amination reactions using different N-electrophilic reagents,including azo reagents,aryldiazonium salts,and imine derivatives,is presented.Furthermore,insights into future developments in this field are offered.
基金Project supported by the National Natural Science Foundation of China(12074373,12474415,U22A20139)the Major Science and Technology Project of Anhui Province(2021e03020007)+1 种基金the Developing Project of Science and Technology of Jilin Province(the Natural Science Foundation,20210101473JC)the Key Laboratory of Advanced Structural Materials(ASM-202205)。
文摘Broadband near-infrared(NIR)phosphor-conve rted light-emitting diode(pc-LED)is a new generation of light source for spectroscopy applications.Current studies generate a broad continuous NIR spectrum to promise the detection of a wide range of substances.This paper reports a discontinuous NIR spectral distribution peaking at 760 and 1400 nm,respectively,by co-doping Cr^(3+)and Ni^(2+)ions into CaLu_(2)Mg_(2)Si_(3)O_(12)garnet.The benefit of such a discontinuous spectrum is its ability to prevent energy waste in specific applications,such as moisture(freshness)and hemoglobin detection,where only spectral bands near 750 and 1500 nm are required.The discontinuous spectrum is attributed to the ene rgy transfer from Cr^(3+)to Ni^(2+)ions.The NIR pc-LED fabricated by the new phosphor shows photoelectric efficiency of 9.12%@10 mA and NIR output power of 11.44 mW@100 mA.The NIR pc-LED also performs well when measuring alcohol solution where only a discontinuous spectrum is needed.These results highlight the potential of NIR phosphors with a discontinuous spectrum across a broad 700-1600 nm range.
基金financially supported by the Caiyun Postdoctoral Innovation Project(No.C615300504089)Yunnan Fundamental Research Project(No.202401AS070128)National Natural Science Foundation of China(No.22165031).
文摘Bifunctional applications in solid state lighting and optical thermometry are attractive in the optical field.Despite Eu^(3+)doped phosphors are widely used in white-LEDs,phosphors with high temperature sensitivity remain rare.Herein,NaLnTe_(2)O_(7):Eu^(3+)(Ln=Y and Gd)phosphors were synthesized using a rapid microwave-assisted solidstate(MASS)method to fulfill these applications.Under 395 nm excitation,NaLnTe_(2)O_(7):Eu^(3+)exhibit the characteristic ^(5)D_(0)→^(7)F_(J)(J=1–4)transitions of Eu^(3+).Substituting Gd^(3+) for Y^(3+) enhances the luminescence by approximately 2.42 times.Structural analyses reveal that the improved luminescent properties are attributed to the more distorted and appropriate coordination environment in NaGdTe_(2)O_(7):Eu^(3+).Finally,white-LEDs using NaGdTe_(2)O_(7):Eu^(3+)as the red-component produce white light with high Ra of 89.Furthermore,the distinct thermal responses of the ^(5)D_(0)→^(7)F_(J) transitions enable NaLnTe_(2)O_(7):Eu^(3+)to function as temperature sensors via fluorescence intensity ratio(FIR)strategy.NaYTe_(2)O_(7):Eu^(3+)possesses the maximum relative/absolute sensitivity of 1.45%/15.93%K^(-1),whereas NaGdTe_(2)O_(7):Eu^(3+)achieves the maximum relative/absolute sensitivity of 1.53%/30.24% K^(-1).This work highlights the significance of cationic substitution in enhancing luminescent properties for multifunctional applications.
基金supported by the National Natural Science Foundation of China(52403403)Guizhou Provincial Basic Research Program(Natural Science)(Qian ke he ji chu-ZK2024 YiBan 095)。
文摘Er^(3+)-doped BaLaGaO_(4)green phosphors was synthesized through a high-temperature solid-state reaction technique.The phase structure and morphology test results of the phosphor indicate that the BaLaGaO_(4)material was successfully synthesized and Er^(3+)ions were successfully doped into the main lattice.This doping does change the basic structure of the crystal.BaLaGaO_(4):Er^(3+)phosphor exhibits bright green emission centered at 545 nm when excited by 381 nm ultraviolet light or 980 nm near-infrared light.The optimal doping concentration is found to be x=0.04.To quantify the temperature sensitivity of the phosphor,the fluorescence intensity ratio method was used.Within the temperature range of 298-473 K,the maximum relative sensitivities are 1.35%/K(298 K,381 nm)and 1.45%/K(298 K,980 nm),respectively.The maximum absolute sensitivities are 0.67%/K(473 K,381 nm)and 0.69%/K(473 K,980 nm),respectively.Finally,white light-emitting diodes(WLEDs)with a high colour index of Ra=82and a relatively low correlated colour temperature of CCT=5064 K are obtained by integrating the synthesized BaLaGaO_(4):0.04Er^(3+)green phosphor into warm WLEDs devices.These results suggest that Er^(3+)-activated BaLaGaO_(4)multifunctional phosphors hold considerable promise in the areas of optical temperature sensing and WLEDs phosphor conversion.
基金supported by the National Natu-ral Science Foundation of China(No.52174342)the Beijing Nat-ural Science Foundation(No.2232044)the Beijing Munic-ipal Education Commission Research Plan General Project(No.KM202410005009).
文摘We demonstrate a case study of Ce-doped yttrium aluminum garnet(YAG)phosphor to illustrate a novel plasma route for the synthesis of multicomponent materials with addressing morphology and structural control.The presented strategy was started directly from liquid precursors without any precipitating agents,and an innovative growth mechanism was proposed to explain the formation of monodispersed spherical particles with an adjusted size distribution.Homogeneous elemental distribution close to that of liquid precursors was also achieved due to the thermal nonequilibrium effect in plasma.Benefiting from the structural feature of the obtained product,a low transformation temperature of 1100℃for YAG phase was obtained and final products exhibit the highest photoluminescence intensity with rather low Ce doping of 0.5 wt.%,together with excellent thermal stability of 92%preservation of initial emission at 473 K.This work well illustrates the advance of plasma strategy in formation of multicomponent com-pounds with excellent performances,and its potential for large-scale production due to the transient and in-flight synthesis process.
基金supported by the Department of Industry and Information Technology of Gansu Province(2024 Provincial Key Talent Program)the National Natural Science Foundation of China(U22A20136)。
文摘A blue-red dual-emitting phosphor,Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+),Mn^(2+)was developed in this study.Eu^(2+)acts as a sensitizer ion in Na_(3)KMg_(7)(PO_(4))_(6):Mn^(2+),which significantly improves the undesirable luminous efficiency of Mn^(2+).The energy transfer between Eu^(2+)and Mn^(2+)significantly boosts both internal quantum efficiency(IQE)and external quantum efficiency(EQE)of the phosphor,achieving values of 72.5%and 42.6%,respectively.Additionally,the phosphor demonstrates exceptional thermal stability,at150℃.maintaining 71.49%of its initial emission intensity.The emission spectrum of the phosphor closely matches the chlorophyll's absorption spectra,with similarities of 75.06%and 94.52%,respectively.This was further confirmed through a fabricated LED with a n-UV chip(395 nm).To further assess the potential for agritech applications,a light-conversion film incorporating the developed phosphor in PDMS glue was prepared.An outdoor cultivation trial with Chlorella showed that the algae's growth rate improves by 27.3%relative to a control group.These results reveal the significant potential of the Na_(3)KMg_(7)(PO_(4))_(6):Eu^(2+),Mn^(2+)phosphor for enhancing plant growth in practical applications.
基金financed by the National Research Foundation of Ukraine(Project No.2022.01/0168).
文摘The work deals with cellulose paper filled with nanocellulose and SrAl_(2)O_(4):Eu,Dy oxide phosphor.It was found that both nanocellulose and oxide improve the tensile strength of the composites obtained.The samples with the oxide demonstrate a long-lasting photoluminescence(PL)under sunlight and ultra-violet(UV)illumination.Room-temperature the PL spectra reveal a wide multicomponent band spreading over all the visible spectral regions.The short-wavelength part of the band is ascribed to the cellulose-related luminescence,while the long-wavelength PL component with maxima near 540 nm corresponds to the luminescence of the SrAl_(2)O_(4):Eu,Dy phosphor.The dependency of the PL intensity on oxide concentration suggests the reabsorption of cellulose emission by the oxide and vice versa.The study of the dielectric properties of composite papers shows the presence of dielectric relaxations at low temperatures(T~−50℃).Similar cellulose materials to those studied can be considered as alternatives for artificial petroleum-based polymers.Low cost,eco-friendliness,biocompatibility,and the simplicity of recycling are among the main advantages of these materials.They are produced from the cellulose which is one of the most abundant renewable materials in nature.The data on the mechanical,dielectric,and optical properties indicate that the papers studied can be used in flexible lighting devices,WLEDs,coating,markers,labels,etc.
文摘Phosphoric acid is a key ingredient in fertilizer production and contains many rare earth elements(REEs).Recovering REEs from phosphoric acid can prevent the accumulation of these elements in the soil and help bridge the gap between supply and demand.In this concern,a new material called Si-6G PAMAMPPAAM dendrimers modified silica gel terminated with phenylphosphonic acid-amide moieties was developed and its ability to adsorb Nd(Ⅲ)and Er(Ⅲ)from the phosphoric acid solution was investigated.K inetics and isotherm of the uptake process were investigated to explo re the so rption characte ristics.The attained results show that both metal ions exhibit the same adsorption performance,and the uptake process is depicted as a chemisorption,monolayer,uniform,and homogeneous process.The equilibrium state is achieved within 120 min,and the maximum uptake capacity is 16.7 mg Nd(Ⅲ)/g,and 14.0 mg Er(Ⅲ)/g.Sorption thermodynamics is an endothermic,spontaneous,and feasible uptake process.Nitric acid(1.0 mol/L)is found to be efficient for adsorbing about 94.3%and 92.5%of neodymium(Ⅲ)and erbium(Ⅲ)respectively,and the prepared Si-6G PAMAM-PPAAM demonstrates excellent stability over five consecutive sorption/desorption cycles.Preliminary tests on commercial phosphoric acid demonstrate that Si-6G PAMAM-PPAAM retains its effective REEs uptake from a complex comm ercial phosph oric acid solution.
基金funded by the Launch Fund of Hainan University High Level Talent,China(RZ2100003226)the National Natural Science Foundation of China(NSFC-31860728).
文摘This investigation evaluated the impact of as-is biochar(BC)and phosphorous(P)-loaded biochar(PBC)(3%)on the growth and biochemical characteristics of rice under exposure to vanadium(V)(60 mg L^(-1)).The results indicate that rice plants exposed to a V-only treatment experienced declines in several growth parameters.Conversely,the inclusion of BC and PBC caused noteworthy increases in physiological traits.PBC performed well in stress environments.Specifically,the shoot and root fresh weights increased by 82.86 and 53.33%,respectively,when compared to the V-only treatment.In addition,the SPAD chlorophyll of the shoot increased by 13.05%relative to the V-amended plants.Moreover,including BC and PBC improved the antioxidant enzyme traits of plant shoot and root,such as significant increases in superoxide dismutase(SOD by 56.11 and 117.35%),catalase(CAT by 34.19 and 35.77%),and peroxidase(POD by 25.90 and 18.74%)when compared to V-only amended plants,respectively.These findings strongly suggest that the application of BC and PBC can trigger biochemical pathways that facilitate biomass accumulation in meristematic cells.However,further investigations are required to elucidate the underlying mechanisms responsible for this growth promotion.
基金financially supported by Jilin Scientific and Technological Development Programs(No.20250102156JC)
文摘Eu^(3+)-activated red phosphors are popular for their classic^(5)D_(0)→^(7)F_(J)(J=0,1,2,3,4)emission characteristics.However,the weak emission of the^(5)D_(0)→^(7)F_(4)transition and the concentration quenching caused by energy migration have become the main obstacles to achieving strong far-red emission.Herein,we report a novel Ba_(3)Sc_(1-x)(BO_(2))9:xEu^(3+)phosphor that simultaneously enhances 5D0→7F4 emission and suppresses quenching through size confinement and low phonon energy.A Sr^(2+)→Ba^(2+)substitution strategy optimizes luminescence,achieving 1.56-fold intensity enhancement and improved quantum efficiency(IQE:83%→92%;EQE:38%→40%).The improvement mechanism was revealed through the local coordination distortion of Eu^(3+)and the change of the band gap when Sr and Ba coexist.Structural analysis reveals enhanced thermal stability(423 K:86%→97%;483 K:78%→95%)originates from increased lattice rigidity.Abnormal thermal quenching(303-363 K)is white light-emitting diodes(WLEDs)device prepared based on Ba_(2.80)Sr_(0.20)Eu(BO_(2))_(9)phosphor shows a color temperature of 4532 K and a color rendering index of 91.6.This article also explores three applications of plant growth,latent fingerprint visualization,and anticounterfeiting QR code.This finding provides a reference for further exploring the design of high concentration quenching and efficient far-red emitting phosphors.
基金supported by Shenzhen Science and Technology Research(Nos.JSGG20201103153807021,GXWD20220811173736002,KCXFZ20230731094904009)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.24qnpy060)+2 种基金Natural Science Foundation of Guangdong Province(No.2021A1515110366)National Natural Science Foundation of China(Nos.22302048,82204231,22275146)Shenzhen Key Laboratory of Advanced Functional Carbon Materials Research and Comprehensive Application。
文摘The significance of axial chiral compounds in asymmetric organic catalysis,functional materials,and pharmaceutical useful molecules has encouraged advancements in the atroposelective synthesis of such compounds.Herein,we report the first atroposelective construction of axially chiral N-aryl benzimidazoles catalyzed by a polymer-supported chiral phosphoric acid.A varied library of atropisomers has been synthesized in 30%-96%yield with 58%-98%enantiomeric excess(ee)under a straightforward reaction setup(without the use of molecular sieves).Notably,even after 12 cycles,the immobilized catalyst maintained its reactivity and selectivity(TON>540).
基金supported by the National Natural Science Foundation of China(61865003)。
文摘To develop new up-conversion luminescent materials for non-contact optical thermometer with high sensitivity and temperature re solution,a battery of KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphors were fabricated through solid reaction process.The crystal structure,up-conversion luminescence,energy transfer,thermal stability and optical temperature sensing performances were studied in detail.Under 980 nm laser excitation,the KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphor exhibits distinctive emission bands of Ho^(3+)at545,660,and 755 nm,and excellent illuminant performance.Based on the thermally coupled levels(TCLs)of Ho^(3+),both the relative sensitivity(S_(r))and absolute sensitivity(S_(a))display similar change trends,with the highest values of 6.73%/K(@298 K)and 5.69%/K(@298 K),respectively.Furthermore,the highest Saof 13.90%/K(@623 K)and the ultimate Srof 0.62%/K(@298 K)are achieved based on non-TCLs of Ho^(3+).Therefore,KBaGd(MoO_(4))_(3):Yb^(3+),Ho^(3+)phosphor is a promising candidate for self-referenced optical thermometry.
