Li_(2)O-Al_(2)O_(3)-SiO_(2)(LAS)glass-ceramics were prepared by a melting method.Effects of different Al_(2)O_(3)content on the structure,crystallization,transmittance and fracture toughness of LAS glassceramics were ...Li_(2)O-Al_(2)O_(3)-SiO_(2)(LAS)glass-ceramics were prepared by a melting method.Effects of different Al_(2)O_(3)content on the structure,crystallization,transmittance and fracture toughness of LAS glassceramics were investigated by means of XRD,FESEM and other methods as well.The results showed that the glass transition temperature and crystallization temperature of samples increased as the content of Al_(2)O_(3)increased from 4.1 wt%to 13.1 wt%,which restrained the precipitation of lithium disilicate crystals.The main crystalline phase of glass-ceramics transformed from lithium disilicate and petalite to silicon dioxide,which reduced the fracture toughness of glass-ceramics.When the Al_(2)O_(3)content was 7.1 wt%,the specimen had outstanding transmittance and fracture toughness.The transmittance was 90.32%.The fracture toughness was 1.13 MPa•m^(1/2).Compared with high-alumina glass,the fracture toughness of the glass-ceramic was greatly improved,and it could be used as a new type of protective material for mobile devices.展开更多
基金State Key Laboratory of Silicate Materials for Architectures(Wuhan University of Technology)(No.2011DA105356)。
文摘Li_(2)O-Al_(2)O_(3)-SiO_(2)(LAS)glass-ceramics were prepared by a melting method.Effects of different Al_(2)O_(3)content on the structure,crystallization,transmittance and fracture toughness of LAS glassceramics were investigated by means of XRD,FESEM and other methods as well.The results showed that the glass transition temperature and crystallization temperature of samples increased as the content of Al_(2)O_(3)increased from 4.1 wt%to 13.1 wt%,which restrained the precipitation of lithium disilicate crystals.The main crystalline phase of glass-ceramics transformed from lithium disilicate and petalite to silicon dioxide,which reduced the fracture toughness of glass-ceramics.When the Al_(2)O_(3)content was 7.1 wt%,the specimen had outstanding transmittance and fracture toughness.The transmittance was 90.32%.The fracture toughness was 1.13 MPa•m^(1/2).Compared with high-alumina glass,the fracture toughness of the glass-ceramic was greatly improved,and it could be used as a new type of protective material for mobile devices.
