The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and...The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and Al2 O3 content were studied. The results indicated that the viscosity decreased with increasing the slag basicity at the same temperature. And the viscosities of the slag initially increased linearly with increasing Al2 O3 content in the slags and then decreased as the Al2 O3 content in the slags continued to increase. Al2 O3 addition has a more signifi- cant effect on the viscosity than slag basicity in the selected slags. Based on the experimental data and the fraction of solid phases calculated by the thermodynamic software, the effect of solid phases on slag viscosity was evaluated. The results indicated that the relationship between the relative viscosity and the volume fraction of solid phases esti- mated from the slag composition can be reasonable by allowing the inverse maximum fraction of solid particles to vary.展开更多
The ferrites of Cuo-ZnO-Fe2o3 solid solution series near the molar ratio of ZnxCu1-x were prepared by direct heating of their coprecipitated hydroxides using NH4OH as precipitating agent where x=0.0, 0.2, 0.5, 0.8 and...The ferrites of Cuo-ZnO-Fe2o3 solid solution series near the molar ratio of ZnxCu1-x were prepared by direct heating of their coprecipitated hydroxides using NH4OH as precipitating agent where x=0.0, 0.2, 0.5, 0.8 and 1.0. Additional amounts of Cu and Zn sulphates were added to compensate the loss during the coprecipitation of the hydroxides. The ferritized samples were characterized by chemical analysis, XRD. DTA, TGA and SEM. XRD of both Zn0.2Cu0.8Fe2O4 and Zn0.5Cu0.5 Fe2O4 that indicates the formation of a heterogeneous ferrite material of ZnFe2O4 and CuFe2O4 mixed with variable amounts of α-Fe2O3. Zn and Cu ferrites were observed only in Zn0.8Cu0.2Fe2O4.From TGA-time relation, the activation energy of the different transformation phases were calculated. It is found that, the activation energy of ZnFe2O4 is slightly equal to 3/2 of that for CuFe2O4. Dielectric measurements show that the electrical behaviour depends on the ordering and disordering of the phases.展开更多
A solid ternary mixture consisting of NaF,silicon and one metal oxide such as La2O3,CeO2,Pr6O11,Nd2O3,and Y2O3 was prepared and usedas de-fluorinated reagent for CF4 decomposition.The results show that 90% conversion ...A solid ternary mixture consisting of NaF,silicon and one metal oxide such as La2O3,CeO2,Pr6O11,Nd2O3,and Y2O3 was prepared and usedas de-fluorinated reagent for CF4 decomposition.The results show that 90% conversion of CF4 can be reached initially over NaF-Si-La2O3,NaF-Si-CeO2,NaF-Si-Nd2O3,and NaF-Si-Y2O3 at 850 C.The fresh and used reagents were characterized using XRD and XPS techniques.It was found that the active components of NaF and metal oxides in NaF-Si-CeO2,NaF-Si-Pr6O11,NaF-Si-Nd2O3,and NaF-Si-Y2O3 weretransformed into inert phases of mixed metal fluorides and silicates,respectively,resulting in an ineffective utilization of these de-fluorinatedreagents,whereas no inert phases from NaF and La2O3 can be observed in the used NaF-Si-La2O3,indicating the NaF-Si-La2O3 reagent couldbe utilized more efficiently than the other reagents in CF4 decomposition.展开更多
基金Item Sponsored by National Natural Science Foundation of China(50874072)Natural Science Foundation of Jiangsu Province of China(BK20130308)China Postdoctoral Science Foundation(2014M561710)
文摘The viscosities for the selected CaO-MgO-SiO2 and CaO-MgO Al2 O3-SiO2 slags were measured by rota- ting cylinder method in a wide temperature range from 1608 K to 1 823 K. The effects of temperature, slag basicity and Al2 O3 content were studied. The results indicated that the viscosity decreased with increasing the slag basicity at the same temperature. And the viscosities of the slag initially increased linearly with increasing Al2 O3 content in the slags and then decreased as the Al2 O3 content in the slags continued to increase. Al2 O3 addition has a more signifi- cant effect on the viscosity than slag basicity in the selected slags. Based on the experimental data and the fraction of solid phases calculated by the thermodynamic software, the effect of solid phases on slag viscosity was evaluated. The results indicated that the relationship between the relative viscosity and the volume fraction of solid phases esti- mated from the slag composition can be reasonable by allowing the inverse maximum fraction of solid particles to vary.
文摘The ferrites of Cuo-ZnO-Fe2o3 solid solution series near the molar ratio of ZnxCu1-x were prepared by direct heating of their coprecipitated hydroxides using NH4OH as precipitating agent where x=0.0, 0.2, 0.5, 0.8 and 1.0. Additional amounts of Cu and Zn sulphates were added to compensate the loss during the coprecipitation of the hydroxides. The ferritized samples were characterized by chemical analysis, XRD. DTA, TGA and SEM. XRD of both Zn0.2Cu0.8Fe2O4 and Zn0.5Cu0.5 Fe2O4 that indicates the formation of a heterogeneous ferrite material of ZnFe2O4 and CuFe2O4 mixed with variable amounts of α-Fe2O3. Zn and Cu ferrites were observed only in Zn0.8Cu0.2Fe2O4.From TGA-time relation, the activation energy of the different transformation phases were calculated. It is found that, the activation energy of ZnFe2O4 is slightly equal to 3/2 of that for CuFe2O4. Dielectric measurements show that the electrical behaviour depends on the ordering and disordering of the phases.
基金supported by the National Natural Science Foundation of China (No. 20976149)
文摘A solid ternary mixture consisting of NaF,silicon and one metal oxide such as La2O3,CeO2,Pr6O11,Nd2O3,and Y2O3 was prepared and usedas de-fluorinated reagent for CF4 decomposition.The results show that 90% conversion of CF4 can be reached initially over NaF-Si-La2O3,NaF-Si-CeO2,NaF-Si-Nd2O3,and NaF-Si-Y2O3 at 850 C.The fresh and used reagents were characterized using XRD and XPS techniques.It was found that the active components of NaF and metal oxides in NaF-Si-CeO2,NaF-Si-Pr6O11,NaF-Si-Nd2O3,and NaF-Si-Y2O3 weretransformed into inert phases of mixed metal fluorides and silicates,respectively,resulting in an ineffective utilization of these de-fluorinatedreagents,whereas no inert phases from NaF and La2O3 can be observed in the used NaF-Si-La2O3,indicating the NaF-Si-La2O3 reagent couldbe utilized more efficiently than the other reagents in CF4 decomposition.
