The synthesis and characterization are reported for a series of bi- and trinuclear complexes of the first transition metal ions with PBDETA, the newly syn thesized polydentate ligand. The electron transition energy in...The synthesis and characterization are reported for a series of bi- and trinuclear complexes of the first transition metal ions with PBDETA, the newly syn thesized polydentate ligand. The electron transition energy in binuclear compound is stronger than that in trinuclear. There is a weak antiferromagnetic exchange interaction in tricopper and trimanganese.展开更多
文摘The synthesis and characterization are reported for a series of bi- and trinuclear complexes of the first transition metal ions with PBDETA, the newly syn thesized polydentate ligand. The electron transition energy in binuclear compound is stronger than that in trinuclear. There is a weak antiferromagnetic exchange interaction in tricopper and trimanganese.
