CO_(2)-to-CO electrolyzer technology converts carbon dioxide into carbon monoxide using electrochemical methods,offering significant environmental and energy benefits by aiding in greenhouse gas mitigation and promoti...CO_(2)-to-CO electrolyzer technology converts carbon dioxide into carbon monoxide using electrochemical methods,offering significant environmental and energy benefits by aiding in greenhouse gas mitigation and promoting a carbon circular economy.Recent study by Strasser et al.in Nature Chemical Engineering presents a high-performance CO_(2)-to-CO electrolyzer utilizing a NiNC catalyst with nearly 100%faradaic efficiency,employing innovative diagnostic tools like the carbon crossover coefficient(CCC)to address transport-related failures and optimize overall efficiency.Strasser’s research demonstrates the potential of NiNC catalysts,particularly NiNC-IMI,for efficient CO production in CO_(2)-to-CO electrolyzers,highlighting their high selectivity and performance.However,challenges such as localized CO_(2)depletion and mass transport limitations underscore the need for further optimization and development of diagnostic tools like CCC.Strategies for optimizing catalyst structure and operational parameters offer avenues for enhancing the performance and reliability of electrochemical CO_(2)reduction catalysts.展开更多
The globally exponential stability of nonlinear impul- sive networked control systems （NINCS） with time delay and packet dropouts is investigated. By applying Lyapunov function theory, sufficient conditions on the g...The globally exponential stability of nonlinear impul- sive networked control systems （NINCS） with time delay and packet dropouts is investigated. By applying Lyapunov function theory, sufficient conditions on the global exponential stability are derived by introducing a comparison system and estimating the corresponding Cauchy matrix. An impulsive controller is explicitly designed to achieve exponential stability and ensure state con- verge with a given decay rate for the system. The Lorenz oscillator system is presented as a numerical example to illustrate the theo- retical results and effectiveness of the proposed controller design procedure.展开更多
基金the University of Oxford for the Mathematical, Physical and Life Sciences Division (MPLS) Enterprise and Innovation Fellowshipthe support of Massachusetts Institute of Technology+1 种基金the support of the National Key R&D Program of China (2021YFB3801600)the National Natural Science Foundation of China (22325204)。
文摘CO_(2)-to-CO electrolyzer technology converts carbon dioxide into carbon monoxide using electrochemical methods,offering significant environmental and energy benefits by aiding in greenhouse gas mitigation and promoting a carbon circular economy.Recent study by Strasser et al.in Nature Chemical Engineering presents a high-performance CO_(2)-to-CO electrolyzer utilizing a NiNC catalyst with nearly 100%faradaic efficiency,employing innovative diagnostic tools like the carbon crossover coefficient(CCC)to address transport-related failures and optimize overall efficiency.Strasser’s research demonstrates the potential of NiNC catalysts,particularly NiNC-IMI,for efficient CO production in CO_(2)-to-CO electrolyzers,highlighting their high selectivity and performance.However,challenges such as localized CO_(2)depletion and mass transport limitations underscore the need for further optimization and development of diagnostic tools like CCC.Strategies for optimizing catalyst structure and operational parameters offer avenues for enhancing the performance and reliability of electrochemical CO_(2)reduction catalysts.
基金supported by the National Natural Science Foundation of China (6090402060574006)the Research Fund for the Doctoral Program of Higher Eolucation of China (20070286039)
文摘The globally exponential stability of nonlinear impul- sive networked control systems （NINCS） with time delay and packet dropouts is investigated. By applying Lyapunov function theory, sufficient conditions on the global exponential stability are derived by introducing a comparison system and estimating the corresponding Cauchy matrix. An impulsive controller is explicitly designed to achieve exponential stability and ensure state con- verge with a given decay rate for the system. The Lorenz oscillator system is presented as a numerical example to illustrate the theo- retical results and effectiveness of the proposed controller design procedure.
