As environmental awareness,waste minimization and conscious living gain widespread attention,endeavors have been dedicated to acquiring new water-based(WB)lubricants for green manufacturing.Zeolitic Imidazolate Framew...As environmental awareness,waste minimization and conscious living gain widespread attention,endeavors have been dedicated to acquiring new water-based(WB)lubricants for green manufacturing.Zeolitic Imidazolate Framework-8(ZIF-8),an important branch of metal organic frameworks(MOFs),can perform ex-ceptional lubricity add-on water conditions.Nevertheless,surface functionalization of ZIF-8 nanoparticles is a key issue for promoting interfacial consistency and mixing stability in aqueous solutions.In this research work,the functionalization approach of ZIF-8 via polydopamine polymerization process(PDA)was adopted to enhance its dispersion durability in water.A ball-on-flat linear reciprocating tribometer was used to test the lubrication achievement of the functionalized ZIF-8@PDA as an additive nanoparticle in water under room temperature.The experimental findings revealed a significant lubrication improvement,with the coefficient of friction(COF)being decreased by 33.9%with a 4.0 wt%content of ZIF-8@PDA.The wear track width distance saw a reduction of 34.4%when utilizing a 2.0 wt%inclusion of ZIF-8@PDA.This lubrication enhancement accounts for mi-crobearing and mending effects provided by ZIF-8@PDA.展开更多
基金Supported by Shaanxi Provincial Natural Science Basic Research Program(Grant No.2025JC-YBMS-353)the Fundamental Research Funds for the Central Universities(Grant No.ZYTS25049)National Natural Science Foundation of China(Grant No.52105205).
文摘As environmental awareness,waste minimization and conscious living gain widespread attention,endeavors have been dedicated to acquiring new water-based(WB)lubricants for green manufacturing.Zeolitic Imidazolate Framework-8(ZIF-8),an important branch of metal organic frameworks(MOFs),can perform ex-ceptional lubricity add-on water conditions.Nevertheless,surface functionalization of ZIF-8 nanoparticles is a key issue for promoting interfacial consistency and mixing stability in aqueous solutions.In this research work,the functionalization approach of ZIF-8 via polydopamine polymerization process(PDA)was adopted to enhance its dispersion durability in water.A ball-on-flat linear reciprocating tribometer was used to test the lubrication achievement of the functionalized ZIF-8@PDA as an additive nanoparticle in water under room temperature.The experimental findings revealed a significant lubrication improvement,with the coefficient of friction(COF)being decreased by 33.9%with a 4.0 wt%content of ZIF-8@PDA.The wear track width distance saw a reduction of 34.4%when utilizing a 2.0 wt%inclusion of ZIF-8@PDA.This lubrication enhancement accounts for mi-crobearing and mending effects provided by ZIF-8@PDA.
