A series of Co-Ni_2P/SBA-15 catalysts with various Co contents, Ni_2P contents and P/Ni molar ratios were prepared by impregnating nickel nitrate, diammonium hydrogen phosphate, and then cobalt nitrate into SBA-15 sup...A series of Co-Ni_2P/SBA-15 catalysts with various Co contents, Ni_2P contents and P/Ni molar ratios were prepared by impregnating nickel nitrate, diammonium hydrogen phosphate, and then cobalt nitrate into SBA-15 support followed by temperature-programmed reduction in a H_2 flow. The catalyst structure was characterized by X-ray diffraction （XRD）, high resolution-transmission electron microscopy （HR-TEM） and N_2 adsorption-desorption techniques and their catalytic performance of the hydrodesulfurization （HDS） of dibenzothiophene （DBT） was evaluated. The effects of Co contents, Ni_2P contents and P/Ni molar ratios on the catalyst structure and HDS of DBT over the Co-Ni_2P/SBA- 15 catalyst were investigated. The results indicated that the mesoporous structure was mainly maintained and the nickel phosphides were well dispersed in all of the characterized catalysts. The 4Co-25Ni_2P/SBA-15 （P/Ni = 0.8） catalyst with the Co and Ni_2P contents of 4 wt% and 25 wt%, respectively, and the P/Ni molar ratio of 0.8 showed the highest catalytic performance for HDS of DBT. Under the reaction conditions of 380 ℃ and 3.0 MPa, the DBT conversion can reach 99.62%. The HDS of DBT proceeded mainly via the direct desulfurization （DDS） pathway with biphenyl （BP） as the dominant product on all of the catalysts and the BP selectivity was slightly enhanced after the introduction of Co promoters.展开更多
A probable new phase was detected in Ni-Ti-Si temary system at 1 100 ℃. ItS composition is aroundM: T: Si = 10: 45: 45 (atom fraction) according to the results of EPMA (Electron Probe Microanalysis) of 4 alloyscontai...A probable new phase was detected in Ni-Ti-Si temary system at 1 100 ℃. ItS composition is aroundM: T: Si = 10: 45: 45 (atom fraction) according to the results of EPMA (Electron Probe Microanalysis) of 4 alloyscontaining the Phase. The SEM microstructure difference of the 4 alloys can give some proof of its existence.展开更多
Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)Ni...Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)NiO_(2)suffers from inferior delithiation kinetics during the first cycle.Herein,we investigated the effects of the cost-effective copper substituted Li_(2)Ni_(1-x)Cu_(x)O_(2)(x=0,0.2,0.3,0.5,0.7)synthesized by a high-temperature solid-phase method on the structure,morphology,electrochemical performance of graphite‖LiFePO_(4)battery.The X-ray diffraction(XRD)refinement result demonstrated that Cu substitution strategy could be favorable for eliminating the NiO_(x)impurity phase and weakening Li-O bond.Analysis on density of states(DOS)indicates that Cu substitution is good for enhancing the electronic conductivity,as well as reducing the delithi-ation voltage polarization confirmed by electrochemical characterizations.Therefore,the optimal Li_(2)Ni_(0.7)Cu_(0.3)O_(2)delivered a high delithiation capacity of 437 mAh·g^(-1),around 8%above that of the pristine Li_(2)NiO_(2).Furthermore,a graphite‖LiFePO_(4)pouch cell with a nominal capacity of 3000 mAh demonstrated a notably improved reversible capacity,energy density and cycle life through introducing 2 wt%Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive,delivering a 6.2 mAh·g^(-1)higher initial discharge capacity and achieving around 5%improvement in capacity retentnion at 0.5P over 1000 cycles.Additionally,the post-mortem analyses testified that the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive could suppress solid electrolyte interphase(SEI)decomposition and homogenize the Li distribution,which benefits to stabilizing interface between graphite and electrolyte,and alleviating dendritic Li plating.In conclusion,the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive may offer advantages such as lower cost,lower delithiation voltage and higher prelithiation capacity compared with Li_(2)NiO_(2),making it a promising candidate of cathode prelithiation additive for next-generation LIBs.展开更多
基金supported by the National Basic Research Program of China(2006CB202503)Petro China Innovation Foundation(2010D-5006-0401)
文摘A series of Co-Ni_2P/SBA-15 catalysts with various Co contents, Ni_2P contents and P/Ni molar ratios were prepared by impregnating nickel nitrate, diammonium hydrogen phosphate, and then cobalt nitrate into SBA-15 support followed by temperature-programmed reduction in a H_2 flow. The catalyst structure was characterized by X-ray diffraction （XRD）, high resolution-transmission electron microscopy （HR-TEM） and N_2 adsorption-desorption techniques and their catalytic performance of the hydrodesulfurization （HDS） of dibenzothiophene （DBT） was evaluated. The effects of Co contents, Ni_2P contents and P/Ni molar ratios on the catalyst structure and HDS of DBT over the Co-Ni_2P/SBA- 15 catalyst were investigated. The results indicated that the mesoporous structure was mainly maintained and the nickel phosphides were well dispersed in all of the characterized catalysts. The 4Co-25Ni_2P/SBA-15 （P/Ni = 0.8） catalyst with the Co and Ni_2P contents of 4 wt% and 25 wt%, respectively, and the P/Ni molar ratio of 0.8 showed the highest catalytic performance for HDS of DBT. Under the reaction conditions of 380 ℃ and 3.0 MPa, the DBT conversion can reach 99.62%. The HDS of DBT proceeded mainly via the direct desulfurization （DDS） pathway with biphenyl （BP） as the dominant product on all of the catalysts and the BP selectivity was slightly enhanced after the introduction of Co promoters.
文摘A probable new phase was detected in Ni-Ti-Si temary system at 1 100 ℃. ItS composition is aroundM: T: Si = 10: 45: 45 (atom fraction) according to the results of EPMA (Electron Probe Microanalysis) of 4 alloyscontaining the Phase. The SEM microstructure difference of the 4 alloys can give some proof of its existence.
基金supported by the Significant Science and Technology Project in Xiamen(Future Industry Field)(Grant No.3502Z20231057).
文摘Lithium nickel oxide(Li_(2)NiO_(2)),as a sacrificial cathode prelithiation additive,has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries(LIBs).However,high-cost Li_(2)NiO_(2)suffers from inferior delithiation kinetics during the first cycle.Herein,we investigated the effects of the cost-effective copper substituted Li_(2)Ni_(1-x)Cu_(x)O_(2)(x=0,0.2,0.3,0.5,0.7)synthesized by a high-temperature solid-phase method on the structure,morphology,electrochemical performance of graphite‖LiFePO_(4)battery.The X-ray diffraction(XRD)refinement result demonstrated that Cu substitution strategy could be favorable for eliminating the NiO_(x)impurity phase and weakening Li-O bond.Analysis on density of states(DOS)indicates that Cu substitution is good for enhancing the electronic conductivity,as well as reducing the delithi-ation voltage polarization confirmed by electrochemical characterizations.Therefore,the optimal Li_(2)Ni_(0.7)Cu_(0.3)O_(2)delivered a high delithiation capacity of 437 mAh·g^(-1),around 8%above that of the pristine Li_(2)NiO_(2).Furthermore,a graphite‖LiFePO_(4)pouch cell with a nominal capacity of 3000 mAh demonstrated a notably improved reversible capacity,energy density and cycle life through introducing 2 wt%Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive,delivering a 6.2 mAh·g^(-1)higher initial discharge capacity and achieving around 5%improvement in capacity retentnion at 0.5P over 1000 cycles.Additionally,the post-mortem analyses testified that the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive could suppress solid electrolyte interphase(SEI)decomposition and homogenize the Li distribution,which benefits to stabilizing interface between graphite and electrolyte,and alleviating dendritic Li plating.In conclusion,the Li_(2)Ni_(0.7)Cu_(0.3)O_(2)additive may offer advantages such as lower cost,lower delithiation voltage and higher prelithiation capacity compared with Li_(2)NiO_(2),making it a promising candidate of cathode prelithiation additive for next-generation LIBs.
