为了制备具有远程可控变形且性能优越的形状记忆聚合物,采用巯基-烯点击化学法制备了PCL/CB复合材料,并用FTIR、DSC、1 H NMR和DMA对复合材料的结构、热性能以及形状记忆特性等进行表征。结果表明:交联复合材料薄膜的热转变温度为50℃,...为了制备具有远程可控变形且性能优越的形状记忆聚合物,采用巯基-烯点击化学法制备了PCL/CB复合材料,并用FTIR、DSC、1 H NMR和DMA对复合材料的结构、热性能以及形状记忆特性等进行表征。结果表明:交联复合材料薄膜的热转变温度为50℃,且当预拉伸的复合材料薄膜受到100 mW/cm^(2)强度的激光照射时,CB颗粒吸收激光光子而产生光热转换且由于各向异性链松弛和应变能释放,致使上层薄膜在受到激光照射时,结晶熔融发生形状记忆效应而收缩,与此同时下层薄膜仍然处于玻璃态,上层薄膜的收缩力使PCL/CB复合材料薄膜朝着激光照射方向发生弯曲变形。同时,弯曲角度可以通过薄膜预拉伸应变量、激光照射时间以及薄膜厚度3个参数进行调控;当预拉伸应变为300%、薄膜厚度为0.4 mm时,最大弯曲角为164°。这种具备局部可编程行为的PCL/CB复合薄膜可为光响应SMP的变形模式提供新思路。展开更多
In order to effectively control the drug-release rate of medical textiles,biodegradable polycaprolactone(PCL) and polyglycolic acid(PGA) were blended at various mass ratios to prepare composite masterbatches for medic...In order to effectively control the drug-release rate of medical textiles,biodegradable polycaprolactone(PCL) and polyglycolic acid(PGA) were blended at various mass ratios to prepare composite masterbatches for medical textiles.The surface morphology and the chemical structure of the masterbatches were analyzed.The crystallization,mass losses,strengths and drug-release rates of the composite masterbatches at different PCL/PGA mass ratios were explored.The results show that the degradation rate of the PGA carrier is obvious higher than that of the PCL carrier,and PCL,PGA and the tea polyphenol(TP) drug just physically mix without chemical reaction.During the degradation,the strength of the composite masterbatches gradually decreases.In addition,the drug-release rates of composite masterbatches at different mass ratios are different,and the more the PGA in the composite masterbatches,the faster the drug release of the composite masterbatches.The drug-release rate of the composite masterbatches can be controlled by adjusting the contents of PCL and PGA.展开更多
A new entire biodegradable scaffold has been developed which does not require precellularization before transplantation.This new kind of vascular scaffold prototype made from porous poly-ε-caprolactone( PCL) membrane...A new entire biodegradable scaffold has been developed which does not require precellularization before transplantation.This new kind of vascular scaffold prototype made from porous poly-ε-caprolactone( PCL) membrane to provide three-dimensional environment for cell growth, and embedded with weft-knitted polylactic acid( PLA) fabric to support mechanics.The aim of this paper is to study the variation tendency of mechanical properties with the fabric spacing changing.The basic geometrical parameters were measured to characterize properties of the samples.The tensile and compressive elastic recovery of the samples were tested by the universal mechanical tester and radial compression apparatus,respectively.Both tensile and compressive properties enhanced when reducing the fabric spacing of the composite vascular scaffold.展开更多
The study on the correlation between electrical percolation and viscoelastic percolation for carbon black（CB） filled high-density polyethylene（HDPE） conductive composites was carried out through examining the fill...The study on the correlation between electrical percolation and viscoelastic percolation for carbon black（CB） filled high-density polyethylene（HDPE） conductive composites was carried out through examining the filler volume fraction dependence of the volume resistivity（ρ） and normalized dynamic storage modulus,G c/G p,in which G c,G p are dynamic storage modulus of the composites and the matrix respectively. The results revealed that the critical filler volume fraction of viscoelastic percolation approached the lower threshold（φ1） of the electrical percolation,indicating an insulator-semiconductor change corresponding to the beginning of network structure formation. Substituting K for A,a modified Kerner-Nielson equation was obtained and used to analyze the formation of network structure. It is suggested that parameter K is associated with CB volume fraction. [WT5HZ]展开更多
采用同轴静电纺丝技术制备聚乳酸(PLA)-聚己内酯(PCL)核-壳结构复合纤维.利用扫描电子显微镜(SEM)观察纺丝电压、收集距离和核层-壳层溶液推进速度对PLA-PCL核-壳结构复合纤维形貌的影响.通过透射扫描电子显微镜(TEM)分析核层-壳层溶液...采用同轴静电纺丝技术制备聚乳酸(PLA)-聚己内酯(PCL)核-壳结构复合纤维.利用扫描电子显微镜(SEM)观察纺丝电压、收集距离和核层-壳层溶液推进速度对PLA-PCL核-壳结构复合纤维形貌的影响.通过透射扫描电子显微镜(TEM)分析核层-壳层溶液推进速度对PLA-PCL核-壳结构形成的影响.研究结果表明:当核-壳溶液推进速度为0.1-0.2和0.1-0.3 m L/h时形成了清晰的核-壳结构;随着壳层溶液推进速度加快,PLA-PCL复合纤维核层含量降低,增加纺丝电压能够有效地降低复合纤维平均直径,而增大收集距离使复合纤维平均直径先降低后增加.展开更多
文摘为了制备具有远程可控变形且性能优越的形状记忆聚合物,采用巯基-烯点击化学法制备了PCL/CB复合材料,并用FTIR、DSC、1 H NMR和DMA对复合材料的结构、热性能以及形状记忆特性等进行表征。结果表明:交联复合材料薄膜的热转变温度为50℃,且当预拉伸的复合材料薄膜受到100 mW/cm^(2)强度的激光照射时,CB颗粒吸收激光光子而产生光热转换且由于各向异性链松弛和应变能释放,致使上层薄膜在受到激光照射时,结晶熔融发生形状记忆效应而收缩,与此同时下层薄膜仍然处于玻璃态,上层薄膜的收缩力使PCL/CB复合材料薄膜朝着激光照射方向发生弯曲变形。同时,弯曲角度可以通过薄膜预拉伸应变量、激光照射时间以及薄膜厚度3个参数进行调控;当预拉伸应变为300%、薄膜厚度为0.4 mm时,最大弯曲角为164°。这种具备局部可编程行为的PCL/CB复合薄膜可为光响应SMP的变形模式提供新思路。
基金Transformation and Guidance of Scientific and Technological Achievements in Shanxi Province,China(No.202104021301053)Fundamental Research Program of Shanxi Province,China(Nos. 20210302123114 and 202203021211146)+1 种基金Transformation of Scientific and Technological Achievements Programs of Higher Education Institutions in Shanxi Province,China(TSTAP)(No. 2020CG014)Open Project Program of Key Lab for Sport Shoes Upper Materials of Fujian Province,Fujian Huafeng New Material Co.,Ltd.,China(No.S SUM213)。
文摘In order to effectively control the drug-release rate of medical textiles,biodegradable polycaprolactone(PCL) and polyglycolic acid(PGA) were blended at various mass ratios to prepare composite masterbatches for medical textiles.The surface morphology and the chemical structure of the masterbatches were analyzed.The crystallization,mass losses,strengths and drug-release rates of the composite masterbatches at different PCL/PGA mass ratios were explored.The results show that the degradation rate of the PGA carrier is obvious higher than that of the PCL carrier,and PCL,PGA and the tea polyphenol(TP) drug just physically mix without chemical reaction.During the degradation,the strength of the composite masterbatches gradually decreases.In addition,the drug-release rates of composite masterbatches at different mass ratios are different,and the more the PGA in the composite masterbatches,the faster the drug release of the composite masterbatches.The drug-release rate of the composite masterbatches can be controlled by adjusting the contents of PCL and PGA.
基金the Fundamental Research Funds for the Central Universities,China，National Natural Science Foundation of China，"111 Project" Biomedical Textile Materials Science and Technology,China，the Donghua University Innovation Fund of Graduate Project,China
文摘A new entire biodegradable scaffold has been developed which does not require precellularization before transplantation.This new kind of vascular scaffold prototype made from porous poly-ε-caprolactone( PCL) membrane to provide three-dimensional environment for cell growth, and embedded with weft-knitted polylactic acid( PLA) fabric to support mechanics.The aim of this paper is to study the variation tendency of mechanical properties with the fabric spacing changing.The basic geometrical parameters were measured to characterize properties of the samples.The tensile and compressive elastic recovery of the samples were tested by the universal mechanical tester and radial compression apparatus,respectively.Both tensile and compressive properties enhanced when reducing the fabric spacing of the composite vascular scaffold.
文摘The study on the correlation between electrical percolation and viscoelastic percolation for carbon black（CB） filled high-density polyethylene（HDPE） conductive composites was carried out through examining the filler volume fraction dependence of the volume resistivity（ρ） and normalized dynamic storage modulus,G c/G p,in which G c,G p are dynamic storage modulus of the composites and the matrix respectively. The results revealed that the critical filler volume fraction of viscoelastic percolation approached the lower threshold（φ1） of the electrical percolation,indicating an insulator-semiconductor change corresponding to the beginning of network structure formation. Substituting K for A,a modified Kerner-Nielson equation was obtained and used to analyze the formation of network structure. It is suggested that parameter K is associated with CB volume fraction. [WT5HZ]
文摘采用同轴静电纺丝技术制备聚乳酸(PLA)-聚己内酯(PCL)核-壳结构复合纤维.利用扫描电子显微镜(SEM)观察纺丝电压、收集距离和核层-壳层溶液推进速度对PLA-PCL核-壳结构复合纤维形貌的影响.通过透射扫描电子显微镜(TEM)分析核层-壳层溶液推进速度对PLA-PCL核-壳结构形成的影响.研究结果表明:当核-壳溶液推进速度为0.1-0.2和0.1-0.3 m L/h时形成了清晰的核-壳结构;随着壳层溶液推进速度加快,PLA-PCL复合纤维核层含量降低,增加纺丝电压能够有效地降低复合纤维平均直径,而增大收集距离使复合纤维平均直径先降低后增加.
