One-dimensional Cd S@TiO_2 core-shell heterostructures were fabricated via the hydrolysis of tetrabutyl titanate(TBT) on preformed Cd S nanowires. The as-prepared products were characterized by X-ray diffraction, tran...One-dimensional Cd S@TiO_2 core-shell heterostructures were fabricated via the hydrolysis of tetrabutyl titanate(TBT) on preformed Cd S nanowires. The as-prepared products were characterized by X-ray diffraction, transmission electron microscopy, selected area electron diffraction and diffuse reflectance spectroscopy techniques. Results demonstrated that the hydrolysis of TBT had a great influence on the morphology of the coated TiO_2 shell, resulting in the formation of TiO_2 nanoparticles and nanolayer-modified Cd S@TiO_2 heterostructures. Degradation of methylene blue using Cd S@TiO_2 core-shell heterostructures as photocatalysts under visible light irradiation was investigated. Comparative photocatalytic tests showed that the TiO_2 nanoparticles-modified heterostructure exhibited a superior activity due to the passivity of photogenerated charge carriers.展开更多
One-dimensional nano-grating standard(ODNGS)is widely recognized as a crucial nanometric standard for metrological technology.However,achieving the ultratiny size of ODNGS with high consistent uniformity and low rough...One-dimensional nano-grating standard(ODNGS)is widely recognized as a crucial nanometric standard for metrological technology.However,achieving the ultratiny size of ODNGS with high consistent uniformity and low roughness by conventional processes such as the inductively coupled plasma(ICP)etching methodpresents a significant challenge in obtaining accurate calibration values.In this work,a 50-nm ODNGS with a conformal buffer layer(Al_(2)O_(3))is successfully obtained,indicating outstanding stability and abrasion resistance.Remarkably,the introduction of hydrogen silsesquioxane(HSQ)and amorphous Al_(2)O_(3)simultaneously guarantees an incredibly small expanded uncertainty(0.5 nm)and repeatability of the standard uniformity(less than 0.3 nm)in the grating dimensions.TheⅠ-Ⅴcurves of ODNGS with an Al_(2)O_(3)buffer layer at room temperature(RT)and200℃are depicted respectively to showcase the sustained favorable insulation properties.Notably,the nanostructure fluctuation,line edge roughness(LER)and line width roughness(LWR)of the standard can be decreased obviously by 64.1%,63%and 70%,respectively.Our results suggest that the ODNGS with Al_(2)O_(3)exhibits exceptional precision and robust calibration reliability for calibrating nanoscale measuring instruments.It holds tremendous potential for manufacturing high-precision nanostructures and grating arrays with precisely controllable dimensions,which will play a pivotal role in the fabrication of microfluidics chips,metasurface and photodetectors in the future.展开更多
One-dimensional(1D) GaN nanomaterials exhibiting various morphologies and atomic structures were prepared via ammoniation of either Ga_2O_3 nanoribbons, Ga_2O_3 nanorods or Ga nanowires filled into carbon nanotubes(CN...One-dimensional(1D) GaN nanomaterials exhibiting various morphologies and atomic structures were prepared via ammoniation of either Ga_2O_3 nanoribbons, Ga_2O_3 nanorods or Ga nanowires filled into carbon nanotubes(CNTs). The 1D GaN nanomaterials transformed from Ga_2O_3 nanoribbons consisted of numerous GaN nanoplatelets having the close-packed plane, i.e.(0002)2H or(111)3C parallel to the axes of starting nanoribbons. The 1D GaN nanomaterials converted from Ga_2O_3 nanorods were polycrystalline rods covered with GaN nanoparticles along the axes. The 1D GaN nanomaterials prepared from Ga nanowires filled into CNTs displayed two dominant morphologies:(i) single crystalline Ga N nanocolumns coated by CNTs, and(ii) pure single crystalline Ga N nanowires. The cross-sectional shape of Ga N nanowires were analyzed through the transmission electron microscopy(TEM) images. Formation mechanism of all-mentioned 1D GaN nanomaterials is then thoroughly discussed.展开更多
A new coordination polymer {[Cd（C_（21）H_（14）N_6）（C_8H_4O_4）]·H_2O}_n（1） was synthesized by an elaborate design via the reaction of 3-（2,6-di（pyrazin-2-yl）pyridin-4-yl）-1H-indole（bppi）,1,4-benzene-...A new coordination polymer {[Cd（C_（21）H_（14）N_6）（C_8H_4O_4）]·H_2O}_n（1） was synthesized by an elaborate design via the reaction of 3-（2,6-di（pyrazin-2-yl）pyridin-4-yl）-1H-indole（bppi）,1,4-benzene-dicarboxylic acid（H2bdc） and cadmium（Ⅱ） nitrate in CH_3OH/H_2O mixed solvents. Complex 1 crystallizes in orthorhombic,space group Ccca with a = 20.012（4）,b = 31.881（6）,c = 19.808（4） ？,V = 12638（4） ？~3,Z = 16,C_（29）H_（20）CdN_6O_5,M_r = 644.91,D_c = 1.356 g·cm^（-3）,μ = 0.735 mm^（-1）,F（000） = 5184,GOOF = 1.046,the final R = 0.0405 and wR = 0.1063 for 6870 observed reflections（I 〉 2σ（I））. The Cd（Ⅱ） centre is hepta-coordinated by three N and four O atoms from one bppi terminal ligand and two bdc2– ligands,respectively,displaying a capped trigonal prism geometry. Structure extension gives coordination polymeric chains,in which the bdc2– linkers connect Cd（Ⅱ） cations into a one-dimensional（1D） coordination polymer along the c axis,giving zigzag chains with the Cd···Cd separation of 11.178（1） ？. The adjacent bppi terminal ligands in the chains are anti-periplanar conformation. The three-dimensional（3D） structure is stabilized by π···π stacking and hydrogen-bonding interactions to form a supramolecular self-penetrating network with 1D channels. In 1,there are voids 2999.7 ？~3 with 23.7% of per unit cell volume. Thermal analysis indicates that the framework of 1 is stable until 651 K and the photoluminescence of 1 in the solid shows very weak fluorescence at 382 and 560 nm upon excitation at 310 nm.展开更多
One-dimensional nanowires with robust magnetism are desirable for spintronic applications. Herein, on the basis of the first-principles calculations, systematic investigations on the electronic and magnetic properties...One-dimensional nanowires with robust magnetism are desirable for spintronic applications. Herein, on the basis of the first-principles calculations, systematic investigations on the electronic and magnetic properties of the CuCl2 nanowire were performed, which can be potentially tailored from its bulk form. The CuCl2 nanowire exhibits a ferromagnetic ground state. The band structures indicate that the CuCl2 nanowire is a ferromagnetic semiconductor. The spin flip gap is large enough for avoiding spin flip. Phonon dispersion and Born-Oppenheimer molecular dynamics simulation manifest that the CuCl2 nanowire is stable. In addition, distinct magnetic properties of the CuCl2 nanowires inside two types of carbon nanotubes were obtained. The study broadens the family of the existing one-dimensional materials with promising applications for spintronics.展开更多
The preparation and crystal structure of complex Co（Hsae）2·2H2O （1, H2sae = N-salicylidene-2-iminoethanol） are reported. X- ray analysis revealed that every six Co（Hsae）2 forms a cyclic chip and every 12 wa...The preparation and crystal structure of complex Co（Hsae）2·2H2O （1, H2sae = N-salicylidene-2-iminoethanol） are reported. X- ray analysis revealed that every six Co（Hsae）2 forms a cyclic chip and every 12 water forms a novel gear-like cluster. Acting as building blocks, the gear-like water cluster and complex chip are connected in A-B fashion and extend into one-dimensional supramolecular chain. Hydrogen bond is the primary bridging force in the formation of supramolecular framework.展开更多
A local alternating segment explicit - implicit method for the solution of 2D diffusion equations is presented in this paper .The method is unconditionally stable and has the obvious property of parallelism. Some nume...A local alternating segment explicit - implicit method for the solution of 2D diffusion equations is presented in this paper .The method is unconditionally stable and has the obvious property of parallelism. Some numerical experiments show the method is not only simple but also more accurate.展开更多
A novel metal organic compound of Zn2+ coordinated with 4,5-diazafluorene- 9-one-N2 (C22H12N6) has been synthesized under solvothermal condition. Single-crystal X-ray diffraction analysis showed that the compound is a...A novel metal organic compound of Zn2+ coordinated with 4,5-diazafluorene- 9-one-N2 (C22H12N6) has been synthesized under solvothermal condition. Single-crystal X-ray diffraction analysis showed that the compound is a one-dimensional zig-zag chain structure combined by Cl…H–C bonds. The crystal is of orthorhombic, space group Pnna, C22H12N6Cl2Zn, Mr = 496.65, a = 8.1132(13), b = 18.983(3), c = 13.116(2) ?, Z = 4, V = 2020.2(5) ?3, Dc = 1.633 g/cm3, μ = 1.504 mm-1, F(000) = 1000, T = 293(2) K, the final R = 0.0626 and wR = 0.1474 for 2390 unique reflections and 150 parameters with I > 2σ(I). The refinement method was full-matrix least-squares on F2 with GOF = 0.951. This compound was also characterized by FT-IR, Raman, UV-vis spectra, and TG-DTA.展开更多
Electrocatalytic reduction of CO_(2)to valuable products possesses huge potential to alleviate environmental and energy crisis.It is well known that Ag favors the conversion of CO_(2)to CO but the exposed active sites...Electrocatalytic reduction of CO_(2)to valuable products possesses huge potential to alleviate environmental and energy crisis.It is well known that Ag favors the conversion of CO_(2)to CO but the exposed active sites and stability are still rather limited.In this study,a novel one-dimensional Ag-based metal-organic framework(1D Ag-NIM-MOF)was successfully synthesized and used in the electrocatalytic CO_(2)reduction reaction(CO_(2)RR)for the first time.As a result,the Faradaic efficiency of CO achieved 94.5%with current density of 12.5 mA·cm^(-2)in an H-type cell and 98.2%with current density of 161 mA·cm^(-2)in a flow cell at–1.0 V(vs.RHE),which stands as a new benchmark of Ag-based MOFs in the electrocatalytic CO_(2)RR.The excellent performance of 1D Ag-NIM-MOF is attributed to its peculiar one-dimensional structure,which is beneficial for diffusion of reactants and products,and exposure of much more catalytic sites.Compared to commercial Ag nanoparticles,1D Ag-NIM-MOF exhibits superior electrocatalytic CO_(2)RR performance with higher catalytic activity and stability.展开更多
For catalytic materials,the characteristics of one-dimension and hollowness are the promotion factors for their full presentation of catalytic activity,and through a template-as sis ted method,both above superiorities...For catalytic materials,the characteristics of one-dimension and hollowness are the promotion factors for their full presentation of catalytic activity,and through a template-as sis ted method,both above superiorities can be fused simultaneously.Here,we proposed a novel strategy inspired by Pearson's principle with Cu_(2)O wires as templates,and prepared FeOOH hollow tubes,which covered by FeOOH scales.When applied as oxygen evolution reaction(OER)catalyst,the FeOOH scaly hollow tubes(FeOOH SHTs)showed outstanding catalytic activity with a low overpotential of 245 mV to drive a current density of10 mA·cm^(-2),excellent kinetics manifesting as a low Tafel slope of 46.9 mV·dec^(-1),and robust stability.This work provides a new synthesis strategy for an ideal OER catalyst,FeOOH,with high inherent activity and enhances the feasibility to broaden the design ideas of transition metalbased catalysts.展开更多
In recent years,vanadate has attracted the attention of researchers for its application in electrode materials due to its high specific capacity and layered crystal structure.Herein,a typical manganese vanadium oxides...In recent years,vanadate has attracted the attention of researchers for its application in electrode materials due to its high specific capacity and layered crystal structure.Herein,a typical manganese vanadium oxides (Mn V_(2)O_(6)) product is efficient synthesis via a simple one-step hydrothermal method at 200℃ for 16 h.The as-prepared Mn V_(2)O_(6) sample is found to be the unique one-dimensional fan-like superstructure consist of several nanorods.From a microcosmic point of view,VO6 octahedra sheets are connected by sharing edges which provides highly-open framework for rapid the intercalation and deintercalation of vip ions Therefore,stable Mn V_(2)O_(6) was prepared and used as a cathode material in aqueous zinc ion batteries,which displayed favorable specific discharge capacity,excellent coulombic efficiency and well cycling performance.展开更多
Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and...Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X-ray diffraction analysis. In the structure of 1, the tin atom is five-coordinated in a distorted trigonal bipyramidal structure. Due to the presence of a close intermolecular Sn...S interaction distance of 0.3666 nm, the structure can be described as a weakly-bridged one-dimensional chain compound. In the structure of 2, the tin atom is five-coordinated with bridging 3-pyridinylcarboxylate ligands N atom and resulting structure is one-dimensional chain compound.展开更多
Dialkyldithiocarbamate （R<sub>2</sub>NCS<sup>-</sup><sub>2</sub>） acting as either bridging or terminal ligand plays an important role in modern coordination chemistry. The molecu...Dialkyldithiocarbamate （R<sub>2</sub>NCS<sup>-</sup><sub>2</sub>） acting as either bridging or terminal ligand plays an important role in modern coordination chemistry. The molecules of the univalent coinage metals （Cu, Ag, and Au） with dialkyldithiocarbamate ligands form a class of compounds in which the sterical restriction influences strongly the crystal structures, and several types of polymerizates were found. However, only a few structures in linear form展开更多
The atomic structure of quasi one-dimensional(1D) van der Waals materials can be regarded as the stacking of atomic chains to form thin flakes or nanoribbons, which substantially differentiates them from typical two-d...The atomic structure of quasi one-dimensional(1D) van der Waals materials can be regarded as the stacking of atomic chains to form thin flakes or nanoribbons, which substantially differentiates them from typical two-dimensional(2D) layered materials and 1D nanotube/nanowire array. Here we present our studies on quasi 1D gold selenide(AuSe) that possesses highly anisotropic crystal structure, excellent electrical conductivity, giant magnetoresistance, and unusual reentrant metallic behavior. The low inplane symmetry of AuSe gives rise to its high anisotropy of vibrational behavior. In contrast, quasi 1D AuSe exhibits high in-plane electrical conductivity along the directions of both atomic chains and perpendicular one, which can be understood as a result of strong interchain interaction. We found that AuSe exhibits a near quadratic nonsaturating giant magnetoresistance of 1841% with the magnetic field perpendicular to its in-plane. We also observe unusual reentrant metallic behavior, which is caused by the carrier mismatch in the multiband transport. Our works help to establish fundamental understandings on quasi 1D van der Waals semimetallic AuSe and identify it as a new candidate for exploring giant magnetoresistance and compensated semimetals.展开更多
Direct Z-scheme CdO-CdS 1-dimensional nanorod arrays were constructed through a facile and simple hydrothermal process. The structure, morphology, photoelectrochemical properties and H2 evolution activity of this cata...Direct Z-scheme CdO-CdS 1-dimensional nanorod arrays were constructed through a facile and simple hydrothermal process. The structure, morphology, photoelectrochemical properties and H2 evolution activity of this catalyst were investigated systematically. The morphology of the obtained nanorod is a regular hexagonal prism with 100-200 nm in diameter. The calcination temperature and time were optimized carefully to achieve the highest photoelectrochemical performance. The as-fabricated hybrid system achieved a photocurrent density up to 6.5 mA/cm2 and H2 evolution rate of 240 μmol·cm-2·h-1 at 0 V vs. Ag/AgCl, which is about 2-fold higher than that of the bare CdS nanorod arrays. The PEC performance exceeds those previously reported similar systems. A direct Z-scheme photocatalytic mechanism was proposed based on the structure and photoelectrochemical performance characterization results, which can well explain the high separation efficiency of photoinduced carriers and the excellent redox ability.展开更多
A novel chain complex was synthesized and its crystal structure has been deter- mined by X-ray diffraction technique. It was found that the local coordination geometry around Cu(Ⅱ) is a distorted tetrahedron and C14H...A novel chain complex was synthesized and its crystal structure has been deter- mined by X-ray diffraction technique. It was found that the local coordination geometry around Cu(Ⅱ) is a distorted tetrahedron and C14H9CuNO3CH3OH is bridged by the carboxylate oxygen atom to form an infinite one-dimensional linear chain. The hydrogen bond exists between O(1) and solvate molecule O(4). The crystal belongs to monoclinic, space group P21 with a = 9.6650(19), b = 7.1280(14), c = 9.925(2) ? b = 98.39(3)? V = 676.4(2) 3, Z = 2, F(000) = 342 and m(MoK? = 1.629 mm-1 .展开更多
In the endeavor to develop three-dimensional(3D)-architected sophisticated hierarchical structures,the synergy between inplane and out-of-plane interactions at interfaces offers new functionalities.This interplay,gove...In the endeavor to develop three-dimensional(3D)-architected sophisticated hierarchical structures,the synergy between inplane and out-of-plane interactions at interfaces offers new functionalities.This interplay,governed by van der Waals(vdW)interfacial nanoarchitectonics,facilitates the design of efficient thermally conductive pathways.This work delves into the kinetics underlying a dual-templating strategy,seamlessly integrating two-dimensional(2D)-graphene sheets with one-dimensional(1D)-cellulose chains at heterointerfaces,thereby transforming into 3D-shaped and 3D-continuously anisotropic structures,termed as(3D^(2)GC)architecture.Hereby,we designed and fabricated an anisotropic graphene cellulose scaffold(GCS)employing a nickel template.The as-grown GCS replicates the 3D-shaped and configuration of the template.The 3D-continuously interconnected fibrous-porous network of the GCS,combined with its anisotropic thermal properties(λ_(axial)/λ_(radial)),not only is promising for advanced thermal technologies but also offers advantages in cost-effectiveness and eco-effectiveness.展开更多
With the advancement of atomic manufacturing technology,single atom array(SAA)has emerged as a groundbreaking advancement in catalysis and materials science.Single atom array catalyst(SAAC),composed of precisely arran...With the advancement of atomic manufacturing technology,single atom array(SAA)has emerged as a groundbreaking advancement in catalysis and materials science.Single atom array catalyst(SAAC),composed of precisely arranged isolated metal atoms,exhibits unique electronic properties and exceptional catalytic efficiencies,making it highly promising for energy conversion processes such as hydrogen production and carbon dioxide reduction.SAA maximizes atomic utilization by using individual atoms as independent catalytic centres,allowing each atom to directly participate in the reaction.The optimized electronic structure of single atoms improves binding efficiency and enhances catalytic performance.Furthermore,single atoms have tunable properties,enabling adaptation to various reactions.Organizing metal atoms into well-defined one-dimensional(1D)or 2D arrays also improves both stability and performance,offering a more efficient alternative to conventional catalysts.However,there are pressing challenges in achieving uniformity,stability,and scalability of SAAC in both synthesis and practical applications.It is urgent to summarize and address these critical issues to unlock the full potential of SAAC for large-scale industrial applications.In this review,we systematically summarize the latest innovations in the synthesis and application of SAA.We also introduce advanced fabrication techniques such as atomic layer deposition,chemical vapor deposition,and electronic interface-guided reduction,and evaluate their impact on catalytic performance in detail.Finally,we emphasize the role of SAA in tackling major energy challenges and propose future research directions to overcome the current barriers,aiming to develop high-performance,sustainable solutions for clean energy technologies.展开更多
Orthorhombic LiMnO_(2)nanoparticles and LiMnO_(2)nanorods have been synthesized by hydrothermal methods.LiMnO_(2)nanoparticles were synthesized by simple one-step hydrothermal method.To obtain rod-like LiMnO_(2),γ-Mn...Orthorhombic LiMnO_(2)nanoparticles and LiMnO_(2)nanorods have been synthesized by hydrothermal methods.LiMnO_(2)nanoparticles were synthesized by simple one-step hydrothermal method.To obtain rod-like LiMnO_(2),γ-MnOOH nanorods were first synthesized and then the H+ions were completely replaced by Li+resulting in LiMnO_(2)nanorods.Their electrochemical performances were thoroughly investigated by galvanostatic tests.Although the LiMnO_(2)nanoparticles have smaller size than LiMnO_(2)nanorods,the latter exhibited higher discharge capacity and better cyclability.For example,the discharge capacities of LiMnO_(2)nanorods reached 200 mA·h/g over many cycles and remained above 180 mA·h/g after 30 cycles.However,the maximum capacity of LiMnO_(2)nanoparticles was only 170 mA·h/g and quickly decreased to 110 mA·h/g after 30 cycles.Nanorods with one-dimensional electronic pathways favor the transport of electrons along the length direction and accommodate volume changes resulting from charge/discharge processes.Thus the morphology of LiMnO_(2)may play an important role in electrochemical performance.展开更多
基金financial support Independent Innovation Foundation of Shandong University(IIFSDU-2009JQ011)
文摘One-dimensional Cd S@TiO_2 core-shell heterostructures were fabricated via the hydrolysis of tetrabutyl titanate(TBT) on preformed Cd S nanowires. The as-prepared products were characterized by X-ray diffraction, transmission electron microscopy, selected area electron diffraction and diffuse reflectance spectroscopy techniques. Results demonstrated that the hydrolysis of TBT had a great influence on the morphology of the coated TiO_2 shell, resulting in the formation of TiO_2 nanoparticles and nanolayer-modified Cd S@TiO_2 heterostructures. Degradation of methylene blue using Cd S@TiO_2 core-shell heterostructures as photocatalysts under visible light irradiation was investigated. Comparative photocatalytic tests showed that the TiO_2 nanoparticles-modified heterostructure exhibited a superior activity due to the passivity of photogenerated charge carriers.
基金financially supported by the National Natural Science Foundation of China(No.52175434)the National Key Research and Development Program of China(No.2022YFB3204801)
文摘One-dimensional nano-grating standard(ODNGS)is widely recognized as a crucial nanometric standard for metrological technology.However,achieving the ultratiny size of ODNGS with high consistent uniformity and low roughness by conventional processes such as the inductively coupled plasma(ICP)etching methodpresents a significant challenge in obtaining accurate calibration values.In this work,a 50-nm ODNGS with a conformal buffer layer(Al_(2)O_(3))is successfully obtained,indicating outstanding stability and abrasion resistance.Remarkably,the introduction of hydrogen silsesquioxane(HSQ)and amorphous Al_(2)O_(3)simultaneously guarantees an incredibly small expanded uncertainty(0.5 nm)and repeatability of the standard uniformity(less than 0.3 nm)in the grating dimensions.TheⅠ-Ⅴcurves of ODNGS with an Al_(2)O_(3)buffer layer at room temperature(RT)and200℃are depicted respectively to showcase the sustained favorable insulation properties.Notably,the nanostructure fluctuation,line edge roughness(LER)and line width roughness(LWR)of the standard can be decreased obviously by 64.1%,63%and 70%,respectively.Our results suggest that the ODNGS with Al_(2)O_(3)exhibits exceptional precision and robust calibration reliability for calibrating nanoscale measuring instruments.It holds tremendous potential for manufacturing high-precision nanostructures and grating arrays with precisely controllable dimensions,which will play a pivotal role in the fabrication of microfluidics chips,metasurface and photodetectors in the future.
基金National Natural Science Foundation of China(No.10774053)Hubei Province Nature Science Foundation of China(No.2007ABB008)Programs Foundation of Ministry of Education of China(No.20070487038)
文摘One-dimensional(1D) GaN nanomaterials exhibiting various morphologies and atomic structures were prepared via ammoniation of either Ga_2O_3 nanoribbons, Ga_2O_3 nanorods or Ga nanowires filled into carbon nanotubes(CNTs). The 1D GaN nanomaterials transformed from Ga_2O_3 nanoribbons consisted of numerous GaN nanoplatelets having the close-packed plane, i.e.(0002)2H or(111)3C parallel to the axes of starting nanoribbons. The 1D GaN nanomaterials converted from Ga_2O_3 nanorods were polycrystalline rods covered with GaN nanoparticles along the axes. The 1D GaN nanomaterials prepared from Ga nanowires filled into CNTs displayed two dominant morphologies:(i) single crystalline Ga N nanocolumns coated by CNTs, and(ii) pure single crystalline Ga N nanowires. The cross-sectional shape of Ga N nanowires were analyzed through the transmission electron microscopy(TEM) images. Formation mechanism of all-mentioned 1D GaN nanomaterials is then thoroughly discussed.
基金supported by the National Natural Science Foundation of China(Nos.21571118&21271121)
文摘A new coordination polymer {[Cd（C_（21）H_（14）N_6）（C_8H_4O_4）]·H_2O}_n（1） was synthesized by an elaborate design via the reaction of 3-（2,6-di（pyrazin-2-yl）pyridin-4-yl）-1H-indole（bppi）,1,4-benzene-dicarboxylic acid（H2bdc） and cadmium（Ⅱ） nitrate in CH_3OH/H_2O mixed solvents. Complex 1 crystallizes in orthorhombic,space group Ccca with a = 20.012（4）,b = 31.881（6）,c = 19.808（4） ？,V = 12638（4） ？~3,Z = 16,C_（29）H_（20）CdN_6O_5,M_r = 644.91,D_c = 1.356 g·cm^（-3）,μ = 0.735 mm^（-1）,F（000） = 5184,GOOF = 1.046,the final R = 0.0405 and wR = 0.1063 for 6870 observed reflections（I 〉 2σ（I））. The Cd（Ⅱ） centre is hepta-coordinated by three N and four O atoms from one bppi terminal ligand and two bdc2– ligands,respectively,displaying a capped trigonal prism geometry. Structure extension gives coordination polymeric chains,in which the bdc2– linkers connect Cd（Ⅱ） cations into a one-dimensional（1D） coordination polymer along the c axis,giving zigzag chains with the Cd···Cd separation of 11.178（1） ？. The adjacent bppi terminal ligands in the chains are anti-periplanar conformation. The three-dimensional（3D） structure is stabilized by π···π stacking and hydrogen-bonding interactions to form a supramolecular self-penetrating network with 1D channels. In 1,there are voids 2999.7 ？~3 with 23.7% of per unit cell volume. Thermal analysis indicates that the framework of 1 is stable until 651 K and the photoluminescence of 1 in the solid shows very weak fluorescence at 382 and 560 nm upon excitation at 310 nm.
基金supported by the Beijing Municipal Natural Science Foundation(No.2182012)the Scientific Research Base Development Program of the Beijing Municipal Commission of Education
文摘One-dimensional nanowires with robust magnetism are desirable for spintronic applications. Herein, on the basis of the first-principles calculations, systematic investigations on the electronic and magnetic properties of the CuCl2 nanowire were performed, which can be potentially tailored from its bulk form. The CuCl2 nanowire exhibits a ferromagnetic ground state. The band structures indicate that the CuCl2 nanowire is a ferromagnetic semiconductor. The spin flip gap is large enough for avoiding spin flip. Phonon dispersion and Born-Oppenheimer molecular dynamics simulation manifest that the CuCl2 nanowire is stable. In addition, distinct magnetic properties of the CuCl2 nanowires inside two types of carbon nanotubes were obtained. The study broadens the family of the existing one-dimensional materials with promising applications for spintronics.
基金supported by the Natural Science Foundation of Education Bureau of Liaoning Province,China(No.05L159).
文摘The preparation and crystal structure of complex Co（Hsae）2·2H2O （1, H2sae = N-salicylidene-2-iminoethanol） are reported. X- ray analysis revealed that every six Co（Hsae）2 forms a cyclic chip and every 12 water forms a novel gear-like cluster. Acting as building blocks, the gear-like water cluster and complex chip are connected in A-B fashion and extend into one-dimensional supramolecular chain. Hydrogen bond is the primary bridging force in the formation of supramolecular framework.
文摘A local alternating segment explicit - implicit method for the solution of 2D diffusion equations is presented in this paper .The method is unconditionally stable and has the obvious property of parallelism. Some numerical experiments show the method is not only simple but also more accurate.
文摘SbNb_3(Se_2)_6, Mr=1347.99, tetragonal, P4/mnc,a=b=9.466(2),c=19.075(3) ,V=1709.0(4) ~3, z=4, Dm=5.2(2)g/cm^3, Dc=5.24g/c^3,λ(Moka)=0.71069 ,μ=287.39cm^(-1), F(000)=2328,T=276(1)k,R=5.9％,Rw=6.9％, for 479 unique observed reflections (1>3σ(1)).The structure is composed of [Nb3(Se2)s]∞ chains along the c axis with Sb atoms inserted between them.
基金This work was supported by the Natural Science Foundation (No. 20201013) and "Plan of Outstanding Talents" of the Chinese Academy of Sciences
文摘A novel metal organic compound of Zn2+ coordinated with 4,5-diazafluorene- 9-one-N2 (C22H12N6) has been synthesized under solvothermal condition. Single-crystal X-ray diffraction analysis showed that the compound is a one-dimensional zig-zag chain structure combined by Cl…H–C bonds. The crystal is of orthorhombic, space group Pnna, C22H12N6Cl2Zn, Mr = 496.65, a = 8.1132(13), b = 18.983(3), c = 13.116(2) ?, Z = 4, V = 2020.2(5) ?3, Dc = 1.633 g/cm3, μ = 1.504 mm-1, F(000) = 1000, T = 293(2) K, the final R = 0.0626 and wR = 0.1474 for 2390 unique reflections and 150 parameters with I > 2σ(I). The refinement method was full-matrix least-squares on F2 with GOF = 0.951. This compound was also characterized by FT-IR, Raman, UV-vis spectra, and TG-DTA.
基金supported by the National Natural Science Foundation of China(Nos.22172116 and 21773176)Natural Science Foundation of Hubei Province(2022CFB130).
文摘Electrocatalytic reduction of CO_(2)to valuable products possesses huge potential to alleviate environmental and energy crisis.It is well known that Ag favors the conversion of CO_(2)to CO but the exposed active sites and stability are still rather limited.In this study,a novel one-dimensional Ag-based metal-organic framework(1D Ag-NIM-MOF)was successfully synthesized and used in the electrocatalytic CO_(2)reduction reaction(CO_(2)RR)for the first time.As a result,the Faradaic efficiency of CO achieved 94.5%with current density of 12.5 mA·cm^(-2)in an H-type cell and 98.2%with current density of 161 mA·cm^(-2)in a flow cell at–1.0 V(vs.RHE),which stands as a new benchmark of Ag-based MOFs in the electrocatalytic CO_(2)RR.The excellent performance of 1D Ag-NIM-MOF is attributed to its peculiar one-dimensional structure,which is beneficial for diffusion of reactants and products,and exposure of much more catalytic sites.Compared to commercial Ag nanoparticles,1D Ag-NIM-MOF exhibits superior electrocatalytic CO_(2)RR performance with higher catalytic activity and stability.
基金financially supported by the National Key Research and Development Program of China(No.2018YFA0703700)the National Natural Science Foundation of China(Nos.12004031,12034002 and 51971025)+3 种基金Beijing Natural Science Foundation(No.2212034)Foshan Talents Special Foundation(No.BKBS202003)the Scientific and Technological Innovation Foundation of Foshan(No.BK22BE005)Foshan Science and Technology Innovation Project(No.2018IT100363)。
文摘For catalytic materials,the characteristics of one-dimension and hollowness are the promotion factors for their full presentation of catalytic activity,and through a template-as sis ted method,both above superiorities can be fused simultaneously.Here,we proposed a novel strategy inspired by Pearson's principle with Cu_(2)O wires as templates,and prepared FeOOH hollow tubes,which covered by FeOOH scales.When applied as oxygen evolution reaction(OER)catalyst,the FeOOH scaly hollow tubes(FeOOH SHTs)showed outstanding catalytic activity with a low overpotential of 245 mV to drive a current density of10 mA·cm^(-2),excellent kinetics manifesting as a low Tafel slope of 46.9 mV·dec^(-1),and robust stability.This work provides a new synthesis strategy for an ideal OER catalyst,FeOOH,with high inherent activity and enhances the feasibility to broaden the design ideas of transition metalbased catalysts.
基金supported by the National Natural Science Foundation of China (No. U1904215)the Natural Science Foundation of Jiangsu Province (No. BK20200044)the Changjiang Scholars Program of the Ministry of Education (No. Q2018270)。
文摘In recent years,vanadate has attracted the attention of researchers for its application in electrode materials due to its high specific capacity and layered crystal structure.Herein,a typical manganese vanadium oxides (Mn V_(2)O_(6)) product is efficient synthesis via a simple one-step hydrothermal method at 200℃ for 16 h.The as-prepared Mn V_(2)O_(6) sample is found to be the unique one-dimensional fan-like superstructure consist of several nanorods.From a microcosmic point of view,VO6 octahedra sheets are connected by sharing edges which provides highly-open framework for rapid the intercalation and deintercalation of vip ions Therefore,stable Mn V_(2)O_(6) was prepared and used as a cathode material in aqueous zinc ion batteries,which displayed favorable specific discharge capacity,excellent coulombic efficiency and well cycling performance.
基金ProjectsupportedbytheNaturalScienceFoundationofShandongProvince (No .Z2 0 0 1B0 2 )andtheFoundationofStateKeyLaborato ryofCrystalMaterials,ShandongUniversity
文摘Triphenyltin thiazole-2-carboxylate (1) and triphenyltin 3-pyridinylcarboxylate (2) were synthesized by the reaction of sodium thiazole-2-carboxylate or sodium 3-pyridinylcarboxylate with the triphenyltin chloride and their crystal structures were determined by single crystal X-ray diffraction analysis. In the structure of 1, the tin atom is five-coordinated in a distorted trigonal bipyramidal structure. Due to the presence of a close intermolecular Sn...S interaction distance of 0.3666 nm, the structure can be described as a weakly-bridged one-dimensional chain compound. In the structure of 2, the tin atom is five-coordinated with bridging 3-pyridinylcarboxylate ligands N atom and resulting structure is one-dimensional chain compound.
基金Project supported by the National Natural Science Foundation of China.
文摘Dialkyldithiocarbamate （R<sub>2</sub>NCS<sup>-</sup><sub>2</sub>） acting as either bridging or terminal ligand plays an important role in modern coordination chemistry. The molecules of the univalent coinage metals （Cu, Ag, and Au） with dialkyldithiocarbamate ligands form a class of compounds in which the sterical restriction influences strongly the crystal structures, and several types of polymerizates were found. However, only a few structures in linear form
基金This work was supported by the Research Grant Council of Hong Kong(N_PolyU540/17)the Shenzhen Science and Technology Innovation Commission(JCYJ20180507183424383)the Hong Kong Polytechnic University(G-SB79 and G-YBPS).
文摘The atomic structure of quasi one-dimensional(1D) van der Waals materials can be regarded as the stacking of atomic chains to form thin flakes or nanoribbons, which substantially differentiates them from typical two-dimensional(2D) layered materials and 1D nanotube/nanowire array. Here we present our studies on quasi 1D gold selenide(AuSe) that possesses highly anisotropic crystal structure, excellent electrical conductivity, giant magnetoresistance, and unusual reentrant metallic behavior. The low inplane symmetry of AuSe gives rise to its high anisotropy of vibrational behavior. In contrast, quasi 1D AuSe exhibits high in-plane electrical conductivity along the directions of both atomic chains and perpendicular one, which can be understood as a result of strong interchain interaction. We found that AuSe exhibits a near quadratic nonsaturating giant magnetoresistance of 1841% with the magnetic field perpendicular to its in-plane. We also observe unusual reentrant metallic behavior, which is caused by the carrier mismatch in the multiband transport. Our works help to establish fundamental understandings on quasi 1D van der Waals semimetallic AuSe and identify it as a new candidate for exploring giant magnetoresistance and compensated semimetals.
基金supported by the National Natural Science Foundation of China(No.U1632273,No.21673214,No.U1732272,and No.U1832165)
文摘Direct Z-scheme CdO-CdS 1-dimensional nanorod arrays were constructed through a facile and simple hydrothermal process. The structure, morphology, photoelectrochemical properties and H2 evolution activity of this catalyst were investigated systematically. The morphology of the obtained nanorod is a regular hexagonal prism with 100-200 nm in diameter. The calcination temperature and time were optimized carefully to achieve the highest photoelectrochemical performance. The as-fabricated hybrid system achieved a photocurrent density up to 6.5 mA/cm2 and H2 evolution rate of 240 μmol·cm-2·h-1 at 0 V vs. Ag/AgCl, which is about 2-fold higher than that of the bare CdS nanorod arrays. The PEC performance exceeds those previously reported similar systems. A direct Z-scheme photocatalytic mechanism was proposed based on the structure and photoelectrochemical performance characterization results, which can well explain the high separation efficiency of photoinduced carriers and the excellent redox ability.
文摘A novel chain complex was synthesized and its crystal structure has been deter- mined by X-ray diffraction technique. It was found that the local coordination geometry around Cu(Ⅱ) is a distorted tetrahedron and C14H9CuNO3CH3OH is bridged by the carboxylate oxygen atom to form an infinite one-dimensional linear chain. The hydrogen bond exists between O(1) and solvate molecule O(4). The crystal belongs to monoclinic, space group P21 with a = 9.6650(19), b = 7.1280(14), c = 9.925(2) ? b = 98.39(3)? V = 676.4(2) 3, Z = 2, F(000) = 342 and m(MoK? = 1.629 mm-1 .
基金supported by the National Natural Science Foundation of China(No.52172046).
文摘In the endeavor to develop three-dimensional(3D)-architected sophisticated hierarchical structures,the synergy between inplane and out-of-plane interactions at interfaces offers new functionalities.This interplay,governed by van der Waals(vdW)interfacial nanoarchitectonics,facilitates the design of efficient thermally conductive pathways.This work delves into the kinetics underlying a dual-templating strategy,seamlessly integrating two-dimensional(2D)-graphene sheets with one-dimensional(1D)-cellulose chains at heterointerfaces,thereby transforming into 3D-shaped and 3D-continuously anisotropic structures,termed as(3D^(2)GC)architecture.Hereby,we designed and fabricated an anisotropic graphene cellulose scaffold(GCS)employing a nickel template.The as-grown GCS replicates the 3D-shaped and configuration of the template.The 3D-continuously interconnected fibrous-porous network of the GCS,combined with its anisotropic thermal properties(λ_(axial)/λ_(radial)),not only is promising for advanced thermal technologies but also offers advantages in cost-effectiveness and eco-effectiveness.
基金supported by the National Natural Science Foundation of China(22202065 and 22479079)Natural Science Foundation of Jiangsu Province(BK20201381)+1 种基金Science Foundation of Nanjing University of Posts and Telecommunications(NY219144 and NY221046)National College Student Innovation and Entrepreneurship Training Program(202310293010Z)。
文摘With the advancement of atomic manufacturing technology,single atom array(SAA)has emerged as a groundbreaking advancement in catalysis and materials science.Single atom array catalyst(SAAC),composed of precisely arranged isolated metal atoms,exhibits unique electronic properties and exceptional catalytic efficiencies,making it highly promising for energy conversion processes such as hydrogen production and carbon dioxide reduction.SAA maximizes atomic utilization by using individual atoms as independent catalytic centres,allowing each atom to directly participate in the reaction.The optimized electronic structure of single atoms improves binding efficiency and enhances catalytic performance.Furthermore,single atoms have tunable properties,enabling adaptation to various reactions.Organizing metal atoms into well-defined one-dimensional(1D)or 2D arrays also improves both stability and performance,offering a more efficient alternative to conventional catalysts.However,there are pressing challenges in achieving uniformity,stability,and scalability of SAAC in both synthesis and practical applications.It is urgent to summarize and address these critical issues to unlock the full potential of SAAC for large-scale industrial applications.In this review,we systematically summarize the latest innovations in the synthesis and application of SAA.We also introduce advanced fabrication techniques such as atomic layer deposition,chemical vapor deposition,and electronic interface-guided reduction,and evaluate their impact on catalytic performance in detail.Finally,we emphasize the role of SAA in tackling major energy challenges and propose future research directions to overcome the current barriers,aiming to develop high-performance,sustainable solutions for clean energy technologies.
基金the National Natural Science Foundation of China(No.90606006)the State Key Project of Fundamental Research for Nanoscience and Nanotechnology(No.2006CB932300).
文摘Orthorhombic LiMnO_(2)nanoparticles and LiMnO_(2)nanorods have been synthesized by hydrothermal methods.LiMnO_(2)nanoparticles were synthesized by simple one-step hydrothermal method.To obtain rod-like LiMnO_(2),γ-MnOOH nanorods were first synthesized and then the H+ions were completely replaced by Li+resulting in LiMnO_(2)nanorods.Their electrochemical performances were thoroughly investigated by galvanostatic tests.Although the LiMnO_(2)nanoparticles have smaller size than LiMnO_(2)nanorods,the latter exhibited higher discharge capacity and better cyclability.For example,the discharge capacities of LiMnO_(2)nanorods reached 200 mA·h/g over many cycles and remained above 180 mA·h/g after 30 cycles.However,the maximum capacity of LiMnO_(2)nanoparticles was only 170 mA·h/g and quickly decreased to 110 mA·h/g after 30 cycles.Nanorods with one-dimensional electronic pathways favor the transport of electrons along the length direction and accommodate volume changes resulting from charge/discharge processes.Thus the morphology of LiMnO_(2)may play an important role in electrochemical performance.
