采用DRI Model 2001A热/光碳分析仪测定了2011年南京地区大气PM1.1中OC、EC的含量,并具体探讨了其来源.结果表明,南师OC、EC年均浓度分别为10.10μg·m-3、2.52μg·m-3,南化分别为11.22μg·m-3、3.12μg·m-3,南化污...采用DRI Model 2001A热/光碳分析仪测定了2011年南京地区大气PM1.1中OC、EC的含量,并具体探讨了其来源.结果表明,南师OC、EC年均浓度分别为10.10μg·m-3、2.52μg·m-3,南化分别为11.22μg·m-3、3.12μg·m-3,南化污染相对严重.夏季两地OC、EC含量较低,而冬春季较高,这与冬春季燃煤量增加,并且受内陆西风及逆温的影响,污染物集中在南京市上空不易扩散有关.两地PM1.1中SOC/TOC均在夏季较高,冬季最低.秋季SOC和O3有较好的相关性,表明秋季光化学反应是SOC的重要生成途径.展开更多
为了解华南背景区域鼎湖山站碳质气溶胶的浓度水平与来源,采用DRI Model 2001A热/光碳分析仪测定了鼎湖山站大气颗粒物分级样品中的有机碳(OC)与元素碳(EC)浓度水平,并分析了碳质组分的浓度特征和粒径分布.结果表明,在PM1.1、PM2.1和PM...为了解华南背景区域鼎湖山站碳质气溶胶的浓度水平与来源,采用DRI Model 2001A热/光碳分析仪测定了鼎湖山站大气颗粒物分级样品中的有机碳(OC)与元素碳(EC)浓度水平,并分析了碳质组分的浓度特征和粒径分布.结果表明,在PM1.1、PM2.1和PM9.0中,鼎湖山OC的平均质量浓度分别为(5.6±2.0)、(7.3±2.4)和(12.8±4.0)μg·m^-3,EC的平均质量浓度分别为(2.3±1.4)、(2.7±1.6)和(3.4±1.7)μg·m^-3.PM1.1和PM2.1中OC分别占PM9.0中OC的43.8%和57.0%,EC占67.6%和79.4%.OC和EC主要富集在细粒子中.PM1.1和PM2.1中OC和EC在秋季最高,OC在冬季最低,EC在夏季最低.PM9.0中OC夏季最高.鼎湖山中碳质气溶胶以OC2、EC1、OC3和OC4为主,夏季OC3>EC1,生物排放源增强,冬季EC1质量浓度最高,局地的机动车排放源更强.OC和EC在4个季节都呈现双峰型分布,细粒径段峰值位于0.43~0.65μm,粗粒径段峰值出现在3.3~5.8μm.PM1.1和PM2.1中OC以一次排放为主,二次有机碳(SOC)在春季最高[(3.0±1.4)μg·m^-3],冬季最低[(1.3±1.4)μg·m^-3],春季二次转化更强.鼎湖山大气细粒径段OC主要来自燃煤和机动车排放,粗粒径段主要来自生物源排放,EC主要受到燃煤、机动车排放和扬尘的影响.展开更多
Long-time large-area haze weather appeared in Wuhan on June 11, 2012. It was monitored that PM2.5 hourly concentration obviously rose, and peak value reached 658 μg/m3. OC and PM2.5 presented high correlation, and co...Long-time large-area haze weather appeared in Wuhan on June 11, 2012. It was monitored that PM2.5 hourly concentration obviously rose, and peak value reached 658 μg/m3. OC and PM2.5 presented high correlation, and correlation coefficient was 0.96. OC daily average concentration occupied 10% -20% in PM2.5, and difference was big between haze and normal weather. EC occupied 5%, and difference was very small between haze and normal weather. By analyzing change trend of OC/EC, it was found that OC/EC presented increasing trend in late May and was even higher than that during 11 -15 June. It was clear that biomass combustion taking straw as the representation has started in late May. But two strong precipitation on May 29 and June 6 inhibited haze weather, and specific meteorological condition caused haze on June 11. Proportion of SOC to OC reached 14% -70%, illustrating that daily difference of secondary photochemical reaction was very big in Wuhan. OC/EC values were respectively 2.7, 3.5 and 4.2 in May, June and haze period. SOC daily means were respectively （5.33 ±4.77） and （32.5 ±23.4） μg/m^3 in May and haze period. Major pollution source of haze weather was biomass combustion, and haze occurrence had very big relationship with special meteorological condition.展开更多
文摘采用DRI Model 2001A热/光碳分析仪测定了2011年南京地区大气PM1.1中OC、EC的含量,并具体探讨了其来源.结果表明,南师OC、EC年均浓度分别为10.10μg·m-3、2.52μg·m-3,南化分别为11.22μg·m-3、3.12μg·m-3,南化污染相对严重.夏季两地OC、EC含量较低,而冬春季较高,这与冬春季燃煤量增加,并且受内陆西风及逆温的影响,污染物集中在南京市上空不易扩散有关.两地PM1.1中SOC/TOC均在夏季较高,冬季最低.秋季SOC和O3有较好的相关性,表明秋季光化学反应是SOC的重要生成途径.
文摘为了解华南背景区域鼎湖山站碳质气溶胶的浓度水平与来源,采用DRI Model 2001A热/光碳分析仪测定了鼎湖山站大气颗粒物分级样品中的有机碳(OC)与元素碳(EC)浓度水平,并分析了碳质组分的浓度特征和粒径分布.结果表明,在PM1.1、PM2.1和PM9.0中,鼎湖山OC的平均质量浓度分别为(5.6±2.0)、(7.3±2.4)和(12.8±4.0)μg·m^-3,EC的平均质量浓度分别为(2.3±1.4)、(2.7±1.6)和(3.4±1.7)μg·m^-3.PM1.1和PM2.1中OC分别占PM9.0中OC的43.8%和57.0%,EC占67.6%和79.4%.OC和EC主要富集在细粒子中.PM1.1和PM2.1中OC和EC在秋季最高,OC在冬季最低,EC在夏季最低.PM9.0中OC夏季最高.鼎湖山中碳质气溶胶以OC2、EC1、OC3和OC4为主,夏季OC3>EC1,生物排放源增强,冬季EC1质量浓度最高,局地的机动车排放源更强.OC和EC在4个季节都呈现双峰型分布,细粒径段峰值位于0.43~0.65μm,粗粒径段峰值出现在3.3~5.8μm.PM1.1和PM2.1中OC以一次排放为主,二次有机碳(SOC)在春季最高[(3.0±1.4)μg·m^-3],冬季最低[(1.3±1.4)μg·m^-3],春季二次转化更强.鼎湖山大气细粒径段OC主要来自燃煤和机动车排放,粗粒径段主要来自生物源排放,EC主要受到燃煤、机动车排放和扬尘的影响.
文摘Long-time large-area haze weather appeared in Wuhan on June 11, 2012. It was monitored that PM2.5 hourly concentration obviously rose, and peak value reached 658 μg/m3. OC and PM2.5 presented high correlation, and correlation coefficient was 0.96. OC daily average concentration occupied 10% -20% in PM2.5, and difference was big between haze and normal weather. EC occupied 5%, and difference was very small between haze and normal weather. By analyzing change trend of OC/EC, it was found that OC/EC presented increasing trend in late May and was even higher than that during 11 -15 June. It was clear that biomass combustion taking straw as the representation has started in late May. But two strong precipitation on May 29 and June 6 inhibited haze weather, and specific meteorological condition caused haze on June 11. Proportion of SOC to OC reached 14% -70%, illustrating that daily difference of secondary photochemical reaction was very big in Wuhan. OC/EC values were respectively 2.7, 3.5 and 4.2 in May, June and haze period. SOC daily means were respectively （5.33 ±4.77） and （32.5 ±23.4） μg/m^3 in May and haze period. Major pollution source of haze weather was biomass combustion, and haze occurrence had very big relationship with special meteorological condition.
