In the wavelength range of 231-275 nm, we have studied the mass-resolved dissociation spectra of OCS＋ via B2∑＋←X2П3/2（000） and B2∑＋←X2П1/2（000, 001） transitions by preparing OCS＋ ions in the well-defined...In the wavelength range of 231-275 nm, we have studied the mass-resolved dissociation spectra of OCS＋ via B2∑＋←X2П3/2（000） and B2∑＋←X2П1/2（000, 001） transitions by preparing OCS＋ ions in the well-defined spin-orbit states. The spectroscopic constants of v1 （CS stretch）=828.9 （810.4） cm-1, u2 （bend）=491.3 cm-1 and v3（CO stretch）=1887.2 cm-1 for OCS＋（B2∑＋） are deduced. The observed dependence of the v2（bend） mode excitation of B2∑＋ on the spin-orbit splitting of X2П（Ω=1/2, 3/2） in the B2∑＋←-X2П transition can be attributed to the K coupling between the （000）2П1/2 and （010）2∑＋/2 vibronic levels of X2П state, which makes the B2∑＋（010）←X2П1/2（000） transition possible.展开更多
The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The nat...The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The natural architecture and composition of native OC interfaces can be replicated using biomaterial scaffolds via regenerative engineering approaches.A novel one-step bioextrusion process was employed to fabricate a unitary synthetic graft(USG),which mimics the native OC interface’s mineral concentration gradient.This novel USG is composed of an agarose-based cartilage layer and a bone layer,consisting of agarose enriched with 20%(200 g/L)hydroxyapatite.The USG features a gradient interface with mineral concentrations transitioning from 0%to 20%(mass fraction),mimicking the transition between the cartilage and bone.Thermogravimetric analysis revealed that the gradient transition lengths of the graft and native OC tissue harvested from bovine knees were similar((647±21)vs.(633±124)μm).The linear viscoelastic properties of the grafts,which were evaluated using strain sweep and frequency sweep tests with oscillatory shear,indicated a dominant storage modulus over loss modulus similar to that of native OC tissues.The compressive and stress relaxation behaviors of the USGs demonstrated that the graft maintained structural integrity under mechanical stress.Viability assays performed after bioextrusion showed that chondrocytes and human fetal osteoblast cells successfully integrated and survived within their designated regions of the graft.The novel USGs exhibit properties similar to native OC tissue and are promising candidates for regenerating OC defects and restoring knee joint functionality.展开更多
The Equilibrium geometrical optimizations on OCS linear and nonlinear molecules in the singlet and triplet states have been made using density functional theory B3LYP method with 6-31l++G**and aug-CC-pVTZ basis sets.T...The Equilibrium geometrical optimizations on OCS linear and nonlinear molecules in the singlet and triplet states have been made using density functional theory B3LYP method with 6-31l++G**and aug-CC-pVTZ basis sets.The ground state is 1∑with linear C∞v symmetry The linear and nonlinear structures in singlet state can be stable,and there is only nonlinear stablestructure in triplet state.展开更多
文摘In the wavelength range of 231-275 nm, we have studied the mass-resolved dissociation spectra of OCS＋ via B2∑＋←X2П3/2（000） and B2∑＋←X2П1/2（000, 001） transitions by preparing OCS＋ ions in the well-defined spin-orbit states. The spectroscopic constants of v1 （CS stretch）=828.9 （810.4） cm-1, u2 （bend）=491.3 cm-1 and v3（CO stretch）=1887.2 cm-1 for OCS＋（B2∑＋） are deduced. The observed dependence of the v2（bend） mode excitation of B2∑＋ on the spin-orbit splitting of X2П（Ω=1/2, 3/2） in the B2∑＋←-X2П transition can be attributed to the K coupling between the （000）2П1/2 and （010）2∑＋/2 vibronic levels of X2П state, which makes the B2∑＋（010）←X2П1/2（000） transition possible.
基金supported by the School of Engineering and Digital Sciences of Nazarbayev University,Astana,Kazakhstan(to CE)。
文摘The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The natural architecture and composition of native OC interfaces can be replicated using biomaterial scaffolds via regenerative engineering approaches.A novel one-step bioextrusion process was employed to fabricate a unitary synthetic graft(USG),which mimics the native OC interface’s mineral concentration gradient.This novel USG is composed of an agarose-based cartilage layer and a bone layer,consisting of agarose enriched with 20%(200 g/L)hydroxyapatite.The USG features a gradient interface with mineral concentrations transitioning from 0%to 20%(mass fraction),mimicking the transition between the cartilage and bone.Thermogravimetric analysis revealed that the gradient transition lengths of the graft and native OC tissue harvested from bovine knees were similar((647±21)vs.(633±124)μm).The linear viscoelastic properties of the grafts,which were evaluated using strain sweep and frequency sweep tests with oscillatory shear,indicated a dominant storage modulus over loss modulus similar to that of native OC tissues.The compressive and stress relaxation behaviors of the USGs demonstrated that the graft maintained structural integrity under mechanical stress.Viability assays performed after bioextrusion showed that chondrocytes and human fetal osteoblast cells successfully integrated and survived within their designated regions of the graft.The novel USGs exhibit properties similar to native OC tissue and are promising candidates for regenerating OC defects and restoring knee joint functionality.
文摘The Equilibrium geometrical optimizations on OCS linear and nonlinear molecules in the singlet and triplet states have been made using density functional theory B3LYP method with 6-31l++G**and aug-CC-pVTZ basis sets.The ground state is 1∑with linear C∞v symmetry The linear and nonlinear structures in singlet state can be stable,and there is only nonlinear stablestructure in triplet state.
