Quaternary intraplate magmatism formed several volcanic islands and seamounts,including Dokdo(DD),Ulleungdo(UD),Simheungtack(ST),Anyongbok,and Isabu in the southwest of the East Sea back-arc basin.In this study,we pre...Quaternary intraplate magmatism formed several volcanic islands and seamounts,including Dokdo(DD),Ulleungdo(UD),Simheungtack(ST),Anyongbok,and Isabu in the southwest of the East Sea back-arc basin.In this study,we present whole-rock geochemical,zircon U–Pb age,and in situ O–Hf isotope data for the submerged volcanic rocks from DD,UD,and ST to provide new insights into the eruption timing of these volcanoes and constrain the magma evolution processes.All samples used in this study were trachytes and exhibited ferroan,alkalic,and metaluminous to weakly peraluminous characteristics.They showed light rare earth element(REE)-enriched patterns with(La/Yb)N ratios of 25.3–31.7 and mostly negative Eu anomalies in a chondrite-normalized REE plot.In addition,they were enriched in large-ion lithophile elements and high field strength elements;they exhibited positive Pb anomalies and strongly negative Ba,Sr,P,and Ti anomalies.The zircons yielded a weighted-mean 206Pb/238U age of 2.61,0.348–0.704,and 2.76–2.94 Ma for the DD,UD,and ST trachytes,respectively.All zircons exhibited lowerδ^(18)O values than normal depleted mantle values,regardless of the crystallization age and spatial distribution of volcanoes.Theδ^(18)O values showed no correlation with U contents or Th/U ratios,indicating that the lowδ^(18)O signatures were of primary magmatic origin.The Hf isotopic compositions of the zircons were relatively heterogeneous but predominately characterized by positive eHf values.Binary O–Hf mixing modeling revealed that low-δ^(18)O rocks with positive eHf values from the UD and ST volcanoes were derived from a hybrid source of recycled juvenile crustal materials with low-δ^(18)O and positive eHf signatures and an enriched mantle source with normalδ^(18)O and negative eHf values.The juvenile oceanic crust in the source was likely metasomatized by seawater at high temperatures prior to melting.In contrast,the felsic magma that formed the DD volcanoes may have assimilated with regional basement rocks(Triassic–Jurassic granitoids),resulting in increasedδ^(18)O values and decreased eHf values relative to those of the UD and ST volcanoes.Our study highlights the significant contribution of recycled oceanic crust materials to the generation of the Quaternary magmas.展开更多
华南地区是我国重要的稀有金属矿产区,绝大部分具经济规模的稀有金属矿床均与高演化的富Li-F花岗岩有成因联系。大坪花岗斑岩位于南岭构造带最东缘福建省永定地区,与区内Nb-Ta矿床形成有关。该岩体SIMS和LA-ICP-MS锆石U-Pb定年结果分别...华南地区是我国重要的稀有金属矿产区,绝大部分具经济规模的稀有金属矿床均与高演化的富Li-F花岗岩有成因联系。大坪花岗斑岩位于南岭构造带最东缘福建省永定地区,与区内Nb-Ta矿床形成有关。该岩体SIMS和LA-ICP-MS锆石U-Pb定年结果分别为186.7±1.2Ma和190.7±1.1Ma,是华南少见的早侏罗世(200~180Ma)侵入的花岗岩侵入体,也是华南最早报道的早侏罗世稀有金属成矿事件。大坪花岗斑岩具高钾低镁、准铝质到弱过铝质的特征,属于高钾钙碱性花岗岩,并显示A型花岗岩的地球化学特征,如富硅(72.81%~76.44%)、高10000×Ga/Al比值、高FeO^T/MgO和高的Zr+Nb+Ce+Y含量、亏损高场强元素和Eu负异常明显等。全岩体系低的Zr/Hf、Nb/Ta比值,指示岩浆具有较高的分异演化程度,Nb 2 O 5和Ta 2 O 5均含量达到了花岗岩型稀有金属矿床的工业品位。花岗斑岩中锆石Hf-O同位素分析结果显示,其具有比较亏损的Hf同位素与比较均一的O同为素组成(εHf(t)=-2.4~3.4,δ^18 O=6.0‰~6.6‰)。结合微量元素地球化学特征,大坪花岗斑岩源区主要来源于软流圈地幔,并有约20%~30%壳源岩浆的加入,在成岩过程中发生了显著的分离结晶。晚期富氟的流体出熔并向上迁移可能对于Nb和Ta的再次富集与分异具有重要作用。大坪花岗斑岩与闽西南地区同时期的火山岩,如藩坑组双峰式火山岩,在空间上可与前人提出的“南岭山脉早侏罗世发育的东西向裂谷岩浆岩带(OIB型玄武岩、辉长岩和A型花岗岩组合)”相对应,是该裂谷带向东的延伸。展开更多
基金This research was supported by a project on the sustainable research and development of Dokdo(Grant No.PG52911)which is funded by the Ministry of Oceans and Fisheries,South Korea.
文摘Quaternary intraplate magmatism formed several volcanic islands and seamounts,including Dokdo(DD),Ulleungdo(UD),Simheungtack(ST),Anyongbok,and Isabu in the southwest of the East Sea back-arc basin.In this study,we present whole-rock geochemical,zircon U–Pb age,and in situ O–Hf isotope data for the submerged volcanic rocks from DD,UD,and ST to provide new insights into the eruption timing of these volcanoes and constrain the magma evolution processes.All samples used in this study were trachytes and exhibited ferroan,alkalic,and metaluminous to weakly peraluminous characteristics.They showed light rare earth element(REE)-enriched patterns with(La/Yb)N ratios of 25.3–31.7 and mostly negative Eu anomalies in a chondrite-normalized REE plot.In addition,they were enriched in large-ion lithophile elements and high field strength elements;they exhibited positive Pb anomalies and strongly negative Ba,Sr,P,and Ti anomalies.The zircons yielded a weighted-mean 206Pb/238U age of 2.61,0.348–0.704,and 2.76–2.94 Ma for the DD,UD,and ST trachytes,respectively.All zircons exhibited lowerδ^(18)O values than normal depleted mantle values,regardless of the crystallization age and spatial distribution of volcanoes.Theδ^(18)O values showed no correlation with U contents or Th/U ratios,indicating that the lowδ^(18)O signatures were of primary magmatic origin.The Hf isotopic compositions of the zircons were relatively heterogeneous but predominately characterized by positive eHf values.Binary O–Hf mixing modeling revealed that low-δ^(18)O rocks with positive eHf values from the UD and ST volcanoes were derived from a hybrid source of recycled juvenile crustal materials with low-δ^(18)O and positive eHf signatures and an enriched mantle source with normalδ^(18)O and negative eHf values.The juvenile oceanic crust in the source was likely metasomatized by seawater at high temperatures prior to melting.In contrast,the felsic magma that formed the DD volcanoes may have assimilated with regional basement rocks(Triassic–Jurassic granitoids),resulting in increasedδ^(18)O values and decreased eHf values relative to those of the UD and ST volcanoes.Our study highlights the significant contribution of recycled oceanic crust materials to the generation of the Quaternary magmas.
文摘华南地区是我国重要的稀有金属矿产区,绝大部分具经济规模的稀有金属矿床均与高演化的富Li-F花岗岩有成因联系。大坪花岗斑岩位于南岭构造带最东缘福建省永定地区,与区内Nb-Ta矿床形成有关。该岩体SIMS和LA-ICP-MS锆石U-Pb定年结果分别为186.7±1.2Ma和190.7±1.1Ma,是华南少见的早侏罗世(200~180Ma)侵入的花岗岩侵入体,也是华南最早报道的早侏罗世稀有金属成矿事件。大坪花岗斑岩具高钾低镁、准铝质到弱过铝质的特征,属于高钾钙碱性花岗岩,并显示A型花岗岩的地球化学特征,如富硅(72.81%~76.44%)、高10000×Ga/Al比值、高FeO^T/MgO和高的Zr+Nb+Ce+Y含量、亏损高场强元素和Eu负异常明显等。全岩体系低的Zr/Hf、Nb/Ta比值,指示岩浆具有较高的分异演化程度,Nb 2 O 5和Ta 2 O 5均含量达到了花岗岩型稀有金属矿床的工业品位。花岗斑岩中锆石Hf-O同位素分析结果显示,其具有比较亏损的Hf同位素与比较均一的O同为素组成(εHf(t)=-2.4~3.4,δ^18 O=6.0‰~6.6‰)。结合微量元素地球化学特征,大坪花岗斑岩源区主要来源于软流圈地幔,并有约20%~30%壳源岩浆的加入,在成岩过程中发生了显著的分离结晶。晚期富氟的流体出熔并向上迁移可能对于Nb和Ta的再次富集与分异具有重要作用。大坪花岗斑岩与闽西南地区同时期的火山岩,如藩坑组双峰式火山岩,在空间上可与前人提出的“南岭山脉早侏罗世发育的东西向裂谷岩浆岩带(OIB型玄武岩、辉长岩和A型花岗岩组合)”相对应,是该裂谷带向东的延伸。
