Hybrid organic-inorganic perovskite photodetectors have gained significant attention due to their superior potential for optoelectronic applications,offering various advantages such as low-cost processing,high charge ...Hybrid organic-inorganic perovskite photodetectors have gained significant attention due to their superior potential for optoelectronic applications,offering various advantages such as low-cost processing,high charge carrier mobility,and lightweight properties.However,these perovskite photodetectors exhibit relatively low absorption in the near-infrared(NIR)range,which limits their potential applications.Here,to address this challenge,the integration of gold nanorods(Au NRs)utilizing localized surface plasmon resonance(LSPR)effects in the NIR range has been developed,leading to enhanced light absorption in the active region and higher photocurrent generation.Additionally,∼7.9 nm of thin polyethyleneimine ethoxylated(PEIE)interlayers were incorporated into the Au NR photodetectors,suppressing dark current by blocking charge injection.As a result,the synergistic effect of the Au NR/PEIE hybrid layer has led to a high-performance photodetector with a responsivity of 0.360 A/W and a detectivity of 1.81×10^(10) Jones,demonstrating a noticeable enhancement compared to the control device.Finite-difference time-domain(FDTD)simulations,morphological characterizations,and photoluminescence studies further support the mechanism for enhancing the performance of the device.We believe that our plasmon-enhanced protocol holds strong potential as a promising platform for perovskite optoelectronic devices.展开更多
基金supported by the National Research Foundation of Korea(NRF)Grant funded by the Korean Government(Nos.2020R1A2C3003958 and 2021R1C1C2010169)the Basic Science Research Program(Priority Research Institute)through the NRF of Korea funded by the Ministry of Education(No.2021R1A6A1A10039823)the Korea Basic Science Institute(National Research Facilities and Equipment Center)grant funded by the Ministry of Education(No.2020R1A6C101B194).
文摘Hybrid organic-inorganic perovskite photodetectors have gained significant attention due to their superior potential for optoelectronic applications,offering various advantages such as low-cost processing,high charge carrier mobility,and lightweight properties.However,these perovskite photodetectors exhibit relatively low absorption in the near-infrared(NIR)range,which limits their potential applications.Here,to address this challenge,the integration of gold nanorods(Au NRs)utilizing localized surface plasmon resonance(LSPR)effects in the NIR range has been developed,leading to enhanced light absorption in the active region and higher photocurrent generation.Additionally,∼7.9 nm of thin polyethyleneimine ethoxylated(PEIE)interlayers were incorporated into the Au NR photodetectors,suppressing dark current by blocking charge injection.As a result,the synergistic effect of the Au NR/PEIE hybrid layer has led to a high-performance photodetector with a responsivity of 0.360 A/W and a detectivity of 1.81×10^(10) Jones,demonstrating a noticeable enhancement compared to the control device.Finite-difference time-domain(FDTD)simulations,morphological characterizations,and photoluminescence studies further support the mechanism for enhancing the performance of the device.We believe that our plasmon-enhanced protocol holds strong potential as a promising platform for perovskite optoelectronic devices.
