A microbial consortium named Y4 capable of producing biopolymers was isolated from petroleum-contaminated soil in the Dagang Oilfield, China. It includes four bacterial strains： Y4-1 （Paenibacillus sp.）, Y4-2 （Act...A microbial consortium named Y4 capable of producing biopolymers was isolated from petroleum-contaminated soil in the Dagang Oilfield, China. It includes four bacterial strains： Y4-1 （Paenibacillus sp.）, Y4-2 （Actinomadura sp.）, Y4-3 （Uncultured bacterium clone） and Y4-4 （Brevibacillus sp.）. The optimal conditions for the growth of the consortium Y4 were as follows： temperature about 46 ℃, pH about 7.0 and salinity about 20.0 g/L. The major metabolites were analyzed with gas chromatographymass spectrometry （GC-MS）. A comparison was made between individual strains and the microbial consortium for biopolymer production in different treatment processes. The experimental results showed that the microbial consortium Y4 could produce more biopolymers than individual strains, and the reason might be attributed to the synergetic action of strains. The biopolymers were observed with optical and electron microscopes and analyzed by paper chromatography. It was found that the biopolymers produced by the microbial consortium Y4 were insoluble in water and were of reticular structure, and it was concluded that the biopolymers were cellulose. Through a series of simulation experiments with sand cores, it was found that the microbial consortium Y4 could reduce the permeability of reservoir beds, and improve the efficiency of water flooding by growing biomass and producing biopolymers. The oil recovery was enhanced by 3.5% on average. The results indicated that the consortium Y4 could be used in microbial enhanced oil recovery and play an important role in bioremediation of oil polluted environments.展开更多
The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated fro...The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media.展开更多
Experiments on surface-active polymer flooding for enhanced oil recovery were carried out by detection analysis and modern physical simulation technique based on reservoirs and fluids in Daqing placanticline oilfield....Experiments on surface-active polymer flooding for enhanced oil recovery were carried out by detection analysis and modern physical simulation technique based on reservoirs and fluids in Daqing placanticline oilfield.The experimental results show that the surface-active polymer is different from other common polymers and polymer-surfactant systems in molecular aggregation,viscosity and flow capacity,and it has larger molecular coil size,higher viscosity and viscosifying capacity,and poorer mobility.The surface-active polymer solution has good performance of viscosity-increasing and viscosity retention,and has good performance of viscoelasticity and deformability to exert positive effects of viscosifying and viscoelastic properties.Surface-active polymer can change the chemical property of interface and reduce interfacial tension,making the reservoir rock turn water-wet,also it can emulsify the oil into relatively stable oil-in-water emulsion,and emulsification capacity is an important property to enhance oil washing efficiency under non-ultralow interfacial tension.The surface-active polymer flooding enlarges swept volume in two ways:Microscopically,the surface-active polymer has mobility control effect and can enter oil-bearing pores not swept by water to drive residual oil,and its mobility control effect has more contribution than oil washing capacity in enhancing oil recovery.Macroscopically,it has plugging capacity,and can emulsify and plug the dominant channels in layers with high permeability,forcing the injected fluid to enter the layer with medium or low permeability and low flow resistance,and thus enlarging swept volume.展开更多
Two main challenges exist in enhancing oil recovery rate from tight oil reservoirs,namely how to create an effective complicated fracture network and how to enhance the imbibition effect of fracturing fluid.In respons...Two main challenges exist in enhancing oil recovery rate from tight oil reservoirs,namely how to create an effective complicated fracture network and how to enhance the imbibition effect of fracturing fluid.In response to the challenges,through modeling experiment in laboratory and evaluation of field application results,a set of integrated efficient fracturing and enhanced oil recovery(EOR)techniques suitable for tight oil development in China has been proposed.(1)Fracturing with temporary plugging agents to realize stimulation in multiple clusters,to form dense fracture network,and thus maximizing the drainage area;(2)Supporting induced fractures with micro-sized proppants during the prepad fluid fracture-making stage,to generate dense fracture network with high conductivity;(3)Using the liquid nanofluid as a fracturing fluid additive to increase oil-water displacement ratio and take advantage of the massive injected fracturing fluid and maximize the oil production after hydraulic fracturing.展开更多
The hydration products and microstructure of class G oil well cement and a newly developed plugging agent （YLD） slurries cured in the simulated temperature and pressure environment, which was of similar temperature ...The hydration products and microstructure of class G oil well cement and a newly developed plugging agent （YLD） slurries cured in the simulated temperature and pressure environment, which was of similar temperature and pressure with those at the bottom of oil well in a normal depth, were investigated using XRD, TG and SEM. Severe leakage is confirmed at the interface between hardened slurries and steel tube during the dynamically curing process, which induces the quick loss of cementing property of slurries. This should be the dominating cause of degradation of class G oil well cement slurry. A secondary hydration process can take place at the eroded interface of hardened YLD plugging agent slurry. Newly formed C-S-H gel has a self-healing effect to repair the damaged interface, which unceasingly maintains the cementing property of the YLD plugging agent slurry. Therefore, the effective using period of YLD plugging agent can be prolonged.展开更多
Tight oil reservoirs in Songliao Basin were taken as subjects and a novel idealized refracturing well concept was proposed by considering the special parameters of volume fracturing horizontal wells, the refracturing ...Tight oil reservoirs in Songliao Basin were taken as subjects and a novel idealized refracturing well concept was proposed by considering the special parameters of volume fracturing horizontal wells, the refracturing potential of candidate wells were graded and prioritized, and a production prediction model of refracturing considering the stress sensitivity was established using numerical simulation method to sort out the optimal refracturing method and timing. The simulations show that: with the same perforation clusters, the order of fracturing technologies with contribution to productivity from big to small is refracturing between existent fractured sections, orientation diversion inside fractures, extended refracturing, refracturing of existent fractures; and the later the refracturing timing, the shorter the effective time. Based on this, the prediction model of breakdown pressure considering the variation of formation pressure was used to find out the variation pattern of breakdown pressure of different positions at different production time. Through the classification of the breakdown pressure, the times of temporary plugging and diverting and the amount of temporary plugging agent were determined under the optimal refracturing timing. Daily oil production per well increased from 2.3 t/d to 16.5 t/d in the field test. The research results provide important reference for refracturing optimization design of similar tight oil reservoirs.展开更多
基金National High Technology Research and Development Program of China(863 Programs)(Grant No:2007AA021306)Department of Scientific and Technical Development of CNPC(Grant No:2008A-1403)
文摘A microbial consortium named Y4 capable of producing biopolymers was isolated from petroleum-contaminated soil in the Dagang Oilfield, China. It includes four bacterial strains： Y4-1 （Paenibacillus sp.）, Y4-2 （Actinomadura sp.）, Y4-3 （Uncultured bacterium clone） and Y4-4 （Brevibacillus sp.）. The optimal conditions for the growth of the consortium Y4 were as follows： temperature about 46 ℃, pH about 7.0 and salinity about 20.0 g/L. The major metabolites were analyzed with gas chromatographymass spectrometry （GC-MS）. A comparison was made between individual strains and the microbial consortium for biopolymer production in different treatment processes. The experimental results showed that the microbial consortium Y4 could produce more biopolymers than individual strains, and the reason might be attributed to the synergetic action of strains. The biopolymers were observed with optical and electron microscopes and analyzed by paper chromatography. It was found that the biopolymers produced by the microbial consortium Y4 were insoluble in water and were of reticular structure, and it was concluded that the biopolymers were cellulose. Through a series of simulation experiments with sand cores, it was found that the microbial consortium Y4 could reduce the permeability of reservoir beds, and improve the efficiency of water flooding by growing biomass and producing biopolymers. The oil recovery was enhanced by 3.5% on average. The results indicated that the consortium Y4 could be used in microbial enhanced oil recovery and play an important role in bioremediation of oil polluted environments.
基金Ministry of Higher Education (Vot No. Q.J130000.2542.08H61)Universiti Teknologi (UTM) Malaysia for supporting this research
文摘The influence of surface-modified silica(SiO_2) nanoparticles on the stability and pore plugging properties of foams in porous media was investigated in this study. The pore plugging ability of foams was estimated from the pressure drop induced during foam propagation in porous media. The results clearly showed that the modified Si02 nanoparticlestabilized foam exhibited high stability, and the differential pressure increased in porous media by as much as three times.The addition of SiO_2 nanoparticles to the foaming dispersions further mitigated the adverse effect of oil toward the foam pore plugging ability. Consequently, the oil recovery increased in the presence of nanoparticles by approximately 15%during the enhanced oil recovery experiment. The study suggested that the addition of surface-modified silica nanoparticles to the surfactant solution could considerably improve the conventional foam stability and pore plugging performance in porous media.
基金Supported by China National Science and Technology Major Project(2016ZX05010002-004 and 2016ZX05023005-001-003)China Postdoctoral Science Foundation(2019M651255)National Natural Science Foundation of China(51804078).
文摘Experiments on surface-active polymer flooding for enhanced oil recovery were carried out by detection analysis and modern physical simulation technique based on reservoirs and fluids in Daqing placanticline oilfield.The experimental results show that the surface-active polymer is different from other common polymers and polymer-surfactant systems in molecular aggregation,viscosity and flow capacity,and it has larger molecular coil size,higher viscosity and viscosifying capacity,and poorer mobility.The surface-active polymer solution has good performance of viscosity-increasing and viscosity retention,and has good performance of viscoelasticity and deformability to exert positive effects of viscosifying and viscoelastic properties.Surface-active polymer can change the chemical property of interface and reduce interfacial tension,making the reservoir rock turn water-wet,also it can emulsify the oil into relatively stable oil-in-water emulsion,and emulsification capacity is an important property to enhance oil washing efficiency under non-ultralow interfacial tension.The surface-active polymer flooding enlarges swept volume in two ways:Microscopically,the surface-active polymer has mobility control effect and can enter oil-bearing pores not swept by water to drive residual oil,and its mobility control effect has more contribution than oil washing capacity in enhancing oil recovery.Macroscopically,it has plugging capacity,and can emulsify and plug the dominant channels in layers with high permeability,forcing the injected fluid to enter the layer with medium or low permeability and low flow resistance,and thus enlarging swept volume.
基金Supported by the China National Science and Technology Major Project(2016ZX05051-03,2016ZX05030-05)PetroChina Innovation Foundation(2018D-5007-0205)the Science Foundation of China University of Petroleum at Beijing(2462017YJRC031).
文摘Two main challenges exist in enhancing oil recovery rate from tight oil reservoirs,namely how to create an effective complicated fracture network and how to enhance the imbibition effect of fracturing fluid.In response to the challenges,through modeling experiment in laboratory and evaluation of field application results,a set of integrated efficient fracturing and enhanced oil recovery(EOR)techniques suitable for tight oil development in China has been proposed.(1)Fracturing with temporary plugging agents to realize stimulation in multiple clusters,to form dense fracture network,and thus maximizing the drainage area;(2)Supporting induced fractures with micro-sized proppants during the prepad fluid fracture-making stage,to generate dense fracture network with high conductivity;(3)Using the liquid nanofluid as a fracturing fluid additive to increase oil-water displacement ratio and take advantage of the massive injected fracturing fluid and maximize the oil production after hydraulic fracturing.
文摘The hydration products and microstructure of class G oil well cement and a newly developed plugging agent （YLD） slurries cured in the simulated temperature and pressure environment, which was of similar temperature and pressure with those at the bottom of oil well in a normal depth, were investigated using XRD, TG and SEM. Severe leakage is confirmed at the interface between hardened slurries and steel tube during the dynamically curing process, which induces the quick loss of cementing property of slurries. This should be the dominating cause of degradation of class G oil well cement slurry. A secondary hydration process can take place at the eroded interface of hardened YLD plugging agent slurry. Newly formed C-S-H gel has a self-healing effect to repair the damaged interface, which unceasingly maintains the cementing property of the YLD plugging agent slurry. Therefore, the effective using period of YLD plugging agent can be prolonged.
基金Supported by the National Natural Science Foundation of China(51525404,51504203)China National Science and Technology Major Project(2016ZX05002002)
文摘Tight oil reservoirs in Songliao Basin were taken as subjects and a novel idealized refracturing well concept was proposed by considering the special parameters of volume fracturing horizontal wells, the refracturing potential of candidate wells were graded and prioritized, and a production prediction model of refracturing considering the stress sensitivity was established using numerical simulation method to sort out the optimal refracturing method and timing. The simulations show that: with the same perforation clusters, the order of fracturing technologies with contribution to productivity from big to small is refracturing between existent fractured sections, orientation diversion inside fractures, extended refracturing, refracturing of existent fractures; and the later the refracturing timing, the shorter the effective time. Based on this, the prediction model of breakdown pressure considering the variation of formation pressure was used to find out the variation pattern of breakdown pressure of different positions at different production time. Through the classification of the breakdown pressure, the times of temporary plugging and diverting and the amount of temporary plugging agent were determined under the optimal refracturing timing. Daily oil production per well increased from 2.3 t/d to 16.5 t/d in the field test. The research results provide important reference for refracturing optimization design of similar tight oil reservoirs.
