Epigenomes including genome-wide histone modification and DNA methylation profiles are important for genome activity and fof defining gene expression patterns of plant development and responses to various environmenta...Epigenomes including genome-wide histone modification and DNA methylation profiles are important for genome activity and fof defining gene expression patterns of plant development and responses to various environmental conditions. Rice is the most important crop plant and serves as a model for cereal genomics. Rice epigenomic landscape is emerging and the function of chromatin modification regulators in gene expression, transposon repression and plant development is being characterized. Epigenomic variation that gives rise to stable or transgenerational heritable epialleles related to variation of important agronomical traits or stress responses is being characterized in rice. Implication of epigenomic variation in rice heterosis is being exploited.展开更多
The Eu3＋-doped La2Zr207 phosphor with rod-like morphology was successfully synthesized by conventional solid state reaction and hydrothermal method. X-ray diffraction patterns, transmission electron microscopy, and p...The Eu3＋-doped La2Zr207 phosphor with rod-like morphology was successfully synthesized by conventional solid state reaction and hydrothermal method. X-ray diffraction patterns, transmission electron microscopy, and photoluminescence spectra were employed to charac- terize its structure and morphology as well as luminescent properties. The results indicated that the red-emitting phosphor La2Zr207：Eu3＋ had well crystallized and belonged to the cubic structure with space group of Fd3m. The as-obtained product mainly appeared as straight nanorods with an average diameter of 47 nm and length of 50-700 nm. The pos- sible growth mechanism was also discussed. It was found that under blue excitation with a wavelength of 466 nm, the La2Zr2OT：Eu3＋ phosphor exhibited a characteristic red emission at 616 nm that was attributed to the hypersensitive 5D0--＊TF2 electric dipole transition of Eu3＋ ions. Meanwhile, it was more interesting to note that the emission of 5D1--＊TFj （J=0, 1, 2） transitions and the splitting patterns of 5D0---＋TFJ （J--l, 2, 4） transitions of Eu3＋ ions can be observed in the luminescent spectra of La2Zr207：Eu3＋. It was demonstrated that Eu3＋ preferred to occupy a low symmetry site.展开更多
In present study, the effect of the solvent annealing temperature on the crystal modifications and the phase transition behavior of the subsequently dried poly（3-octylthiophene） （P3OT） film has been investigated b...In present study, the effect of the solvent annealing temperature on the crystal modifications and the phase transition behavior of the subsequently dried poly（3-octylthiophene） （P3OT） film has been investigated by the combination of DSC, WAXD and FTIR techniques. When chloroform is employed as the solvent, it is unexpectedly found that form I and form II crystal modifications of P3OT could be respectively obtained by room temperature and low temperature annealing. Comparing to the mostly used solvent reported for preparing form II, i.e. carbon disulfide （CS2） which is toxic and corrosive, chloroform is less toxic and corrosive and more suitable for solution processing of P3OT. Therefore, this finding provides an alternative way to obtain form II. By temperature dependent IR spectroscopy, the structural evolution of P3OT during the form II to form I phase transition process has also been studied in detail.展开更多
Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is...Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is not very great,but their magnetic behaviours are different from each other.The magnetization loops of these compounds have been measured at 77K.The coexistence of superconductivity with magnetic ordering (COSM) found in the samples with RE=Gd,Dy,Ho,Er,Tm,indicates that there are two possible ways of coexistence in the samples.These expertments show that the relation of paramagnetism to the atomtc number of rare earth elements for these superconductors is similar to that of rare earth ions in some paramagnetic salt crystals,which indicates that the magnetism of the samples origi- nates from the local magnetic moments of rare earth ions.In some samples there is antiferromagnetie ordering at low temperatures,and the effective Bohr magneton numbers are consistent with that of free rare earth ions. Some superconducting parameters including the critical current density are calculated according to Ginzburg-Landau theory and the critical state model.展开更多
We have researched the performances of organic photovoltaic devices with the bulk heterojunction （BHJ） structure using the organic solution-processable functionalized graphene （SPFGraphene） material as the electro...We have researched the performances of organic photovoltaic devices with the bulk heterojunction （BHJ） structure using the organic solution-processable functionalized graphene （SPFGraphene） material as the electron-accepter material and P3OT as the donor material. The structural configuration of the device is ITO/PEDOT：PSS/P3OT：PCBM-SPFGraphene/LiF/A1. Given the P3OT/PCBM （1：1） mixture with 8wt% of SPFGraphene, the open-circuit voltage （Voc） of the device reaches 0.64 V, a short-circuit current density （J^c） reaches 5.7 mA/cm2, a fill factor （FF） reaches 0.42, and the power conversion efficiency （7？） reaches 1.53% at illumination at 100 mW/cm2 AM1.5. We further studied the reason for the device performances improvement In the P3OT：PCBM-SPFGraphene composite, the SPFGraphene material acts as exciton dissociation sites and provides the transport pathways of the lowest unoccupied molecular orbital （LUMO）-SPFGraphene-A1. Furthermore, adding SPFGraphene to P3OT results in appropriate energetic distance between the highest occupied molecular orbital （HOMO） and LUMO of the donoffacceptor and provides higher exciton dissociation volume mobility of carrier transport. We have researched the effect of annealing treatment for the devices and found that the devices with annealing treatment at 180℃ show better performances compared with devices without annealed treatment. The devices with annealed treatment show the best performance, with an enhancement of the power conversion efficiency from 1.53% to 1.75%.展开更多
基金supported by a grant of the Transgenic Program of the Chinese Ministry of Agriculture (No.2009ZX08009-078B)the National High-Tech R&D Program(863 Program)on rice functional genomics of the Ministry ofScience and Technology(Nos.2012AA10A303 and 2012AA10A304)supported by the program blanc CERES of the French Agence Nationale de la Recherche
文摘Epigenomes including genome-wide histone modification and DNA methylation profiles are important for genome activity and fof defining gene expression patterns of plant development and responses to various environmental conditions. Rice is the most important crop plant and serves as a model for cereal genomics. Rice epigenomic landscape is emerging and the function of chromatin modification regulators in gene expression, transposon repression and plant development is being characterized. Epigenomic variation that gives rise to stable or transgenerational heritable epialleles related to variation of important agronomical traits or stress responses is being characterized in rice. Implication of epigenomic variation in rice heterosis is being exploited.
文摘The Eu3＋-doped La2Zr207 phosphor with rod-like morphology was successfully synthesized by conventional solid state reaction and hydrothermal method. X-ray diffraction patterns, transmission electron microscopy, and photoluminescence spectra were employed to charac- terize its structure and morphology as well as luminescent properties. The results indicated that the red-emitting phosphor La2Zr207：Eu3＋ had well crystallized and belonged to the cubic structure with space group of Fd3m. The as-obtained product mainly appeared as straight nanorods with an average diameter of 47 nm and length of 50-700 nm. The pos- sible growth mechanism was also discussed. It was found that under blue excitation with a wavelength of 466 nm, the La2Zr2OT：Eu3＋ phosphor exhibited a characteristic red emission at 616 nm that was attributed to the hypersensitive 5D0--＊TF2 electric dipole transition of Eu3＋ ions. Meanwhile, it was more interesting to note that the emission of 5D1--＊TFj （J=0, 1, 2） transitions and the splitting patterns of 5D0---＋TFJ （J--l, 2, 4） transitions of Eu3＋ ions can be observed in the luminescent spectra of La2Zr207：Eu3＋. It was demonstrated that Eu3＋ preferred to occupy a low symmetry site.
基金financially supported by the Taishan Mountain Scholar Constructive Engineering Foundation(No.TS20081120)Natural Science Fund for Distinguished Young Scholars of Shandong Province(No.JQ200905)
文摘In present study, the effect of the solvent annealing temperature on the crystal modifications and the phase transition behavior of the subsequently dried poly（3-octylthiophene） （P3OT） film has been investigated by the combination of DSC, WAXD and FTIR techniques. When chloroform is employed as the solvent, it is unexpectedly found that form I and form II crystal modifications of P3OT could be respectively obtained by room temperature and low temperature annealing. Comparing to the mostly used solvent reported for preparing form II, i.e. carbon disulfide （CS2） which is toxic and corrosive, chloroform is less toxic and corrosive and more suitable for solution processing of P3OT. Therefore, this finding provides an alternative way to obtain form II. By temperature dependent IR spectroscopy, the structural evolution of P3OT during the form II to form I phase transition process has also been studied in detail.
基金Supported by the Chinese National Science Foundation and originally published in J.Chin.RE Soc.(Chin.ed.),1989,7(2),63.
文摘Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is not very great,but their magnetic behaviours are different from each other.The magnetization loops of these compounds have been measured at 77K.The coexistence of superconductivity with magnetic ordering (COSM) found in the samples with RE=Gd,Dy,Ho,Er,Tm,indicates that there are two possible ways of coexistence in the samples.These expertments show that the relation of paramagnetism to the atomtc number of rare earth elements for these superconductors is similar to that of rare earth ions in some paramagnetic salt crystals,which indicates that the magnetism of the samples origi- nates from the local magnetic moments of rare earth ions.In some samples there is antiferromagnetie ordering at low temperatures,and the effective Bohr magneton numbers are consistent with that of free rare earth ions. Some superconducting parameters including the critical current density are calculated according to Ginzburg-Landau theory and the critical state model.
基金supported by the National Outstanding Youth Science Foundation (Grant No. 60825407)the National Basic Research Program of China (Grant Nos. 2011CB932700 and 2011CB932703)+3 种基金the National Natural Science Foundation of China (Grant Nos. 60877025 and61077044)Beijing Science and Technology Committee (Grant Nos.Z101103055810003 and D090803044009001)Beijing Natural Science Fund Project (Grant No. 2092024)the Excellent Doctor’s Science and Technology Innovation Foundation of Beijing Jiaotong University, China(Grant No. 2011YJS279)
文摘We have researched the performances of organic photovoltaic devices with the bulk heterojunction （BHJ） structure using the organic solution-processable functionalized graphene （SPFGraphene） material as the electron-accepter material and P3OT as the donor material. The structural configuration of the device is ITO/PEDOT：PSS/P3OT：PCBM-SPFGraphene/LiF/A1. Given the P3OT/PCBM （1：1） mixture with 8wt% of SPFGraphene, the open-circuit voltage （Voc） of the device reaches 0.64 V, a short-circuit current density （J^c） reaches 5.7 mA/cm2, a fill factor （FF） reaches 0.42, and the power conversion efficiency （7？） reaches 1.53% at illumination at 100 mW/cm2 AM1.5. We further studied the reason for the device performances improvement In the P3OT：PCBM-SPFGraphene composite, the SPFGraphene material acts as exciton dissociation sites and provides the transport pathways of the lowest unoccupied molecular orbital （LUMO）-SPFGraphene-A1. Furthermore, adding SPFGraphene to P3OT results in appropriate energetic distance between the highest occupied molecular orbital （HOMO） and LUMO of the donoffacceptor and provides higher exciton dissociation volume mobility of carrier transport. We have researched the effect of annealing treatment for the devices and found that the devices with annealing treatment at 180℃ show better performances compared with devices without annealed treatment. The devices with annealed treatment show the best performance, with an enhancement of the power conversion efficiency from 1.53% to 1.75%.
