The reaction of[CpMo(CO)_2]_2 with 8,8'-diquinolyl disulphide C_9H_6NSSNC_9H_6 resulted in the cleavage of Mo≡Mo triple bond to give a new nononuclear complex CpMo(CO)_2(N,S-C_9H_6NS)which was refluxed with PPh_3...The reaction of[CpMo(CO)_2]_2 with 8,8'-diquinolyl disulphide C_9H_6NSSNC_9H_6 resulted in the cleavage of Mo≡Mo triple bond to give a new nononuclear complex CpMo(CO)_2(N,S-C_9H_6NS)which was refluxed with PPh_3 in THF to form the title complex.The crystal structure of the title complex was determined by X-ray diffraction.展开更多
文摘The reaction of[CpMo(CO)_2]_2 with 8,8'-diquinolyl disulphide C_9H_6NSSNC_9H_6 resulted in the cleavage of Mo≡Mo triple bond to give a new nononuclear complex CpMo(CO)_2(N,S-C_9H_6NS)which was refluxed with PPh_3 in THF to form the title complex.The crystal structure of the title complex was determined by X-ray diffraction.
