奥氏体耐热钢由于良好的高温性能因而在火电、核电、航空航天等领域有着重要的应用.细小的晶粒尺寸及基体中弥散分布的碳化物是奥氏体钢具有优异高温性能的关键.奥氏体钢在服役过程中受热循环的影响,其显微组织发生衰退.为探究热循环过...奥氏体耐热钢由于良好的高温性能因而在火电、核电、航空航天等领域有着重要的应用.细小的晶粒尺寸及基体中弥散分布的碳化物是奥氏体钢具有优异高温性能的关键.奥氏体钢在服役过程中受热循环的影响,其显微组织发生衰退.为探究热循环过程中组织演变对力学性能的影响,针对一种供货态的奥氏体耐热钢0Cr25Ni13Si2MoN开展了三组热循环实验.借助光镜(optical microscope,OM)、扫描电镜(scanning electron microscope,SEM)、透射电镜(transmission electron microscope,TEM)和冲击试验机等试验设备,对不同热循环次数后的试样分别进行了显微组织及力学性能分析.结果表明:热循环过程中的组织演变表现出一定的时间依赖性,一次热循环过程完成了回复与再结晶,晶界处析出网状分布的M 23 C 6,降低了材料的韧性.后两次的热循环过程退火孪晶密度增大,但晶界处碳化物数量增加并发生粗化,材料的韧性逐渐恶化.展开更多
A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS an...A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS analysis.The alloy after solution treatment,80%cold rolling and aging at450°C for1h had the best comprehensive properties with hardness of HV314,electrical conductivity of19.4%IACS,tensile strength of1017MPa,and average annual corrosion rate of0.028mm/a.The oxides and chloride products formed at first,followed by the formation of dyroxides products.The alloy showed super-high strength,good electrical conductivity and corrosion resistant because Ni2Si hindered the precipitation of large NiAl at the grain boundary and the denickelefication of the alloy.展开更多
文摘奥氏体耐热钢由于良好的高温性能因而在火电、核电、航空航天等领域有着重要的应用.细小的晶粒尺寸及基体中弥散分布的碳化物是奥氏体钢具有优异高温性能的关键.奥氏体钢在服役过程中受热循环的影响,其显微组织发生衰退.为探究热循环过程中组织演变对力学性能的影响,针对一种供货态的奥氏体耐热钢0Cr25Ni13Si2MoN开展了三组热循环实验.借助光镜(optical microscope,OM)、扫描电镜(scanning electron microscope,SEM)、透射电镜(transmission electron microscope,TEM)和冲击试验机等试验设备,对不同热循环次数后的试样分别进行了显微组织及力学性能分析.结果表明:热循环过程中的组织演变表现出一定的时间依赖性,一次热循环过程完成了回复与再结晶,晶界处析出网状分布的M 23 C 6,降低了材料的韧性.后两次的热循环过程退火孪晶密度增大,但晶界处碳化物数量增加并发生粗化,材料的韧性逐渐恶化.
基金Project(51271203)supported by the National Natural Science Foundation of China
文摘A novel Cu?6.5Ni?1Al?1Si?0.15Mg?0.15Ce alloy with super-high strength was designed and its corrosion behavior in3.5%NaCl solution at25°C was investigated by the means of SEM observation,TEM observation and XPS analysis.The alloy after solution treatment,80%cold rolling and aging at450°C for1h had the best comprehensive properties with hardness of HV314,electrical conductivity of19.4%IACS,tensile strength of1017MPa,and average annual corrosion rate of0.028mm/a.The oxides and chloride products formed at first,followed by the formation of dyroxides products.The alloy showed super-high strength,good electrical conductivity and corrosion resistant because Ni2Si hindered the precipitation of large NiAl at the grain boundary and the denickelefication of the alloy.
