Abstract The gas phase nucleation process of anatase TiO2 in atmospheric non-thermal plasma enhanced chemical vapor deposition is studied. The particles synthesized in the plasma gas phase at different power density w...Abstract The gas phase nucleation process of anatase TiO2 in atmospheric non-thermal plasma enhanced chemical vapor deposition is studied. The particles synthesized in the plasma gas phase at different power density were collected outside of the reactor. The structure of the collected particles has been investigated by field scanning electron microscope （FESEM）, X-ray diffraction （XRD）, high resolution transmission electron microscopy （HRTEM） and selected area electron diffraction （SAED）. The analysis shows that uniform crystalline nuclei with average size of several nanometers have been formed in the scale of micro second through this reactive atmo- spheric plasma gas process. The crystallinity of the nanoparticles increases with power density. The high density of crystalline nanonuclei in the plasma gas phase and the low gas temperature are beneficial to the fast deposition of the 3D porous anatase TiO2 film.展开更多
Solid-state phase transformation plays an important role in adjusting the microstructure and thus tuning the properties of materials. A general modular, analytical model has been widely applied to describe the kinetic...Solid-state phase transformation plays an important role in adjusting the microstructure and thus tuning the properties of materials. A general modular, analytical model has been widely applied to describe the kinetics of solid-state phase transformation involving nucleation, growth and impingement; the basic conception for iso-kinetics which constitutes a physical foundation for the kinetic models or recipes can be extended by the analytical model. Applying the model, the evolution of kinetic parameters is an effective tool for describing the crystallization of enormous amorphous alloys. In order to further improve the effectiveness of this kinetic model, recently, the recipes and the model fitting procedures were extended, with more factors （e.g., anisotropic growth, soft impingement, and thermodynamic driving force） taken into consideration in the modified models. The recent development in the field of analytical model suggests that it is a general, flexible and open kinetic model for describing the solid-state phase transformation kinetics.展开更多
Earth’s crust is an anisotropic and purely heterogeneous medium, which is justified by existence of different discontinuities;our study aims to show the effect of the variation of coefficient of friction on the evolu...Earth’s crust is an anisotropic and purely heterogeneous medium, which is justified by existence of different discontinuities;our study aims to show the effect of the variation of coefficient of friction on the evolution of temperature and its impact on seismic forecasting. In this work, we are model in 2D the variation of thermal energy and temperature produced by friction at the level of fault lip as function of depth of the seismic focus and at different value of time. Earthquakes are born when the energy accumulated by friction at the level of fault is suddenly released causing damage, sometimes noticeable on the surface of earth (macroseisms), and sometimes not at all noticeable on the surface of earth (microseisms), then energy which occurs before is important to forecasting earthquake. Assuming that coefficient of friction is variable, our results have enabled us to highlight the fact that, the greater the coefficient of friction, more the temperature increases, although the temperature profile increase over time but not linearly reflecting the presence of different asperities and discontinuities zone;slip generated at the level of fault occur a variation of temperature on specific points called roughness in common agreement with the literature. A large part of energy produced by friction is dissipated in heat causing a local increases in temperature which a very short duration and called flash contact temperature, and that despite the fact that the temperature evolved in time and space, it all converged towards a perfectly distinguishable fixed point.展开更多
Freezing processes of several liquids under static magnetic field(SMF) less than 50 mT were investigated. Central temperature of liquid samples held in glass test tubes immersed in a liquid bath was measured and colle...Freezing processes of several liquids under static magnetic field(SMF) less than 50 mT were investigated. Central temperature of liquid samples held in glass test tubes immersed in a liquid bath was measured and collected. Nucleation temperature and phase transition time were obtained from freezing curves. Normality tests were performed for nucleation temperature of these liquids with/without magnetic field and normality distributions were justified. Analysis of variances was carried out for nucleation temperature of these liquids with magnetic field flux density as the influencing factor. Results showed that no significant difference was found for deionized water with or without SMF. However, differences exist in 0.9% NaCl solution and 5% ethylene glycol solution with and without SMF. Nucleation temperature of 0.9% NaCl with SMF is lower than that without SMF, while its phase transition time is shorter than that without SMF. Nucleation temperature of 5% ethylene glycol with SMF is higher than that without SMF, while its phase transition time is not modified with SMF.展开更多
A series of ternary blends of polypropylene/ethylene-propylene random copolymer/ethylene-propylene segmented copolymer（HPP/EPR/Eb P） whose microstructures are similar to those of impact polypropylene copolymer（IPC...A series of ternary blends of polypropylene/ethylene-propylene random copolymer/ethylene-propylene segmented copolymer（HPP/EPR/Eb P） whose microstructures are similar to those of impact polypropylene copolymer（IPC） were prepared in order to systematically investigate the effects of composition on microstructure and crystallization behavior of IPC. The observation of primary phase morphology reveals that the dispersed phase with core-shell structure could be rebuilt in certain composition and excessive EPR leads to a bicontinuous phase structure in ternary blends. After undergoing same quiescent crystallization including isothermal and non-isothermal crystallization, these blend samples exhibit special composition-dependent melting behavior, i.e., the melting point increases markedly with the increase of EPR content until it turns down at a critical content（about 30 wt%）. The crystallization behavior is mainly ascribed to the different nucleation abilities. It is suggested that although the compatibility between EPR and HPP components becomes worse with the increase of EPR content due to the increased interfacial area and the decreased concentration of Eb P, higher EPR content in the blend facilitates to heterogeneous nucleation except for the appearance of obvious bicontinuous phase structure.展开更多
基金supported by National Natural Science Foundation of China(Nos.1083500410775031 and 11375042)+1 种基金Shanghai Municipal Committee of Science and Technology of China(10XD1400100)Outstanding Young Investigator Award(No.11005017)
文摘Abstract The gas phase nucleation process of anatase TiO2 in atmospheric non-thermal plasma enhanced chemical vapor deposition is studied. The particles synthesized in the plasma gas phase at different power density were collected outside of the reactor. The structure of the collected particles has been investigated by field scanning electron microscope （FESEM）, X-ray diffraction （XRD）, high resolution transmission electron microscopy （HRTEM） and selected area electron diffraction （SAED）. The analysis shows that uniform crystalline nuclei with average size of several nanometers have been formed in the scale of micro second through this reactive atmo- spheric plasma gas process. The crystallinity of the nanoparticles increases with power density. The high density of crystalline nanonuclei in the plasma gas phase and the low gas temperature are beneficial to the fast deposition of the 3D porous anatase TiO2 film.
基金financial support of the National Basic Research Program of China (No. 2011CB610403)the National Natural Science Foundation of China (Nos. 51134011 and 51431008)+1 种基金the Fundamental Research Fund of Northwestern Polytechnical University (No. JC20120223)the China National Funds for Distinguished Young Scientists (No. 51125002)
文摘Solid-state phase transformation plays an important role in adjusting the microstructure and thus tuning the properties of materials. A general modular, analytical model has been widely applied to describe the kinetics of solid-state phase transformation involving nucleation, growth and impingement; the basic conception for iso-kinetics which constitutes a physical foundation for the kinetic models or recipes can be extended by the analytical model. Applying the model, the evolution of kinetic parameters is an effective tool for describing the crystallization of enormous amorphous alloys. In order to further improve the effectiveness of this kinetic model, recently, the recipes and the model fitting procedures were extended, with more factors （e.g., anisotropic growth, soft impingement, and thermodynamic driving force） taken into consideration in the modified models. The recent development in the field of analytical model suggests that it is a general, flexible and open kinetic model for describing the solid-state phase transformation kinetics.
文摘Earth’s crust is an anisotropic and purely heterogeneous medium, which is justified by existence of different discontinuities;our study aims to show the effect of the variation of coefficient of friction on the evolution of temperature and its impact on seismic forecasting. In this work, we are model in 2D the variation of thermal energy and temperature produced by friction at the level of fault lip as function of depth of the seismic focus and at different value of time. Earthquakes are born when the energy accumulated by friction at the level of fault is suddenly released causing damage, sometimes noticeable on the surface of earth (macroseisms), and sometimes not at all noticeable on the surface of earth (microseisms), then energy which occurs before is important to forecasting earthquake. Assuming that coefficient of friction is variable, our results have enabled us to highlight the fact that, the greater the coefficient of friction, more the temperature increases, although the temperature profile increase over time but not linearly reflecting the presence of different asperities and discontinuities zone;slip generated at the level of fault occur a variation of temperature on specific points called roughness in common agreement with the literature. A large part of energy produced by friction is dissipated in heat causing a local increases in temperature which a very short duration and called flash contact temperature, and that despite the fact that the temperature evolved in time and space, it all converged towards a perfectly distinguishable fixed point.
基金Supported by the National Natural Science Foundation of China(51306104)
文摘Freezing processes of several liquids under static magnetic field(SMF) less than 50 mT were investigated. Central temperature of liquid samples held in glass test tubes immersed in a liquid bath was measured and collected. Nucleation temperature and phase transition time were obtained from freezing curves. Normality tests were performed for nucleation temperature of these liquids with/without magnetic field and normality distributions were justified. Analysis of variances was carried out for nucleation temperature of these liquids with magnetic field flux density as the influencing factor. Results showed that no significant difference was found for deionized water with or without SMF. However, differences exist in 0.9% NaCl solution and 5% ethylene glycol solution with and without SMF. Nucleation temperature of 0.9% NaCl with SMF is lower than that without SMF, while its phase transition time is shorter than that without SMF. Nucleation temperature of 5% ethylene glycol with SMF is higher than that without SMF, while its phase transition time is not modified with SMF.
基金financially supported by the National Natural Science Foundation of China(Nos.51173157 and 51173165)the Fundamental Research Funds for the Central Universities(No.2013QNA4048)Nature Science Foundation of Zhejiang Province(No.Y4100314)
文摘A series of ternary blends of polypropylene/ethylene-propylene random copolymer/ethylene-propylene segmented copolymer（HPP/EPR/Eb P） whose microstructures are similar to those of impact polypropylene copolymer（IPC） were prepared in order to systematically investigate the effects of composition on microstructure and crystallization behavior of IPC. The observation of primary phase morphology reveals that the dispersed phase with core-shell structure could be rebuilt in certain composition and excessive EPR leads to a bicontinuous phase structure in ternary blends. After undergoing same quiescent crystallization including isothermal and non-isothermal crystallization, these blend samples exhibit special composition-dependent melting behavior, i.e., the melting point increases markedly with the increase of EPR content until it turns down at a critical content（about 30 wt%）. The crystallization behavior is mainly ascribed to the different nucleation abilities. It is suggested that although the compatibility between EPR and HPP components becomes worse with the increase of EPR content due to the increased interfacial area and the decreased concentration of Eb P, higher EPR content in the blend facilitates to heterogeneous nucleation except for the appearance of obvious bicontinuous phase structure.
