The terahertz （THz） spectrum absorptions of nematic liquid crystal （LC） material, i.e. N-（p-methoxybenzylidene）- p-butylaniline （MBBA）, and its relevant compounds are simulated in this paper by using the densi...The terahertz （THz） spectrum absorptions of nematic liquid crystal （LC） material, i.e. N-（p-methoxybenzylidene）- p-butylaniline （MBBA）, and its relevant compounds are simulated in this paper by using the density functional theory （DFT） method. A strong absorptive frequency is located at 3.65THz for the MBBA, which is in agreement with experimental data found in the literature. The result suggests that the DFT method is effective for dealing with the anisotropic nematic LC compounds.展开更多
Six samples of linear high randomness 60PHB/ PET thermotropic liquid crystal copolyesters are made by melt copolymerization at 290℃ , whose randomness about 0.955 is measured by the discernible ’H-NMR spectrometer. ...Six samples of linear high randomness 60PHB/ PET thermotropic liquid crystal copolyesters are made by melt copolymerization at 290℃ , whose randomness about 0.955 is measured by the discernible ’H-NMR spectrometer. High tenacity, high module fiber is prepared by melt spinning in liquid crystal phase. The effect of molecular weight, shear rate, temperature as well as spinning drawn ratio on the mechanical behavior of 60PHB / PET copolyester fiber are shown that, lower shear rate (2<sup> </sup>10 s<sup>-1</sup>), higher temperature melting （300℃ ）, lower temperature spinning （280℃ ） and higher molecular weight are favourable to the increase of the fiber mechanical properties. With the variance of drawn ratio, fiber mechanical property has a transition point due to traversion from shear-orientation to drawn-orientation. The copolyester fiber has high crystallinity, high orientation at the crystalline region, high chain orientation and high regular fibrillar structure.展开更多
用 X 射线衍射仪法、广角 X 射线行射照相法,同时借助 DSC、偏光显微镜,对 PET/PHB 液晶共聚酯摩尔比为40/60体系在液晶温区中的结构作了研究。结果表明,270℃开始出现向列型液晶;280℃～300℃温区中 PHB 微晶已完全熔融,向列型液晶的...用 X 射线衍射仪法、广角 X 射线行射照相法,同时借助 DSC、偏光显微镜,对 PET/PHB 液晶共聚酯摩尔比为40/60体系在液晶温区中的结构作了研究。结果表明,270℃开始出现向列型液晶;280℃～300℃温区中 PHB 微晶已完全熔融,向列型液晶的局部有序区尚未产生物理形态分离,此时的取向度最高,是纺丝的较理想的温区。该体系在熔体中的 PET 以液晶的局部有序微区的介质形式存在,与液晶微区有一定的相互作用,其结构有序性与纯 PET 无定形有所不同。展开更多
针对像素电极与公共电极换位(P-ITO and C-ITO Interchanged,PCI)结构薄膜晶体管液晶显示器(Thin Film Transistor-Liquid Crystal Display,TFT-LCD)产品中出现的一种竖Mura,结合生产工艺的实际情况,本文运用关键尺寸(Critical Dimensio...针对像素电极与公共电极换位(P-ITO and C-ITO Interchanged,PCI)结构薄膜晶体管液晶显示器(Thin Film Transistor-Liquid Crystal Display,TFT-LCD)产品中出现的一种竖Mura,结合生产工艺的实际情况,本文运用关键尺寸(Critical Dimension,CD)、EPM(Electrical Properties Measurement)、SEM(Scanning Electron Microscope,扫描电子显微镜)等检测设备,进行了大量的实验测试、数据处理和理论分析工作。通过测量Cell Gap、膜厚、CD、Overlay等特性参数,进行产品设计对比、光效模拟和Lens恶化实验,发现该不良与PCI结构的特殊性有关。其产生的根本原因是不良区域内两层ITO之间左右非交叠区域CD差异造成电场分布异常导致液晶偏转角度异常,最终导致屏幕亮暗不均。通过改变ITO对位方式提高两层ITO之间左右非交叠区域的均一性,有效地降低了不良的发生率(从26%下降到0.1%以内)。展开更多
In this paper,the sequence distribution in the copolyester made from polyethyleneterephthalate （PET） and p-hydroxybenzoic acid （PHB） at 290℃has been investigated by 400MHz <sup>1</sup>H-NMR.It has bee...In this paper,the sequence distribution in the copolyester made from polyethyleneterephthalate （PET） and p-hydroxybenzoic acid （PHB） at 290℃has been investigated by 400MHz <sup>1</sup>H-NMR.It has been found that reference factor m of PET/PHB copo!yester linearly de-creases when PHB molar fraction increases.In addition,a series of sequence structure parameters,such as PET,PHB segment mean length,randomness,etc.are calculated from a probability modelby m,X<sub>PHB</sub>%.This copolyester made at 290℃ is found to be nearer to that of completely randomcopolymer compared with that of the eopolyester made at 270℃,as in the case of the generalcopolycondensation.PHB-rich phase is formed only when PHB per number≥4,basing on thisconclusion,we establish the relationship between theoretical contents of PHB-rich phaseW<sub>PHB</sub>% and PHB contents X<sub>PHB</sub>% :W<sub>PHB</sub>%=104.0X<sub>PHB</sub><sup>4.40</sup> The minimum PHB-rich phase con-tent forming liquid crystal phase is 1.1% wt.展开更多
Splendidly colored lyotropic liquid crystals formed in the ternary system of a novel cationic surfactant, 3-p-nonylphenoxy-2-hydroxypropyl trimethyl ammonium bromide (NPTAB)-n-butanol-water system, had been ob-served ...Splendidly colored lyotropic liquid crystals formed in the ternary system of a novel cationic surfactant, 3-p-nonylphenoxy-2-hydroxypropyl trimethyl ammonium bromide (NPTAB)-n-butanol-water system, had been ob-served under polarized light microscope. Small-angle X-ray scattering (SAXS), 2H (deuterium) quadrupolar splitting (2H NMR) were employed to confirm the structures of these liq-uid crystals. The structural transformation of these special lyotropic liquid crystals had been confirmed by differential scanning calorimetry (DSC). The influences of liquid crystal film thickness, temperature and conserving time on the color of liquid crystals have been investigated. It is also theoreti-cally discussed for forming and changing of liquid crystal color.展开更多
文摘The terahertz （THz） spectrum absorptions of nematic liquid crystal （LC） material, i.e. N-（p-methoxybenzylidene）- p-butylaniline （MBBA）, and its relevant compounds are simulated in this paper by using the density functional theory （DFT） method. A strong absorptive frequency is located at 3.65THz for the MBBA, which is in agreement with experimental data found in the literature. The result suggests that the DFT method is effective for dealing with the anisotropic nematic LC compounds.
文摘Six samples of linear high randomness 60PHB/ PET thermotropic liquid crystal copolyesters are made by melt copolymerization at 290℃ , whose randomness about 0.955 is measured by the discernible ’H-NMR spectrometer. High tenacity, high module fiber is prepared by melt spinning in liquid crystal phase. The effect of molecular weight, shear rate, temperature as well as spinning drawn ratio on the mechanical behavior of 60PHB / PET copolyester fiber are shown that, lower shear rate (2<sup> </sup>10 s<sup>-1</sup>), higher temperature melting （300℃ ）, lower temperature spinning （280℃ ） and higher molecular weight are favourable to the increase of the fiber mechanical properties. With the variance of drawn ratio, fiber mechanical property has a transition point due to traversion from shear-orientation to drawn-orientation. The copolyester fiber has high crystallinity, high orientation at the crystalline region, high chain orientation and high regular fibrillar structure.
文摘用 X 射线衍射仪法、广角 X 射线行射照相法,同时借助 DSC、偏光显微镜,对 PET/PHB 液晶共聚酯摩尔比为40/60体系在液晶温区中的结构作了研究。结果表明,270℃开始出现向列型液晶;280℃～300℃温区中 PHB 微晶已完全熔融,向列型液晶的局部有序区尚未产生物理形态分离,此时的取向度最高,是纺丝的较理想的温区。该体系在熔体中的 PET 以液晶的局部有序微区的介质形式存在,与液晶微区有一定的相互作用,其结构有序性与纯 PET 无定形有所不同。
文摘针对像素电极与公共电极换位(P-ITO and C-ITO Interchanged,PCI)结构薄膜晶体管液晶显示器(Thin Film Transistor-Liquid Crystal Display,TFT-LCD)产品中出现的一种竖Mura,结合生产工艺的实际情况,本文运用关键尺寸(Critical Dimension,CD)、EPM(Electrical Properties Measurement)、SEM(Scanning Electron Microscope,扫描电子显微镜)等检测设备,进行了大量的实验测试、数据处理和理论分析工作。通过测量Cell Gap、膜厚、CD、Overlay等特性参数,进行产品设计对比、光效模拟和Lens恶化实验,发现该不良与PCI结构的特殊性有关。其产生的根本原因是不良区域内两层ITO之间左右非交叠区域CD差异造成电场分布异常导致液晶偏转角度异常,最终导致屏幕亮暗不均。通过改变ITO对位方式提高两层ITO之间左右非交叠区域的均一性,有效地降低了不良的发生率(从26%下降到0.1%以内)。
文摘In this paper,the sequence distribution in the copolyester made from polyethyleneterephthalate （PET） and p-hydroxybenzoic acid （PHB） at 290℃has been investigated by 400MHz <sup>1</sup>H-NMR.It has been found that reference factor m of PET/PHB copo!yester linearly de-creases when PHB molar fraction increases.In addition,a series of sequence structure parameters,such as PET,PHB segment mean length,randomness,etc.are calculated from a probability modelby m,X<sub>PHB</sub>%.This copolyester made at 290℃ is found to be nearer to that of completely randomcopolymer compared with that of the eopolyester made at 270℃,as in the case of the generalcopolycondensation.PHB-rich phase is formed only when PHB per number≥4,basing on thisconclusion,we establish the relationship between theoretical contents of PHB-rich phaseW<sub>PHB</sub>% and PHB contents X<sub>PHB</sub>% :W<sub>PHB</sub>%=104.0X<sub>PHB</sub><sup>4.40</sup> The minimum PHB-rich phase con-tent forming liquid crystal phase is 1.1% wt.
基金This work was supported by the National Natural Science Foundation of China(Grant No.30370945)the Science Research Developed Foundation of Liaocheng University.
文摘Splendidly colored lyotropic liquid crystals formed in the ternary system of a novel cationic surfactant, 3-p-nonylphenoxy-2-hydroxypropyl trimethyl ammonium bromide (NPTAB)-n-butanol-water system, had been ob-served under polarized light microscope. Small-angle X-ray scattering (SAXS), 2H (deuterium) quadrupolar splitting (2H NMR) were employed to confirm the structures of these liq-uid crystals. The structural transformation of these special lyotropic liquid crystals had been confirmed by differential scanning calorimetry (DSC). The influences of liquid crystal film thickness, temperature and conserving time on the color of liquid crystals have been investigated. It is also theoreti-cally discussed for forming and changing of liquid crystal color.
