The power conversion efficiency （PCE） of poly（3-hexylthiophene） （P3HT） and [6,6]-phenyl C61-butyric acid methyl ester （P061BM） based organic solar cells （OSCs） is significantly improved by using benzyl aceta...The power conversion efficiency （PCE） of poly（3-hexylthiophene） （P3HT） and [6,6]-phenyl C61-butyric acid methyl ester （P061BM） based organic solar cells （OSCs） is significantly improved by using benzyl acetate （BA）, an organic compound without any halogen or sulphur atom, as a processing additive to control the blend morphology. The solar cells show PCE of 3.85% with a fill factor （FF） of 65.22%, which are higher than those of the common thermal annealing device （PCE 3.30%, FF 60.83%）. The overall increased PCE depends upon the enhanced crystallinity of P3HT and good carriers transport, with a high balanced charge carrier mobility.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 61405209,61107090,21172187,51273168,20102139 and 51173199the National Basic Research Program of China under Grant Nos 2014CB643501 and 2010DFA52310+3 种基金the Shandong Provincial Natural Science Foundation under Grant No ZR2011BZ007the Key Project of Hunan Province Education Department under Grant No 13A102the Innovation Group and Xiangtan Joint Project of Hunan Natural Science Foundation under Grant Nos 12JJ7002 and 12JJ8001the Scientific Research Fund of Hunan Provincial Education Department under Grant Nos 11CY023 and 12B123
文摘The power conversion efficiency （PCE） of poly（3-hexylthiophene） （P3HT） and [6,6]-phenyl C61-butyric acid methyl ester （P061BM） based organic solar cells （OSCs） is significantly improved by using benzyl acetate （BA）, an organic compound without any halogen or sulphur atom, as a processing additive to control the blend morphology. The solar cells show PCE of 3.85% with a fill factor （FF） of 65.22%, which are higher than those of the common thermal annealing device （PCE 3.30%, FF 60.83%）. The overall increased PCE depends upon the enhanced crystallinity of P3HT and good carriers transport, with a high balanced charge carrier mobility.
