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Global transplantation:Lessons from organ transplantation organizations worldwide
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作者 Solonas Symeou Eleni Avramidou +1 位作者 Vassilios Papalois Georgios Tsoulfas 《World Journal of Transplantation》 2025年第1期44-56,共13页
Although national transplant organizations share common visions and goals,the creation of a unified global organization remains impractical.Differences in ethnicity,culture,religion,and education shape local practices... Although national transplant organizations share common visions and goals,the creation of a unified global organization remains impractical.Differences in ethnicity,culture,religion,and education shape local practices and infrastructure,making the establishment of a single global entity unfeasible.Even with these social disparities aside,logistical factors such as time and distance between organ procurement and transplantation sites pose significant challenges.While technological advancements have extended organ preservation times,they have yet to support the demands of transcontinental transplantations effectively.This review presents a comparative analysis of the structures,operational frameworks,policies,and legislation governing various transplant organizations around the world.Key differences pertain to the administration of these organizations,trends in organ donation,and organ allocation policies,which reflect the financial,cultural,and religious diversity across different regions.While a global transplant organization may be out of reach,agreeing on best practices for the benefit of patients is essential. 展开更多
关键词 organ transplantation National transplant organizations organ donation Global transplantation Transplant systems
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PDINN sandwiched silver nanowires for solution-processed semitransparent organic photovoltaics with over 4%light utilization efficiency and nearly 100%bifaciality factor
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作者 Junjie Wu Menghua Cao +4 位作者 Xin Liu Rihong Zhu Jie Zhou Jiangsheng Yu Gang Li 《Journal of Energy Chemistry》 2025年第5期1-9,共9页
Semitransparent organic photovoltaics(ST-OPVs)for building integration represent a pivotal direction in the development of photovoltaic industry.Solution-processed silver nanowires(AgNWs)are considered promising candi... Semitransparent organic photovoltaics(ST-OPVs)for building integration represent a pivotal direction in the development of photovoltaic industry.Solution-processed silver nanowires(AgNWs)are considered promising candidates for transparent electrodes in semitransparent devices due to their high transparency-conductivity-efficiency merit,large-scale processability,and low cost.In this work,we develop two solution-processed organic–inorganic hybrid electrodes,named AgNWs-PD and AgNWsPC,utilizing AgNWs as the conductive framework and aliphatic amine-functionalized perylene-diimide(PDINN)as the sandwiched material,while AgNWs-PC exhibits significantly improved electrical conductivity and enhanced contact area with the underlying electron transport layer.The optimized device achieves a power conversion efficiency of 9.45%with an open circuit voltage of 0.846 V,a high filling factor of 75.4%,and an average visible transmittance(AVT)of 44.0%,delivering an outstanding light utilization efficiency(LUE)of 4.16%,which is the highest reported value for all solution-processed ST-OPVs.In addition,by coupling a 30-nm tellurium dioxide atop AgNWs-PC,the bifaciality factor of derivative devices improves from 73.7%to 99.4%,while maintaining a high bifacial LUE over 3.7%.Our results emphasize the superiority and effectiveness of PDINN-sandwiched AgNWs electrodes for highperformance and all solution-processed ST-OPVs. 展开更多
关键词 Semitransparent organic photovoltaics Solution-processed Silver nanowire electrode Conventional structure Light utilization efficiency Bifaciality factor
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Impact of classification granularity on interdisciplinary performance assessment of research institutes and organizations
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作者 Jiandong Zhang Sonia Gruber Rainer Frietsch 《Journal of Data and Information Science》 2025年第2期61-79,共19页
Purpose:Interdisciplinary research has become a critical approach to addressing complex societal,economic,technological,and environmental challenges,driving innovation and integrating scientific knowledge.While interd... Purpose:Interdisciplinary research has become a critical approach to addressing complex societal,economic,technological,and environmental challenges,driving innovation and integrating scientific knowledge.While interdisciplinarity indicators are widely used to evaluate research performance,the impact of classification granularity on these assessments remains underexplored.Design/methodology/approach:This study investigates how different levels of classification granularity-macro,meso,and micro-affect the evaluation of interdisciplinarity in research institutes.Using a dataset of 262 institutes from four major German non-university organizations(FHG,HGF,MPG,WGL)from 2018 to 2022,we examine inconsistencies in interdisciplinarity across levels,analyze ranking changes,and explore the influence of institutional fields and research focus(applied vs.basic).Findings:Our findings reveal significant inconsistencies in interdisciplinarity across classification levels,with rankings varying substantially.Notably,the Fraunhofer Society(FHG),which performs well at the macro level,experiences significant ranking declines at meso and micro levels.Normalizing interdisciplinarity by research field confirmed that these declines persist.The research focus of institutes,whether applied,basic,or mixed,does not significantly explain the observed ranking dynamics.Research limitations:This study has only considered the publication-based dimension of institutional interdisciplinarity and has not explored other aspects.Practical implications:The findings provide insights for policymakers,research managers,and scholars to better interpret interdisciplinarity metrics and support interdisciplinary research effectively.Originality/value:This study underscores the critical role of classification granularity in interdisciplinarity assessment and emphasizes the need for standardized approaches to ensure robust and fair evaluations. 展开更多
关键词 Interdisciplinarity Paper-level classification system organization evaluation
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Utilization of Spent Mushroom Substrate and Local Organic Wastes as Sustainable Growth Media for Enhanced Cocoa Seedling Development
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作者 Karupakorn Laeid-on Arunrussamee Sangsila +1 位作者 Worrawat Promden Tepporn Lomarak 《Journal of Environmental & Earth Sciences》 2025年第1期540-549,共10页
This study examines the effects of germination substrates incorporating spent mushroom substrate(SMS)and locally sourced organic materials on the growth and vigor of cocoa seedlings.Seven treatments were evaluated usi... This study examines the effects of germination substrates incorporating spent mushroom substrate(SMS)and locally sourced organic materials on the growth and vigor of cocoa seedlings.Seven treatments were evaluated using a Completely Randomized Design(CRD),comprising combinations of coconut coir,rice husk,sugarcane bagasse,and biochar.Key findings reveal that treatments combining SMS,sugarcane bagasse,and either coconut coir or biochar(T6 and T7)achieved significantly higher survival rates and Dickson Quality Index(DQI)scores compared to conventional soil(T1).These treatments provided favorable chemical properties,including optimal pH,electrical conductivity,and nutrient content(N,P,K),which are critical for cocoa seedling development.The results suggest that using SMS with agricultural waste as an alternative germination medium can reduce cultivation costs,enhance seedling growth,and contribute to sustainable agricultural practices by repurposing organic waste.This approach not only offers cost-effective benefits for farmers but also mitigates environmental impacts associated with waste disposal. 展开更多
关键词 Spent Mushroom Substrate organic Materials Seeding Cocoa
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The Reform Trends and Model Selection of University Scientific Research Organizations in the Post-College Era
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作者 Kuiya Cheng 《Journal of Contemporary Educational Research》 2025年第1期145-150,共6页
In the post-college era,university research organizations are facing unprecedented changes in their structure and operational models.In terms of organizational form,these institutions are transitioning from single-dis... In the post-college era,university research organizations are facing unprecedented changes in their structure and operational models.In terms of organizational form,these institutions are transitioning from single-disciplinebased models to interdisciplinary and multidisciplinary collaboration models.This shift reflects the growing need to address complex,real-world problems that require expertise from multiple fields.From a management perspective,interdisciplinary research organizations face unique challenges.They must coordinate researchers from diverse disciplinary backgrounds,navigate potential conflicts between traditional departments and interdisciplinary units,and address differences in goals and organizational culture among members.These complexities make management more intricate and demanding.Simultaneously,the focus of university research organizations has become increasingly interest-driven,with research objectives,content,and participants reflecting specific areas of interest or societal demand.To adapt to these evolving trends,university research organizations must adopt flexible models tailored to their unique development needs.This approach will ensure the efficient execution of research activities and facilitate the effective transformation of research outcomes into practical applications. 展开更多
关键词 Post-college era University scientific research organization Interdisciplinary research
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Research on the High-Quality Development of Grassroots Teaching Organizations in Universities from the Perspective of Dual-Track Drive:An Analysis Based on the Synergetic Evolution of Institutions and Teachers
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作者 Fan Yu 《Journal of Contemporary Educational Research》 2025年第10期181-189,共9页
The high-quality development of grassroots teaching organizations in universities is crucial to improving the quality of higher education.From the perspective of dual-track drive,this paper deeply analyzes the synerge... The high-quality development of grassroots teaching organizations in universities is crucial to improving the quality of higher education.From the perspective of dual-track drive,this paper deeply analyzes the synergetic evolution relationship between institutions and teachers in the development of grassroots teaching organizations in universities.At present,the development of grassroots teaching organizations in universities is faced with such dilemmas as lagging institutional supply,insufficient motivation for teachers’development,and lack of synergy mechanisms.These interwoven problems have formed systemic obstacles restricting high-quality development,which urgently need in-depth analysis and resolution.Currently,only from the perspective of synergistic promotion of institutions and teachers and by constructing a systematic implementation framework can the existing problems be effectively solved.Through three dimensions-goal guidance,resource guarantee,and mechanism optimization-this paper refines nine specific measures,aiming to break the barriers between institutional development and teachers’development,form a joint force,provide theoretical support and practical paths for improving the efficiency of grassroots teaching organizations,promote the overall improvement of education and teaching quality,enhance the quality of talent training in universities,and advance the in-depth development of education and teaching reform. 展开更多
关键词 Dual-track drive Grassroots teaching organizations in universities High-quality development
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Metal extraction and recovery from cathode material of spent lithium-ion batteries utilizing an organic acid reagent scheme
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作者 WU Jia-jia KIM Jaeyeon +1 位作者 AHN Junmo LEE Jaeheon 《Journal of Central South University》 2025年第9期3645-3656,共12页
This study focuses on using a green reagent scheme of methanesulfonic acid (MSA) and citric acid (CA) to extract valuable metals from the cathodes, aiming to minimize environmental impact during the recycling process.... This study focuses on using a green reagent scheme of methanesulfonic acid (MSA) and citric acid (CA) to extract valuable metals from the cathodes, aiming to minimize environmental impact during the recycling process. Leaching studies on LiCoO_(2) identified optimal conditions as follows: 2.4 mol/L MSA, 1.6 mol/L CA, S/L ratio of 80 g/L, leaching temperature of 90oC and leaching time of 6 h. The maximum Co and Li extraction achieved was 92% and 85%, respectively. LiCoO_(2) dissolution in MSA-CA leaching solution is highly impacted by temperature;Avrami equation showed a good fitting for the leaching data. The experimental activation energy of Co and Li was 50.98 kJ/mol and 50.55 kJ/mol, respectively, indicating that it is a chemical reaction-controlled process. Furthermore, cobalt was efficiently recovered from the leachate using oxalic acid, achieving a precipitation efficiency of 99.91% and a high-purity cobalt oxalate product (99.85 wt.%). In the MSA-CA leaching solution, MSA served as a lixiviant, while CA played a key role in reducing Co in LiCoO_(2). The overall organic acid leaching methodology presents an attractive option due to its reduced environmental impact. 展开更多
关键词 methanesulfonic acid citric acid cathode material leaching organic acid reagent scheme
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Estimation of Soil Organic Carbon Stocks Utilizing Machine Learning Algorithms and Multi-source Geospatial Data in Coastal Wetlands of Tianjin and Hebei,China
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作者 YANG Rui LIU Mingyue +10 位作者 ZHANG Yongbin MAN Weidong TONG Jingfen LIU Dong ZHANG Qingwen KOU Caiyao LI Xiang LIU Yahui TIAN Di YIN Xuan HE Jiannan 《Chinese Geographical Science》 2025年第4期707-721,I0003,共16页
Coastal wetlands are crucial for the‘blue carbon sink’,significantly contributing to regulating climate change.This study util-ized 160 soil samples,35 remote sensing features,and 5 geo-climatic data to accurately e... Coastal wetlands are crucial for the‘blue carbon sink’,significantly contributing to regulating climate change.This study util-ized 160 soil samples,35 remote sensing features,and 5 geo-climatic data to accurately estimate the soil organic carbon stocks(SOCS)in the coastal wetlands of Tianjin and Hebei,China.To reduce data redundancy,simplify model complexity,and improve model inter-pretability,Pearson correlation analysis(PsCA),Boruta,and recursive feature elimination(RFE)were employed to optimize features.Combined with the optimized features,the soil organic carbon density(SOCD)prediction model was constructed by using multivariate adaptive regression splines(MARS),extreme gradient boosting(XGBoost),and random forest(RF)algorithms and applied to predict the spatial distribution of SOCD and estimate the SOCS of different wetland types in 2020.The results show that:1)different feature combinations have a significant influence on the model performance.Better prediction performance was attained by building a model using RFE-based feature combinations.RF has the best prediction accuracy(R^(2)=0.587,RMSE=0.798 kg/m^(2),MAE=0.660 kg/m^(2)).2)Optical features are more important than radar and geo-climatic features in the MARS,XGBoost,and RF algorithms.3)The size of SOCS is related to SOCD and the area of each wetland type,aquaculture pond has the highest SOCS,followed by marsh,salt pan,mud-flat,and sand shore. 展开更多
关键词 soil organic carbon stocks(SOCS) soil organic carbon density(SOCD) multivariate adaptive regression spline(MARS) extreme gradient boosting(XGBoost) random forest(RF) residual kriging(RK) feature optimization coastal wetlands Tianjin and Hebei China
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Attention Markets of Blockchain-Based Decentralized Autonomous Organizations 被引量:1
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作者 Juanjuan Li Rui Qin +3 位作者 Sangtian Guan Wenwen Ding Fei Lin Fei-Yue Wang 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第6期1370-1380,共11页
The attention is a scarce resource in decentralized autonomous organizations(DAOs),as their self-governance relies heavily on the attention-intensive decision-making process of“proposal and voting”.To prevent the ne... The attention is a scarce resource in decentralized autonomous organizations(DAOs),as their self-governance relies heavily on the attention-intensive decision-making process of“proposal and voting”.To prevent the negative effects of pro-posers’attention-capturing strategies that contribute to the“tragedy of the commons”and ensure an efficient distribution of attention among multiple proposals,it is necessary to establish a market-driven allocation scheme for DAOs’attention.First,the Harberger tax-based attention markets are designed to facilitate its allocation via continuous and automated trading,where the individualized Harberger tax rate(HTR)determined by the pro-posers’reputation is adopted.Then,the Stackelberg game model is formulated in these markets,casting attention to owners in the role of leaders and other competitive proposers as followers.Its equilibrium trading strategies are also discussed to unravel the intricate dynamics of attention pricing.Moreover,utilizing the single-round Stackelberg game as an illustrative example,the existence of Nash equilibrium trading strategies is demonstrated.Finally,the impact of individualized HTR on trading strategies is investigated,and results suggest that it has a negative correlation with leaders’self-accessed prices and ownership duration,but its effect on their revenues varies under different conditions.This study is expected to provide valuable insights into leveraging attention resources to improve DAOs’governance and decision-making process. 展开更多
关键词 ATTENTION decentralized autonomous organizations Harberger tax Stackelberg game.
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Utilizing GIS in Nonprofit Organizations for Urban Planning Applications: Experiences from the Field 被引量:3
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作者 Kheir Al-Kodmany 《Journal of Geographic Information System》 2012年第4期279-297,共19页
This paper provides detailed examinations on the use of GIS in nonprofit organizations. We interviewed planners and GIS experts in key nonprofit organizations in the City of Chicago to comprehend their actual usages o... This paper provides detailed examinations on the use of GIS in nonprofit organizations. We interviewed planners and GIS experts in key nonprofit organizations in the City of Chicago to comprehend their actual usages of GIS, faced challenges, and accumulated experiences. Organizations reported on dozens of projects where GIS was used for practical urban planning applications. Findings indicate that nonprofit organizations offer extremely useful lessons on using GIS for projects at the local, regional, and national levels. They provide extensive experiences on GIS technical problems and solutions, methodologies, and data issues. Their projects often support philanthropic efforts and respond to the needs of low-income communities. However, the organizations’ resources are dwindling. This paper raises a concern about the importance of sustaining their GIS operations particularly with the current economic downturn. We call on government officials to support nonprofit organizations in order to ensure the continuity of their GIS activities. 展开更多
关键词 CHALLENGES BENEFITS NONPROFIT organizations GIS STORIES
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Multilevel analysis of the central-peripheral-target organ pathway:contributing to recovery after peripheral nerve injury 被引量:1
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作者 Xizi Song Ruixin Li +6 位作者 Xiaolei Chu Qi Li Ruihua Li Qingwen Li Kai-Yu Tong Xiaosong Gu Dong Ming 《Neural Regeneration Research》 SCIE CAS 2025年第10期2807-2822,共16页
Peripheral nerve injury is a common neurological condition that often leads to severe functional limitations and disabilities.Research on the pathogenesis of peripheral nerve injury has focused on pathological changes... Peripheral nerve injury is a common neurological condition that often leads to severe functional limitations and disabilities.Research on the pathogenesis of peripheral nerve injury has focused on pathological changes at individual injury sites,neglecting multilevel pathological analysis of the overall nervous system and target organs.This has led to restrictions on current therapeutic approaches.In this paper,we first summarize the potential mechanisms of peripheral nerve injury from a holistic perspective,covering the central nervous system,peripheral nervous system,and target organs.After peripheral nerve injury,the cortical plasticity of the brain is altered due to damage to and regeneration of peripheral nerves;changes such as neuronal apoptosis and axonal demyelination occur in the spinal cord.The nerve will undergo axonal regeneration,activation of Schwann cells,inflammatory response,and vascular system regeneration at the injury site.Corresponding damage to target organs can occur,including skeletal muscle atrophy and sensory receptor disruption.We then provide a brief review of the research advances in therapeutic approaches to peripheral nerve injury.The main current treatments are conducted passively and include physical factor rehabilitation,pharmacological treatments,cell-based therapies,and physical exercise.However,most treatments only partially address the problem and cannot complete the systematic recovery of the entire central nervous system-peripheral nervous system-target organ pathway.Therefore,we should further explore multilevel treatment options that produce effective,long-lasting results,perhaps requiring a combination of passive(traditional)and active(novel)treatment methods to stimulate rehabilitation at the central-peripheral-target organ levels to achieve better functional recovery. 展开更多
关键词 central nervous system central peripheral target organ multilevel pathological analysis nerve regeneration peripheral nerve injury peripheral nervous system target organs therapeutic approach
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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells 被引量:1
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作者 Shuai Xu Youdi Zhang +6 位作者 Yanna Sun Pei Cheng Zhaoyang Yao Ning Li Long Ye Lijian Zuo Ke Gao 《Nano-Micro Letters》 SCIE EI CAS 2025年第2期372-375,共4页
Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network act... Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer deposition.This optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture capability.This approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs. 展开更多
关键词 organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management
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The storage and utilization of carbohydrates in response to elevation mediated by tree organs in subtropical evergreen broad-leaved forests
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作者 Bin Xu Xueli Jiang +4 位作者 Yingying Zong G.Geoff Wang Fusheng Chen Zhenyu Zhao Xiangmin Fang 《Forest Ecosystems》 SCIE CSCD 2024年第1期52-61,共10页
Global climate change can affect tree growth and carbon sink function by influencing plant carbohydrate synthesis and utilization,while elevation can be used as an ideal setting under natural conditions to simulate cl... Global climate change can affect tree growth and carbon sink function by influencing plant carbohydrate synthesis and utilization,while elevation can be used as an ideal setting under natural conditions to simulate climate change effects.The effect of elevation on tree growth may depend on organ type.However,the allocation patterns of nonstructural and structural carbohydrates(NSCs and SCs,respectively)in different tree organs and their response to elevation remain unclear.We selected four dominant tree species,Schima superba,Castanopsis eyrei,Castanopsis fargesii and Michelia maudiae,along an elevation gradient from 609 to 1,207 m in subtropical evergreen broad-leaved forests and analyzed leaf,trunk,and fine root NSCs,carbon(C),nitrogen(N)and phosphorus(P)concentrations and the relative abundance of SCs.Leaf NSCs increased initially and then decreased,and trunk NSCs increased with increasing elevation.However,root NSCs decreased with increasing elevation.The relative abundance of SCs in leaves and trunks decreased,while the relative abundance of root SCs increased with increasing elevation.No significant correlations between SCs and NSCs in leaves were detected,while there were negative correlations between SCs and NSCs in trunks,roots,and all organs.Hierarchical partitioning analysis indicated that plant C/N and C/P were the main predictors of changes in SCs and NSCs.Our results suggest that tree organs have divergent responses to elevation and that increasing elevation will inhibit the aboveground part growth and enhance the root growth of trees.A tradeoff between the C distribution used for growth and storage was confirmed along the elevation gradient,which is mainly manifested in the"sink"organs of NSCs.Our results provide insight into tree growth in the context of global climate change scenarios in subtropical forest ecosystems. 展开更多
关键词 Nonstructural carbohydrates Structural carbohydrates ELEVATION Subtropical evergreen broad-leaved forests Tree organs
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New chapter in reform and development of organ donation and transplantation in China: Embracing past, grounding in national conditions, upholding steadfast belief, and looking forward to future 被引量:2
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作者 Hong-Tao Zhao Shu-Sen Zheng +12 位作者 Jia Fan Jia-Hong Dong Zhong-Hua Chen Wu-Jun Xue Qi-Fa Ye Hai-Bo Wang Jing-Yu Chen Zhe Zheng Feng Huo Xiao-Shun He Miao Pu Jie Zhao Jie-Fu Huang 《Hepatobiliary & Pancreatic Diseases International》 2025年第1期6-13,共8页
The reform stems from honesty and determination. Since 2005, organ donation and transplantation in China has undergone thorough reform, which complies with legislation requirements and ethical principles established b... The reform stems from honesty and determination. Since 2005, organ donation and transplantation in China has undergone thorough reform, which complies with legislation requirements and ethical principles established by the World Health Organization(WHO). Reform in China has demonstrated the unwavering confidence and utmost determination of the Chinese government and the Chinese transplantation community. The year 2015 marked a historic turning point when voluntary donations from Chinese citizens became the sole legitimate source for organ transplantation. Since 2015, China has gradually established and refined the “Chinese Mode” and “China System” for organ donation and transplantation, fulfilling its political pledge of reform, and has garnered international recognition, and fostered a social culture which promotes organ donation. This article reviewed the history of reform on organ donation and transplantation in China, presented a new pattern of establishment of organ donation system in the new era of the country, and the direction of advances in the future. 展开更多
关键词 Reform LEGISLATION organ donation organ transplantation Chinese mode High quality development
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Synthesis,structures,and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid 被引量:1
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作者 HOU Jimin LI Mengyang +4 位作者 GONG Chunhua ZHANG Shaozhuang ZHAN Caihong XU Hao XIE Jingli 《无机化学学报》 北大核心 2025年第3期549-560,共12页
(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under... (2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4. 展开更多
关键词 bipyridyl ligands metal⁃organic frameworks photocatalytic degradation Knoevenagel condensation
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Humic-like components in dissolved organic matter inhibit cadmium sequestration by sediment 被引量:3
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作者 Bolin Li Zhongwu Li +3 位作者 Jia Chen Changsheng Jin Weicheng Cao Bo Peng 《Journal of Environmental Sciences》 2025年第4期645-656,共12页
China’s lakes are plagued by cadmium(Cd)pollution.Dissolved organic matter(DOM)significantly regulates Cd(II)transport properties at the sediment-water interface.Understanding the effects of different DOM components ... China’s lakes are plagued by cadmium(Cd)pollution.Dissolved organic matter(DOM)significantly regulates Cd(II)transport properties at the sediment-water interface.Understanding the effects of different DOM components on the transportation properties of Cd(II)at the sediment-water interface is essential.In this study,typical DOM from different sources was selected to study Cd(II)mobility at the sediment-water interface.Results showed that terrestrial-derived DOM(fulvic acids,FA)and autochthonous-derived DOM(α-amylase,B1)inhibit Cd(II)sequestration by sediments(42.5%and 5.8%,respectively),while anthropogenic-derived DOM(sodium dodecyl benzene sulfonate,SDBS)increased the Cd(II)adsorption capacity by sediments by 2.8%.Fluorescence quenching coupling with parallel factor analysis(EEM-PARAFAC)was used to characterize different DOM components.The results showed that FA contains three kinds of components(C1,C3:protein-like components,C2:humic-like components);SDBS contains two kinds of components(C1,C2:protein-like components);B1 contains three kinds of components(C1,C2:protein-like components,C3:humic-like components).Three complex reaction modelswere used to characterize the ability of Cd(II)complex with DOM,and it was found that the humic-like component could hardly be complex with Cd(II).Accordingly,humic-like components compete for Cd(II)adsorption sites on the sediment surface and inhibit Cd(II)adsorption fromsediments.Fourier transform infrared spectroscopy(FTIR)of the sediment surface before and after Cd(II)addition was analyzed and proved the competitive adsorption theory.This study provides a better understanding of the Cd(II)mobilization behavior at the sediment-water interface and indicates that the input of humic-like DOM will increase the bioavailability of Cd. 展开更多
关键词 Dissolved organic matter Cadmium Sediments EEM-PARAFAC Adsorption
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Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance 被引量:1
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作者 ZHAI Haoying WEN Lanzong +3 位作者 LIAO Wenjie LI Qin ZHOU Wenjun CAO Kun 《无机化学学报》 北大核心 2025年第5期1037-1048,共12页
Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nano... Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nanorods,which had many voids.The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction(OER)performance with a low overpotential of 273 mV at 10 mA·cm^(-2)and a small Tafel slope of 36 mV·dec^(-1)in 1 mol·L^(-1)KOH.The potential remained at 1.48 V(vs RHE)at 10 mA·cm^(-2)under continuous testing for 15 h,implying that S-FeCoTA had good stability.The Faraday efficiency of S-FeCoTA was 94%.The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S,Fe,and Co,thus promoting electron transfer,reducing the reaction kinetic barrier,and enhancing the OER performance. 展开更多
关键词 hydrothermal method tannic acid metal‑organic framework ELECTROCATALYSIS oxygen evolution reaction
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How Software Engineering Transforms Organizations: An Open and Qualitative Study on the Organizational Objectives and Motivations in Agile Transformations
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作者 Alonso Alvarez Borja Bordel Sánchez 《Computers, Materials & Continua》 SCIE EI 2024年第11期2935-2966,共32页
Agile Transformations are challenging processes for organizations that look to extend the benefits of Agile philosophy and methods beyond software engineering.Despite the impact of these transformations on orga-nizati... Agile Transformations are challenging processes for organizations that look to extend the benefits of Agile philosophy and methods beyond software engineering.Despite the impact of these transformations on orga-nizations,they have not been extensively studied in academia.We conducted a study grounded in workshops and interviews with 99 participants from 30 organizations,including organizations undergoing transformations(“final organizations”)and companies supporting these processes(“consultants”).The study aims to understand the motivations,objectives,and factors driving and challenging these transformations.Over 700 responses were collected to the question and categorized into 32 objectives.The findings show that organizations primarily aim to achieve customer centricity and adaptability,both with 8%of the mentions.Other primary important objectives,with above 4%of mentions,include alignment of goals,lean delivery,sustainable processes,and a flatter,more team-based organizational structure.We also detect discrepancies in perspectives between the objectives identified by the two kinds of organizations and the existing agile literature and models.This misalignment highlights the need for practitioners to understand with the practical realities the organizations face. 展开更多
关键词 Business agility AGILE agile transformations agile enterprises adaptive organizations ADAPTABILITY agile software development software engineering computer engineering
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Organic fertilizer enhances soil aggregate stability by altering greenhouse soil content of iron oxide and organic carbon 被引量:1
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作者 Lijun Ren Han Yang +4 位作者 Jin Li Nan Zhang Yanyu Han Hongtao Zou Yulong Zhang 《Journal of Integrative Agriculture》 2025年第1期306-321,共16页
Both soil organic carbon (SOC) and iron (Fe) oxide content, among other factors, drive the formation and stability of soil aggregates.However, the mechanism of these drivers in greenhouse soil fertilized with organic ... Both soil organic carbon (SOC) and iron (Fe) oxide content, among other factors, drive the formation and stability of soil aggregates.However, the mechanism of these drivers in greenhouse soil fertilized with organic fertilizer is not well understood.In a 3-year field experiment, we aimed to investigate the factors which drive the stability of soil aggregates in greenhouse soil.To explore the impact of organic fertilizer on soil aggregates, we established four treatments:no fertilization (CK);inorganic fertilizer (CF);organic fertilizer (OF);and combined application of inorganic and organic fertilizers(COF).The application of organic fertilizer significantly enhanced the stability of aggregates, that is it enhanced the mean weight diameter, geometric mean diameter and aggregate content (%) of>0.25 mm aggregate fractions.OF and COF treatments increased the concentration of SOC, especially the aliphatic-C, aromatic-C and polysaccharide-C components of SOC, particularly in>0.25 mm aggregates.Organic fertilizer application significantly increased the content of free Fe(Fed), reactive Fe (Feo), and non-crystalline Fe in both bulk soil and aggregates.Furthermore, non-crystalline Fe showed a positive correlation with SOC content in both bulk soil and aggregates.Both non-crystalline Fe and SOC were significantly positively correlated with>2 mm mean weight diameter.Overall, we believe that the increase of SOC, aromatic-C, and non-crystal ine Fe concentrations in soil after the application of organic fertilizer is the reason for improving soil aggregate stability. 展开更多
关键词 organic fertilizer soil aggregates soil organic carbon iron oxides greenhouse soil
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Genome-wide and candidate gene association studies identify BnPAP17 as conferring the utilization of organic phosphorus in oilseed rape
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作者 Ping Xu Hao Li +6 位作者 Haiyuan Li Ge Zhao Shengjie Dai Xiaoyu Cui Zhenning Liu Lei Shi Xiaohua Wang 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第4期1134-1149,共16页
Phosphorus(P)is essential for living plants,and P deficiency is one of the key factors limiting the yield in rapeseed production worldwide.As the most important organ for plants,root morphology traits(RMTs)play a key ... Phosphorus(P)is essential for living plants,and P deficiency is one of the key factors limiting the yield in rapeseed production worldwide.As the most important organ for plants,root morphology traits(RMTs)play a key role in P absorption.To investigate the genetic variability of RMT under low P availability,we dissected the genetic structure of RMTs by genome-wide association studies(GWAS),linkage mapping and candidate gene association studies(CGAS).A total of 52 suggestive loci were associated with RMTs under P stress conditions in 405 oilseed rape accessions.The purple acid phosphatase gene BnPAP17 was found to control the lateral root number(LRN)and root dry weight(RDW)under low P stress.The expression of BnPAP17 was increased in shoot tissue in P-efficient cultivars compared to root tissue and P-inefficient cultivars in response to low P stress.Moreover,the haplotype of BnPAP17^(Hap3)was detected for the selective breeding of P efficiency in oilseed rape.Over-expression of the BnPAP17^(Hap3)could promote the shoot and root growth with enhanced tolerance to low P stress and organic phosphorus(Po)utilization in oilseed rape.Collectively,these findings increase our understanding of the mechanisms underlying BnPAP17-mediated low P stress tolerance in oilseed rape. 展开更多
关键词 genome-wide association studies(GWAS) root morphology traits(RMTs) organic phosphorus(Po) oilseed rape BnPAP17
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