The work of Chinese scientists conducted at the Joint Institute for Nuclear Research(JINR)(1956–1965)was inextricably linked to the Sino-Soviet relations in the 1950 s–1960 s.During the early stage of the JINR,with ...The work of Chinese scientists conducted at the Joint Institute for Nuclear Research(JINR)(1956–1965)was inextricably linked to the Sino-Soviet relations in the 1950 s–1960 s.During the early stage of the JINR,with the aid of advanced equipment and the international cooperation mechanism,Chinese scientists yielded significant results,such as the discovery of the antisigma-minus hyperon and the proof of the law of partial conservation of axial current(PCAC).After the Sino-Soviet split,Chinese scientists’activities at the institute were hampered by political tensions,eventually resulting in China’s withdrawal from the JINR in 1965.But through the involvement at the JINR,Chinese scientists were trained in scientific practices and participated in international exchange and cooperation which turned them into a new force in China’s nuclear industry,boosting its nuclear weapons,particle physics theory,and accelerator technology.In the meantime,the scientists’activities extended the international influence of the JINR.The withdrawal of China from the institute impacted both the JINR and the development of science in China.展开更多
Geometric structures of 135 polychlorinated acenaphthylene （PCAC） molecules were optimized using density functional theory （DFT） at the B3LYP/6-311G^＊＊ level and some thermodynamic properties of them in the idea...Geometric structures of 135 polychlorinated acenaphthylene （PCAC） molecules were optimized using density functional theory （DFT） at the B3LYP/6-311G^＊＊ level and some thermodynamic properties of them in the ideal gas state were calculated. The relations of these thermodynamic properties with the number and position of chlorine atoms were also explored, from which the relative stability of PCAC congeners was theoretically proposed according to the magnitude of the relative standard Gibbs free energy of formation （△r,fGθ）. The results show that all PCAC isomers have planar geometric configuration. There exists intramolecular Cl···Cl weak interaction in some PCAC molecules. The change of △fHθ and fGθ of most stable PCAC isomers with increasing the number of chlorine atoms is different from that in the least stable PCAC congeners. The values of fHθ and fGθ for PCAC isomers with the same number of chlorine atoms show a strong dependence on the position of chlorine atoms and the relative stability of PCAC congeners has close relation with the intramolecular Cl···Cl nuclear repulsive interaction.展开更多
基金supported in part by the Youth Innovation Promotion Association CAS(2018186)the National Science Foundation of China(NSFC)under Grant No.11775207。
文摘The work of Chinese scientists conducted at the Joint Institute for Nuclear Research(JINR)(1956–1965)was inextricably linked to the Sino-Soviet relations in the 1950 s–1960 s.During the early stage of the JINR,with the aid of advanced equipment and the international cooperation mechanism,Chinese scientists yielded significant results,such as the discovery of the antisigma-minus hyperon and the proof of the law of partial conservation of axial current(PCAC).After the Sino-Soviet split,Chinese scientists’activities at the institute were hampered by political tensions,eventually resulting in China’s withdrawal from the JINR in 1965.But through the involvement at the JINR,Chinese scientists were trained in scientific practices and participated in international exchange and cooperation which turned them into a new force in China’s nuclear industry,boosting its nuclear weapons,particle physics theory,and accelerator technology.In the meantime,the scientists’activities extended the international influence of the JINR.The withdrawal of China from the institute impacted both the JINR and the development of science in China.
基金supported by the Natural Science Research Program of Henan Provincial Department of Education (No. 2009A150022)the Young Talented Teacher Foundation of Xinyang Normal University
文摘Geometric structures of 135 polychlorinated acenaphthylene （PCAC） molecules were optimized using density functional theory （DFT） at the B3LYP/6-311G^＊＊ level and some thermodynamic properties of them in the ideal gas state were calculated. The relations of these thermodynamic properties with the number and position of chlorine atoms were also explored, from which the relative stability of PCAC congeners was theoretically proposed according to the magnitude of the relative standard Gibbs free energy of formation （△r,fGθ）. The results show that all PCAC isomers have planar geometric configuration. There exists intramolecular Cl···Cl weak interaction in some PCAC molecules. The change of △fHθ and fGθ of most stable PCAC isomers with increasing the number of chlorine atoms is different from that in the least stable PCAC congeners. The values of fHθ and fGθ for PCAC isomers with the same number of chlorine atoms show a strong dependence on the position of chlorine atoms and the relative stability of PCAC congeners has close relation with the intramolecular Cl···Cl nuclear repulsive interaction.
