High-pressure crystallization behavior of poly(ethylene terephthalate)(PET)/biphenol-A polycarbonate(PC) blends were investigated by scanning electron microscopy(SEM) and atomic force microscopy(AFM).Two novel spherul...High-pressure crystallization behavior of poly(ethylene terephthalate)(PET)/biphenol-A polycarbonate(PC) blends were investigated by scanning electron microscopy(SEM) and atomic force microscopy(AFM).Two novel spherulitic structures,i.e.bamboo-shoot-like spherulite and brain-like spherulite,were observed in the polyester extended-chain crystals.The extended-chain lamellar crystal may be the substructure of these spherulites.This morphology,which is quite different from that of usual spherulite and extended-chain crystal,may promote the understanding of formation process and mechanism for both polymer spherulites and extended-chain crystals.展开更多
文摘High-pressure crystallization behavior of poly(ethylene terephthalate)(PET)/biphenol-A polycarbonate(PC) blends were investigated by scanning electron microscopy(SEM) and atomic force microscopy(AFM).Two novel spherulitic structures,i.e.bamboo-shoot-like spherulite and brain-like spherulite,were observed in the polyester extended-chain crystals.The extended-chain lamellar crystal may be the substructure of these spherulites.This morphology,which is quite different from that of usual spherulite and extended-chain crystal,may promote the understanding of formation process and mechanism for both polymer spherulites and extended-chain crystals.
