Understanding the formation of lithium-rich pegmatites is critical for meeting global lithium demand.The 509 Daobanxi Li pegmatite deposit,located in the West Kunlun orogenic belt of northwestern China,represents a si...Understanding the formation of lithium-rich pegmatites is critical for meeting global lithium demand.The 509 Daobanxi Li pegmatite deposit,located in the West Kunlun orogenic belt of northwestern China,represents a significant example of an LCT-type(Li-Cs-Ta)pegmatite system.This study investigates the paragenetic sequence of lithium(Li)minerals and the factors controlling their crystallization,providing new insights into the magmatic-hydrothermal evolution of rare-element pegmatites.Pegmatite dikes exhibit distinct zonation,comprising a wall rock zone,a border zone(aplitic layer),and a core zone(pegmatitic layer),with Li mineralization concentrated in the pegmatitic and aplitic layers.The primary Li minerals include spodumene(Spd),montebrasite(Mbs),eucryptite(Ecr),elbaite(Elb),and lepidolite(Lpd),which crystallize in the order of spodumene→montebrasite→elbaite→lepidolite.Spodumene,the dominant Li-bearing mineral,crystallizes from a Li-saturated melt during the magmatic stage.Montebrasite,a Li-phosphate mineral,forms in P-rich environments,coexisting with spodumene and columbite-group minerals(CGM).During the magmatic-hydrothermal transition,elbaite crystallizes from a B-rich melt,exhibiting skeletal and patchy zoning due to undercooling and disequilibrium crystallization.Hydrothermal alteration leads to the breakdown of spodumene and the formation of secondary minerals such as eucryptite and lepidolite,with lepidolite being the final Li-bearing phase,enriched in fluorine.The coupled dissolution-precipitation processes during the magmatic-hydrothermal transition play a critical role in the remobilization and enrichment of rare elements such as Li,Nb,Ta,and Sn.This deposit,characterized by spodumene crystallization in the Spd+Quartz stability field(≥300 MPa,≤725℃)and subsequent alteration to Ecr+quartz assemblages(<270℃,<160 MPa),exhibits broader temperature-pressure conditions exceeding typical global pegmatites like Tanco,with no petalite formation observed due to its persistent exclusion from petalite stability fields throughout mineralization.The shear zone controls the pegmatite emplacement and lithium enrichment in the 509 Daobanxi lithium deposit,and its deformation-fluid coupling mechanism provides new insights for the exploration of LCT pegmatite deposits.The present study highlights the importance of understanding both magmatic and hydrothermal processes in the formation of LCT-type pegmatites and provides valuable insights for the exploration of critical metal resources in similar geological settings.展开更多
The Duanfengshan deposit is a newly discovered large pegmatitic-type Nb-Ta deposit in the central section of the Jiangnan orogenic belt,South China.There are three types of pegmatite in the Duanfengshan area:microclin...The Duanfengshan deposit is a newly discovered large pegmatitic-type Nb-Ta deposit in the central section of the Jiangnan orogenic belt,South China.There are three types of pegmatite in the Duanfengshan area:microcline pegmatite,microcline-albite pegmatite and albite pegmatite.Although several geological,geochronological and geochemical studies of this deposit have been carried out,the relationships between the evolution degree of different types of pegmatites and mineralization are still unclear.We address this problem through systematic petrographic and geochemical studies of muscovite and feldspars from two representative pegmatite veins,the No.328 microcline-albite pegmatite vein,and the No.610 albite pegmatite vein.The results of electron probe microanalysis(EPMA)and laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS)analyses of muscovite and K-feldspar reveal that K/Rb ratios decrease with increasing Rb,Cs,Ga,Nb and Ta contents alongside decreasing Ba and Sr contents,suggesting that magmatic differentiation played a dominant role in rare metal mineralization.A comparison of the analytical results of this study with those from rare metal pegmatites globally suggests that the No.610 vein has a high mineralization potential,whereas the No.328 vein has relatively low mineralization potential.The results from this study may be applied to the evaluation of mineralization potential for other pegmatite veins in the Duanfengshan area and other rare metal pegmatite fields with similar geological settings.展开更多
The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masse...The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masses,pockets and/or veins of very coarse-grained pegmatites,which consist mainly of K-feldspar,quartz and albite with subordinate muscovite,garnet,and biotite.Radiometric data revealed that e U-and e Th-contents of the pegmatites reach up to 39 ppm and 82 ppm,respectively.The studied pegmatites are enriched in primary U and Th minerals(uraninite,coffinite,thorianite and uranothorite)as well as Hf-rich zircon and monazite,which give rise to anomalous radioactive zones.Niobium-tantalium-bearing minerals(i.e.ferrocolumbite,microlite and uranopyrochlore),xenotime,barite,galena,fluorite,and apatite are ubiquitous,and,consequently,the studied pegmatites belong tothe Niobium-Yttrium-Fluorine-type(NYF)family.The noble metal mineralization includes argentite(Ag_(2)S),native Ni and Bi as well as bismite and bismoclite.In addition,beryl and tourmaline are observed in pegmatites near the contact with metasediments and ultramafic bodies.The observed compositional variations of Ta/(Ta+Nb)and Mn/(Mn+Fe)ratios in columbite(0.08-0.45 and 0.11-0.57,respectively)and Hf contents in zircon(3.54-6.46 wt%)may reflectan extreme degree of magmatic fractionation leading to formation of the pegmatite orebody.展开更多
The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously cont...The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously controlled by the fold system.There exists apparent in jectionrelationship between the pegmatites and the surrounding Sinian schist and granulitite.The granitoidsextensively distributed in the field belong either to the Variscan or to the Yenshanian cycle,and it is evidentthat the pegmatites are genetically related to Variscan migmatitic granites. The pegmatites can be grouped into four types:muscovite-orthoclase-albite pegmatite（I）.muscovitedlbite-orthoclase pegmatite（Ⅱ）,muscovite-orthoclase-albite pegmatite（Ⅲ）,and muscovite-albitespodumene pegmatite（IV）.Owing to strong metasomatism and multi-stage emplacement of pegmatitic meltsolution,the sequence of interior assemblage zones in the pegmatites does not always represent the sequenceof original crystallization. The mineral composition of the pegmatites is extremely complicated.81 kinds of minerals have so farbeen found、From type I to type IV,the mineral assemblage tend to get increasingly complex.together withthe synchronous intensification of rare-metal and Sn mineralizations.Most of the type-IV pegmatites are ofeconomic value The features of fluid inclusions in the minerals are significantly different not only in different typos ofpegmatite,but also in different parts of a single pegmatite vein.Theδ18O values of migmatitic granite andpegmatites are comparatively low（9.3-10.4‰）,and those of rock-forming fluids are higher than 9.5‰ Isotopic ages of the pegmatites brangs from 235 to 328 Ma with initial 87Sr/86Sr ratios being ”.715-0.746. According to the temporal and spatial relationships between the pegmatites and the migmatitic granitecombined with the features of the pegmatites themselves,it can be concluded that the Xikeng pegmatites arethe product of differentiation closely related to the migmatitic granite.展开更多
Excellent outcrops in Matale Sri Lanka provide unique insight into the emplacement and evolution history of hydrothermal and pegmatitic rocks in the central highlands of Sri Lanka. Field, structural, petrological, the...Excellent outcrops in Matale Sri Lanka provide unique insight into the emplacement and evolution history of hydrothermal and pegmatitic rocks in the central highlands of Sri Lanka. Field, structural, petrological, thermo-barometric studies in the metamorphic basement rocks in the central highlands and related hydrothermal deposits are presented in this study. Detailed petrographic and mineralogical data reveal peak metamorphic conditions for the crustal unit in the study area as 854 ± 44oC at 10.83 ± 0.86 kbar. Hydrothermal veins consisting of quartz and mica are closely related to cross-cutting pegmatites, which significantly post-date the peak metamorphic conditions of the crustal unit. Field relations indicate that the veins originated as ductile-brittle fractures have subsequently sealed by pegmatites and hydrothermal crystallization. Geological, textural and mineralogical data suggest that most enriched hydrothermal veins have evolved from a fractionated granitic melt progressively enriched in H2O, F, etc. Quartz, K-feldspar, mica, tourmaline, fluorite and topaz bear evidence of multistage crystallization that alternated with episodes of resorption. It was suggested that the level of emplacement of pegmatites of the Matale District was middle crust, near the crustal scale brittle-ductile transition zone at a temperature of about 600oC. For this crustal level and temperature range, it is considered very unlikely that intruding pegmatitic melts followed pre-existing cracks. As such the emplacement temperatures of the pegmatites could be well below the peak metamorphic estimates in the mafic granulites. The metamorphic P-T strategy and position of formation of hydrothermal deposits and pegmatites is summarized in the modified P-T-t-D diagrams.展开更多
The study was carried out to determine the rare metal mineralization potential of some pegmatites associated with metasediments in the Igangan 240 NW sheet. Geological mapping on a scale of 1:50,000 revealed the pegma...The study was carried out to determine the rare metal mineralization potential of some pegmatites associated with metasediments in the Igangan 240 NW sheet. Geological mapping on a scale of 1:50,000 revealed the pegmatites intrude metasediments and geochemical analysis for major, trace and rare earth elements were carried out using ICP MS/AES. Petrographic studies reveal a mineral assemblage of quartz, microcline and tourmaline;SEM studies revealed garnet and tourmaline to be close to the spessartine end-member and schorl respectively with albite occurring as the dominant plagioclase feldspar in the pegmatites. Result of geochemical analysis revealed SiO2 with an average of 73.91% in the whole rock pegmatite Al2O3 with an average of 13.93%, and average concentration of 0.57%, 4.3% and 4.77% for CaO, Na2O and K2O respectively. It also revealed average concentration of 29 ppm, 153 ppm, 30 ppm, 118 ppm and 129 ppm for W, Li, Ta, Nb and Sn in the mica respectively which is above the average values in the whole rock, felspars and tourmaline extracts. REE abundance in the whole rock pegmatites is low to moderate with ∑REE varying between 8 - 220 ppm, 2 - 23 ppm in feldspars and 3 - 32 ppm in mica signifying no form of REE enrichment. Geochemical analysis results and trace elemental plots such as K/Rb vs. Rb, Ta vs. Ga, Ta vs. Cs were used to assess rare metal mineralization and it revealed the pegmatites have low level of rare metal and rare earth element mineralization with average k/Rb values of 177 indicative of low fractionation levels in the pegmatites.展开更多
The aim of this work was to study the petrography, geochemistry of the pegmatites, their relationship to the mineralisation in Gitarama and Gatumba areas, and current processes that occurred after the primary emplaced...The aim of this work was to study the petrography, geochemistry of the pegmatites, their relationship to the mineralisation in Gitarama and Gatumba areas, and current processes that occurred after the primary emplaced neoproterozoic rare element pegmatites. Previous works on pegmatites were geochemistry and geological maps which are not enough for focused exploration and mine planning. Therefore, geological, petrographic, geochemical studies of neoproterozoic rare element pegmatites of Gatumba and Gitarama areas in relation to their mineralisation were carried out. The samples were analysed for mineral assemblages by petrographic light microscope;major elements by ICP AES;trace and rare earth elements by ICP MS. Petrographic studies revealed the mineral assemblages included quartz, microcline, biotite and major muscovites, which implied that there was the process of muscovitisation occurred after the primary emplacement of pegmatites. The results of geochemical analysis revealed that the silica content (in wt%) ranges from 59.5 - 80.5 with an average of 67.13 (in wt%) for the weathered pegmatite in Gatumba area ,and high percentages of SiO2 (in wt%) range 73.9 - 75.0 with an average of 73.15 (in wt%) for fresh pegmatite in Gitarama area. The pegmatites from Gatumba area were altered and much enriched in Rb (227 - 3460 ppm), Cs (2.59 - 24.7 ppm), Ta (2.6 - 268 ppm), Li (40 - 9224 ppm), W (240 - 10,000 ppm), Nb (13 - 517 ppm), Sn (24 - 8870 ppm). Their enrichment is commonly used as a marker of a magmatic-hydrothermal alteration. Conversely, the pegmatites from Gitarama area showed the low to moderate concentrations in Rb (321 - 337 ppm), Cs (5.47 - 5.62 ppm), Ta (1.3 - 1.6 ppm), Li (~20 ppm), W (5540 - 6410 ppm), Nb (3.9 - 4.3 ppm), Sn (28 - 44 ppm). The variation plot of ratios: Al2O3/(Na2O + K2O) versus Al2O3/(CaO + Na2O + K2O) for the pegmatites from study areas are higher than one (A/NK vs. A/CNK > 1) indicating peraluminous, the other samples of pegmatites indicated metaluminous (A/NK > 1 and A/CNK ΣREE varying between 12.1 - 72.78 ppm and 45 - 54.37 ppm respectively, signifying low to medium form of enrichment. The pegmatite from Gatumba and Gitarama areas showed the K/Rb ratios ranging from 15.74 to 80.26 and from 190.41 to 199.39 respectively. As the pegmatite samples show K/Rb ratios less than 100 are commonly accepted for mineralization, therefore the pegmatites from Gatumba area were found mineralised, conversely to the pegmatite samples from Gitarama area, which were found barren.展开更多
The Guanpo pegmatite field in the North Qinling orogenic belt(NQB),China,hosts the most abundant LCT pegmatites.However,their emplacement conditions and structural control remain unexplored.In this contribution,we inv...The Guanpo pegmatite field in the North Qinling orogenic belt(NQB),China,hosts the most abundant LCT pegmatites.However,their emplacement conditions and structural control remain unexplored.In this contribution,we investigated it combining pegmatite orientation measurement with oxygen isotope geothermometry and fluid inclusion study.The orientations of type A1 pegmatites(P_(f)<σ_(2))are predominantly influenced by P-and T-fractures due to simple shearing in Shiziping dextral thrust shear zone during D_(2)deformation,whereas type A2 pegmatites(contemporaneous with D_(4))are governed by hydraulic fractures aligned with S_(0)and S_(0+1)stemming from fluid pressure(P_(f)<σ_(2)).Additionally,type B pegmatites(P_(f)≤σ_(2))exhibit orientations shaped by en echelon extensional fractures in local ductile shear zones(contemporaneous with D_(3)).The albite-quartz oxygen isotope geothermometry and microthermometric analysis of fluid inclusions in elbaites from the latest pegmatites(including types B and A2)suggest that the crystallization P-T for late magmatic and hydrothermal stages are 527.5-559.2℃,320℃,3.1-3.6 kbar and 2.0 kbar,respectively.Our observations along with previous studies suggest that the genesis of the LCT pegmatites was a long-term,multi-stage event during early Paleozoic orogeny(including the collision stage)of the NQB,and was facilitated by various local fractures.展开更多
Lack of information regarding lithium(Li)crystal chemistry in numerous minerals,especially those containing trace amounts of Li(ranging from a few to tens of ppm),limits our understanding of Li isotopic fractionation ...Lack of information regarding lithium(Li)crystal chemistry in numerous minerals,especially those containing trace amounts of Li(ranging from a few to tens of ppm),limits our understanding of Li isotopic fractionation in pegmatites.In this study,we examined the Li isotopic composition and Li content in various Li-poor(e.g.,quartz or feldspar)together with Li-rich(sopdumene or lepidolite)mineral phases within granitic pegmatites.We compiled a comprehensive dataset,encompassing a broad spectrum of Li contents(ranging from a few to tens of thousands of ppm)and Li isotopic values(-8‰to 41‰).The minerals exhibit distinct Li isotopic signatures.Specifically,elbaite and beryl show the highest values,while biotite displays a negative average.Compared to individual minerals,whole rocks demonstrate lower Li isotopic values,with pegmatites exhibiting the highest and non-granitic pegmatite wall rocks showing the lowest.Our study also uncovers a clear“V”shape relationship between Li isotopic values and logarithm of Li contents,with different mineral groups occupying specific regions within this shape.Furthermore,a significant correlation was observed between average Li isotopic values and Li-O(OH,F)bond lengths in various minerals.These discoveries underscore the crucial role of crystal chemistry in shaping the Li isotopic behavior in pegmatites from a statistical perspective.展开更多
The Wadi Ibib area is situated in the northern part of the Neoproterozoic Hamisana Shear Zone(HSZ), which is a high strain zone evolved during the late stages of the Pan-African orogeny, likely as a tectonic escape st...The Wadi Ibib area is situated in the northern part of the Neoproterozoic Hamisana Shear Zone(HSZ), which is a high strain zone evolved during the late stages of the Pan-African orogeny, likely as a tectonic escape structure. Amphibolite facies pelitic metasedimentary windows crop out in the axial parts of the HSZ and are noticeably associated with numerous N-trending pegmatite dikes. Whole-rock geochemistry of the pegmatites reveals a peraluminous(S-type) affinity, with low K/Rb ratios and elevated concentrations of U, Th, REE, Rb, Li, Cs, Y, Nb and Ta. Structurally, the pegmatite sets intrude along the shear plane of the HSZ, corresponding to the regional N-trending tectonic fabrics, such as axial planar foliation and dextral-shearing in the metasedimentary host rock. Field relationships, including structural context, coupled with geochemical characteristics of the Wadi Ibib pegmatites, do not support their formation as a complementary part of evolved granitic magmas. Space-localized decompression-induced partial melting of peraluminous garnet-bearing metapelites was alternatively the underlying process for formation of these pegmatites. Such decompression was associated with regional escape tectonics and stress axes permutations during the late deformation stage(D3) in the evolution of the south Eastern Desert terrane, due to end-orogeny system pressure-release.展开更多
The P-Li-Nb pegmatites are located in the south of Brazil, in the states of Minas Gerais and Espirito Santos. They represent the largest pegmatite fields of Brazil and the richest in precious stones. Two types of pegm...The P-Li-Nb pegmatites are located in the south of Brazil, in the states of Minas Gerais and Espirito Santos. They represent the largest pegmatite fields of Brazil and the richest in precious stones. Two types of pegmatites are characterized by their mineralogical characteristics and tectonic and magmatic relations. The first group occurred during a compressive deformation phase D1 about 582 Ma and 550℃ - 700℃ and 4 - 5 kb. The second pegmatites group was formed during the decompression phase D2 (520 - 500 Ma) of the Brasiliano metamorphic rock fusion. The geochemical parameters of the P-Li-Be bearing pegmatites of the first group show the same trend fractionation, as suggested by the mineralogical composition. The variation of tourmaline and columbite-tantalite composition of the first group game again applies a change of melt composition during the regional development of the pegmatites. A systematic compositional trend seems to suggest a petrogenetic link between the pegmatites of the region. The Fe/Mn ratio of tourmaline in samples of the first group shows the same behavior as in columbite-tantalite and garnets. The simple pegmatites are transiting north in the gem-rich pegmatites. The Fe/Mn ratio not only shows qualitatively the fractionation index, the degree of regional development, but also the internal development of the body. The ratio shows a negative correlation with lithium. The Co, Zn and Nb contents are rising at first group, but falling when starting crystallization of garnet, columbite-tantalite, and Behierit.展开更多
The lithium potential in the Aïr massif is represented by mineral index of spodumene pegmatites and, lepidolite pegmatites. The mineral deposits of lithium occur in cluster or veins that cut the host rock or are ...The lithium potential in the Aïr massif is represented by mineral index of spodumene pegmatites and, lepidolite pegmatites. The mineral deposits of lithium occur in cluster or veins that cut the host rock or are located near the contact between the greenstone belt and granitic massif. The evidence of lithium is in the form of clusters or disseminated and stockwerk. Mineralogical characteristics show similarities between the Air Massif pegmatites and indicate the same homogenous source during the magma-generation process. The pegmatite rocks attracted the attention due to their wide exposure and composition, well appearance, and economically hosting of significant rare earth metals such as Sn and W. The mineralogical and petrographical investigations on the eight pegmatites rocks samples observed have a relative similarity, while a little difference in the shapes attributed to the ratio in the pegmatite rocks of the minerals. The occurrence of the kink band indicates the influence of the tectonic processes which affected the Aïr massif after the emplacement of late magmatic or post-magmatic pegmatites by injection into fractured rocks in the upper part of the crust. The Air Massif pegmatite has higher concentrations Li and of all trace elements except Hf and occasionally Zr, Ti, Sn and Mg of for the economic exploration.展开更多
THE crystalline-fluid melt inclusions in aquamarines in pegmatites from Mufushan (Hunan Prov.) andAilaoshan (Yunnan Prov.) have been studied. The research shows that there are obvious differences inthe chemical compos...THE crystalline-fluid melt inclusions in aquamarines in pegmatites from Mufushan (Hunan Prov.) andAilaoshan (Yunnan Prov.) have been studied. The research shows that there are obvious differences inthe chemical composition of the inclusions in the aquamarines, which is of great importance for studyingthe forming mechanism and origin of pegmatites. 1 General geology of pegmatites Mufushan is situated in the middle sector of the Jiangnan Ancient Land. The granitic pegmatitesmainly outcrop in granite mass of late Yanshanian (105-145 Ma) which was intruded in middle sector ofthe middle Proterozoic strata. Part of the pegmatites occur in the contact zone of the granite and the metamorphic rocks. The pegmatite veins may be divided into four types, all of them were originated from mag-展开更多
0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization i...0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization in peraluminous pegmatites.展开更多
Leucogranite,pegmatite,and aplite from selected areas in the Wadi El Gemal area in the southern Eastern Desert of Egypt were investigated geochemically for their petrogenesis.These rocks represent a significant episod...Leucogranite,pegmatite,and aplite from selected areas in the Wadi El Gemal area in the southern Eastern Desert of Egypt were investigated geochemically for their petrogenesis.These rocks represent a significant episode of felsic magmatism during the late stage of the Pan-African orogeny in the evolution of the Arabian–Nubian Shield(ANS)during the Late Neoproterozoic.On a petrographic basis,the leucogranite is sometimes garnetiferous and can be distinguished into monzogranite,syenogranite,and alkali feldspar granite.The analyses of muscovite,biotite,garnet,and apatite reveal the magmatic nature of the studied leucogranite.The investigated leucogranite,pegmatite,and aplite are alkali-calcic,calc-alkaline,and peraluminous.The peraluminous nature of these rocks is evidenced by using the chemical analyses of biotite.These studied rocks show a slight enrichment in light rare-earth elements(LREEs)and large-ion lithophile elements(LILE,especially Rb and Th),with an insignificant depletion of heavy rareearth elements(HREEs).On a geochemical basis,the leucogranite,pegmatite,and aplite in the study area crystallized from multiple-sourced melts that include mafic,metagraywake,and pelitic.They were derived from melts generated at crystallization temperatures around 568-900℃ for leucogranite,553-781℃ for pegmatite,and 639-779℃ for aplite based on the Zr saturation geothermometers,and at a pressure around 0.39-0.48 GPa,i.e.shallow depth intrusions.The studied felsic rocks have strong negative Eu anomalies,which are very consistent with an upper crust composition,indicating fractionation of feldspar cumulates.Also,they show a moderate La/Sm ratio indicating combined magmatic processes represented by partial melting and fractional crystallization.Integration of whole-rock chemical composition and mineral microanalysis suggests that felsic magmatism in the west Wadi El Gemal area produced voluminous masses of syn-to post-collisional granite,pegmatite,and aplite.An evolutionary three-stage model is presented to understand late magmatism in the ANS in terms of a geodynamic model.Such a model discusses the propagation of felsic magmatism in the ANS during syn-collisional to post-collisional stages.展开更多
Lithium is a critical strategic metal with signifi-cant reserves in pegmatites,serving as the primary source for global Li production.Apatite has attracted increasing attention as an indicator in petrogenesis studies ...Lithium is a critical strategic metal with signifi-cant reserves in pegmatites,serving as the primary source for global Li production.Apatite has attracted increasing attention as an indicator in petrogenesis studies and for the exploration of ore deposits.In this study,we investigated the volatile compositions and major and trace elements of apatite from the Qiongjiagang pegmatite-type lithium deposit in Himalaya.Apatite derived from spodumene pegmatite exhibits relatively constant and high total rare earth element(ΣREE+Y)concentrations,ranging from 5899 to 8540 ppm.In contrast,apatite in barren pegmatite displays evidently lower(ΣREE+Y)concentrations,varying between 1345 and 3095 ppm.The REE patterns of apatite in spodumene pegmatite generally exhibit a flat shape[(La/Yb)N=1.55-2.15)],with distinctively negative Eu anomalies(Eu_(N)/Eu_(N)^(*)=0.14-0.22),slightly positive Ce anomalies(Ce_(N)/Ce_(N)^(*)=1.03-1.13),and low Y/Ho ratios(28-30).By contrast,apatite in barren pegmatite shows middle rare earth element(MREE)-depleted downward-convex patterns[(La/Yb)N=1.99-20.4)],strongly negative Eu anomalies(Eu_(N)/Eu_(N)^(*)=0.01-0.14),slightly positive Ce anomalies(Ce_(N)/Ce_(N)^(*)=1.10-1.24),and high Y/Ho ratios(30-55,with an average of 50).Overall,the high concentrations ofΣREE(and Y)and low Th/U and Y/Ho ratios can serve as diagnostic indicators to distinguish apatite in spodumene pegmatite from that in barren pegmatite.Furthermore,the flat REE pattern may represent a common feature of apatite from lithium deposits.Differences in the Ce and Eu anomalies between apatite from these two kinds of pegmatites likely reflect formation under different redox conditions.Consequently,based on calculations derived from apatite volatile compositions,the melt associated with spodumene pegmatite may contain higher water content compared to that of the barren one.Therefore,the mineralized pegmatite system may incorporate substantial amounts of H_(2)O-rich fluids,which play a crucial role in lithium mineralization.展开更多
The Gabo lithium deposit represents a newly discovered pegmatite-type lithium deposit within the Himalayan metallogenic belt.The tourmaline-muscovite granite,the largest leucogranite in the mining area,displays a clos...The Gabo lithium deposit represents a newly discovered pegmatite-type lithium deposit within the Himalayan metallogenic belt.The tourmaline-muscovite granite,the largest leucogranite in the mining area,displays a close spatial correlation with the Li-pegmatite veins.This study aims to examine the genesis of tourmaline and evaluate the significance and potential of pegmatite lithium deposits.Tourmaline is extensively distributed in tourmaline-muscovite granite at Gabo deposit in Luozha county(Xizang).Investigation of the compositional and in situ boron isotopes of the tourmaline revealed that the tourmalines mainly belong to the schorl group and exhibit uniform elevated Li-Sn contents andδ^(11)B values(-11.6‰to-10.5‰).This indicates that the tourmaline mainly crystallized from a boron-rich granitic magma undergoing enrichment in elemental lithium during the tourmaline crystallization process.Compared with the principal rare metal leucogranite-pegmatites in the Himalayan orogen,it is proposed that the elevated lithium(Li)content of tourmaline serves as an eff ective mineral indicator for the highly evolved pegmatite-type rare metal deposits.展开更多
Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rar...Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rare metal enrichment remain poorly understood.The Late Jurassic Shihuiyao Nb-Ta-(Rb-Be-Li)deposit is one of the largest rare-metal deposits in the Southern Great Xing’an Range(SGXR),Northeast China.Exploratory trenches expose distinct layered zones from top to bottom:alternating microcline pegmatite and aplite layers(zone I),topaz lepidolite albite granite and lepidolite amazonite pegmatite(zone II),and muscovite albite granite(zoneⅢ).We conducted U-Pb dating of cassiterite,monazite,and Nb-Ta oxide,monazite Nd isotopes,and whole-rock and mineral geochemistry for the three zones.Multi-mineral U-Pb ages indicate that the three zones formed during the Late Jurassic-Early Cretaceous(147-142 Ma).Geochemical analyses of whole-rock,mica,and microcline suggest an evolutionary sequence from zone I to zoneⅢ,and finally to zone II.The Zr/Hf,Nb/Ta,Y/Ho,and K/Rb ratios combined with the rare earth element(REE)tetrad effects suggest higher degree of differentiation and fluid-melt interaction of the Shihuiyao leucogranite without a pegmatite shell compared to coeval barren granites from both Shihuiyao and the SGXR.A progressive increase in the degree of evolution is evident from the leucogranite without a pegmatite shell to the leucogranite with a discontinuous shell,and ultimately to the leucogranite with a continuous shell.The pegmatite shell acted as a geochemical barrier that facilitated the accumulation of Li and F in the underlying magma,which played a crucial role in lowering the solidus temperature of the granitic magma.This process prolonged the crystallization duration while reducing melt viscosity and density,thereby creating favorable conditions for magma differentiation and fluid-melt interaction.Rapid crystallization of the earlier water-and Be-rich melt led to the Be mineralization in the pegmatite shell.Moreover,the formation of this shell served as a barrier for Li mineralization in the underlying topaz lepidolite albite granite.This study enhances our understanding of the critical contribution of pegmatite shells to magmatic evolution and rare-metal mineralization.展开更多
Biotite content critically influences rock mechanical behavior and threatens underground engineering stability.Uniaxial compression tests with acoustic emission(AE)monitoring were conducted on granite pegmatite sample...Biotite content critically influences rock mechanical behavior and threatens underground engineering stability.Uniaxial compression tests with acoustic emission(AE)monitoring were conducted on granite pegmatite samples having varying biotite content.Peak frequency distribution analysis,rise angleaverage frequency(RA-AF)analysis,multifractal theory,and a dynamic multifractal algorithm were applied to explore the relationship between damage evolution and AE characteristics.Results indicate that increased biotite content reduces uniaxial compressive strength and elastic modulus,enhances plastic deformation,and increases the proportion of shear cracks.The segmented evolution of the dynamic multifractal parameter Δα_(m) is biotite-dependent.Oscillations during the elastic phase signify localized shear crack initiation and propagation;their attenuation in the plastic phase reflects frictional closure along biotite cleavage planes,promoting elastic energy storage and delaying release.AE-based damage models and time-varying signals characterize rock damage progression.Stress concentrations around biotite minerals foster localized shear band formation,leading to concentrated shear failure at lower damage levels.Higher biotite content accelerates crack propagation,while smooth cleavage planes lower the fracture energy threshold,reducing strength and stiffness.These findings enhance understanding of biotite-influenced progressive rock damage and underpin stability monitoring and early-warning systems for underground engineering.展开更多
The middle-scale Heima zinnwaldite deposit is situated in the southeastern Tibetan Plateau,SW China.The NNW-to NS-trending orebodies are hosted in the Gaoligongshan metamorphic zone.To clarify the zinnwaldite genesis ...The middle-scale Heima zinnwaldite deposit is situated in the southeastern Tibetan Plateau,SW China.The NNW-to NS-trending orebodies are hosted in the Gaoligongshan metamorphic zone.To clarify the zinnwaldite genesis at Heima,this study presents an integrated investigation of the Heima pegmatites,combining precise geochronology,isotopic tracing,and detailed mineral chemistry to constrain its formation age,petrogenetic origin,and mineralization processes.Our robust geochronological framework,employing magmatic zircon(56.93±0.53 Ma)and cassiterite(57.0±4.2 Ma),establishes the pegmatite emplacement during the Late Paleocene to Early Eocene,representing the maximum age of lithium mineralization.Hf isotopic compositions(εHf_((t))=−14.3 to−12.4)demonstrate that the Heima pegmatite originated from remelting of ancient sediments,distinguishing it from contemporaneous Eocene Gangdese-Tengchong granites(εHf_((t))=−12.7 to+11.0)that show mantle contributions.This crustal signature aligns with the evolutionary trend of Hf isotopes in regional gneissic granites(600−420 Ma),supporting an anatectic origin from ancient continental crust rather than being derivatives of nearby Eocene granitic plutons.Detailed geochemical analysis of Li-micas reveals two distinct generations with contrasting formation mechanisms.The primary mica-Ia(53.45±0.86 Ma,Rb-Sr age)exhibits extreme incompatible element enrichment(Li,Be,Rb,Cs)and remarkably low K/Rb ratios(3.98-4.37),characteristic of crystallization from highly fractionated granitic melts.In contrast,secondary mica-Ib and mica-Ⅱ(17.9-16.0 Ma,Rb-Sr age)show significant Nb-Ta-W enrichment,reflecting precipitation from F-P-rich hydrothermal fluids during Miocene metamorphic-hydrothermal events.Principal component analysis(PCA)confirms the compositional disparity between these mica generations,with the later phases attributed to fluid-induced alteration and reworking.Regional correlation identifies two distinct lithium mineralization episodes in the Gongshan area,southeast Tibetan Plateau.The Eocene phase(~55 Ma)is zinnwaldite-dominant(e.g.,Heima,Puladi),associated with crustal melting following Neo-Tethyan closure.The Miocene phase(~17 Ma)is spodumene-dominant(e.g.,Danzhu,Peili),linked to Himalayan leucogranites formed as the rapid exhumation,denudation,and decompression partial melting of Himalayan Crystalline Complex.展开更多
基金supported by the National Natural Science Foundation of China(Nos.42250202,92162323,42272075)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.24lgqb01).
文摘Understanding the formation of lithium-rich pegmatites is critical for meeting global lithium demand.The 509 Daobanxi Li pegmatite deposit,located in the West Kunlun orogenic belt of northwestern China,represents a significant example of an LCT-type(Li-Cs-Ta)pegmatite system.This study investigates the paragenetic sequence of lithium(Li)minerals and the factors controlling their crystallization,providing new insights into the magmatic-hydrothermal evolution of rare-element pegmatites.Pegmatite dikes exhibit distinct zonation,comprising a wall rock zone,a border zone(aplitic layer),and a core zone(pegmatitic layer),with Li mineralization concentrated in the pegmatitic and aplitic layers.The primary Li minerals include spodumene(Spd),montebrasite(Mbs),eucryptite(Ecr),elbaite(Elb),and lepidolite(Lpd),which crystallize in the order of spodumene→montebrasite→elbaite→lepidolite.Spodumene,the dominant Li-bearing mineral,crystallizes from a Li-saturated melt during the magmatic stage.Montebrasite,a Li-phosphate mineral,forms in P-rich environments,coexisting with spodumene and columbite-group minerals(CGM).During the magmatic-hydrothermal transition,elbaite crystallizes from a B-rich melt,exhibiting skeletal and patchy zoning due to undercooling and disequilibrium crystallization.Hydrothermal alteration leads to the breakdown of spodumene and the formation of secondary minerals such as eucryptite and lepidolite,with lepidolite being the final Li-bearing phase,enriched in fluorine.The coupled dissolution-precipitation processes during the magmatic-hydrothermal transition play a critical role in the remobilization and enrichment of rare elements such as Li,Nb,Ta,and Sn.This deposit,characterized by spodumene crystallization in the Spd+Quartz stability field(≥300 MPa,≤725℃)and subsequent alteration to Ecr+quartz assemblages(<270℃,<160 MPa),exhibits broader temperature-pressure conditions exceeding typical global pegmatites like Tanco,with no petalite formation observed due to its persistent exclusion from petalite stability fields throughout mineralization.The shear zone controls the pegmatite emplacement and lithium enrichment in the 509 Daobanxi lithium deposit,and its deformation-fluid coupling mechanism provides new insights for the exploration of LCT pegmatite deposits.The present study highlights the importance of understanding both magmatic and hydrothermal processes in the formation of LCT-type pegmatites and provides valuable insights for the exploration of critical metal resources in similar geological settings.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.42102110,U2444204,42472111 and U2344220).
文摘The Duanfengshan deposit is a newly discovered large pegmatitic-type Nb-Ta deposit in the central section of the Jiangnan orogenic belt,South China.There are three types of pegmatite in the Duanfengshan area:microcline pegmatite,microcline-albite pegmatite and albite pegmatite.Although several geological,geochronological and geochemical studies of this deposit have been carried out,the relationships between the evolution degree of different types of pegmatites and mineralization are still unclear.We address this problem through systematic petrographic and geochemical studies of muscovite and feldspars from two representative pegmatite veins,the No.328 microcline-albite pegmatite vein,and the No.610 albite pegmatite vein.The results of electron probe microanalysis(EPMA)and laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS)analyses of muscovite and K-feldspar reveal that K/Rb ratios decrease with increasing Rb,Cs,Ga,Nb and Ta contents alongside decreasing Ba and Sr contents,suggesting that magmatic differentiation played a dominant role in rare metal mineralization.A comparison of the analytical results of this study with those from rare metal pegmatites globally suggests that the No.610 vein has a high mineralization potential,whereas the No.328 vein has relatively low mineralization potential.The results from this study may be applied to the evaluation of mineralization potential for other pegmatite veins in the Duanfengshan area and other rare metal pegmatite fields with similar geological settings.
文摘The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masses,pockets and/or veins of very coarse-grained pegmatites,which consist mainly of K-feldspar,quartz and albite with subordinate muscovite,garnet,and biotite.Radiometric data revealed that e U-and e Th-contents of the pegmatites reach up to 39 ppm and 82 ppm,respectively.The studied pegmatites are enriched in primary U and Th minerals(uraninite,coffinite,thorianite and uranothorite)as well as Hf-rich zircon and monazite,which give rise to anomalous radioactive zones.Niobium-tantalium-bearing minerals(i.e.ferrocolumbite,microlite and uranopyrochlore),xenotime,barite,galena,fluorite,and apatite are ubiquitous,and,consequently,the studied pegmatites belong tothe Niobium-Yttrium-Fluorine-type(NYF)family.The noble metal mineralization includes argentite(Ag_(2)S),native Ni and Bi as well as bismite and bismoclite.In addition,beryl and tourmaline are observed in pegmatites near the contact with metasediments and ultramafic bodies.The observed compositional variations of Ta/(Ta+Nb)and Mn/(Mn+Fe)ratios in columbite(0.08-0.45 and 0.11-0.57,respectively)and Hf contents in zircon(3.54-6.46 wt%)may reflectan extreme degree of magmatic fractionation leading to formation of the pegmatite orebody.
文摘The Xikeng pegmatite field lies on the eastern margin of the south China fold system in Fujian Province,and it is located at the junction of three major tectonic units. The distribution of pegmatites is obviously controlled by the fold system.There exists apparent in jectionrelationship between the pegmatites and the surrounding Sinian schist and granulitite.The granitoidsextensively distributed in the field belong either to the Variscan or to the Yenshanian cycle,and it is evidentthat the pegmatites are genetically related to Variscan migmatitic granites. The pegmatites can be grouped into four types:muscovite-orthoclase-albite pegmatite（I）.muscovitedlbite-orthoclase pegmatite（Ⅱ）,muscovite-orthoclase-albite pegmatite（Ⅲ）,and muscovite-albitespodumene pegmatite（IV）.Owing to strong metasomatism and multi-stage emplacement of pegmatitic meltsolution,the sequence of interior assemblage zones in the pegmatites does not always represent the sequenceof original crystallization. The mineral composition of the pegmatites is extremely complicated.81 kinds of minerals have so farbeen found、From type I to type IV,the mineral assemblage tend to get increasingly complex.together withthe synchronous intensification of rare-metal and Sn mineralizations.Most of the type-IV pegmatites are ofeconomic value The features of fluid inclusions in the minerals are significantly different not only in different typos ofpegmatite,but also in different parts of a single pegmatite vein.Theδ18O values of migmatitic granite andpegmatites are comparatively low（9.3-10.4‰）,and those of rock-forming fluids are higher than 9.5‰ Isotopic ages of the pegmatites brangs from 235 to 328 Ma with initial 87Sr/86Sr ratios being ”.715-0.746. According to the temporal and spatial relationships between the pegmatites and the migmatitic granitecombined with the features of the pegmatites themselves,it can be concluded that the Xikeng pegmatites arethe product of differentiation closely related to the migmatitic granite.
文摘Excellent outcrops in Matale Sri Lanka provide unique insight into the emplacement and evolution history of hydrothermal and pegmatitic rocks in the central highlands of Sri Lanka. Field, structural, petrological, thermo-barometric studies in the metamorphic basement rocks in the central highlands and related hydrothermal deposits are presented in this study. Detailed petrographic and mineralogical data reveal peak metamorphic conditions for the crustal unit in the study area as 854 ± 44oC at 10.83 ± 0.86 kbar. Hydrothermal veins consisting of quartz and mica are closely related to cross-cutting pegmatites, which significantly post-date the peak metamorphic conditions of the crustal unit. Field relations indicate that the veins originated as ductile-brittle fractures have subsequently sealed by pegmatites and hydrothermal crystallization. Geological, textural and mineralogical data suggest that most enriched hydrothermal veins have evolved from a fractionated granitic melt progressively enriched in H2O, F, etc. Quartz, K-feldspar, mica, tourmaline, fluorite and topaz bear evidence of multistage crystallization that alternated with episodes of resorption. It was suggested that the level of emplacement of pegmatites of the Matale District was middle crust, near the crustal scale brittle-ductile transition zone at a temperature of about 600oC. For this crustal level and temperature range, it is considered very unlikely that intruding pegmatitic melts followed pre-existing cracks. As such the emplacement temperatures of the pegmatites could be well below the peak metamorphic estimates in the mafic granulites. The metamorphic P-T strategy and position of formation of hydrothermal deposits and pegmatites is summarized in the modified P-T-t-D diagrams.
文摘The study was carried out to determine the rare metal mineralization potential of some pegmatites associated with metasediments in the Igangan 240 NW sheet. Geological mapping on a scale of 1:50,000 revealed the pegmatites intrude metasediments and geochemical analysis for major, trace and rare earth elements were carried out using ICP MS/AES. Petrographic studies reveal a mineral assemblage of quartz, microcline and tourmaline;SEM studies revealed garnet and tourmaline to be close to the spessartine end-member and schorl respectively with albite occurring as the dominant plagioclase feldspar in the pegmatites. Result of geochemical analysis revealed SiO2 with an average of 73.91% in the whole rock pegmatite Al2O3 with an average of 13.93%, and average concentration of 0.57%, 4.3% and 4.77% for CaO, Na2O and K2O respectively. It also revealed average concentration of 29 ppm, 153 ppm, 30 ppm, 118 ppm and 129 ppm for W, Li, Ta, Nb and Sn in the mica respectively which is above the average values in the whole rock, felspars and tourmaline extracts. REE abundance in the whole rock pegmatites is low to moderate with ∑REE varying between 8 - 220 ppm, 2 - 23 ppm in feldspars and 3 - 32 ppm in mica signifying no form of REE enrichment. Geochemical analysis results and trace elemental plots such as K/Rb vs. Rb, Ta vs. Ga, Ta vs. Cs were used to assess rare metal mineralization and it revealed the pegmatites have low level of rare metal and rare earth element mineralization with average k/Rb values of 177 indicative of low fractionation levels in the pegmatites.
文摘The aim of this work was to study the petrography, geochemistry of the pegmatites, their relationship to the mineralisation in Gitarama and Gatumba areas, and current processes that occurred after the primary emplaced neoproterozoic rare element pegmatites. Previous works on pegmatites were geochemistry and geological maps which are not enough for focused exploration and mine planning. Therefore, geological, petrographic, geochemical studies of neoproterozoic rare element pegmatites of Gatumba and Gitarama areas in relation to their mineralisation were carried out. The samples were analysed for mineral assemblages by petrographic light microscope;major elements by ICP AES;trace and rare earth elements by ICP MS. Petrographic studies revealed the mineral assemblages included quartz, microcline, biotite and major muscovites, which implied that there was the process of muscovitisation occurred after the primary emplacement of pegmatites. The results of geochemical analysis revealed that the silica content (in wt%) ranges from 59.5 - 80.5 with an average of 67.13 (in wt%) for the weathered pegmatite in Gatumba area ,and high percentages of SiO2 (in wt%) range 73.9 - 75.0 with an average of 73.15 (in wt%) for fresh pegmatite in Gitarama area. The pegmatites from Gatumba area were altered and much enriched in Rb (227 - 3460 ppm), Cs (2.59 - 24.7 ppm), Ta (2.6 - 268 ppm), Li (40 - 9224 ppm), W (240 - 10,000 ppm), Nb (13 - 517 ppm), Sn (24 - 8870 ppm). Their enrichment is commonly used as a marker of a magmatic-hydrothermal alteration. Conversely, the pegmatites from Gitarama area showed the low to moderate concentrations in Rb (321 - 337 ppm), Cs (5.47 - 5.62 ppm), Ta (1.3 - 1.6 ppm), Li (~20 ppm), W (5540 - 6410 ppm), Nb (3.9 - 4.3 ppm), Sn (28 - 44 ppm). The variation plot of ratios: Al2O3/(Na2O + K2O) versus Al2O3/(CaO + Na2O + K2O) for the pegmatites from study areas are higher than one (A/NK vs. A/CNK > 1) indicating peraluminous, the other samples of pegmatites indicated metaluminous (A/NK > 1 and A/CNK ΣREE varying between 12.1 - 72.78 ppm and 45 - 54.37 ppm respectively, signifying low to medium form of enrichment. The pegmatite from Gatumba and Gitarama areas showed the K/Rb ratios ranging from 15.74 to 80.26 and from 190.41 to 199.39 respectively. As the pegmatite samples show K/Rb ratios less than 100 are commonly accepted for mineralization, therefore the pegmatites from Gatumba area were found mineralised, conversely to the pegmatite samples from Gitarama area, which were found barren.
基金supported by the National Key R&D Program of China(Grant Nos.2021YFC2901902 and 2019YFC0605202)。
文摘The Guanpo pegmatite field in the North Qinling orogenic belt(NQB),China,hosts the most abundant LCT pegmatites.However,their emplacement conditions and structural control remain unexplored.In this contribution,we investigated it combining pegmatite orientation measurement with oxygen isotope geothermometry and fluid inclusion study.The orientations of type A1 pegmatites(P_(f)<σ_(2))are predominantly influenced by P-and T-fractures due to simple shearing in Shiziping dextral thrust shear zone during D_(2)deformation,whereas type A2 pegmatites(contemporaneous with D_(4))are governed by hydraulic fractures aligned with S_(0)and S_(0+1)stemming from fluid pressure(P_(f)<σ_(2)).Additionally,type B pegmatites(P_(f)≤σ_(2))exhibit orientations shaped by en echelon extensional fractures in local ductile shear zones(contemporaneous with D_(3)).The albite-quartz oxygen isotope geothermometry and microthermometric analysis of fluid inclusions in elbaites from the latest pegmatites(including types B and A2)suggest that the crystallization P-T for late magmatic and hydrothermal stages are 527.5-559.2℃,320℃,3.1-3.6 kbar and 2.0 kbar,respectively.Our observations along with previous studies suggest that the genesis of the LCT pegmatites was a long-term,multi-stage event during early Paleozoic orogeny(including the collision stage)of the NQB,and was facilitated by various local fractures.
基金financially supported by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0802)。
文摘Lack of information regarding lithium(Li)crystal chemistry in numerous minerals,especially those containing trace amounts of Li(ranging from a few to tens of ppm),limits our understanding of Li isotopic fractionation in pegmatites.In this study,we examined the Li isotopic composition and Li content in various Li-poor(e.g.,quartz or feldspar)together with Li-rich(sopdumene or lepidolite)mineral phases within granitic pegmatites.We compiled a comprehensive dataset,encompassing a broad spectrum of Li contents(ranging from a few to tens of thousands of ppm)and Li isotopic values(-8‰to 41‰).The minerals exhibit distinct Li isotopic signatures.Specifically,elbaite and beryl show the highest values,while biotite displays a negative average.Compared to individual minerals,whole rocks demonstrate lower Li isotopic values,with pegmatites exhibiting the highest and non-granitic pegmatite wall rocks showing the lowest.Our study also uncovers a clear“V”shape relationship between Li isotopic values and logarithm of Li contents,with different mineral groups occupying specific regions within this shape.Furthermore,a significant correlation was observed between average Li isotopic values and Li-O(OH,F)bond lengths in various minerals.These discoveries underscore the crucial role of crystal chemistry in shaping the Li isotopic behavior in pegmatites from a statistical perspective.
基金supported by a research cooperation(Grant No.3TE1107T)between Kyushu University,Japan and the Egyptian Nuclear Materials Authority(NMA)。
文摘The Wadi Ibib area is situated in the northern part of the Neoproterozoic Hamisana Shear Zone(HSZ), which is a high strain zone evolved during the late stages of the Pan-African orogeny, likely as a tectonic escape structure. Amphibolite facies pelitic metasedimentary windows crop out in the axial parts of the HSZ and are noticeably associated with numerous N-trending pegmatite dikes. Whole-rock geochemistry of the pegmatites reveals a peraluminous(S-type) affinity, with low K/Rb ratios and elevated concentrations of U, Th, REE, Rb, Li, Cs, Y, Nb and Ta. Structurally, the pegmatite sets intrude along the shear plane of the HSZ, corresponding to the regional N-trending tectonic fabrics, such as axial planar foliation and dextral-shearing in the metasedimentary host rock. Field relationships, including structural context, coupled with geochemical characteristics of the Wadi Ibib pegmatites, do not support their formation as a complementary part of evolved granitic magmas. Space-localized decompression-induced partial melting of peraluminous garnet-bearing metapelites was alternatively the underlying process for formation of these pegmatites. Such decompression was associated with regional escape tectonics and stress axes permutations during the late deformation stage(D3) in the evolution of the south Eastern Desert terrane, due to end-orogeny system pressure-release.
文摘The P-Li-Nb pegmatites are located in the south of Brazil, in the states of Minas Gerais and Espirito Santos. They represent the largest pegmatite fields of Brazil and the richest in precious stones. Two types of pegmatites are characterized by their mineralogical characteristics and tectonic and magmatic relations. The first group occurred during a compressive deformation phase D1 about 582 Ma and 550℃ - 700℃ and 4 - 5 kb. The second pegmatites group was formed during the decompression phase D2 (520 - 500 Ma) of the Brasiliano metamorphic rock fusion. The geochemical parameters of the P-Li-Be bearing pegmatites of the first group show the same trend fractionation, as suggested by the mineralogical composition. The variation of tourmaline and columbite-tantalite composition of the first group game again applies a change of melt composition during the regional development of the pegmatites. A systematic compositional trend seems to suggest a petrogenetic link between the pegmatites of the region. The Fe/Mn ratio of tourmaline in samples of the first group shows the same behavior as in columbite-tantalite and garnets. The simple pegmatites are transiting north in the gem-rich pegmatites. The Fe/Mn ratio not only shows qualitatively the fractionation index, the degree of regional development, but also the internal development of the body. The ratio shows a negative correlation with lithium. The Co, Zn and Nb contents are rising at first group, but falling when starting crystallization of garnet, columbite-tantalite, and Behierit.
文摘The lithium potential in the Aïr massif is represented by mineral index of spodumene pegmatites and, lepidolite pegmatites. The mineral deposits of lithium occur in cluster or veins that cut the host rock or are located near the contact between the greenstone belt and granitic massif. The evidence of lithium is in the form of clusters or disseminated and stockwerk. Mineralogical characteristics show similarities between the Air Massif pegmatites and indicate the same homogenous source during the magma-generation process. The pegmatite rocks attracted the attention due to their wide exposure and composition, well appearance, and economically hosting of significant rare earth metals such as Sn and W. The mineralogical and petrographical investigations on the eight pegmatites rocks samples observed have a relative similarity, while a little difference in the shapes attributed to the ratio in the pegmatite rocks of the minerals. The occurrence of the kink band indicates the influence of the tectonic processes which affected the Aïr massif after the emplacement of late magmatic or post-magmatic pegmatites by injection into fractured rocks in the upper part of the crust. The Air Massif pegmatite has higher concentrations Li and of all trace elements except Hf and occasionally Zr, Ti, Sn and Mg of for the economic exploration.
文摘THE crystalline-fluid melt inclusions in aquamarines in pegmatites from Mufushan (Hunan Prov.) andAilaoshan (Yunnan Prov.) have been studied. The research shows that there are obvious differences inthe chemical composition of the inclusions in the aquamarines, which is of great importance for studyingthe forming mechanism and origin of pegmatites. 1 General geology of pegmatites Mufushan is situated in the middle sector of the Jiangnan Ancient Land. The granitic pegmatitesmainly outcrop in granite mass of late Yanshanian (105-145 Ma) which was intruded in middle sector ofthe middle Proterozoic strata. Part of the pegmatites occur in the contact zone of the granite and the metamorphic rocks. The pegmatite veins may be divided into four types, all of them were originated from mag-
基金funded by the National Natural Science Foundation of China(Nos.42403065 and 92462302)the Frontiers Science Center for Deep-time Digital Earth(No.2652023001)the Open Research Project from the State Key Laboratory of Critical Earth Material Cycling and Mineral Deposits,Nanjing University(No.2025-K16).
文摘0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization in peraluminous pegmatites.
基金finational supported by the Foundation of Science,Technology and Innovation Funding Authority(STDF)(Award Number:47106Recipient:Mokhles K K.Azer)。
文摘Leucogranite,pegmatite,and aplite from selected areas in the Wadi El Gemal area in the southern Eastern Desert of Egypt were investigated geochemically for their petrogenesis.These rocks represent a significant episode of felsic magmatism during the late stage of the Pan-African orogeny in the evolution of the Arabian–Nubian Shield(ANS)during the Late Neoproterozoic.On a petrographic basis,the leucogranite is sometimes garnetiferous and can be distinguished into monzogranite,syenogranite,and alkali feldspar granite.The analyses of muscovite,biotite,garnet,and apatite reveal the magmatic nature of the studied leucogranite.The investigated leucogranite,pegmatite,and aplite are alkali-calcic,calc-alkaline,and peraluminous.The peraluminous nature of these rocks is evidenced by using the chemical analyses of biotite.These studied rocks show a slight enrichment in light rare-earth elements(LREEs)and large-ion lithophile elements(LILE,especially Rb and Th),with an insignificant depletion of heavy rareearth elements(HREEs).On a geochemical basis,the leucogranite,pegmatite,and aplite in the study area crystallized from multiple-sourced melts that include mafic,metagraywake,and pelitic.They were derived from melts generated at crystallization temperatures around 568-900℃ for leucogranite,553-781℃ for pegmatite,and 639-779℃ for aplite based on the Zr saturation geothermometers,and at a pressure around 0.39-0.48 GPa,i.e.shallow depth intrusions.The studied felsic rocks have strong negative Eu anomalies,which are very consistent with an upper crust composition,indicating fractionation of feldspar cumulates.Also,they show a moderate La/Sm ratio indicating combined magmatic processes represented by partial melting and fractional crystallization.Integration of whole-rock chemical composition and mineral microanalysis suggests that felsic magmatism in the west Wadi El Gemal area produced voluminous masses of syn-to post-collisional granite,pegmatite,and aplite.An evolutionary three-stage model is presented to understand late magmatism in the ANS in terms of a geodynamic model.Such a model discusses the propagation of felsic magmatism in the ANS during syn-collisional to post-collisional stages.
基金funded by the Major Research Plan of the National Natural Science Foundation of China(92162323)Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0430101)Guizhou Provincial Science and Technology Projects No.ZK[2023]052.
文摘Lithium is a critical strategic metal with signifi-cant reserves in pegmatites,serving as the primary source for global Li production.Apatite has attracted increasing attention as an indicator in petrogenesis studies and for the exploration of ore deposits.In this study,we investigated the volatile compositions and major and trace elements of apatite from the Qiongjiagang pegmatite-type lithium deposit in Himalaya.Apatite derived from spodumene pegmatite exhibits relatively constant and high total rare earth element(ΣREE+Y)concentrations,ranging from 5899 to 8540 ppm.In contrast,apatite in barren pegmatite displays evidently lower(ΣREE+Y)concentrations,varying between 1345 and 3095 ppm.The REE patterns of apatite in spodumene pegmatite generally exhibit a flat shape[(La/Yb)N=1.55-2.15)],with distinctively negative Eu anomalies(Eu_(N)/Eu_(N)^(*)=0.14-0.22),slightly positive Ce anomalies(Ce_(N)/Ce_(N)^(*)=1.03-1.13),and low Y/Ho ratios(28-30).By contrast,apatite in barren pegmatite shows middle rare earth element(MREE)-depleted downward-convex patterns[(La/Yb)N=1.99-20.4)],strongly negative Eu anomalies(Eu_(N)/Eu_(N)^(*)=0.01-0.14),slightly positive Ce anomalies(Ce_(N)/Ce_(N)^(*)=1.10-1.24),and high Y/Ho ratios(30-55,with an average of 50).Overall,the high concentrations ofΣREE(and Y)and low Th/U and Y/Ho ratios can serve as diagnostic indicators to distinguish apatite in spodumene pegmatite from that in barren pegmatite.Furthermore,the flat REE pattern may represent a common feature of apatite from lithium deposits.Differences in the Ce and Eu anomalies between apatite from these two kinds of pegmatites likely reflect formation under different redox conditions.Consequently,based on calculations derived from apatite volatile compositions,the melt associated with spodumene pegmatite may contain higher water content compared to that of the barren one.Therefore,the mineralized pegmatite system may incorporate substantial amounts of H_(2)O-rich fluids,which play a crucial role in lithium mineralization.
基金The National Key Research and Development Program of China(No.2021YFC2901903)the National Key Research and Development Program of China(No.2023YFC2906805)+1 种基金the Second Comprehensive Scientific Expedition to the Qinghai-Tibet Plateau(No.2019QZKK0806)the Geological Survey Project of China Geological Survey,(Nos.DD20240071,DD20240014,DD20211690,DD20240069)。
文摘The Gabo lithium deposit represents a newly discovered pegmatite-type lithium deposit within the Himalayan metallogenic belt.The tourmaline-muscovite granite,the largest leucogranite in the mining area,displays a close spatial correlation with the Li-pegmatite veins.This study aims to examine the genesis of tourmaline and evaluate the significance and potential of pegmatite lithium deposits.Tourmaline is extensively distributed in tourmaline-muscovite granite at Gabo deposit in Luozha county(Xizang).Investigation of the compositional and in situ boron isotopes of the tourmaline revealed that the tourmalines mainly belong to the schorl group and exhibit uniform elevated Li-Sn contents andδ^(11)B values(-11.6‰to-10.5‰).This indicates that the tourmaline mainly crystallized from a boron-rich granitic magma undergoing enrichment in elemental lithium during the tourmaline crystallization process.Compared with the principal rare metal leucogranite-pegmatites in the Himalayan orogen,it is proposed that the elevated lithium(Li)content of tourmaline serves as an eff ective mineral indicator for the highly evolved pegmatite-type rare metal deposits.
基金supported by the Key Research Program of the Institute of Geology&Geophysics,CAS(IGGCAS-202205)the National Natural Science Foundation of China(Grant No.92062216 and 42102046)+1 种基金Doctoral Students'Scientific Research and Innovation Capability Enhancement Program of Jilin Province(JJKH20250074BS)Graduate Innovation Fund of Jilin University(2024CX231).
文摘Highly evolved granite associated with pegmatite shells exhibits significant potential for rare metal mineralization;however,the mechanisms through which these pegmatite shells contribute to magmatic evolution and rare metal enrichment remain poorly understood.The Late Jurassic Shihuiyao Nb-Ta-(Rb-Be-Li)deposit is one of the largest rare-metal deposits in the Southern Great Xing’an Range(SGXR),Northeast China.Exploratory trenches expose distinct layered zones from top to bottom:alternating microcline pegmatite and aplite layers(zone I),topaz lepidolite albite granite and lepidolite amazonite pegmatite(zone II),and muscovite albite granite(zoneⅢ).We conducted U-Pb dating of cassiterite,monazite,and Nb-Ta oxide,monazite Nd isotopes,and whole-rock and mineral geochemistry for the three zones.Multi-mineral U-Pb ages indicate that the three zones formed during the Late Jurassic-Early Cretaceous(147-142 Ma).Geochemical analyses of whole-rock,mica,and microcline suggest an evolutionary sequence from zone I to zoneⅢ,and finally to zone II.The Zr/Hf,Nb/Ta,Y/Ho,and K/Rb ratios combined with the rare earth element(REE)tetrad effects suggest higher degree of differentiation and fluid-melt interaction of the Shihuiyao leucogranite without a pegmatite shell compared to coeval barren granites from both Shihuiyao and the SGXR.A progressive increase in the degree of evolution is evident from the leucogranite without a pegmatite shell to the leucogranite with a discontinuous shell,and ultimately to the leucogranite with a continuous shell.The pegmatite shell acted as a geochemical barrier that facilitated the accumulation of Li and F in the underlying magma,which played a crucial role in lowering the solidus temperature of the granitic magma.This process prolonged the crystallization duration while reducing melt viscosity and density,thereby creating favorable conditions for magma differentiation and fluid-melt interaction.Rapid crystallization of the earlier water-and Be-rich melt led to the Be mineralization in the pegmatite shell.Moreover,the formation of this shell served as a barrier for Li mineralization in the underlying topaz lepidolite albite granite.This study enhances our understanding of the critical contribution of pegmatite shells to magmatic evolution and rare-metal mineralization.
基金provided by the National Key R&D Program of China(No.2024YFC3012605)the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Independent Research Project(Nos.SKLGP2022Z001,SKLGP2023Z029 and SKLGP2022K027)。
文摘Biotite content critically influences rock mechanical behavior and threatens underground engineering stability.Uniaxial compression tests with acoustic emission(AE)monitoring were conducted on granite pegmatite samples having varying biotite content.Peak frequency distribution analysis,rise angleaverage frequency(RA-AF)analysis,multifractal theory,and a dynamic multifractal algorithm were applied to explore the relationship between damage evolution and AE characteristics.Results indicate that increased biotite content reduces uniaxial compressive strength and elastic modulus,enhances plastic deformation,and increases the proportion of shear cracks.The segmented evolution of the dynamic multifractal parameter Δα_(m) is biotite-dependent.Oscillations during the elastic phase signify localized shear crack initiation and propagation;their attenuation in the plastic phase reflects frictional closure along biotite cleavage planes,promoting elastic energy storage and delaying release.AE-based damage models and time-varying signals characterize rock damage progression.Stress concentrations around biotite minerals foster localized shear band formation,leading to concentrated shear failure at lower damage levels.Higher biotite content accelerates crack propagation,while smooth cleavage planes lower the fracture energy threshold,reducing strength and stiffness.These findings enhance understanding of biotite-influenced progressive rock damage and underpin stability monitoring and early-warning systems for underground engineering.
基金supported by the Ministry of Natural Resources-Provincial Joint Cooperation Project in 2024(No.2024ZRBSHZ126)The Second Comprehensive Scientific Research Project on the Qinghai-Tibetan Plateau“Assessment of Current Status and Future Prospects for Rare Metal Resources”(No.2019QZKK0802)+4 种基金Yunnan Foundation Project(No.202201AU070162)Career Development Fund for Early-Career Geologists at YIGS(No.YDKYR[2024]3)YDIG Expert Innovation Studio(No.YDIG[2024]24)New round of Yunnan Province prospecting Action and Project of Geological Exploration Fund(No.K202408)KUST-NSRF Talent Development Project(No.KKZ3202421133).
文摘The middle-scale Heima zinnwaldite deposit is situated in the southeastern Tibetan Plateau,SW China.The NNW-to NS-trending orebodies are hosted in the Gaoligongshan metamorphic zone.To clarify the zinnwaldite genesis at Heima,this study presents an integrated investigation of the Heima pegmatites,combining precise geochronology,isotopic tracing,and detailed mineral chemistry to constrain its formation age,petrogenetic origin,and mineralization processes.Our robust geochronological framework,employing magmatic zircon(56.93±0.53 Ma)and cassiterite(57.0±4.2 Ma),establishes the pegmatite emplacement during the Late Paleocene to Early Eocene,representing the maximum age of lithium mineralization.Hf isotopic compositions(εHf_((t))=−14.3 to−12.4)demonstrate that the Heima pegmatite originated from remelting of ancient sediments,distinguishing it from contemporaneous Eocene Gangdese-Tengchong granites(εHf_((t))=−12.7 to+11.0)that show mantle contributions.This crustal signature aligns with the evolutionary trend of Hf isotopes in regional gneissic granites(600−420 Ma),supporting an anatectic origin from ancient continental crust rather than being derivatives of nearby Eocene granitic plutons.Detailed geochemical analysis of Li-micas reveals two distinct generations with contrasting formation mechanisms.The primary mica-Ia(53.45±0.86 Ma,Rb-Sr age)exhibits extreme incompatible element enrichment(Li,Be,Rb,Cs)and remarkably low K/Rb ratios(3.98-4.37),characteristic of crystallization from highly fractionated granitic melts.In contrast,secondary mica-Ib and mica-Ⅱ(17.9-16.0 Ma,Rb-Sr age)show significant Nb-Ta-W enrichment,reflecting precipitation from F-P-rich hydrothermal fluids during Miocene metamorphic-hydrothermal events.Principal component analysis(PCA)confirms the compositional disparity between these mica generations,with the later phases attributed to fluid-induced alteration and reworking.Regional correlation identifies two distinct lithium mineralization episodes in the Gongshan area,southeast Tibetan Plateau.The Eocene phase(~55 Ma)is zinnwaldite-dominant(e.g.,Heima,Puladi),associated with crustal melting following Neo-Tethyan closure.The Miocene phase(~17 Ma)is spodumene-dominant(e.g.,Danzhu,Peili),linked to Himalayan leucogranites formed as the rapid exhumation,denudation,and decompression partial melting of Himalayan Crystalline Complex.
