The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emi...The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emissions or through new particle formation events.However,their variations during the lockdown period are under investigation.This study focuses on Luohe,a city on the southern edge of the North China Plain,analyzing the changes in PNC and its sources before,during,and after the COVID-19 lockdown.From March 25^(th)to May 31^(st),2022,real-time PNC measurements were conducted using a Scanning Mobility Particle Sizer for particle size.Results showed an 11.2%decrease in PNC during the lockdown compared to pre-lockdown and a 3.6%decrease compared to post-lockdown,indicating reduced local emissions and weakened regional transportation during the lockdown.Positive Matrix Factorization analysis identified six sources contributing to the total PNC,including photochemical nucleation,aged photochemical nucleation,gasoline vehicle emissions,diesel vehicle emissions,coal and biomass combustion,and secondary aerosols.The significant changes in source emissions indicate a substantially reduced traffic volume after the implementation of lockdown measures(2644.8#/cm^(3),2202.2#/cm^(3),2792.7#/cm^(3)).Concurrently,photochemical nucleation(310.1#/cm^(3),306.3#/cm^(3),393.1#/cm^(3))and photochemical nucleation aging(592.8#/cm^(3),744.1#/cm^(3),810.7#/cm^(3))exhibited increasing trends,while coal/biomass combustion(1656.6#/cm^(3),1586.2#/cm^(3),980.0#/cm^(3))and secondary sources(999.4#/cm^(3),791.1#/cm^(3),804.1#/cm^(3))showed decreasing trends.In summary,the contributions of traffic emissions to PNC highlight the potential for targeted traffic management strategies to improve urban air quality.展开更多
The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteri...The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteristics of fine particles of the different observation seasons. Relative high number concentrations for the particles in the diameter range of 10-500 nm were observed in both seasons. It was found that the dominant number distributed in particle diameter smaller than 100 nm and the percentage over the number concentration of all air particles is much higher than what has been measured in other urban sites over the world. The number mean diameter in summer was much smaller than in winter, strongly suggesting the different origin of ultrafine particles in different seasons. That is, particles in ultrafine mode mainly came from nucleation and new particle formation in summer while from traffic emission in winter. The diurnal variation also supported this point. Number concentration in the diameter range of 10-200 um got their peak values at noontime, well correlated with the mixing ratio of SO2 and the intensity of solar radiation in summer. While in winter, those in the same diameter range showed the main peaks during the traffic hours happened in the morning and evening.展开更多
A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles ...A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles （ 〉2μm） increased more significantly than fine particles （ 〈2μm） during the dust storm due to dust weather, while the anthropogenic aerosols collected during the non-dust-storm period tended to be associated with fine particles. Elemental compositions were analyzed by using proton-induced X-ray emission （PIXE）. The results show that 20 elements in the dust storm were much higher than in the non-dust-storm period. The calculated soil dust concentration during the dust storm was, on average, 251.8μg m^-3, while it was only 52.1μg m^-3 on non-dust-storm days. The enrichment factors for Mg, A1, P, K, Ca, Ti, Mn, Fe, C1, Cu, Pb, and Zn show small variations between the dust storm and the non-dust-storm period, while those for Ca, Ni and Cr in the dust storm were much lower than those in the non-dust-storm period due to significant local emission sources. A high concentration and enrichment factor for S were observed during the dust storm, which implies that the dust particles were contaminated by aerosol particles from anthropogenic emissions during the long-range transport. A statistical analysis shows that the elemental composition of particles collected during the dust storm in Beijing were better correlated with those of desert soil colleted from desert regions in Inner Mongolia. Air mass back-trajectory analysis further confirmed that this dust storm event could be identified as streaks of dust plumes originating from Inner Mongolia.展开更多
The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts th...The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts the cloud number concentration(Nc)explicitly in aspects of warm-rain hydrometeors number concentrations and DSDs,the simulation of the WDM6 scheme is compared with airborne observations of a flight trial,as well as with the simulations of the Thompson scheme and Morrison scheme.Results show that the WDM6 scheme produces smaller(larger)cloud(rain)number concentrations and wider cloud DSDs compared to the observations,with the largest biases at upper levels of stratiform cloud(SC).The Thompson scheme and the Morrison scheme,both of which set the Nc as a constant,compare better to the observations than the WDM6 scheme in aspects of Nc and DSD.Sensitivity tests of the initial cloud condensation nuclei(CCN)number concentration(CCN0)of the WDM6 scheme show that a better choice of the initial CCN0 may improve the simulation of convective cloud but helps little in terms of SC.The simulation of rain number concentration and DSD is not sensitive to the CCN0 in the WDM6 scheme.展开更多
In this study, a three-dimensional model based on RANS, slender-body theory and Newton-Euler dynamics is established to study the number concentration, one of the most important fluidization characteristics of cylindr...In this study, a three-dimensional model based on RANS, slender-body theory and Newton-Euler dynamics is established to study the number concentration, one of the most important fluidization characteristics of cylindrical particles. Also, the effects of interaction between cylindrical particles are taken into account by introducing the rigid collision dynamics. To validate the model, the fluidization experiments of cylindrical particles in a cold-state fluidized bed are carried out. The number concentration characteristics of cylindrical particles are obtained from computational fluid dynamics (CFD) simulation. It is found that cylindrical particles arriving at the exit of the riser the earliest come from the near-wall regions, the horizontal transfer of so many cylindrical particles from the radial centre regions to the near-wall regions is evident. Meanwhile, there is no distinct relationship between the number concentration and inlet wind velocity.展开更多
Ultrafine particles are associated with adverse health effects. Total Particle Number Concentration（TNC） of fine particles were measured during 2002 at the St. Louis — Midwest supersite. The time series showed over...Ultrafine particles are associated with adverse health effects. Total Particle Number Concentration（TNC） of fine particles were measured during 2002 at the St. Louis — Midwest supersite. The time series showed overall low level with frequent large peaks. The time series was analyzed alongside criteria pollutant measurements and meteorological observations. Multiple regression analysis was used to identify further contributing factors and to determine the association of different pollutants with TNC levels. This showed the strong contribution of sulfur dioxide（SO2） and nitrogen oxides（NO x） to high TNC levels. The analysis also suggested that increased dispersion resulting from faster winds and higher mixing heights led to higher TNC levels. Overall, the results show that there were intense particle nucleation events in a SO2 rich plume reaching the site which contributed around 29% of TNC. A further 40% was associated with primary emissions from mobile sources. By separating the remaining TNC by time of day and clear sky conditions,we suggest that most likely 8% of TNC are due to regional nucleation events and 23% are associated with the general urban background.展开更多
Particle size distribution of 12-500 nm was measured at Mt. Waliguan, China Global Atmosphere Watch Baseline Observatory, from Aug. in 2005 to May in 2007.72-hr back-trajectories at 100-m arrival height above ground l...Particle size distribution of 12-500 nm was measured at Mt. Waliguan, China Global Atmosphere Watch Baseline Observatory, from Aug. in 2005 to May in 2007.72-hr back-trajectories at 100-m arrival height above ground level for the same period were calculated at 6：00, 12：00, and 21：00 （Beijing Time） for each day using the Hybrid Single-Particle Lagrangian Integrated Trajectory （HYSPLIT-4） model developed by NOAA/ARL. It was found that air mass sources significantly impact particle number concentration and size distribution at Mt. Waliguan. Cluster analysis of back-trajectories show that higher Aitken mode particle number concentration was observed when air masses came from or passed by the northeastern section of Mt. Waliguan, with short trajectory length. High number concentration of nucleation mode was associated with air masses from clean regions, with long trajectory length.展开更多
Particulate mass concentration (PM10, PM2.5), aerosol number concentration (NOPC), aerosol size distribu-tion and atmospheric visibility were simultaneously measured in Beijing in the summer and winter of 2001. From t...Particulate mass concentration (PM10, PM2.5), aerosol number concentration (NOPC), aerosol size distribu-tion and atmospheric visibility were simultaneously measured in Beijing in the summer and winter of 2001. From the profuse data collected, the following conclusions can be drown: (1) there are two peaks for the average diurnal variations of PM10 and NOPC in the summer, an obvious valley can be seen between 12:30 and 15:00 for their average diurnal variation in the winter; (2) there is one single peak for the average diurnal variation of atmospheric visibility in the summer, while there are two peaks in the winter; (3) PM10 and NOPC are usually smaller in the summer than those in the winter; (4) the average visibility is much lower during 00:00~09:00 in the summer than that in the winter, because of the very high relative humidity and higher concentration of the large particles (r>1.25 mm) in the summer during the period; (5) aerosol size distributions usually depend closely on season and relative humidity at the same place.展开更多
The time series of indoor and outdoor particle number concentrations in a naturally ventilated residential building in Xi＇an were tested simultaneously for 7 days in summer. The relationships between indoor and outdo...The time series of indoor and outdoor particle number concentrations in a naturally ventilated residential building in Xi＇an were tested simultaneously for 7 days in summer. The relationships between indoor and outdoor concentrations were examined and discussed, and linear regression analysis was employed to correlate the indoor and outdoor concentrations. The diurnal cycles of indoor and outdoor particle concentrations of different particle size ranges all showed positive correlations between indoor and outdoor number concentrations, The I/O ratios of number concentrations varied with the increase of particle size in the range of 0.89 （±0.19） to 0.99 （±0.15）.展开更多
Identifying supercooled liquid water(SLW)in clouds is critical for weather modification,aviation safety,and atmospheric radiation calculations.Currently,aircraft identification in the SLW area mostly depends on empric...Identifying supercooled liquid water(SLW)in clouds is critical for weather modification,aviation safety,and atmospheric radiation calculations.Currently,aircraft identification in the SLW area mostly depends on emprical estimation of cloud particle number concentration(N_(c))in China,and scientific verification and quantitative identification criteria are urgently needed.In this study,the observations are from the Fast Cloud Droplets Probe,Rosemount ice detector(RICE),and Cloud Particle Imager(CP_(i))onboard a King Air aircraft during seven flights in 2018 and 2019 over central and eastern China.Based on this,the correlation among N_(c),the proportion of spherical particles(P_(s)),and the probability of icing(P_(i))in supercooled stratiform and cumulus-stratus clouds is statistically analyzed.Subsequently,this study proposes a method to identify SLW areas using N_(c) in combination with ambient temperature.The reliability of this method is evaluated through the true skill statistics(TSS)and threat score(TS)methods.Numerous airborne observations during the seven flights reveal a strong correlation among Nc,P_(s),and P_(i)at the temperature from 0 to−18°C.When Nc is greater than a certain threshold of 5 cm^(−3),there is always the SLW,i.e.,P_(i)and P_(s)are high.Evaluation results demonstrate that the TSS and TS values for Nc=5 cm^(−3)are higher than those for Nc<5 cm^(−3),and a larger Nc threshold(>5 cm^(−3))corresponds to a higher SLW identification hit rate and a higher SLW content.Therefore,Nc=5 cm^(−3)can be used as the minimum criterion for identifying the SLW in clouds at temperature lower than 0°C.The SLW identification method proposed in this study is especially helpful in common situations where aircraft are equipped with only Nc probes and without the CP_(i)and RICE.展开更多
Evolution of number concentration of nanoparticles undergoing Brownian coagulation in the transition regime is studied theoretically and numerically. The results show that the curves of particle size distribution move...Evolution of number concentration of nanoparticles undergoing Brownian coagulation in the transition regime is studied theoretically and numerically. The results show that the curves of particle size distribution move toward the area with large particle diameters, the curve peak becomes lower and the range that particle diameters cover becomes wider as time elapses. In the process of coagulation the particles with small diameter disappear gradually and the particle size distribution remains a log-normal distribution. The change rate of the particle size distribution is more appreciable at the initial stage than that at the final stage. The initial Knudsen number has a significant effect on the coagulation rate which increases with decreasing the initial Knudsen number. The larger the initial geometric standard deviation is, the smaller the curve peak is, and the wider the area that curves cover is. The initial geometric standard deviation has a significant effect on the particle size distribution which can remain a self-preserving state when the initial geometric standard deviation is smaller than 2. With the increase of the diversity of initial particle size, the particle size distribution does not obey the log-normal distribution any more as time elapses.展开更多
Molar concentration of gold nanoparticles is one of the most critical parameters of gold colloids in order to develop their applications in sensing, diagnostics and nanomedicine. Previous methods often stand just for ...Molar concentration of gold nanoparticles is one of the most critical parameters of gold colloids in order to develop their applications in sensing, diagnostics and nanomedicine. Previous methods often stand just for gold nanoparticles with regular shape and narrow size distribution. In the present work, we proposed an absolute quantification method that determined the molar concentration of gold nanoparticles with arbitrary shapes and polydisperse sizes. This approach involved the real time monitoring and counting of individual nanoparticles collision events, from which the quantification of molar concentration was achieved using a theoretical model consisting of Fiek＇s laws of diffusion and Stokes-Einstein equation. The determination of spherical gold nanoparticles concentration resulted in excellent agreement with traditional spectrometry method. It was further demonstrated that the present approach can be expanded to determine the molar concentration of gold nanoparticles with arbitrary shapes and poly-diversed distributions.展开更多
By using the microphysical data of stratiform cloud in Henan which were observed by PMS airborne cloud particle measure system on March 23 in 2007 and combining with the radar,satellite,sounding data,the macro and mic...By using the microphysical data of stratiform cloud in Henan which were observed by PMS airborne cloud particle measure system on March 23 in 2007 and combining with the radar,satellite,sounding data,the macro and micro physical structure characteristics of cloud were analyzed.The results showed that the average diameter of small cloud drop which was measured by FSSP-100 in the warm layer of cloud was mainly during 5-12 μm,and the average value was 7.33 μm.The biggest diameter of small cloud drop changed during 14-47 μm,and the average value was 27.80 μm.The total number concentration scope of small cloud drop was during 47.73-352.00 drop/cm3,and the average value was 160 drop/cm3.In the cold layer of cloud,the biggest diameter of small cloud particle(included the cloud droplet and the ice crystals)which was measured by FSSP-100 was 24.8 μm.The total number concentration scope of small cloud particle was during 0.899-641.000 drop/cm3,and the average value was 297 drop/cm3.The airborne King heat line liquid water content instrument observed that the super-cooling liquid water existed in the cloud.The super-cooling cloud water content changed during 0.02-0.20 g/m3,and the average value was 0.093 g/m3.The biggest value which was 0.202 g/m3 appeared in 4 368 m height(the temperature was-8.5 ℃).The particle spectrum type in the cloud was mainly the negative exponent type and the single peak type.展开更多
To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed ...To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed during one event of November 4-9, 2010. Results show that the size distribution of aerosol concentration is bimodal on pollution days and normal days, with peak values at 60- 70 and 200-300 nm, respectively. Aerosol concentration is 104 cm-3.nm-1 on pollution days. The peak value of spectrum distribution of aerosol concentration on pollution days is 1.5-3.3 times higher than that on a normal day. Crop residual burning has a great impact on the concentration of fine particles. Diurnal variation of aerosol concentration is trimodal on pollution days and normal days, with peak values at 03：00, 09：00 and 19：00 local standard time. The first peak is impacted by meteorological elements, while the second and third peaks are due to human activities, such as rush hour traffic. Crop residual burning has the greatest impact on SO2 concentration, followed by NO2, 03 is hardly affected. The impact of crop residual burning on fine particles （〈 2.1 μm） is larger than on coarse particles （〉 2.1 μm）, thus ion concentration in fine particles is higher than that in coarse particles. Crop residual burning leads to similar increase in all ion components, thus it has a small impact on the water-soluble ions order. Crop residual burning has a strong impact on the size distribution of K^＋, Cl^-, Na^＋, and F- and has a weak impact on the size distributions of NH4^＋, Ca^2＋, NO3^- and SO4^2-.展开更多
Novel applications of nanotechnology may lead to the release of engineered nanoparticles（ENPs）, which result in concerns over their potential environmental hazardous impact. It is essential for the research workers ...Novel applications of nanotechnology may lead to the release of engineered nanoparticles（ENPs）, which result in concerns over their potential environmental hazardous impact. It is essential for the research workers to be able to quantitatively characterise ENPs in the environment and subsequently to assist the risk assessment of the ENPs. This study hence explored the application of nanoparticle tracking system（NTA） to quantitatively describe the behaviour of the ENPs in natural sediment-water systems. The NTA allows the measurement of both particle number concentration（PNC） and particle size distribution（PSD） of the ENPs. The developed NTA method was applied to a range of gold and magnetite ENPs with a selection of surface properties. The results showed that the positively-charged ENPs interacted more strongly with the sediment than neutral and negatively-charged ENPs. It was also found that the citrate coated Au ENPs had a higher distribution percentage（53%） than 11-mercaptoundecanoic acid coated Au ENPs（20%） and citrate coated magnetite ENPs（21%）. The principles of the electrostatic interactions between hard（and soft） acids and bases（HSAB） are used to explain such behaviours; the hard base coating（i.e. citrate ions） will interact more strongly with hard acid（i.e. magnetite） than soft acid（i.e. gold）.The results indicate that NTA is a complementary method to existing approaches to characterise the fate and behaviour of ENPs in natural sediment.展开更多
Number concentration and size distribution of atmospheric aerosols were measured in Beijing by an optical particle counter. The relationship between aerosol size distribution and relative humidity is discussed. The re...Number concentration and size distribution of atmospheric aerosols were measured in Beijing by an optical particle counter. The relationship between aerosol size distribution and relative humidity is discussed. The results show that the size distribution, diurnal variation, daily variation of atmospheric aerosols have a good relation to relative humidity and Richardson number. Key words Atmospheric aerosol - Number concentration - Size distribution - Relative humidity - Richardson number This work is financially supported by NKBRSF Project (G1999043400), Knowledge Creative Project (8-2101 and 82303) founded by TAP, CAS.The authors would like to express their thanks to Prof. Zhang Wen for his work in this observation.展开更多
Emission characterization of particle number as well as particle mass from three diesel passenger cars equipped with diesel particulate filter（DPF）, diesel oxidation catalyst（DOC）and exhaust gas recirculation（EGR...Emission characterization of particle number as well as particle mass from three diesel passenger cars equipped with diesel particulate filter（DPF）, diesel oxidation catalyst（DOC）and exhaust gas recirculation（EGR） under the vehicle driving cycles and regulatory cycle.Total particle number emissions（PNEs） decreased gradually during speed-up of vehicle from 17.3 to 97.3 km/hr. As the average vehicle speed increases, the size-segregated peak of particle number concentration shifts to smaller size ranges of particles. The correlation analysis with various particulate components such as particle number concentration（PNC）,ultrafine particle number concentration（UFPNC） and particulate matter（PM） mass was conducted to compare gaseous compounds（CO, CO2, HC and NOx）. The UFPNC and PM were not only emitted highly in Seoul during severe traffic jam conditions, but also have good correlation with hydrocarbons and NOxinfluencing high potential on secondary aerosol generation. The effect of the dilution temperature on total PNC under the New European Driving Cycle（NEDC）, was slightly higher than the dilution ratio. In addition, the nuclei mode（DP： ≤ 13 nm） was confirmed to be more sensitive to the dilution temperature rather than other particle size ranges. Comparison with particle composition between vehicle speed cycles and regulatory cycle showed that sulfate was slightly increased at regulatory cycle, while other components were relatively similar. During cold start test, semivolatile nucleation particles were increased due to effect of cold environment. Research on particle formation dependent on dilution conditions of diesel passenger cars under the NEDC is important to verify impact on vehicular traffic and secondary aerosol formation in Seoul.展开更多
Particulate matter（PM） from cooking has caused seriously indoor air pollutant and aroused risk to human health.It is urged to get deep knowledge of their spatial-temporal distribution of source emission characterist...Particulate matter（PM） from cooking has caused seriously indoor air pollutant and aroused risk to human health.It is urged to get deep knowledge of their spatial-temporal distribution of source emission characteristics,especially ultrafine particles（UFP ＆lt; 100 nm） and accumulation mode particles（AMP 100-555 nm）.Four commercial cooking oils are auto dipped water to simulate cooking fume under heating to 255℃ to investigate PM emission and decay features between 0.03 and 10 μm size dimension by electrical low pressure impactor（ELPI） without ventilation.Rapeseed and sunflower produced high PM_（2.5） around5.1 mg/m^3,in comparison with those of soybean and corn（5.87 and 4.55 mg/m^3,respectively）at peak emission time between 340 and 450 sec since heating oil,but with the same level of particle numbers 6-9 × 10~5/cm^3.Mean values of PM_（1.0）/PM_（2.5） and PM_（2.5）/PM_（10） at peak emission time are around 0.51-0.55 and 0.23-0.29.After 15 min naturally deposition,decay rates of PM_（1.0）,PM_（2.5） and PM_（10） are 13.3%-29.8%,20.1%-33.9%and 41.2%-54.7%,which manifest that PM_（1.0） is quite hard to decay than larger particles,PM_（2.5） and PM_（1.0）.The majority of the particle emission locates at 43 nm with the largest decay rate at 75%,and shifts to a larger size between137 and 555 nm after 15 min decay.The decay rates of the particles are sensitive to the oil type.展开更多
Simulation results of the WDM6 scheme and the Thompson scheme,both of which are commonly-used double-moment bulkmicrophysics schemes,are compared within theWeather Research and Forecasting model.The purpose of the com...Simulation results of the WDM6 scheme and the Thompson scheme,both of which are commonly-used double-moment bulkmicrophysics schemes,are compared within theWeather Research and Forecasting model.The purpose of the comparison is to study the difference in the aspects of the warm-rain hydrometeor number concentrations,the droplet size distributions,and the budgets of the rain mixing ratio and number concentration.It is found that the WDM6 scheme overestimates the ratio and the amount of large precipitation,and underestimates those of small precipitation,compared to the Thompson scheme.The cloud number concentration(CNC)predicted in the WDM6 scheme is one to three orders ofmagnitude smaller than that of the Thompson scheme,which is set to the specific valueof CNC.The cloud droplet spectra of the WDM6 scheme are broader.The WDM6 scheme produces a larger rain number concentration and smaller mass mean diameter of raindrops under the influence of both warm and cold rain processes—specifically,autoconversion and melting of snow and graupel.The WDM6 scheme produces a larger autoconversion rate and smaller total melting rate of snow and graupel than the Thompson scheme in the rain mixing ratio budget.The sign of the difference in the rain-cloud collection varieswith region,and the rain-cloud collection process together with evaporation of rain have a major influence on the sign of the surface precipitation difference between the two schemes.展开更多
From first principles, we find that the radar threshold reflectivity between nonprecipitating clouds and precipitating clouds is strongly related to not only the cloud droplet number concentration but also the spectra...From first principles, we find that the radar threshold reflectivity between nonprecipitating clouds and precipitating clouds is strongly related to not only the cloud droplet number concentration but also the spectral dispersion of cloud droplet size distributions. The further investigation indicates that the threshold value is an increasing function of spectral dispersion and cloud droplet number concentration. These results may improve our understanding of the cloud-precipitation interaction and the aerosol indirect effect.展开更多
基金supported by the National Research Program for Key Issues in Air Pollution Control in China(No.DQGG202137)the National Natural Science Foundation of China(No.42277429)。
文摘The COVID-19 lockdown was a typical example of extreme emission reduction,providing an opportunity to study the impact of lockdown measures on air pollution.Particle number concentrations(PNC)originate from direct emissions or through new particle formation events.However,their variations during the lockdown period are under investigation.This study focuses on Luohe,a city on the southern edge of the North China Plain,analyzing the changes in PNC and its sources before,during,and after the COVID-19 lockdown.From March 25^(th)to May 31^(st),2022,real-time PNC measurements were conducted using a Scanning Mobility Particle Sizer for particle size.Results showed an 11.2%decrease in PNC during the lockdown compared to pre-lockdown and a 3.6%decrease compared to post-lockdown,indicating reduced local emissions and weakened regional transportation during the lockdown.Positive Matrix Factorization analysis identified six sources contributing to the total PNC,including photochemical nucleation,aged photochemical nucleation,gasoline vehicle emissions,diesel vehicle emissions,coal and biomass combustion,and secondary aerosols.The significant changes in source emissions indicate a substantially reduced traffic volume after the implementation of lockdown measures(2644.8#/cm^(3),2202.2#/cm^(3),2792.7#/cm^(3)).Concurrently,photochemical nucleation(310.1#/cm^(3),306.3#/cm^(3),393.1#/cm^(3))and photochemical nucleation aging(592.8#/cm^(3),744.1#/cm^(3),810.7#/cm^(3))exhibited increasing trends,while coal/biomass combustion(1656.6#/cm^(3),1586.2#/cm^(3),980.0#/cm^(3))and secondary sources(999.4#/cm^(3),791.1#/cm^(3),804.1#/cm^(3))showed decreasing trends.In summary,the contributions of traffic emissions to PNC highlight the potential for targeted traffic management strategies to improve urban air quality.
基金Project supported by the National Basic Research Project(973)of China(No.2005CB422203)the National Post-Doctor Foundation of China(No.20060390990).
文摘The aerosol number concentration and size distribution were measured with the newly developed Wide-range Particle Spectrometer in summer and winter of 2006 at the urban site of Jinan City. Here reported the characteristics of fine particles of the different observation seasons. Relative high number concentrations for the particles in the diameter range of 10-500 nm were observed in both seasons. It was found that the dominant number distributed in particle diameter smaller than 100 nm and the percentage over the number concentration of all air particles is much higher than what has been measured in other urban sites over the world. The number mean diameter in summer was much smaller than in winter, strongly suggesting the different origin of ultrafine particles in different seasons. That is, particles in ultrafine mode mainly came from nucleation and new particle formation in summer while from traffic emission in winter. The diurnal variation also supported this point. Number concentration in the diameter range of 10-200 um got their peak values at noontime, well correlated with the mixing ratio of SO2 and the intensity of solar radiation in summer. While in winter, those in the same diameter range showed the main peaks during the traffic hours happened in the morning and evening.
文摘A continuous measurement of number size distributions and chemical composition of aerosol particles was conducted in Beijing in a dust storm event during 21-26 March 2001. The number concentration of coarse particles （ 〉2μm） increased more significantly than fine particles （ 〈2μm） during the dust storm due to dust weather, while the anthropogenic aerosols collected during the non-dust-storm period tended to be associated with fine particles. Elemental compositions were analyzed by using proton-induced X-ray emission （PIXE）. The results show that 20 elements in the dust storm were much higher than in the non-dust-storm period. The calculated soil dust concentration during the dust storm was, on average, 251.8μg m^-3, while it was only 52.1μg m^-3 on non-dust-storm days. The enrichment factors for Mg, A1, P, K, Ca, Ti, Mn, Fe, C1, Cu, Pb, and Zn show small variations between the dust storm and the non-dust-storm period, while those for Ca, Ni and Cr in the dust storm were much lower than those in the non-dust-storm period due to significant local emission sources. A high concentration and enrichment factor for S were observed during the dust storm, which implies that the dust particles were contaminated by aerosol particles from anthropogenic emissions during the long-range transport. A statistical analysis shows that the elemental composition of particles collected during the dust storm in Beijing were better correlated with those of desert soil colleted from desert regions in Inner Mongolia. Air mass back-trajectory analysis further confirmed that this dust storm event could be identified as streaks of dust plumes originating from Inner Mongolia.
基金sponsored by the National Natural Science Foundation of China [grant number 41530427 and41875172]supported by the demonstration project of artificial precipitation enhancement and hail suppression operation technology at the eastern side of Taihang Mountains [Grant No.hbrywcsy-2017-2]
文摘The number concentrations and drop size distributions(DSDs)of warm-rain hydrometeors play an important role in the simulation of microphysical processes.To evaluate the performance of the WDM6 scheme,which predicts the cloud number concentration(Nc)explicitly in aspects of warm-rain hydrometeors number concentrations and DSDs,the simulation of the WDM6 scheme is compared with airborne observations of a flight trial,as well as with the simulations of the Thompson scheme and Morrison scheme.Results show that the WDM6 scheme produces smaller(larger)cloud(rain)number concentrations and wider cloud DSDs compared to the observations,with the largest biases at upper levels of stratiform cloud(SC).The Thompson scheme and the Morrison scheme,both of which set the Nc as a constant,compare better to the observations than the WDM6 scheme in aspects of Nc and DSD.Sensitivity tests of the initial cloud condensation nuclei(CCN)number concentration(CCN0)of the WDM6 scheme show that a better choice of the initial CCN0 may improve the simulation of convective cloud but helps little in terms of SC.The simulation of rain number concentration and DSD is not sensitive to the CCN0 in the WDM6 scheme.
基金Supported by the Natural Science Fund for Colleges and Universities in Jiangsu Province(2011112TSJ0149)Jiangsu Key Laboratory of Process Enhancement & New Energy Equipment Technology at Nanjing University of Technology,China
文摘In this study, a three-dimensional model based on RANS, slender-body theory and Newton-Euler dynamics is established to study the number concentration, one of the most important fluidization characteristics of cylindrical particles. Also, the effects of interaction between cylindrical particles are taken into account by introducing the rigid collision dynamics. To validate the model, the fluidization experiments of cylindrical particles in a cold-state fluidized bed are carried out. The number concentration characteristics of cylindrical particles are obtained from computational fluid dynamics (CFD) simulation. It is found that cylindrical particles arriving at the exit of the riser the earliest come from the near-wall regions, the horizontal transfer of so many cylindrical particles from the radial centre regions to the near-wall regions is evident. Meanwhile, there is no distinct relationship between the number concentration and inlet wind velocity.
基金funded the present analysis through grant number RD-83455701the original measurements through cooperative agreement R-82805901-0
文摘Ultrafine particles are associated with adverse health effects. Total Particle Number Concentration（TNC） of fine particles were measured during 2002 at the St. Louis — Midwest supersite. The time series showed overall low level with frequent large peaks. The time series was analyzed alongside criteria pollutant measurements and meteorological observations. Multiple regression analysis was used to identify further contributing factors and to determine the association of different pollutants with TNC levels. This showed the strong contribution of sulfur dioxide（SO2） and nitrogen oxides（NO x） to high TNC levels. The analysis also suggested that increased dispersion resulting from faster winds and higher mixing heights led to higher TNC levels. Overall, the results show that there were intense particle nucleation events in a SO2 rich plume reaching the site which contributed around 29% of TNC. A further 40% was associated with primary emissions from mobile sources. By separating the remaining TNC by time of day and clear sky conditions,we suggest that most likely 8% of TNC are due to regional nucleation events and 23% are associated with the general urban background.
基金sponsored by National Key Development Program for Fundamental Research (973 Program) Project(Nos.2006CB403703 and 2006CB403701)
文摘Particle size distribution of 12-500 nm was measured at Mt. Waliguan, China Global Atmosphere Watch Baseline Observatory, from Aug. in 2005 to May in 2007.72-hr back-trajectories at 100-m arrival height above ground level for the same period were calculated at 6：00, 12：00, and 21：00 （Beijing Time） for each day using the Hybrid Single-Particle Lagrangian Integrated Trajectory （HYSPLIT-4） model developed by NOAA/ARL. It was found that air mass sources significantly impact particle number concentration and size distribution at Mt. Waliguan. Cluster analysis of back-trajectories show that higher Aitken mode particle number concentration was observed when air masses came from or passed by the northeastern section of Mt. Waliguan, with short trajectory length. High number concentration of nucleation mode was associated with air masses from clean regions, with long trajectory length.
文摘Particulate mass concentration (PM10, PM2.5), aerosol number concentration (NOPC), aerosol size distribu-tion and atmospheric visibility were simultaneously measured in Beijing in the summer and winter of 2001. From the profuse data collected, the following conclusions can be drown: (1) there are two peaks for the average diurnal variations of PM10 and NOPC in the summer, an obvious valley can be seen between 12:30 and 15:00 for their average diurnal variation in the winter; (2) there is one single peak for the average diurnal variation of atmospheric visibility in the summer, while there are two peaks in the winter; (3) PM10 and NOPC are usually smaller in the summer than those in the winter; (4) the average visibility is much lower during 00:00~09:00 in the summer than that in the winter, because of the very high relative humidity and higher concentration of the large particles (r>1.25 mm) in the summer during the period; (5) aerosol size distributions usually depend closely on season and relative humidity at the same place.
基金This work was supported by the National Natural Science Foundation of China （Grant No. 50578034, Grant No. 40475047）Shanghai Educational Development Foundation Titled ＂Shuguang Project＂, P.R. China （Grant No. 03SG30）.
文摘The time series of indoor and outdoor particle number concentrations in a naturally ventilated residential building in Xi＇an were tested simultaneously for 7 days in summer. The relationships between indoor and outdoor concentrations were examined and discussed, and linear regression analysis was employed to correlate the indoor and outdoor concentrations. The diurnal cycles of indoor and outdoor particle concentrations of different particle size ranges all showed positive correlations between indoor and outdoor number concentrations, The I/O ratios of number concentrations varied with the increase of particle size in the range of 0.89 （±0.19） to 0.99 （±0.15）.
基金Supported by the National Key Research and Development Program of China(2016YFA0601701)Fengyun Application Pioneering Project(FY-APP-2021.0102)National High Technology Research and Development Program of China(2012AA120902).
文摘Identifying supercooled liquid water(SLW)in clouds is critical for weather modification,aviation safety,and atmospheric radiation calculations.Currently,aircraft identification in the SLW area mostly depends on emprical estimation of cloud particle number concentration(N_(c))in China,and scientific verification and quantitative identification criteria are urgently needed.In this study,the observations are from the Fast Cloud Droplets Probe,Rosemount ice detector(RICE),and Cloud Particle Imager(CP_(i))onboard a King Air aircraft during seven flights in 2018 and 2019 over central and eastern China.Based on this,the correlation among N_(c),the proportion of spherical particles(P_(s)),and the probability of icing(P_(i))in supercooled stratiform and cumulus-stratus clouds is statistically analyzed.Subsequently,this study proposes a method to identify SLW areas using N_(c) in combination with ambient temperature.The reliability of this method is evaluated through the true skill statistics(TSS)and threat score(TS)methods.Numerous airborne observations during the seven flights reveal a strong correlation among Nc,P_(s),and P_(i)at the temperature from 0 to−18°C.When Nc is greater than a certain threshold of 5 cm^(−3),there is always the SLW,i.e.,P_(i)and P_(s)are high.Evaluation results demonstrate that the TSS and TS values for Nc=5 cm^(−3)are higher than those for Nc<5 cm^(−3),and a larger Nc threshold(>5 cm^(−3))corresponds to a higher SLW identification hit rate and a higher SLW content.Therefore,Nc=5 cm^(−3)can be used as the minimum criterion for identifying the SLW in clouds at temperature lower than 0°C.The SLW identification method proposed in this study is especially helpful in common situations where aircraft are equipped with only Nc probes and without the CP_(i)and RICE.
基金Project supported by the Major Program of the National Natural Science Foundation of China(Grant No.10632070)
文摘Evolution of number concentration of nanoparticles undergoing Brownian coagulation in the transition regime is studied theoretically and numerically. The results show that the curves of particle size distribution move toward the area with large particle diameters, the curve peak becomes lower and the range that particle diameters cover becomes wider as time elapses. In the process of coagulation the particles with small diameter disappear gradually and the particle size distribution remains a log-normal distribution. The change rate of the particle size distribution is more appreciable at the initial stage than that at the final stage. The initial Knudsen number has a significant effect on the coagulation rate which increases with decreasing the initial Knudsen number. The larger the initial geometric standard deviation is, the smaller the curve peak is, and the wider the area that curves cover is. The initial geometric standard deviation has a significant effect on the particle size distribution which can remain a self-preserving state when the initial geometric standard deviation is smaller than 2. With the increase of the diversity of initial particle size, the particle size distribution does not obey the log-normal distribution any more as time elapses.
基金supported by the National Natural Science Foundation of China(21405080)the Natural Science Foundation of Jiangsu Province(BK20150013,BK20140592)
文摘Molar concentration of gold nanoparticles is one of the most critical parameters of gold colloids in order to develop their applications in sensing, diagnostics and nanomedicine. Previous methods often stand just for gold nanoparticles with regular shape and narrow size distribution. In the present work, we proposed an absolute quantification method that determined the molar concentration of gold nanoparticles with arbitrary shapes and polydisperse sizes. This approach involved the real time monitoring and counting of individual nanoparticles collision events, from which the quantification of molar concentration was achieved using a theoretical model consisting of Fiek＇s laws of diffusion and Stokes-Einstein equation. The determination of spherical gold nanoparticles concentration resulted in excellent agreement with traditional spectrometry method. It was further demonstrated that the present approach can be expanded to determine the molar concentration of gold nanoparticles with arbitrary shapes and poly-diversed distributions.
基金Supported by Henan Meteorological Science and Technology Research Project(Z200407)
文摘By using the microphysical data of stratiform cloud in Henan which were observed by PMS airborne cloud particle measure system on March 23 in 2007 and combining with the radar,satellite,sounding data,the macro and micro physical structure characteristics of cloud were analyzed.The results showed that the average diameter of small cloud drop which was measured by FSSP-100 in the warm layer of cloud was mainly during 5-12 μm,and the average value was 7.33 μm.The biggest diameter of small cloud drop changed during 14-47 μm,and the average value was 27.80 μm.The total number concentration scope of small cloud drop was during 47.73-352.00 drop/cm3,and the average value was 160 drop/cm3.In the cold layer of cloud,the biggest diameter of small cloud particle(included the cloud droplet and the ice crystals)which was measured by FSSP-100 was 24.8 μm.The total number concentration scope of small cloud particle was during 0.899-641.000 drop/cm3,and the average value was 297 drop/cm3.The airborne King heat line liquid water content instrument observed that the super-cooling liquid water existed in the cloud.The super-cooling cloud water content changed during 0.02-0.20 g/m3,and the average value was 0.093 g/m3.The biggest value which was 0.202 g/m3 appeared in 4 368 m height(the temperature was-8.5 ℃).The particle spectrum type in the cloud was mainly the negative exponent type and the single peak type.
基金supported by the National Basic Research Program (973) of China (No. 2010CB428505)the National Natural Science Foundation of China (No. 41030962,40875078)+2 种基金the Research Fund for the Doctoral Program of Higher Education of China (No. 20093228110003)the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Jiangsu Provinc eGraduate Cultivation Innovative Project (No. CXZZ11-0616)
文摘To investigate the impact on urban air pollution by crop residual burning outside Nanjing, aerosol concentration, pollution gas concentration, mass concentration, and water-soluble ion size distribution were observed during one event of November 4-9, 2010. Results show that the size distribution of aerosol concentration is bimodal on pollution days and normal days, with peak values at 60- 70 and 200-300 nm, respectively. Aerosol concentration is 104 cm-3.nm-1 on pollution days. The peak value of spectrum distribution of aerosol concentration on pollution days is 1.5-3.3 times higher than that on a normal day. Crop residual burning has a great impact on the concentration of fine particles. Diurnal variation of aerosol concentration is trimodal on pollution days and normal days, with peak values at 03：00, 09：00 and 19：00 local standard time. The first peak is impacted by meteorological elements, while the second and third peaks are due to human activities, such as rush hour traffic. Crop residual burning has the greatest impact on SO2 concentration, followed by NO2, 03 is hardly affected. The impact of crop residual burning on fine particles （〈 2.1 μm） is larger than on coarse particles （〉 2.1 μm）, thus ion concentration in fine particles is higher than that in coarse particles. Crop residual burning leads to similar increase in all ion components, thus it has a small impact on the water-soluble ions order. Crop residual burning has a strong impact on the size distribution of K^＋, Cl^-, Na^＋, and F- and has a weak impact on the size distributions of NH4^＋, Ca^2＋, NO3^- and SO4^2-.
基金CEFIC LRI,Natural Science Foundation of Jiangsu Province(No.BK20130186)the Fundamental Research Funds for the Central Universities(No.2013QNA18)for funding this project
文摘Novel applications of nanotechnology may lead to the release of engineered nanoparticles（ENPs）, which result in concerns over their potential environmental hazardous impact. It is essential for the research workers to be able to quantitatively characterise ENPs in the environment and subsequently to assist the risk assessment of the ENPs. This study hence explored the application of nanoparticle tracking system（NTA） to quantitatively describe the behaviour of the ENPs in natural sediment-water systems. The NTA allows the measurement of both particle number concentration（PNC） and particle size distribution（PSD） of the ENPs. The developed NTA method was applied to a range of gold and magnetite ENPs with a selection of surface properties. The results showed that the positively-charged ENPs interacted more strongly with the sediment than neutral and negatively-charged ENPs. It was also found that the citrate coated Au ENPs had a higher distribution percentage（53%） than 11-mercaptoundecanoic acid coated Au ENPs（20%） and citrate coated magnetite ENPs（21%）. The principles of the electrostatic interactions between hard（and soft） acids and bases（HSAB） are used to explain such behaviours; the hard base coating（i.e. citrate ions） will interact more strongly with hard acid（i.e. magnetite） than soft acid（i.e. gold）.The results indicate that NTA is a complementary method to existing approaches to characterise the fate and behaviour of ENPs in natural sediment.
基金This work is financially supported by NKBRSF Project !(G1999043400) Knowledge Creative Project(8-2101 and 82303) founded by
文摘Number concentration and size distribution of atmospheric aerosols were measured in Beijing by an optical particle counter. The relationship between aerosol size distribution and relative humidity is discussed. The results show that the size distribution, diurnal variation, daily variation of atmospheric aerosols have a good relation to relative humidity and Richardson number. Key words Atmospheric aerosol - Number concentration - Size distribution - Relative humidity - Richardson number This work is financially supported by NKBRSF Project (G1999043400), Knowledge Creative Project (8-2101 and 82303) founded by TAP, CAS.The authors would like to express their thanks to Prof. Zhang Wen for his work in this observation.
基金supported by Transportation Pollution Research Center,National Institute of Environmental Research in Republic of Korea
文摘Emission characterization of particle number as well as particle mass from three diesel passenger cars equipped with diesel particulate filter（DPF）, diesel oxidation catalyst（DOC）and exhaust gas recirculation（EGR） under the vehicle driving cycles and regulatory cycle.Total particle number emissions（PNEs） decreased gradually during speed-up of vehicle from 17.3 to 97.3 km/hr. As the average vehicle speed increases, the size-segregated peak of particle number concentration shifts to smaller size ranges of particles. The correlation analysis with various particulate components such as particle number concentration（PNC）,ultrafine particle number concentration（UFPNC） and particulate matter（PM） mass was conducted to compare gaseous compounds（CO, CO2, HC and NOx）. The UFPNC and PM were not only emitted highly in Seoul during severe traffic jam conditions, but also have good correlation with hydrocarbons and NOxinfluencing high potential on secondary aerosol generation. The effect of the dilution temperature on total PNC under the New European Driving Cycle（NEDC）, was slightly higher than the dilution ratio. In addition, the nuclei mode（DP： ≤ 13 nm） was confirmed to be more sensitive to the dilution temperature rather than other particle size ranges. Comparison with particle composition between vehicle speed cycles and regulatory cycle showed that sulfate was slightly increased at regulatory cycle, while other components were relatively similar. During cold start test, semivolatile nucleation particles were increased due to effect of cold environment. Research on particle formation dependent on dilution conditions of diesel passenger cars under the NEDC is important to verify impact on vehicular traffic and secondary aerosol formation in Seoul.
基金supported by the strategic project of science and technology of Chinese Academy of Sciences(No.XDB05050000)
文摘Particulate matter（PM） from cooking has caused seriously indoor air pollutant and aroused risk to human health.It is urged to get deep knowledge of their spatial-temporal distribution of source emission characteristics,especially ultrafine particles（UFP ＆lt; 100 nm） and accumulation mode particles（AMP 100-555 nm）.Four commercial cooking oils are auto dipped water to simulate cooking fume under heating to 255℃ to investigate PM emission and decay features between 0.03 and 10 μm size dimension by electrical low pressure impactor（ELPI） without ventilation.Rapeseed and sunflower produced high PM_（2.5） around5.1 mg/m^3,in comparison with those of soybean and corn（5.87 and 4.55 mg/m^3,respectively）at peak emission time between 340 and 450 sec since heating oil,but with the same level of particle numbers 6-9 × 10~5/cm^3.Mean values of PM_（1.0）/PM_（2.5） and PM_（2.5）/PM_（10） at peak emission time are around 0.51-0.55 and 0.23-0.29.After 15 min naturally deposition,decay rates of PM_（1.0）,PM_（2.5） and PM_（10） are 13.3%-29.8%,20.1%-33.9%and 41.2%-54.7%,which manifest that PM_（1.0） is quite hard to decay than larger particles,PM_（2.5） and PM_（1.0）.The majority of the particle emission locates at 43 nm with the largest decay rate at 75%,and shifts to a larger size between137 and 555 nm after 15 min decay.The decay rates of the particles are sensitive to the oil type.
基金sponsored by the National Natural Science Foundation of China [grant number 41530427]
文摘Simulation results of the WDM6 scheme and the Thompson scheme,both of which are commonly-used double-moment bulkmicrophysics schemes,are compared within theWeather Research and Forecasting model.The purpose of the comparison is to study the difference in the aspects of the warm-rain hydrometeor number concentrations,the droplet size distributions,and the budgets of the rain mixing ratio and number concentration.It is found that the WDM6 scheme overestimates the ratio and the amount of large precipitation,and underestimates those of small precipitation,compared to the Thompson scheme.The cloud number concentration(CNC)predicted in the WDM6 scheme is one to three orders ofmagnitude smaller than that of the Thompson scheme,which is set to the specific valueof CNC.The cloud droplet spectra of the WDM6 scheme are broader.The WDM6 scheme produces a larger rain number concentration and smaller mass mean diameter of raindrops under the influence of both warm and cold rain processes—specifically,autoconversion and melting of snow and graupel.The WDM6 scheme produces a larger autoconversion rate and smaller total melting rate of snow and graupel than the Thompson scheme in the rain mixing ratio budget.The sign of the difference in the rain-cloud collection varieswith region,and the rain-cloud collection process together with evaporation of rain have a major influence on the sign of the surface precipitation difference between the two schemes.
基金Project supported by the Special Foundation for China Nonprofit Industry (Grant No. GYHY200706036)the National Excellent Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 40825008)the National Basic Research Program of China (Grant No. 2010CB833406)
文摘From first principles, we find that the radar threshold reflectivity between nonprecipitating clouds and precipitating clouds is strongly related to not only the cloud droplet number concentration but also the spectral dispersion of cloud droplet size distributions. The further investigation indicates that the threshold value is an increasing function of spectral dispersion and cloud droplet number concentration. These results may improve our understanding of the cloud-precipitation interaction and the aerosol indirect effect.
