Through the study of the oxidized zone of the Debao skarn-type Cu-Sn deposit in Guangxi, the authorshave found 14 arsenate minerals, most of which are for the first time reported in China. They are mainly Cuarsenate m...Through the study of the oxidized zone of the Debao skarn-type Cu-Sn deposit in Guangxi, the authorshave found 14 arsenate minerals, most of which are for the first time reported in China. They are mainly Cuarsenate minerals with subordinate Cu-Pb arsenate minerals and minor Fe-Pb-Ba varieties. Based on their paragenesis these minerals may be divided into the following series: (1) the clinoclasite-olivenite-cornwallite- cornubite- debaoite- copper silicarsenate association, (2) the scorodite- carminite- beudan-tite-bayldonite- duftite association, and (3) the scorodite-Ba-bearing pharmacosiderite- dussertite association. Arsenate minerals are formed generally in the oxidized zone of the sulfide-type deposits which lie in thewarm, humid and rainy torrid-subtropical zone with pH=6-8 and contain large amounts of arsenopyrite andcarbonate rocks.展开更多
According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely...According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely, intenselyoxidized, weakly-oxidized, redox and unoxidized primary subzones. The elemental geochemical characteristics of the four subzones have been studied in detail, and the results show that U, together with other elements such as Re, Mo, Se, Sr, S, REE, Corganic etc., is enriched in the redox subzone. Re and U have similar geochemical properties in the reductionoxidation process. The geochemical properties of Mo and Se are similar to those of U in the reduction condition, but different from those of U in the oxidation condition. It is proposed that the ore-hosting layers can provide a curtain mount of uranium for uranium mineralization.展开更多
In the creep fatigue crack growth of GH4169 alloy,oxidation is a prominent damage source,which is mainly manifested as the oxidation damage zone in front of crack tip.In order to investigate the property of the oxidat...In the creep fatigue crack growth of GH4169 alloy,oxidation is a prominent damage source,which is mainly manifested as the oxidation damage zone in front of crack tip.In order to investigate the property of the oxidation damage zone formed in the creep fatigue crack growth,crack growth tests of directly aged GH4169 alloy were conducted at 650℃ in air under various load conditions.Interrupted tests were performed to observe the damage characteristics at crack tip.Block tests were systematically executed to quantify the dependency of oxidation damage zone size on load and holding time.The crack propagation of the GH4169 alloy has a close relationship with grain boundary oxidation at 650℃.An oxidation damage zone in front of crack tip includes intergranular microcracks and oxidised but uncracked grain boundaries.Its size has been calculated from transient crack growth rate and described as a function of maximum stress intensity factor and holding time.Based on oxidation damage zone size,a novel model has been developed to predict the creep fatigue crack growth rate of the GH4169 alloy at 650℃.展开更多
The Sain Us gold deposit is a typical auriferous sulphide quartz vein deposit in the InnerMongolian arid steppe climatic region. The oxidation zone has been controlled by the arid cli-mate since the beginning of the H...The Sain Us gold deposit is a typical auriferous sulphide quartz vein deposit in the InnerMongolian arid steppe climatic region. The oxidation zone has been controlled by the arid cli-mate since the beginning of the Holocene. Gold supergene evolution is characterized by enlarge-ment of gold grains, complication of the gold form, raising of the gold grade and increase of thegold fineness; besides, gold and silver have two enrichment peaks at the same depth, which is insharp contrast to the unimodal enrichment of gold and silver and the occurrence of gold aboveand silver below in a humid climatic region. Sun pumping is the main cause for the bimodalenrichment of gold and silver. Illite 2 M_1 is one of the main causes for the upper enrichment peakof gold and silver.展开更多
On the basis of heat transfer and chemical kinetics theory, both connections coal self ignite with oxygen concentration and range of oxidation zone with air leak intensity are analyzed, and calculating method is deduc...On the basis of heat transfer and chemical kinetics theory, both connections coal self ignite with oxygen concentration and range of oxidation zone with air leak intensity are analyzed, and calculating method is deduced to gain the lower limit of oxygen concentration and the range of oxidation zone. The change rule of correlative parameter is quantitatively researched between before nitrogen injection and after nitrogen injection in gob, such as oxygen concentration, oxidation zone width, etc. According to theoretical calculation, the relation position and flow of nitrogen injection with oxidation zone width is conformed, and computational formulas of the best flow and position of nitrogen injection are obtained. It offers a theoretic criterion for preventing and controlling float coal self ignite by nitrogen injection in gob.展开更多
In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the mi...In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the microstructural deterioration of 9Cr ferritic/martensitic(F/M)steel under thermal aging at 550℃for 2,000,10,000,or 20,000 h and its effect on oxidation corrosion in an LBE environment using multiscale characterization techniques.The results indicated that the thickness of the internal oxidation zone(IOZ)increased significantly with extended thermal aging,whereas that of the spinel layer remained relatively constant.The abundant subgrain boundaries that emerged during extensive thermal aging facil-itated Fe diffusion,and the enlarged Cr-rich M23C6 carbides contributed to the formation of preferential oxidation regions,accelerating IOZ layer growth.The spinel layer formed from the IOZ was influenced by microstructural defects within the IOZ.A theoretical model describing the accelerated oxide layer growth due to thermal aging was developed.These findings support the advancement of LFR technology.展开更多
The oxidation behavior of Ti?22Al?(27?x)Nb?xZr (x=0, 1, 6) alloys at 800 °C for exposure time up to 100 h was examined. It is shown that oxidation rate of experimental alloys obeys the parabolic kinetics. Ti?22Al...The oxidation behavior of Ti?22Al?(27?x)Nb?xZr (x=0, 1, 6) alloys at 800 °C for exposure time up to 100 h was examined. It is shown that oxidation rate of experimental alloys obeys the parabolic kinetics. Ti?22Al?26Nb?1Zr alloy demonstrates more excellent oxidation resistance than the other two alloys. The main oxidation products are TiO2, Al2O3 and AlNbO4 phases for all these alloys. For the Ti?22Al?26Nb?1Zr alloy, Zr addition can modify the growth mechanism of oxide scale, which can effectively hinder the diffusion of oxygen. Whereas, reaction of Zr with oxygen leads to the formation of ZrO2 precipitates for the Ti?22Al?21Nb?6Zr alloy, which promotes the oxygen ingress into the substrate. Meanwhile, oxidation affected zones, including internal-oxidation layer and oxygen-enriched zone, are present beneath the outmost oxide scale. The difference in these zones is derived from the phase constitution in the starting Ti?22Al?(27?x)Nb?xZr (x=0, 1, 6) alloys.展开更多
The source of ground water supply in Dawu is an extremely huge one in Shandong province. Now it is faced with serious pollution of petroleum in Hougao area. Aiming at this problem, the petroleum pollution in aeration ...The source of ground water supply in Dawu is an extremely huge one in Shandong province. Now it is faced with serious pollution of petroleum in Hougao area. Aiming at this problem, the petroleum pollution in aeration zone and in groundwater was analyzed. The result shows that the contaminant of groundwater comes from the leaching of petroleum in the soil horizon of aeration zone through precipitation, and the quick flow of groundwater makes the convection dominate themigration of contaminant. So movement of groundwater controls the distribution of petroleum contaminant, which is consistent with the direction of ground flow. Building a groundwater closure zone in Hougao is an effective method to stop the contaminated groundwater flowing toward the water supply source of Dawu. The petroleum contaminant can be effectively reduced through using the aeration, biological and oxidation technologies.展开更多
文摘Through the study of the oxidized zone of the Debao skarn-type Cu-Sn deposit in Guangxi, the authorshave found 14 arsenate minerals, most of which are for the first time reported in China. They are mainly Cuarsenate minerals with subordinate Cu-Pb arsenate minerals and minor Fe-Pb-Ba varieties. Based on their paragenesis these minerals may be divided into the following series: (1) the clinoclasite-olivenite-cornwallite- cornubite- debaoite- copper silicarsenate association, (2) the scorodite- carminite- beudan-tite-bayldonite- duftite association, and (3) the scorodite-Ba-bearing pharmacosiderite- dussertite association. Arsenate minerals are formed generally in the oxidized zone of the sulfide-type deposits which lie in thewarm, humid and rainy torrid-subtropical zone with pH=6-8 and contain large amounts of arsenopyrite andcarbonate rocks.
文摘According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely, intenselyoxidized, weakly-oxidized, redox and unoxidized primary subzones. The elemental geochemical characteristics of the four subzones have been studied in detail, and the results show that U, together with other elements such as Re, Mo, Se, Sr, S, REE, Corganic etc., is enriched in the redox subzone. Re and U have similar geochemical properties in the reductionoxidation process. The geochemical properties of Mo and Se are similar to those of U in the reduction condition, but different from those of U in the oxidation condition. It is proposed that the ore-hosting layers can provide a curtain mount of uranium for uranium mineralization.
基金supported by the National Key R&D Program of China(No.2022YFF0609300)the National Major Science and Technology Projects of China(J2019-VI-0021-0137).
文摘In the creep fatigue crack growth of GH4169 alloy,oxidation is a prominent damage source,which is mainly manifested as the oxidation damage zone in front of crack tip.In order to investigate the property of the oxidation damage zone formed in the creep fatigue crack growth,crack growth tests of directly aged GH4169 alloy were conducted at 650℃ in air under various load conditions.Interrupted tests were performed to observe the damage characteristics at crack tip.Block tests were systematically executed to quantify the dependency of oxidation damage zone size on load and holding time.The crack propagation of the GH4169 alloy has a close relationship with grain boundary oxidation at 650℃.An oxidation damage zone in front of crack tip includes intergranular microcracks and oxidised but uncracked grain boundaries.Its size has been calculated from transient crack growth rate and described as a function of maximum stress intensity factor and holding time.Based on oxidation damage zone size,a novel model has been developed to predict the creep fatigue crack growth rate of the GH4169 alloy at 650℃.
文摘The Sain Us gold deposit is a typical auriferous sulphide quartz vein deposit in the InnerMongolian arid steppe climatic region. The oxidation zone has been controlled by the arid cli-mate since the beginning of the Holocene. Gold supergene evolution is characterized by enlarge-ment of gold grains, complication of the gold form, raising of the gold grade and increase of thegold fineness; besides, gold and silver have two enrichment peaks at the same depth, which is insharp contrast to the unimodal enrichment of gold and silver and the occurrence of gold aboveand silver below in a humid climatic region. Sun pumping is the main cause for the bimodalenrichment of gold and silver. Illite 2 M_1 is one of the main causes for the upper enrichment peakof gold and silver.
基金NationalNaturalScienceFoundationofChina! (No .5 99740 2 0 )
文摘On the basis of heat transfer and chemical kinetics theory, both connections coal self ignite with oxygen concentration and range of oxidation zone with air leak intensity are analyzed, and calculating method is deduced to gain the lower limit of oxygen concentration and the range of oxidation zone. The change rule of correlative parameter is quantitatively researched between before nitrogen injection and after nitrogen injection in gob, such as oxygen concentration, oxidation zone width, etc. According to theoretical calculation, the relation position and flow of nitrogen injection with oxidation zone width is conformed, and computational formulas of the best flow and position of nitrogen injection are obtained. It offers a theoretic criterion for preventing and controlling float coal self ignite by nitrogen injection in gob.
基金supported by the Natural Science Foundation of Shandong Province with grant No.ZR2023ME196the Science and Technology Support Plan for Young Innovation of Colleges and Universities of Shandong Province with grant No.2022KJ273+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences with grant No.2017486the Patent Navigation Project of Shandong Province with grant No.D202327.
文摘In lead-cooled fast reactor(LFR)systems,the liquid lead-bismuth eutectic(LBE)coolant provides a cor-rosive environment that damages the steel components during high-temperature operation.This study investigated the microstructural deterioration of 9Cr ferritic/martensitic(F/M)steel under thermal aging at 550℃for 2,000,10,000,or 20,000 h and its effect on oxidation corrosion in an LBE environment using multiscale characterization techniques.The results indicated that the thickness of the internal oxidation zone(IOZ)increased significantly with extended thermal aging,whereas that of the spinel layer remained relatively constant.The abundant subgrain boundaries that emerged during extensive thermal aging facil-itated Fe diffusion,and the enlarged Cr-rich M23C6 carbides contributed to the formation of preferential oxidation regions,accelerating IOZ layer growth.The spinel layer formed from the IOZ was influenced by microstructural defects within the IOZ.A theoretical model describing the accelerated oxide layer growth due to thermal aging was developed.These findings support the advancement of LFR technology.
基金Project(2011CB605503)supported by the National Basic Research Program of China
文摘The oxidation behavior of Ti?22Al?(27?x)Nb?xZr (x=0, 1, 6) alloys at 800 °C for exposure time up to 100 h was examined. It is shown that oxidation rate of experimental alloys obeys the parabolic kinetics. Ti?22Al?26Nb?1Zr alloy demonstrates more excellent oxidation resistance than the other two alloys. The main oxidation products are TiO2, Al2O3 and AlNbO4 phases for all these alloys. For the Ti?22Al?26Nb?1Zr alloy, Zr addition can modify the growth mechanism of oxide scale, which can effectively hinder the diffusion of oxygen. Whereas, reaction of Zr with oxygen leads to the formation of ZrO2 precipitates for the Ti?22Al?21Nb?6Zr alloy, which promotes the oxygen ingress into the substrate. Meanwhile, oxidation affected zones, including internal-oxidation layer and oxygen-enriched zone, are present beneath the outmost oxide scale. The difference in these zones is derived from the phase constitution in the starting Ti?22Al?(27?x)Nb?xZr (x=0, 1, 6) alloys.
文摘The source of ground water supply in Dawu is an extremely huge one in Shandong province. Now it is faced with serious pollution of petroleum in Hougao area. Aiming at this problem, the petroleum pollution in aeration zone and in groundwater was analyzed. The result shows that the contaminant of groundwater comes from the leaching of petroleum in the soil horizon of aeration zone through precipitation, and the quick flow of groundwater makes the convection dominate themigration of contaminant. So movement of groundwater controls the distribution of petroleum contaminant, which is consistent with the direction of ground flow. Building a groundwater closure zone in Hougao is an effective method to stop the contaminated groundwater flowing toward the water supply source of Dawu. The petroleum contaminant can be effectively reduced through using the aeration, biological and oxidation technologies.
