Light-driven CO_(2) reduction reaction(CO_(2)RR)to value-added ethylene(C2H4)holds significant promise for addressing energy and environmental challenges.While the high energy barriers for*CO intermediates hydrogenati...Light-driven CO_(2) reduction reaction(CO_(2)RR)to value-added ethylene(C2H4)holds significant promise for addressing energy and environmental challenges.While the high energy barriers for*CO intermediates hydrogenation and C–C coupling limit the C_(2)H_(4)generation.Herein,CuxP/g-C_(3)N_(4) heterojunction prepared by an in-situ phosphating technique,achieved collaborative photocatalytic CO_(2) and H2O,producing CO and C_(2)H_(4)as the main products.Notably,the selectivity of C_(2)H_(4)produced by CuxP/g-C_(3)N_(4) attained to 64.25%,which was 9.85 times that of CuxP(6.52%).Detailed time-resolution photoluminescence spectra,femtosecond transient absorption spectroscopy tests and density functional theory(DFT)calculation validate the ultra-fast interfacial electron transfer mechanism in CuxP/g-C_(3)N_(4) heterojunction.Successive*H on P sites caused by adsorbed H2O splitting with moderate hydrogenation ability enables the multi-step hydrogenation during CO_(2)RR process over CuxP/g-C_(3)N_(4).With the aid of mediated asymmetric Cu and P dual sites by g-C_(3)N_(4) nanosheet,the produced*CHO shows an energetically favorable for C–C coupling.The coupling formed*CHOCHO further accepts photoexcited efficient e–and*H to deeply produce C_(2)H_(4)according to the C^(2+)intermediates,which has been detected by in-situ diffuse reflectance infrared Fourier transform spectroscopy and interpreted by DFT calculation.The novel insight mechanism offers an essential understanding for the development of CuxP-based heterojunctions for photocatalytic CO_(2) to C^(2+)value-added fuels.展开更多
将随机游走法和层次法相结合,采用层次化随机游走法对静态P/G网(Power and Ground Networks)进行分析.针对大规模的电路,在通过多层的参数提取和建模得到静态P/G网模型后,运用层次法将P/G网分割,在子网内采用随机游走法,并且在此基础上...将随机游走法和层次法相结合,采用层次化随机游走法对静态P/G网(Power and Ground Networks)进行分析.针对大规模的电路,在通过多层的参数提取和建模得到静态P/G网模型后,运用层次法将P/G网分割,在子网内采用随机游走法,并且在此基础上比较5种加速算法.实验数据表明,改进的双共轭梯度(BCG)随机游走法的计算速度是普通随机游走法的6倍以及是层次法的14倍.新方法有效地节省了计算时间,有益于对P/G网的研究.展开更多
Constructing step-scheme(S-scheme)heterojunctions can considerably facilitate separation and transfer of photocarriers,as well as promote strong redox ability.The interface resistance of heterojunctions immediately af...Constructing step-scheme(S-scheme)heterojunctions can considerably facilitate separation and transfer of photocarriers,as well as promote strong redox ability.The interface resistance of heterojunctions immediately affects photocarrier separation and determines the photocatalytic activity.Herein,we constructed a novel Bi OBr/Ni_(2)P/g-C_(3)N_(4) heterojunction using Ni_(2)P as a novel electron bridge to reduce the interfacial resistance of photocarriers between Bi OBr and g-C3N4.The as-prepared 10% BiOBr/Ni2P/g-C_(3)N_(4) sample exhibited outstanding visible-light photocatalytic performance for methyl orange and rhodamine B removal,with degradation efficiencies of 91.4% and 98.9%,respectively.The excellent photocatalytic activity of Bi OBr/Ni_(2)P/g-C_(3)N_(4) was mainly attributed to the synergistic effects of the Ni2P cocatalyst and S-scheme heterojunction,which not only reduced the interface resistance but also retained the strong redox potential of the photocarriers.In addition,the formation of the S-scheme system was supported by active oxygen species investigation,current-voltage curves,and density functional theory calculations.This work provides a guideline for the design of highly efficient S-scheme photocatalysts with transition metal phosphates as electron bridges to improve photocarriers separation.展开更多
Power integrity (PI) has become a limiting factor for the chip's overall performance, and how to place in-package decoupling capacitors to improve a chip's PI performance has become a hot issue. In this paper,...Power integrity (PI) has become a limiting factor for the chip's overall performance, and how to place in-package decoupling capacitors to improve a chip's PI performance has become a hot issue. In this paper, we propose an improved trans- mission matrix method (TMM) for fast decoupling capacitance allocation. An irregular grid partition mechanism is proposed, which helps speed up the impedance computation and complies better with the irregular power/ground (P/G) plane or planes with many vias and decoupling capacitors. Furthermore, we also ameliorate the computation procedure of the impedance matrix whenever decoupling capacitors are inserted or removed at specific ports. With the fast computation of impedance change, in-package decoupling capacitor allocation is done with an efficient change based method in the frequency domain. Experimental results show that our approach can gain about 5× speedup compared with a general TMM, and is efficient in restraining the noise on the P/G plane.展开更多
针对传统综合能源系统存在的能源产物种类单一、污染气体排放量高以及经济性差等问题,提出一种集成电转氢(power to hydrogen,P2H)、氢转气(hydrogen to gas,H2G)、氢转氨(hydrogen to ammonia,H2A)等电力多元转换(power to X,P2X)技术...针对传统综合能源系统存在的能源产物种类单一、污染气体排放量高以及经济性差等问题,提出一种集成电转氢(power to hydrogen,P2H)、氢转气(hydrogen to gas,H2G)、氢转氨(hydrogen to ammonia,H2A)等电力多元转换(power to X,P2X)技术的电热联供综合能源系统构型。首先,在系统模型方面,通过引入碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)与火电机组富氧/掺氨燃烧等技术,构建电转氢/气/氨(power to hydrogen/gas/ammonia,P2H/G/A)耦合系统;其次,在电力系统低碳经济转型方面,构建综合考虑富氧燃烧-H2G耦合模型碳减排、增加供热经济收益效果以及H2A-掺氨燃烧耦合模型降低煤耗成本和燃煤碳排放效果的综合能源系统目标函数;最后,基于内蒙古某示范基地构建算例,对比分析不同能源转化技术的经济效益与碳减排效果,结果表明:所提集成系统能够显著优化能源结构,实现多能协同低碳经济运行;相比传统综合能源系统,经济性成本减少了7.5×10^(5)元(19.5%),环保性成本减少了5.0×10^(5)元(11.5%)。展开更多
文摘Light-driven CO_(2) reduction reaction(CO_(2)RR)to value-added ethylene(C2H4)holds significant promise for addressing energy and environmental challenges.While the high energy barriers for*CO intermediates hydrogenation and C–C coupling limit the C_(2)H_(4)generation.Herein,CuxP/g-C_(3)N_(4) heterojunction prepared by an in-situ phosphating technique,achieved collaborative photocatalytic CO_(2) and H2O,producing CO and C_(2)H_(4)as the main products.Notably,the selectivity of C_(2)H_(4)produced by CuxP/g-C_(3)N_(4) attained to 64.25%,which was 9.85 times that of CuxP(6.52%).Detailed time-resolution photoluminescence spectra,femtosecond transient absorption spectroscopy tests and density functional theory(DFT)calculation validate the ultra-fast interfacial electron transfer mechanism in CuxP/g-C_(3)N_(4) heterojunction.Successive*H on P sites caused by adsorbed H2O splitting with moderate hydrogenation ability enables the multi-step hydrogenation during CO_(2)RR process over CuxP/g-C_(3)N_(4).With the aid of mediated asymmetric Cu and P dual sites by g-C_(3)N_(4) nanosheet,the produced*CHO shows an energetically favorable for C–C coupling.The coupling formed*CHOCHO further accepts photoexcited efficient e–and*H to deeply produce C_(2)H_(4)according to the C^(2+)intermediates,which has been detected by in-situ diffuse reflectance infrared Fourier transform spectroscopy and interpreted by DFT calculation.The novel insight mechanism offers an essential understanding for the development of CuxP-based heterojunctions for photocatalytic CO_(2) to C^(2+)value-added fuels.
文摘将随机游走法和层次法相结合,采用层次化随机游走法对静态P/G网(Power and Ground Networks)进行分析.针对大规模的电路,在通过多层的参数提取和建模得到静态P/G网模型后,运用层次法将P/G网分割,在子网内采用随机游走法,并且在此基础上比较5种加速算法.实验数据表明,改进的双共轭梯度(BCG)随机游走法的计算速度是普通随机游走法的6倍以及是层次法的14倍.新方法有效地节省了计算时间,有益于对P/G网的研究.
文摘Constructing step-scheme(S-scheme)heterojunctions can considerably facilitate separation and transfer of photocarriers,as well as promote strong redox ability.The interface resistance of heterojunctions immediately affects photocarrier separation and determines the photocatalytic activity.Herein,we constructed a novel Bi OBr/Ni_(2)P/g-C_(3)N_(4) heterojunction using Ni_(2)P as a novel electron bridge to reduce the interfacial resistance of photocarriers between Bi OBr and g-C3N4.The as-prepared 10% BiOBr/Ni2P/g-C_(3)N_(4) sample exhibited outstanding visible-light photocatalytic performance for methyl orange and rhodamine B removal,with degradation efficiencies of 91.4% and 98.9%,respectively.The excellent photocatalytic activity of Bi OBr/Ni_(2)P/g-C_(3)N_(4) was mainly attributed to the synergistic effects of the Ni2P cocatalyst and S-scheme heterojunction,which not only reduced the interface resistance but also retained the strong redox potential of the photocarriers.In addition,the formation of the S-scheme system was supported by active oxygen species investigation,current-voltage curves,and density functional theory calculations.This work provides a guideline for the design of highly efficient S-scheme photocatalysts with transition metal phosphates as electron bridges to improve photocarriers separation.
基金the Ph.D Programs Foundation of Ministry of Education of China (No. 20060335065)the Natural Science Foundation of Zhejiang Province, China (No. Y106513)
文摘Power integrity (PI) has become a limiting factor for the chip's overall performance, and how to place in-package decoupling capacitors to improve a chip's PI performance has become a hot issue. In this paper, we propose an improved trans- mission matrix method (TMM) for fast decoupling capacitance allocation. An irregular grid partition mechanism is proposed, which helps speed up the impedance computation and complies better with the irregular power/ground (P/G) plane or planes with many vias and decoupling capacitors. Furthermore, we also ameliorate the computation procedure of the impedance matrix whenever decoupling capacitors are inserted or removed at specific ports. With the fast computation of impedance change, in-package decoupling capacitor allocation is done with an efficient change based method in the frequency domain. Experimental results show that our approach can gain about 5× speedup compared with a general TMM, and is efficient in restraining the noise on the P/G plane.
文摘针对传统综合能源系统存在的能源产物种类单一、污染气体排放量高以及经济性差等问题,提出一种集成电转氢(power to hydrogen,P2H)、氢转气(hydrogen to gas,H2G)、氢转氨(hydrogen to ammonia,H2A)等电力多元转换(power to X,P2X)技术的电热联供综合能源系统构型。首先,在系统模型方面,通过引入碳捕集、利用与封存(carbon capture,utilization and storage,CCUS)与火电机组富氧/掺氨燃烧等技术,构建电转氢/气/氨(power to hydrogen/gas/ammonia,P2H/G/A)耦合系统;其次,在电力系统低碳经济转型方面,构建综合考虑富氧燃烧-H2G耦合模型碳减排、增加供热经济收益效果以及H2A-掺氨燃烧耦合模型降低煤耗成本和燃煤碳排放效果的综合能源系统目标函数;最后,基于内蒙古某示范基地构建算例,对比分析不同能源转化技术的经济效益与碳减排效果,结果表明:所提集成系统能够显著优化能源结构,实现多能协同低碳经济运行;相比传统综合能源系统,经济性成本减少了7.5×10^(5)元(19.5%),环保性成本减少了5.0×10^(5)元(11.5%)。
