To expand the study on the structures and biological activities of the anthracyclines anticancer drugs and reduce their toxic side effects,the new anthraquinone derivatives,9‑pyridylanthrahydrazone(9‑PAH)and 9,10‑bisp...To expand the study on the structures and biological activities of the anthracyclines anticancer drugs and reduce their toxic side effects,the new anthraquinone derivatives,9‑pyridylanthrahydrazone(9‑PAH)and 9,10‑bispyridylanthrahydrazone(9,10‑PAH)were designed and synthesized.Utilizing 9‑PAH and 9,10‑PAH as promising anticancer ligands,their respective copper complexes,namely[Cu(L1)Cl_(2)]Cl(1)and{[Cu_(4)(μ_(2)‑Cl)_(3)Cl_(4)(9,10‑PAH)_(2)(DMSO)_(2)]Cl_(2)}_(n)(2),were subsequently synthesized,where the new ligand L1 is formed by coupling two 9‑PAH ligands in the coordination reaction.The chemical and crystal structures of 1 and 2 were elucidated by IR,MS,elemental analysis,and single‑crystal X‑ray diffraction.Complex 1 forms a mononuclear structure.L1 coordinates with Cu through its three N atoms,together with two Cl atoms,to form a five‑coordinated square pyramidal geometry.Complex 2 constitutes a polymeric structure,wherein each structural unit centrosymmetrically encompasses two five‑coordinated binuclear copper complexes(Cu1,Cu2)of 9,10‑PAH,with similar square pyramidal geometry.A chlorine atom(Cl_(2)),located at the symmetry center,bridges Cu1 and Cu1A to connect the two binuclear copper structures.Meanwhile,the two five‑coordinated Cu2 atoms symmetrically bridge the adjacent structural units via one coordinated Cl atom,respectively,thus forming a 1D chain‑like polymeric structure.In vitro anticancer activity assessments revealed that 1 and 2 showed significant cytotoxicity even higher than cisplatin.Specifically,the IC_(50)values of 2 against HeLa‑229 and SK‑OV‑3 cancer cell lines were determined to be(5.92±0.32)μmol·L^(-1)and(6.48±0.39)μmol·L^(-1),respectively.2 could also block the proliferation of HeLa‑229 cells in S phase and significantly induce cell apoptosis.In addition,fluorescence quenching competition experiments suggested that 2 might interact with DNA by an intercalative binding mode,offering insights into its underlying anticancer mechanism.CCDC:2388918,1;2388919,2.展开更多
The microstructure of single crystal superalloy is relatively simple,consisting primarily ofγdendrites andγ/γ′eutectics.During the directional solidification process of Ni-based single crystal superalloys,withdraw...The microstructure of single crystal superalloy is relatively simple,consisting primarily ofγdendrites andγ/γ′eutectics.During the directional solidification process of Ni-based single crystal superalloys,withdrawal rate is a critical parameter affecting the spatial distribution ofγ/γ′eutectic along gravity direction.The results show that theγ/γ′eutectic fraction of the upper platform surface is always higher than that of the lower one,regardless of withdrawal rate.As the withdrawal rate decreases,there is a significant increase inγ/γ′eutectic fraction on the upper surface,while it decreases on the lower surface.The upward accumulation ofγ/γ′eutectic becomes more severe as the withdrawal rate decreases.It is also found that the percentage of Al+Ta is positively correlated with theγ/γ′eutectic fraction.Thermo-solute convection of Al and Ta solutes in the solidification front is the prime reason for the non-uniform distribution of eutectic.The non-uniform distribution ofγ/γ′eutectic cannot be eliminated even after subsequent solution heat treatment,resulting in excess eutectic on the upper surface and thus leading to the scrapping of the blade.展开更多
Recent research progress on the use of Ni-based catalysts supported by various carbon materials,such as carbon nanotubes,graphene,and activated carbon,for the hydrogenation of CO_(2)to CH4 is summarized.The influence ...Recent research progress on the use of Ni-based catalysts supported by various carbon materials,such as carbon nanotubes,graphene,and activated carbon,for the hydrogenation of CO_(2)to CH4 is summarized.The influence of additives and surface modification methods on improving their catalytic performance is discussed as is the reaction mechanism,especially the structurefunction relationship produced by the carbon.The review provides a comprehensive directory for the rational design of carbon-supported Ni-based catalysts for the methanation of CO_(2).展开更多
Metal complexes hold significant promise in tumor diagnosis and treatment.However,their potential applications in photodynamic therapy(PDT)are hindered by issues such as poor photostability,low yield of reactive oxyge...Metal complexes hold significant promise in tumor diagnosis and treatment.However,their potential applications in photodynamic therapy(PDT)are hindered by issues such as poor photostability,low yield of reactive oxygen species(ROS),and aggregation-induced ROS quenching.To address these challenges,we present a molecular self-assembly strategy utilizing aggregation-induced emission(AIE)conjugates for metal complexes.As a proof of concept,we synthesized a mitochondrial-targeting cyclometalated Ir(Ⅲ)photosensitizer Ir-TPE.This approach significantly enhances the photodynamic effect while mitigating the dark toxicity associated with AIE groups.Ir-TPE readily self-assembles into nanoaggregates in aqueous solution,leading to a significant production of ROS upon light irradiation.Photoirradiated Ir-TPE triggers multiple modes of death by excessively accumulating ROS in the mitochondria,resulting in mitochondrial DNA damage.This damage can lead to ferroptosis and autophagy,two forms of cell death that are highly cytotoxic to cancer cells.The aggregation-enhanced photodynamic effect of Ir-TPE significantly enhances the production of ROS,leading to a more pronounced cytotoxic effect.In vitro and in vivo experiments demonstrate this aggregation-enhanced PDT approach achieves effective in situ tumor eradication.This study not only addresses the limitations of metal complexes in terms of low ROS production due to aggregation but also highlights the potential of this strategy for enhancing ROS production in PDT.展开更多
The microstructure evolution and deformation mechanism of a DZ125 superalloy during high-temperature creep were studied by means of microstructure observation and creep-property tests.The results show that at the init...The microstructure evolution and deformation mechanism of a DZ125 superalloy during high-temperature creep were studied by means of microstructure observation and creep-property tests.The results show that at the initial stage of high-temperature creep,two sets of dislocations with different Burgers vectors move and meet inγmatrix channels,and react to form a quadrilateral dislocation network.Andγ′phases with raft-like microstructure are generated after the formation of dislocation networks.As creep progresses,the quadrilateral dislocation network is gradually transformed into hexagonal and quadrilateral dislocation networks.During steady stage of creep,the superalloy undergoes deformation with the mechanism that a great number of dislocations slip and climb in the matrix across the raft-likeγ′phases.At the later stage of creep,the raft-likeγ′phases are sheared by dislocations at the breakage of dislocation networks,and then alternate slip occurs,which distorts and breaks the raft-likeγ′/γphases,resulting in the accumulation of micropores at the raft-likeγ′/γinterfaces and the formation of microcracks.As creep continues,the microcracks continue to expand until creep fracture occurs,which is the damage and fracture mechanism of the alloy at the later stage of creep at high temperature.展开更多
Two novel lanthanide complexes,[Sm_(2)(BA)_(6)(4-OH-terpy)_(2)]·2H_(2)O·2EtOH(1)and[Pr_(2)(BA)_(6)(4-OH-terpy)_(2)(H_(2)O)_(2)]·HBA·H_(2)O(2),where HBA=benzoic acid,4-OH-terpy=4-hydroxy-2,2'∶6...Two novel lanthanide complexes,[Sm_(2)(BA)_(6)(4-OH-terpy)_(2)]·2H_(2)O·2EtOH(1)and[Pr_(2)(BA)_(6)(4-OH-terpy)_(2)(H_(2)O)_(2)]·HBA·H_(2)O(2),where HBA=benzoic acid,4-OH-terpy=4-hydroxy-2,2'∶6',2″-terpyridine,were successfully synthesized using ultrasonic dissolution and the conventional solution method with two mixed ligands HBA and 4-OH-terpy.During the synthesis,4-OH-terpy was involved in the reaction as a neutral ligand,while HBA,in its deprotonated form(BA-),coordinated with the lanthanide ions as an acidic ligand.The crystal structures of these two complexes were precisely determined by single-crystal X-ray diffraction.Elemental analysis,infrared and Raman spectroscopy,and powder X-ray diffraction techniques were also employed to further explore the physicochemical properties of the two complexes.The single-crystal X-ray diffraction data indicate that,despite their structural differences,both complexes belong to the triclinic crystal system P1 space group.The central lanthanide ions have the same coordination number but exhibit different coordination environments.To comprehensively evaluate the thermal stability of these two complexes,comprehensive tests including thermogravimetric analysis,differential thermogravimetric analysis,differential scanning calorimetry,Fourier transform infrared spectroscopy,and mass spectrometry were conducted.Meanwhile,an in-depth investigation was conducted into the 3D infrared stacked images and mass spectra of the gases emitted from the complexes.In addition,studies of the fluorescence properties of complex1 showed that it exhibited fluorescence emission matching the Sm^(3+)characteristic transition.展开更多
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni...With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.展开更多
To achieve efficient catalytic hydrogenation of CO_(2)to formate,we employed a transmetallation strategy to develop three novel iridium(Ⅰ)complexes,which feature N‑heterocyclic carbene‑nitrogen‑phosphine ligands(CNP)...To achieve efficient catalytic hydrogenation of CO_(2)to formate,we employed a transmetallation strategy to develop three novel iridium(Ⅰ)complexes,which feature N‑heterocyclic carbene‑nitrogen‑phosphine ligands(CNP)and a 1,5‑cyclooctadiene(cod)molecule:[Ir(cod)(κ^(3)‑CN^(im)P)]Cl(1⁃Cl),[Ir(cod)(κ^(3)‑CN^(im)P)]PF6(1⁃PF_(6)),and[Ir(cod)(κ^(3)‑CNHP)]Cl(2).The^(1)H NMR spectra,^(31)P NMR spectra,and high‑resolution mass spectra verify the successful synthesis of these three Ir(Ⅰ)‑CNP complexes.Furthermore,single‑crystal X‑ray diffraction analysis confirms the coordination geometry of 1⁃PF_(6).The strong Ir—C(NHC)bond suggests that the carbene carbon plays an enhanced anchoring role to iridium due to its strongσ‑donating ability,which helps stabilize the active metal species during CO_(2)hydrogenation.As a result,the Ir(Ⅰ)‑CNP complex exhibits remarkable activity and long catalytic lifetime for the hydrogenation of CO_(2)to formate,reaching a turnover number(TON)of 1.16×10^(6)after 150 h at a high temperature of 170℃,which was a relatively high value among all the Ir complexes.CCDC:2384071,1⁃PF_(6).展开更多
The effect of carbon content on the microstructures and stress rupture properties of a newly developed polycrystalline Ni-based superalloy with high Cr content has been studied.It was observed that both grain size and...The effect of carbon content on the microstructures and stress rupture properties of a newly developed polycrystalline Ni-based superalloy with high Cr content has been studied.It was observed that both grain size and the number of carbides increased with an increase in carbon content.After heat treatment,granular M_(23)C_(6)carbides were dispersed around MC carbides along grain boundaries and inside grains.The quantity of granular M_(23)C_(6)carbides increased while their sizes decreased.These findings can be verified with the results of thermodynamic calculation and differential scanning calorimetry analysis.The stress rupture times(975℃/225 MPa)increased from 13.3 to 25.5 h with the carbon content increased from 0.1 to 0.2 wt.%.The improvement can be attributed to two primary factors.Firstly,grain boundary is typically weak region during deformation process and the grain size increased as carbon content increased in the alloy.Secondly,carbides act as hindrances to impede dislocation movement,leading to dislocation entanglement.As carbon content rose,the quantity of carbides in interdendritic regions and grain boundaries increased,providing a certain degree of strengthening effect and resulting in a longer stress rupture time.展开更多
To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(...To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(6)](X_(2)pdt=(SCH_(2))_(2)CX_(2),X=Me,H)with aminodiphosphines(Ph_(2)PCH_(2))_(2)NY(Y=(CH_(2))_(2)OH,(CH_(2))_(3)OH)to obtain two new diiron aminophosphine complexes[Fe_(2)(L1)(μ-Me_(2)pdt)(CO)_(5)](1)and[Fe_(2)(L2)(μ-H_(2)pdt)(CO)_(5)](2),where L1=3-[(diphe-nylphosphaneyl)methyl]oxazolidine,L2=3-[(diphenylphosphaneyl)methyl]-1,3-oxazinane.Moreover,the structures of 1 and 2 have been fully confirmed by elemental analysis,spectroscopic techniques,and single-crystal X-ray diffraction.Using cyclic voltammetry(CV),we investigated the electrochemical redox performance and proton reduc-tion activities of 1 and 2 in acetic acid(HOAc).The CV study indicates that diiron aminophosphine complexes 1 and 2 can be considered to be hydrogenase-inspired diiron molecular electrocatalysts for the reduction of protons into H 2 generation in the presence of HOAc.CCDC:2443967,1;2443969,2.展开更多
Ni-based superalloys play a critical role in the aerospace industry due to their exceptional mechanical properties and oxidation resistance.However,the conventional development of new superalloys is often constrained ...Ni-based superalloys play a critical role in the aerospace industry due to their exceptional mechanical properties and oxidation resistance.However,the conventional development of new superalloys is often constrained by lengthy experimental cycles and high costs.To address these challenges,machine learning has emerged as an effective strategy for accelerating alloy design by efficiently exploring composition-property relationship,optimizing processing parameters,and enhancing predictive accuracy.This review summarizes recent progress in applying machine learning to composition optimization and mechanical property prediction of Ni-based superalloys,emphasizing the integration of theoretical modeling and experimental validation.The importance of feature engineering,including data collection,preprocessing,feature construction,and dimensionality reduction,was first highlighted.Subsequently,the machine learning approaches for novel alloy design and prediction of key properties including fatigue resistance,creep resistance,and oxidation resistance were discussed.Through data-driven approaches,machine learning not only enhances predictive capabilities but also uncovers complex composition-property relationship,which accelerates the development of next-generation Ni-based superalloys.We anticipate that the continued advancements in this field will drive more efficient and cost-effective alloy design,ultimately accelerating the transition from computational predictions to experimental realizations.展开更多
The creep behavior of two PM superalloys,U720Li and RR1000,each alloyed with trace amount of Sc,was systematically investigated.Findings reveal that RR1000 alloy with 0.064 wt.%Sc(R-0.064)demonstrates superior creep r...The creep behavior of two PM superalloys,U720Li and RR1000,each alloyed with trace amount of Sc,was systematically investigated.Findings reveal that RR1000 alloy with 0.064 wt.%Sc(R-0.064)demonstrates superior creep resistance compared to U720Li alloy with 0.043 wt.%Sc(U-0.043),at 650℃ and 1000 MPa,and the primary creep mechanisms in both alloys are identified as dislocation shearing and precipitate bypassing.When tested at 700℃ and 700 MPa,the U-0.043 alloy predominantly exhibits micro-twinning and dislocation bypassing,while the R-0.064 alloy engages in extended stacking fault shearing ofγ'precipitate,dislocation bypassing and climb.At 750℃ and 460 MPa,dislocation bypassing and climb emerge as the main creep mechanisms for both alloys.展开更多
The performance of welded Ni-based superalloys at high temperatures is essential to be evaluated due to their particular service environment for aero-engines and high-speed aircrafts.The tensile properties and related...The performance of welded Ni-based superalloys at high temperatures is essential to be evaluated due to their particular service environment for aero-engines and high-speed aircrafts.The tensile properties and related microstructural evolutions such as the carbide precipitate and grain of a laser-welded Ni-based alloy were experimentally and numerically investigated at different temperatures(20,300,500,800℃).The results show that at room temperature,the strength of the Base Material(BM)was slightly smaller,with a difference of less than 1%,than the Welded Material(WM),which can be attributed to the more uniformly distributed needle-shaped carbide precipitates in the WM than those nonuniformly coarser spherical ones in the BM.While at 300℃ and 500℃,the strength of WM decreased more obviously compared with that of BM due to the more apparent growth of grain:13.52%loss in yield strength in WM alloys as compared with BM alloys at 300℃,and 16.57% at 500℃.At 800℃,the strength of BM and WM both decreased to a similar level due to Dynamic Recrystallization(DRX).However,a much higher elongation was observed for the BM than WM(less than 50%of BM),which can be attributed to the enhanced dislocation accumulation capability of the large spherical carbides along grain boundaries on the fracture surface in BM.Furthermore,a unified model considering the welding effects on both microstructures(dislocation,carbides,and grain)and mechanical properties evolutions at different temperatures was developed and validated.Based on this model,the key temperature ranges(20–600℃)where apparent weakening of strength and uniform plasticity occurs for welded structures were identified,providing a direct guidance for potential structure and process design.展开更多
This study investigates the microstructural evolution of a novel low-cost second-generation Ni-based single crystal superalloy during long-term thermal exposure at different temperatures(982℃,1038℃,1093℃)and its im...This study investigates the microstructural evolution of a novel low-cost second-generation Ni-based single crystal superalloy during long-term thermal exposure at different temperatures(982℃,1038℃,1093℃)and its impact on the stress rupture properties of alloy.The results reveal that theγ′phase undergoes coarsening and rafting at high temperatures,and its growth behavior follows the Ostwald ripening mechanism.With the increase in aging temperature and extension of aging time,the coarsening rate of theγ′phase increases significantly.Particularly at 1093℃,theγ′phase undergoes the most pronounced growth,leading to a remarkable deterioration of its precipitation strengthening effect.Furthermore,under conditions of higher temperature and longer time,minor amounts of topologically close-packed(TCP)phase precipitate.As the aging temperature rises and time elapses,the precipitation tendency of the TCP phase shows a slight increase.The stress rupture testing at 1100℃/120 MPa demonstrates that the stress rupture life decreases significantly with the increase in thermal exposure temperature and time.This is mainly attributed to the diminished precipitation strengthening effect of theγ′phase and the deteriorating effect of the TCP phase.However,under the same conditions,the stress rupture properties of this alloy are comparable to those of the DD5 alloy.This research provides theoretical support for enhancing the service stability and reliability of single crystal turbine blades,and offers a reference for the development of cost-effective and highperformance turbine blade materials.展开更多
Surface recrystallization(RX) is a typical grain defect observed in directionally solidified(DS) Ni-based superalloys. Most studies have focused on the RX behavior and its impact on the mechanical properties of single...Surface recrystallization(RX) is a typical grain defect observed in directionally solidified(DS) Ni-based superalloys. Most studies have focused on the RX behavior and its impact on the mechanical properties of single-crystal(SC) superalloys, with limited research on its influence on the high-temperature mechanical properties of DS superalloys. This study systematically investigated the effect of RX on the high-temperature tensile properties of a DS DZ409 superalloy. The results show that at 650℃, the yield strength decreases almost linearly with an increase in RX fraction. A significant reduction in elongation is observed as the RX fraction increases from 0% to 4.9%. However, beyond this point, further increase in RX fraction leads to minimal changes in elongation. At 950℃, both yield strength and elongation decrease as the RX fraction increases from 0% to 4.9%. At 650℃, fractures in the RX DS superalloys exhibit a mixed mode of transgranular and intergranular cleavage fracture, while at 950℃, it features a combination of ductile and intergranular dimple fractures. The failure mechanism of the RX DS superalloy is associated with the introduction of transverse grain boundaries(GBs) during RX. In the early stages of tensile testing at intermediate and high temperatures, cracks can easily initiate at these GBs. Subsequently, the cracks propagate along the GBs into the DS matrix, ultimately leading to failure of the DS superalloy.展开更多
Four powder metallurgy(PM)Ni-based superalloys with different Hf and Ta contents were creep-tested at 650℃ and 970 MPa,700℃ and 770 MPa,and 750℃ and 580 MPa,respectively.The effect of Hf and Ta on creep deformation...Four powder metallurgy(PM)Ni-based superalloys with different Hf and Ta contents were creep-tested at 650℃ and 970 MPa,700℃ and 770 MPa,and 750℃ and 580 MPa,respectively.The effect of Hf and Ta on creep deformation behaviors of the superalloys was studied from multiple scales by SEM,electron backscatter diffraction(EBSD),and aberration-corrected scanning transmission electron microscope(AC-STEM).The results showed that Hf and Ta suppressed the intergranular fracture and initiation of cracks during the acceleration creep stage,which prolonged the creep rupture time.Hf and Ta inhibited the stacking faults extending and the dislocation climbing and promoted the Suzuki segregation of W during the steady-state creep stage,which reduced the minimum creep rate and delayed the start time of the acceleration creep stage.The Suzuki segregation of Co,Cr,Mo,Ti,Nb,W,and Ta along stacking faults was observed after Hf and Ta addition,leading to the localized phase transformation in the γ′phase,and the stacking fault phase was chemically disordered.This study provided ideas for the composition design of novel PM Ni-based superalloys and theoretical foundations for the combined addition of Hf and Ta.展开更多
Nickel-based catalysts have emerged as crucial components in alkaline oxygen evolution reactions(OER)due to their exceptional catalytic performance and unique structural properties.However,the understanding of their c...Nickel-based catalysts have emerged as crucial components in alkaline oxygen evolution reactions(OER)due to their exceptional catalytic performance and unique structural properties.However,the understanding of their catalytic mechanisms remains incomplete.This review systematically explores the various types of Ni-based catalysts,including metal-organic frameworks(MOFs),perovskites,and layered double hydroxides(LDHs),while emphasizing their performance metrics.We critically assess the application of advanced in situ characterization techniques,such as in situ Raman spectroscopy and X-ray absorption spectroscopy(XAS),in elucidating the structural evolution and active species during the OER process.By addressing the interplay between catalyst structure and performance,this review aims to provide insights that drive future research efforts toward the optimization of Ni-based catalysts for sustainable hydrogen production.Key areas for potential research advancements are also identified.展开更多
The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to si...The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to simulate the IFW process of a Ni-based superalloy and reveal the omnidirectional thermo-mechanical coupling mechanism of the friction interface.The numerical model successfully simulated the deceleration,deformation processes,and peak torsional moments in IFW and captured the evolution of temperature,contact pressure,and stress.The simulated results were validated through measured thermal history,optical macrography,and axial shortening.The results indicated that interfacial friction heat was the primary heat source,and plastic deformation energy only accounted for 4%of the total.The increase in initial rotational speed and friction pressure elevated the peak temperature,reaching a maximum of 1525.5K at an initial rotational speed of 2000 r/min and friction pressure of 400 MPa.The interface heat generation could form an axial temperature gradient exceeding 320K/mm.The radial inhomogeneities of heat generation and temperature were manifested in a concentric ring distribution with maximum heat flux and temperature ranging from 2/5 to 2/3 radius.The radial inhomogeneities were caused by increasing linear velocity along the radius and an opposite distribution of contact pressure,which could reach 1.7 times the set pressure at the center.The circumferential inhomogeneity of thermomechanical distribution during rotary friction welding was revealed for the first time,benefiting from the 3D model.The deflection and transformation of distribution in contact pressure and Mises stress were indicators of plastic deformation and transition of quasi-steady state welding.The critical Mises stress was 0.5 times the friction pressure in this study.The presented modeling provides a reliable insight into the thermo-mechanical coupling mechanism of IFW and lays a solid foundation for predicting the microstructures and mechanical properties of inertia friction welded joints.展开更多
Two Gd_(2)complexes,namely[Gd_(2)(dbm)_(2)(HL_(1))_(2)(CH_(3)OH)_(2)]·4CH_(3)OH(1)and[Gd_(2)(dbm)_(2)(L_(2))_(2)(CH_(3)OH)_(2)]·2CH_(3)OH(2),where H_(3)L_(1)=(Z)-N'-[4-(diethylamino)-2-hydroxybenzylidene...Two Gd_(2)complexes,namely[Gd_(2)(dbm)_(2)(HL_(1))_(2)(CH_(3)OH)_(2)]·4CH_(3)OH(1)and[Gd_(2)(dbm)_(2)(L_(2))_(2)(CH_(3)OH)_(2)]·2CH_(3)OH(2),where H_(3)L_(1)=(Z)-N'-[4-(diethylamino)-2-hydroxybenzylidene]-2-hydroxyacetohydrazide,H_(2)L_(2)=(E)-N'-(5-bromo-2-hydroxy-3-methoxybenzylidene)nicotinohydrazide,Hdbm=dibenzoylmethane,have been constructed by adopting the solvothermal method.Structural characterization unveils that both complexes 1 and 2 are constituted by two Gd^(3+)ions,two dbm-ions,two CH_(3)OH molecules,and two polydentate Schiff-base ligands(HL_(1)^(2-)or L_(2)^(2-)).In addition,complex 1 contains four free methanol molecules,whereas complex 2 harbors two free methanol molecules.By investigating the interactions between complexes 1 and 2 and four types of bacteria(Bacillus subtilis,Escherichia coli,Staphylococcus aureus,Candida albicans),it was found that both complexes 1 and 2 exhibited potent antibacte-rial activities.The interaction mechanisms between the ligands H_(3)L_(1),H_(2)L_(2),complexes 1 and 2,and calf thymus DNA(CT-DNA)were studied using ultraviolet-visible spectroscopy,fluorescence titration,and cyclic voltammetry.The results demonstrated that both complexes 1 and 2 can intercalate into CT-DNA molecules,thereby inhibiting bacterial proliferation to achieve the antibacterial effects.CCDC:2401116,1;2401117,2.展开更多
We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic ligh...We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction.展开更多
文摘To expand the study on the structures and biological activities of the anthracyclines anticancer drugs and reduce their toxic side effects,the new anthraquinone derivatives,9‑pyridylanthrahydrazone(9‑PAH)and 9,10‑bispyridylanthrahydrazone(9,10‑PAH)were designed and synthesized.Utilizing 9‑PAH and 9,10‑PAH as promising anticancer ligands,their respective copper complexes,namely[Cu(L1)Cl_(2)]Cl(1)and{[Cu_(4)(μ_(2)‑Cl)_(3)Cl_(4)(9,10‑PAH)_(2)(DMSO)_(2)]Cl_(2)}_(n)(2),were subsequently synthesized,where the new ligand L1 is formed by coupling two 9‑PAH ligands in the coordination reaction.The chemical and crystal structures of 1 and 2 were elucidated by IR,MS,elemental analysis,and single‑crystal X‑ray diffraction.Complex 1 forms a mononuclear structure.L1 coordinates with Cu through its three N atoms,together with two Cl atoms,to form a five‑coordinated square pyramidal geometry.Complex 2 constitutes a polymeric structure,wherein each structural unit centrosymmetrically encompasses two five‑coordinated binuclear copper complexes(Cu1,Cu2)of 9,10‑PAH,with similar square pyramidal geometry.A chlorine atom(Cl_(2)),located at the symmetry center,bridges Cu1 and Cu1A to connect the two binuclear copper structures.Meanwhile,the two five‑coordinated Cu2 atoms symmetrically bridge the adjacent structural units via one coordinated Cl atom,respectively,thus forming a 1D chain‑like polymeric structure.In vitro anticancer activity assessments revealed that 1 and 2 showed significant cytotoxicity even higher than cisplatin.Specifically,the IC_(50)values of 2 against HeLa‑229 and SK‑OV‑3 cancer cell lines were determined to be(5.92±0.32)μmol·L^(-1)and(6.48±0.39)μmol·L^(-1),respectively.2 could also block the proliferation of HeLa‑229 cells in S phase and significantly induce cell apoptosis.In addition,fluorescence quenching competition experiments suggested that 2 might interact with DNA by an intercalative binding mode,offering insights into its underlying anticancer mechanism.CCDC:2388918,1;2388919,2.
基金Shenzhen Science and Technology Program(JSGG20220831092800001)。
文摘The microstructure of single crystal superalloy is relatively simple,consisting primarily ofγdendrites andγ/γ′eutectics.During the directional solidification process of Ni-based single crystal superalloys,withdrawal rate is a critical parameter affecting the spatial distribution ofγ/γ′eutectic along gravity direction.The results show that theγ/γ′eutectic fraction of the upper platform surface is always higher than that of the lower one,regardless of withdrawal rate.As the withdrawal rate decreases,there is a significant increase inγ/γ′eutectic fraction on the upper surface,while it decreases on the lower surface.The upward accumulation ofγ/γ′eutectic becomes more severe as the withdrawal rate decreases.It is also found that the percentage of Al+Ta is positively correlated with theγ/γ′eutectic fraction.Thermo-solute convection of Al and Ta solutes in the solidification front is the prime reason for the non-uniform distribution of eutectic.The non-uniform distribution ofγ/γ′eutectic cannot be eliminated even after subsequent solution heat treatment,resulting in excess eutectic on the upper surface and thus leading to the scrapping of the blade.
文摘Recent research progress on the use of Ni-based catalysts supported by various carbon materials,such as carbon nanotubes,graphene,and activated carbon,for the hydrogenation of CO_(2)to CH4 is summarized.The influence of additives and surface modification methods on improving their catalytic performance is discussed as is the reaction mechanism,especially the structurefunction relationship produced by the carbon.The review provides a comprehensive directory for the rational design of carbon-supported Ni-based catalysts for the methanation of CO_(2).
基金support from the National Natural Science Foundation of China(Nos.22277056,21977052)the Distinguished Young Scholars of Jiangsu Province(No.BK20230006)+2 种基金the Natural Science Foundation of Jiangsu Province(Nos.BK20230977,BK20231090)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.23KJB150020)the Jiangsu Excellent Postdoctoral Program(No.2022ZB758)。
文摘Metal complexes hold significant promise in tumor diagnosis and treatment.However,their potential applications in photodynamic therapy(PDT)are hindered by issues such as poor photostability,low yield of reactive oxygen species(ROS),and aggregation-induced ROS quenching.To address these challenges,we present a molecular self-assembly strategy utilizing aggregation-induced emission(AIE)conjugates for metal complexes.As a proof of concept,we synthesized a mitochondrial-targeting cyclometalated Ir(Ⅲ)photosensitizer Ir-TPE.This approach significantly enhances the photodynamic effect while mitigating the dark toxicity associated with AIE groups.Ir-TPE readily self-assembles into nanoaggregates in aqueous solution,leading to a significant production of ROS upon light irradiation.Photoirradiated Ir-TPE triggers multiple modes of death by excessively accumulating ROS in the mitochondria,resulting in mitochondrial DNA damage.This damage can lead to ferroptosis and autophagy,two forms of cell death that are highly cytotoxic to cancer cells.The aggregation-enhanced photodynamic effect of Ir-TPE significantly enhances the production of ROS,leading to a more pronounced cytotoxic effect.In vitro and in vivo experiments demonstrate this aggregation-enhanced PDT approach achieves effective in situ tumor eradication.This study not only addresses the limitations of metal complexes in terms of low ROS production due to aggregation but also highlights the potential of this strategy for enhancing ROS production in PDT.
基金Guizhou Province Science and Technology Plan Project(QKHJC-ZK[2024]yiban604)Guizhou Province Science and Technology Plan Project(CXTD[2021]008)+4 种基金Bijie City Science and Technology Project(BKLH[2023]9)Technology Project of Bijie City(BKLH[2023]36)Natural Science Research Project of Guizhou Higher Education Institutions of China(QJJ[2023]047)Science and Technology Project of Guizhou Department of Transportation(2022-121-011)Sanmenxia City Science and Technology Bureau Science and Technology Research Project(2022002005)。
文摘The microstructure evolution and deformation mechanism of a DZ125 superalloy during high-temperature creep were studied by means of microstructure observation and creep-property tests.The results show that at the initial stage of high-temperature creep,two sets of dislocations with different Burgers vectors move and meet inγmatrix channels,and react to form a quadrilateral dislocation network.Andγ′phases with raft-like microstructure are generated after the formation of dislocation networks.As creep progresses,the quadrilateral dislocation network is gradually transformed into hexagonal and quadrilateral dislocation networks.During steady stage of creep,the superalloy undergoes deformation with the mechanism that a great number of dislocations slip and climb in the matrix across the raft-likeγ′phases.At the later stage of creep,the raft-likeγ′phases are sheared by dislocations at the breakage of dislocation networks,and then alternate slip occurs,which distorts and breaks the raft-likeγ′/γphases,resulting in the accumulation of micropores at the raft-likeγ′/γinterfaces and the formation of microcracks.As creep continues,the microcracks continue to expand until creep fracture occurs,which is the damage and fracture mechanism of the alloy at the later stage of creep at high temperature.
文摘Two novel lanthanide complexes,[Sm_(2)(BA)_(6)(4-OH-terpy)_(2)]·2H_(2)O·2EtOH(1)and[Pr_(2)(BA)_(6)(4-OH-terpy)_(2)(H_(2)O)_(2)]·HBA·H_(2)O(2),where HBA=benzoic acid,4-OH-terpy=4-hydroxy-2,2'∶6',2″-terpyridine,were successfully synthesized using ultrasonic dissolution and the conventional solution method with two mixed ligands HBA and 4-OH-terpy.During the synthesis,4-OH-terpy was involved in the reaction as a neutral ligand,while HBA,in its deprotonated form(BA-),coordinated with the lanthanide ions as an acidic ligand.The crystal structures of these two complexes were precisely determined by single-crystal X-ray diffraction.Elemental analysis,infrared and Raman spectroscopy,and powder X-ray diffraction techniques were also employed to further explore the physicochemical properties of the two complexes.The single-crystal X-ray diffraction data indicate that,despite their structural differences,both complexes belong to the triclinic crystal system P1 space group.The central lanthanide ions have the same coordination number but exhibit different coordination environments.To comprehensively evaluate the thermal stability of these two complexes,comprehensive tests including thermogravimetric analysis,differential thermogravimetric analysis,differential scanning calorimetry,Fourier transform infrared spectroscopy,and mass spectrometry were conducted.Meanwhile,an in-depth investigation was conducted into the 3D infrared stacked images and mass spectra of the gases emitted from the complexes.In addition,studies of the fluorescence properties of complex1 showed that it exhibited fluorescence emission matching the Sm^(3+)characteristic transition.
基金supported by the Natural Science Foundation of Shanxi Province(202203021221155)the Foundation of National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal(J23-24-902)。
文摘With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.
文摘To achieve efficient catalytic hydrogenation of CO_(2)to formate,we employed a transmetallation strategy to develop three novel iridium(Ⅰ)complexes,which feature N‑heterocyclic carbene‑nitrogen‑phosphine ligands(CNP)and a 1,5‑cyclooctadiene(cod)molecule:[Ir(cod)(κ^(3)‑CN^(im)P)]Cl(1⁃Cl),[Ir(cod)(κ^(3)‑CN^(im)P)]PF6(1⁃PF_(6)),and[Ir(cod)(κ^(3)‑CNHP)]Cl(2).The^(1)H NMR spectra,^(31)P NMR spectra,and high‑resolution mass spectra verify the successful synthesis of these three Ir(Ⅰ)‑CNP complexes.Furthermore,single‑crystal X‑ray diffraction analysis confirms the coordination geometry of 1⁃PF_(6).The strong Ir—C(NHC)bond suggests that the carbene carbon plays an enhanced anchoring role to iridium due to its strongσ‑donating ability,which helps stabilize the active metal species during CO_(2)hydrogenation.As a result,the Ir(Ⅰ)‑CNP complex exhibits remarkable activity and long catalytic lifetime for the hydrogenation of CO_(2)to formate,reaching a turnover number(TON)of 1.16×10^(6)after 150 h at a high temperature of 170℃,which was a relatively high value among all the Ir complexes.CCDC:2384071,1⁃PF_(6).
基金supported by the National Natural Science Foundation of China(No.52303394)the National Key Research and Development Program of China(No.2022YFB3705000)+1 种基金the Natural Science Foundation of Liaoning Province(No.2023-BS-015)the Science Center for Gas Turbine Project(No.P2022-C-IV-002-001).
文摘The effect of carbon content on the microstructures and stress rupture properties of a newly developed polycrystalline Ni-based superalloy with high Cr content has been studied.It was observed that both grain size and the number of carbides increased with an increase in carbon content.After heat treatment,granular M_(23)C_(6)carbides were dispersed around MC carbides along grain boundaries and inside grains.The quantity of granular M_(23)C_(6)carbides increased while their sizes decreased.These findings can be verified with the results of thermodynamic calculation and differential scanning calorimetry analysis.The stress rupture times(975℃/225 MPa)increased from 13.3 to 25.5 h with the carbon content increased from 0.1 to 0.2 wt.%.The improvement can be attributed to two primary factors.Firstly,grain boundary is typically weak region during deformation process and the grain size increased as carbon content increased in the alloy.Secondly,carbides act as hindrances to impede dislocation movement,leading to dislocation entanglement.As carbon content rose,the quantity of carbides in interdendritic regions and grain boundaries increased,providing a certain degree of strengthening effect and resulting in a longer stress rupture time.
文摘To extend a new family of aminophosphine-coordinated[FeFe]-hydrogenase mimics for catalytic hydro-gen(H_(2))evolution,we carried out the ligand substitutions of diiron hexacarbonyl precursors[Fe_(2)(μ-X_(2)pdt)(CO)_(6)](X_(2)pdt=(SCH_(2))_(2)CX_(2),X=Me,H)with aminodiphosphines(Ph_(2)PCH_(2))_(2)NY(Y=(CH_(2))_(2)OH,(CH_(2))_(3)OH)to obtain two new diiron aminophosphine complexes[Fe_(2)(L1)(μ-Me_(2)pdt)(CO)_(5)](1)and[Fe_(2)(L2)(μ-H_(2)pdt)(CO)_(5)](2),where L1=3-[(diphe-nylphosphaneyl)methyl]oxazolidine,L2=3-[(diphenylphosphaneyl)methyl]-1,3-oxazinane.Moreover,the structures of 1 and 2 have been fully confirmed by elemental analysis,spectroscopic techniques,and single-crystal X-ray diffraction.Using cyclic voltammetry(CV),we investigated the electrochemical redox performance and proton reduc-tion activities of 1 and 2 in acetic acid(HOAc).The CV study indicates that diiron aminophosphine complexes 1 and 2 can be considered to be hydrogenase-inspired diiron molecular electrocatalysts for the reduction of protons into H 2 generation in the presence of HOAc.CCDC:2443967,1;2443969,2.
基金financially supported by the National Natural Science Foundation of China(Nos.52201203 and 52471004)the Fundamental Research Funds for the Central Universities(No.N2423030)the Science and Technology Project of Hebei Education Department(No.QN2023155).
文摘Ni-based superalloys play a critical role in the aerospace industry due to their exceptional mechanical properties and oxidation resistance.However,the conventional development of new superalloys is often constrained by lengthy experimental cycles and high costs.To address these challenges,machine learning has emerged as an effective strategy for accelerating alloy design by efficiently exploring composition-property relationship,optimizing processing parameters,and enhancing predictive accuracy.This review summarizes recent progress in applying machine learning to composition optimization and mechanical property prediction of Ni-based superalloys,emphasizing the integration of theoretical modeling and experimental validation.The importance of feature engineering,including data collection,preprocessing,feature construction,and dimensionality reduction,was first highlighted.Subsequently,the machine learning approaches for novel alloy design and prediction of key properties including fatigue resistance,creep resistance,and oxidation resistance were discussed.Through data-driven approaches,machine learning not only enhances predictive capabilities but also uncovers complex composition-property relationship,which accelerates the development of next-generation Ni-based superalloys.We anticipate that the continued advancements in this field will drive more efficient and cost-effective alloy design,ultimately accelerating the transition from computational predictions to experimental realizations.
基金supported by the Natural Science Foundation of China(No.52074366)the Top Ten Science and Technology Projects in Hunan Province,China(No.2024GK1080)+4 种基金the Aero Engine Corporation of China(No.HFZL2022CXY029)the Young Elite Scientists Sponsorship Program by CAST,China(No.2022QNRC001)the Natural Science Foundation of Hunan Province,China(No.2021JJ40757)the Science and Technology Innovation Program of Hunan Province,China(No.2021RC3131)the High Performance Computing Center of Central South University,and the Project supported by State Key Laboratory of Powder Metallurgy,Central South University,China.
文摘The creep behavior of two PM superalloys,U720Li and RR1000,each alloyed with trace amount of Sc,was systematically investigated.Findings reveal that RR1000 alloy with 0.064 wt.%Sc(R-0.064)demonstrates superior creep resistance compared to U720Li alloy with 0.043 wt.%Sc(U-0.043),at 650℃ and 1000 MPa,and the primary creep mechanisms in both alloys are identified as dislocation shearing and precipitate bypassing.When tested at 700℃ and 700 MPa,the U-0.043 alloy predominantly exhibits micro-twinning and dislocation bypassing,while the R-0.064 alloy engages in extended stacking fault shearing ofγ'precipitate,dislocation bypassing and climb.At 750℃ and 460 MPa,dislocation bypassing and climb emerge as the main creep mechanisms for both alloys.
基金co-supported by the financial support from the Fundamental Research Funds for the Central Universities,China(Nos.YWF-23-L-1012,YWF-22-L-1017)the National Natural Science Foundation of China(No.52005020)。
文摘The performance of welded Ni-based superalloys at high temperatures is essential to be evaluated due to their particular service environment for aero-engines and high-speed aircrafts.The tensile properties and related microstructural evolutions such as the carbide precipitate and grain of a laser-welded Ni-based alloy were experimentally and numerically investigated at different temperatures(20,300,500,800℃).The results show that at room temperature,the strength of the Base Material(BM)was slightly smaller,with a difference of less than 1%,than the Welded Material(WM),which can be attributed to the more uniformly distributed needle-shaped carbide precipitates in the WM than those nonuniformly coarser spherical ones in the BM.While at 300℃ and 500℃,the strength of WM decreased more obviously compared with that of BM due to the more apparent growth of grain:13.52%loss in yield strength in WM alloys as compared with BM alloys at 300℃,and 16.57% at 500℃.At 800℃,the strength of BM and WM both decreased to a similar level due to Dynamic Recrystallization(DRX).However,a much higher elongation was observed for the BM than WM(less than 50%of BM),which can be attributed to the enhanced dislocation accumulation capability of the large spherical carbides along grain boundaries on the fracture surface in BM.Furthermore,a unified model considering the welding effects on both microstructures(dislocation,carbides,and grain)and mechanical properties evolutions at different temperatures was developed and validated.Based on this model,the key temperature ranges(20–600℃)where apparent weakening of strength and uniform plasticity occurs for welded structures were identified,providing a direct guidance for potential structure and process design.
文摘This study investigates the microstructural evolution of a novel low-cost second-generation Ni-based single crystal superalloy during long-term thermal exposure at different temperatures(982℃,1038℃,1093℃)and its impact on the stress rupture properties of alloy.The results reveal that theγ′phase undergoes coarsening and rafting at high temperatures,and its growth behavior follows the Ostwald ripening mechanism.With the increase in aging temperature and extension of aging time,the coarsening rate of theγ′phase increases significantly.Particularly at 1093℃,theγ′phase undergoes the most pronounced growth,leading to a remarkable deterioration of its precipitation strengthening effect.Furthermore,under conditions of higher temperature and longer time,minor amounts of topologically close-packed(TCP)phase precipitate.As the aging temperature rises and time elapses,the precipitation tendency of the TCP phase shows a slight increase.The stress rupture testing at 1100℃/120 MPa demonstrates that the stress rupture life decreases significantly with the increase in thermal exposure temperature and time.This is mainly attributed to the diminished precipitation strengthening effect of theγ′phase and the deteriorating effect of the TCP phase.However,under the same conditions,the stress rupture properties of this alloy are comparable to those of the DD5 alloy.This research provides theoretical support for enhancing the service stability and reliability of single crystal turbine blades,and offers a reference for the development of cost-effective and highperformance turbine blade materials.
基金supported by the National Science and Technology Major Project(No.HT-J2019-VI-0020-0136)the National Youth Talent Support Program,and the Fundamental Research Funds for the Central Universities(No.xtr072024004).
文摘Surface recrystallization(RX) is a typical grain defect observed in directionally solidified(DS) Ni-based superalloys. Most studies have focused on the RX behavior and its impact on the mechanical properties of single-crystal(SC) superalloys, with limited research on its influence on the high-temperature mechanical properties of DS superalloys. This study systematically investigated the effect of RX on the high-temperature tensile properties of a DS DZ409 superalloy. The results show that at 650℃, the yield strength decreases almost linearly with an increase in RX fraction. A significant reduction in elongation is observed as the RX fraction increases from 0% to 4.9%. However, beyond this point, further increase in RX fraction leads to minimal changes in elongation. At 950℃, both yield strength and elongation decrease as the RX fraction increases from 0% to 4.9%. At 650℃, fractures in the RX DS superalloys exhibit a mixed mode of transgranular and intergranular cleavage fracture, while at 950℃, it features a combination of ductile and intergranular dimple fractures. The failure mechanism of the RX DS superalloy is associated with the introduction of transverse grain boundaries(GBs) during RX. In the early stages of tensile testing at intermediate and high temperatures, cracks can easily initiate at these GBs. Subsequently, the cracks propagate along the GBs into the DS matrix, ultimately leading to failure of the DS superalloy.
基金financially supported by the National Science and Technology Major Project of China(No.2017-Ⅵ-0008-0078)。
文摘Four powder metallurgy(PM)Ni-based superalloys with different Hf and Ta contents were creep-tested at 650℃ and 970 MPa,700℃ and 770 MPa,and 750℃ and 580 MPa,respectively.The effect of Hf and Ta on creep deformation behaviors of the superalloys was studied from multiple scales by SEM,electron backscatter diffraction(EBSD),and aberration-corrected scanning transmission electron microscope(AC-STEM).The results showed that Hf and Ta suppressed the intergranular fracture and initiation of cracks during the acceleration creep stage,which prolonged the creep rupture time.Hf and Ta inhibited the stacking faults extending and the dislocation climbing and promoted the Suzuki segregation of W during the steady-state creep stage,which reduced the minimum creep rate and delayed the start time of the acceleration creep stage.The Suzuki segregation of Co,Cr,Mo,Ti,Nb,W,and Ta along stacking faults was observed after Hf and Ta addition,leading to the localized phase transformation in the γ′phase,and the stacking fault phase was chemically disordered.This study provided ideas for the composition design of novel PM Ni-based superalloys and theoretical foundations for the combined addition of Hf and Ta.
基金supported by the Fundamental Research Funds for the Central Universities(20822041H4082).
文摘Nickel-based catalysts have emerged as crucial components in alkaline oxygen evolution reactions(OER)due to their exceptional catalytic performance and unique structural properties.However,the understanding of their catalytic mechanisms remains incomplete.This review systematically explores the various types of Ni-based catalysts,including metal-organic frameworks(MOFs),perovskites,and layered double hydroxides(LDHs),while emphasizing their performance metrics.We critically assess the application of advanced in situ characterization techniques,such as in situ Raman spectroscopy and X-ray absorption spectroscopy(XAS),in elucidating the structural evolution and active species during the OER process.By addressing the interplay between catalyst structure and performance,this review aims to provide insights that drive future research efforts toward the optimization of Ni-based catalysts for sustainable hydrogen production.Key areas for potential research advancements are also identified.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFB3404904)。
文摘The coupling between heat and pressure is the kernel of inertia friction welding(IFW)and is still not fully understood.A novel 3D fully coupled finite element model based on a plastic friction pair was developed to simulate the IFW process of a Ni-based superalloy and reveal the omnidirectional thermo-mechanical coupling mechanism of the friction interface.The numerical model successfully simulated the deceleration,deformation processes,and peak torsional moments in IFW and captured the evolution of temperature,contact pressure,and stress.The simulated results were validated through measured thermal history,optical macrography,and axial shortening.The results indicated that interfacial friction heat was the primary heat source,and plastic deformation energy only accounted for 4%of the total.The increase in initial rotational speed and friction pressure elevated the peak temperature,reaching a maximum of 1525.5K at an initial rotational speed of 2000 r/min and friction pressure of 400 MPa.The interface heat generation could form an axial temperature gradient exceeding 320K/mm.The radial inhomogeneities of heat generation and temperature were manifested in a concentric ring distribution with maximum heat flux and temperature ranging from 2/5 to 2/3 radius.The radial inhomogeneities were caused by increasing linear velocity along the radius and an opposite distribution of contact pressure,which could reach 1.7 times the set pressure at the center.The circumferential inhomogeneity of thermomechanical distribution during rotary friction welding was revealed for the first time,benefiting from the 3D model.The deflection and transformation of distribution in contact pressure and Mises stress were indicators of plastic deformation and transition of quasi-steady state welding.The critical Mises stress was 0.5 times the friction pressure in this study.The presented modeling provides a reliable insight into the thermo-mechanical coupling mechanism of IFW and lays a solid foundation for predicting the microstructures and mechanical properties of inertia friction welded joints.
文摘Two Gd_(2)complexes,namely[Gd_(2)(dbm)_(2)(HL_(1))_(2)(CH_(3)OH)_(2)]·4CH_(3)OH(1)and[Gd_(2)(dbm)_(2)(L_(2))_(2)(CH_(3)OH)_(2)]·2CH_(3)OH(2),where H_(3)L_(1)=(Z)-N'-[4-(diethylamino)-2-hydroxybenzylidene]-2-hydroxyacetohydrazide,H_(2)L_(2)=(E)-N'-(5-bromo-2-hydroxy-3-methoxybenzylidene)nicotinohydrazide,Hdbm=dibenzoylmethane,have been constructed by adopting the solvothermal method.Structural characterization unveils that both complexes 1 and 2 are constituted by two Gd^(3+)ions,two dbm-ions,two CH_(3)OH molecules,and two polydentate Schiff-base ligands(HL_(1)^(2-)or L_(2)^(2-)).In addition,complex 1 contains four free methanol molecules,whereas complex 2 harbors two free methanol molecules.By investigating the interactions between complexes 1 and 2 and four types of bacteria(Bacillus subtilis,Escherichia coli,Staphylococcus aureus,Candida albicans),it was found that both complexes 1 and 2 exhibited potent antibacte-rial activities.The interaction mechanisms between the ligands H_(3)L_(1),H_(2)L_(2),complexes 1 and 2,and calf thymus DNA(CT-DNA)were studied using ultraviolet-visible spectroscopy,fluorescence titration,and cyclic voltammetry.The results demonstrated that both complexes 1 and 2 can intercalate into CT-DNA molecules,thereby inhibiting bacterial proliferation to achieve the antibacterial effects.CCDC:2401116,1;2401117,2.
文摘We have examined the theoretical implications of combining two main and three auxiliary ligands to form several Ir(Ⅲ)complexes featuring a transition metal as their core atom to identify some appropriate organic lightemitting diode(OLED)materials.By utilizing electronic structure,frontier molecular orbitals,minimum single-line absorption,triplet excited states,and emission spectral data derived from the density functional theory,the usefulness of these Ir(Ⅲ)complexes,including(piq)_(2)Ir(acac),(piq)_(2)Ir(tmd),(piq)_(2)Ir(tpip),(fpiq)_(2)Ir(acac),(fpiq)_(2)Ir(tmd),and(fpiq)_(2)Ir(tpip),in OLEDs was examined,where piq=1-phenylisoquinoline,fpiq=1-(4-fluorophenyl)isoquinoline,acac=(3Z)-4-hydroxypent-3-en-2-one,tmd=(4Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one,and tpip=tetraphenylimido-diphosphonate.These complexes all have low-efficiency roll-off properties,especially(fpiq)_(2)Ir(tpip).Some researchers have successfully synthesized complexes extremely similar to(piq)_(2)Ir(acac)through the Suzuki-Miyaura coupling reaction.
