Lanthanide-doped upconversion nanoparticles exhibit unique optical properties,enabling the conversion of low-energy photons into high-energy ones.This capability has facilitated their extensive application in fields s...Lanthanide-doped upconversion nanoparticles exhibit unique optical properties,enabling the conversion of low-energy photons into high-energy ones.This capability has facilitated their extensive application in fields such as bioimaging and information security.Traditional research has primarily focused on steady-state characteristics,with strategies such as core-shell structural design,ion doping,and surface passivation being employed to achieve high-brightness luminescence and color tuning.Over the past decade,the study of non-steady-state characteristics has emerged as a research hotspot and has introduced a new dimension for the dynamic con-trol of luminescence.This review systematically surveys the mechanisms,manipulation strategies,and charac-terization methods of non-steady-state upconversion luminescence and provides an overview of the latest advancements in its applications,including multi-dimensional anti-counterfeiting,full-color volumetric display,velocimetry,photonic coding,and logic operation.Furthermore,this review analyzes the current limitations in studying the non-steady-state characteristics of lanthanide-doped fluoride nanostructures and offers perspectives on future development directions.Collectively,these efforts provide a comprehensive framework of knowledge for the field and lay the foundation for further development and expansion of non-steady-state upconversion technologies.We anticipate that this review will provide fundamental insights and guidance for manipulating upconversion properties,thereby further promoting their applications and advancing non-steady-state upcon-version technologies.展开更多
NT build 443, or profile fitting method, is often used to measure the diffusion coefficient of chloride in concrete. However, this method is quite laborious and needs special equipment. Colorimetric method is a quick ...NT build 443, or profile fitting method, is often used to measure the diffusion coefficient of chloride in concrete. However, this method is quite laborious and needs special equipment. Colorimetric method is a quick and simple method to measure the penetration depth of chloride by spraying 0.1 mol/L silver nitrate solution. The objective of this work is to study the possibility of the use of colorimetric method in the calculation of non-steady-state diffusion coefficient. Twelve concrete mixtures with different supplementary cementitious materials and water-to-cement ratios of 0.35, 0.48 and 0.6 were used for study. According to NT build 443, the concrete specimens were immersed in 165 g/L NaC1 （2.8 mol/L） solution for 42 d. Both water-soluble （convert to free chloride） chloride and acid-soluble chloride at different layers of specimens were measured. The results show that the mean value of free chloride concentration at the color change boundary Cd was 0.306 mol/L. The surface free chloride concentration cs was obtained by profile fitting method, which was 40% lower than the chloride concentration of exposure solution after an immersion period of 42 d. Chloride diffusion coefficients obtained by the colorimetric method was not well correlated with those obtained by profile fitting method.展开更多
Knowledge of the oxygen mass transfer of aerators under operational conditions in a full-scale wastewater treatment plant （WWTP） is meaningful for the optimization of WWTP, however, scarce to best of our knowledge. ...Knowledge of the oxygen mass transfer of aerators under operational conditions in a full-scale wastewater treatment plant （WWTP） is meaningful for the optimization of WWTP, however, scarce to best of our knowledge. Through analyzing a plug flow aeration tank in the Lucun WWTP, in Wuxi, China, the oxygenation capacity of fine-bubble aerators under process conditions have been measured in- situ using the off-gas method and the non-steady-state method. The off-gas method demonstrated that the aerators in different corridors in the aeration tank of WWTP had significantly different oxygen transfer performance; furthermore, the aerators in the same corridor shared almost equal oxygen transfer performance over the course of a day. Results measured by the two methods showed that the oxygen transfer performance of fine-bubble aerators in the aeration tank decreased dramatically compared with that in the clean water. The loss of oxygen transfer coefficient was over 50% under low-aeration conditions （aeration amount 〈 0.67 Nm 3 /hr）. However, as the aeration amount reached 0.96 Nm 3 /hr, the discrepancy of oxygen transfer between the process condition and clean water was negligible. The analysis also indicated that the non-steady-state and off-gas methods resulted in comparable estimates of oxygen transfer parameters for the aerators under process conditions.展开更多
By scanning modulated or un-modulated earthquakes spatio-temporally in the region of Sichuan-Yunnan,short-term non-stationary seismic precursory patterns were extracted with significant difference and the characterist...By scanning modulated or un-modulated earthquakes spatio-temporally in the region of Sichuan-Yunnan,short-term non-stationary seismic precursory patterns were extracted with significant difference and the characteristic of non-stationary short-term seismic anomalies were analyzed as well as prediction efficiency of modulated small earthquakes before a strong earthquake. Besides,small earthquake modulation ratios near the region of the epicenter were calculated and sorted by time. The results indicated that there were significant effects using the modulated earthquake method to predict earthquakes greater than MS6. 0 in a short time. Before the MS8. 0 Wenchuan earthquake,there were obvious short-term precursory seismicity gap patterns of modulated small earthquakes.展开更多
基金supported by National Natural Science Foundation of China(52272141,52572155)Natural Science Foundation of Fujian Province(2024J02014,2021J01190).
文摘Lanthanide-doped upconversion nanoparticles exhibit unique optical properties,enabling the conversion of low-energy photons into high-energy ones.This capability has facilitated their extensive application in fields such as bioimaging and information security.Traditional research has primarily focused on steady-state characteristics,with strategies such as core-shell structural design,ion doping,and surface passivation being employed to achieve high-brightness luminescence and color tuning.Over the past decade,the study of non-steady-state characteristics has emerged as a research hotspot and has introduced a new dimension for the dynamic con-trol of luminescence.This review systematically surveys the mechanisms,manipulation strategies,and charac-terization methods of non-steady-state upconversion luminescence and provides an overview of the latest advancements in its applications,including multi-dimensional anti-counterfeiting,full-color volumetric display,velocimetry,photonic coding,and logic operation.Furthermore,this review analyzes the current limitations in studying the non-steady-state characteristics of lanthanide-doped fluoride nanostructures and offers perspectives on future development directions.Collectively,these efforts provide a comprehensive framework of knowledge for the field and lay the foundation for further development and expansion of non-steady-state upconversion technologies.We anticipate that this review will provide fundamental insights and guidance for manipulating upconversion properties,thereby further promoting their applications and advancing non-steady-state upcon-version technologies.
基金Project(2010QZZD018) supported by Central South Universtiy,China,and Ghent University,Belgium
文摘NT build 443, or profile fitting method, is often used to measure the diffusion coefficient of chloride in concrete. However, this method is quite laborious and needs special equipment. Colorimetric method is a quick and simple method to measure the penetration depth of chloride by spraying 0.1 mol/L silver nitrate solution. The objective of this work is to study the possibility of the use of colorimetric method in the calculation of non-steady-state diffusion coefficient. Twelve concrete mixtures with different supplementary cementitious materials and water-to-cement ratios of 0.35, 0.48 and 0.6 were used for study. According to NT build 443, the concrete specimens were immersed in 165 g/L NaC1 （2.8 mol/L） solution for 42 d. Both water-soluble （convert to free chloride） chloride and acid-soluble chloride at different layers of specimens were measured. The results show that the mean value of free chloride concentration at the color change boundary Cd was 0.306 mol/L. The surface free chloride concentration cs was obtained by profile fitting method, which was 40% lower than the chloride concentration of exposure solution after an immersion period of 42 d. Chloride diffusion coefficients obtained by the colorimetric method was not well correlated with those obtained by profile fitting method.
基金supported by the Major Water Project of the National Science and Technology (No.2011ZX07319-001-004, 2011ZX07301-002)
文摘Knowledge of the oxygen mass transfer of aerators under operational conditions in a full-scale wastewater treatment plant （WWTP） is meaningful for the optimization of WWTP, however, scarce to best of our knowledge. Through analyzing a plug flow aeration tank in the Lucun WWTP, in Wuxi, China, the oxygenation capacity of fine-bubble aerators under process conditions have been measured in- situ using the off-gas method and the non-steady-state method. The off-gas method demonstrated that the aerators in different corridors in the aeration tank of WWTP had significantly different oxygen transfer performance; furthermore, the aerators in the same corridor shared almost equal oxygen transfer performance over the course of a day. Results measured by the two methods showed that the oxygen transfer performance of fine-bubble aerators in the aeration tank decreased dramatically compared with that in the clean water. The loss of oxygen transfer coefficient was over 50% under low-aeration conditions （aeration amount 〈 0.67 Nm 3 /hr）. However, as the aeration amount reached 0.96 Nm 3 /hr, the discrepancy of oxygen transfer between the process condition and clean water was negligible. The analysis also indicated that the non-steady-state and off-gas methods resulted in comparable estimates of oxygen transfer parameters for the aerators under process conditions.
基金supported by the National Basic ResearchProgram (973 Program),entitled Global deep geophysical field and the relation between its geodynamic effect and Wenchuan Earthquake
文摘By scanning modulated or un-modulated earthquakes spatio-temporally in the region of Sichuan-Yunnan,short-term non-stationary seismic precursory patterns were extracted with significant difference and the characteristic of non-stationary short-term seismic anomalies were analyzed as well as prediction efficiency of modulated small earthquakes before a strong earthquake. Besides,small earthquake modulation ratios near the region of the epicenter were calculated and sorted by time. The results indicated that there were significant effects using the modulated earthquake method to predict earthquakes greater than MS6. 0 in a short time. Before the MS8. 0 Wenchuan earthquake,there were obvious short-term precursory seismicity gap patterns of modulated small earthquakes.
