The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983...The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.展开更多
基金Supported by the Key Laboratory of Non-ferrous Metal Materials and New Processing TechnologyMinistry of Education and the State Key Laboratory of Coordination Chemistry
文摘The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
