Ferromagnetic high damping(FHA)alloys with a wide temperature range from-150℃to 300℃have unique application value in extreme environments.In the present work,the damping behaviors of Fe-21 Ga-xLa(x=0.12 wt.%,0.24 wt...Ferromagnetic high damping(FHA)alloys with a wide temperature range from-150℃to 300℃have unique application value in extreme environments.In the present work,the damping behaviors of Fe-21 Ga-xLa(x=0.12 wt.%,0.24 wt.%,0.47 wt.%,1.18 wt.%,and 2.33 wt.%La)alloys have been studied in detail,and a new phenomenological model has been proposed.With the increase of La content,the Laves phase(LaGa_(2))in the matrix increases gradually,and the resistance opposing the domain movement increases as well.Combined with the results of synchrotron radiation X-ray diffraction,neutron diffraction,and magnetic domain observation,the resistance mainly comes from three parts:the average stress related to the lattice distortion of the matrix,the average stress related to the increasing area energy of domain walls(DWs),and the ave rage stress related to the increasing demagnetization energy induced by the Laves phase.Different from the traditional method of reducing internal stress through annealing to improve the damping capacity,the proper internal stress barriers are necessary to Barkhausen jumps to dissipate energy.Therefore,proper doping to balance resistance and mobility of DWs is a reliable way to improve damping capacity.Meanwhile,for Fe-Al and Fe-Cr based Alloys,the new model also has a good fitting effect.This study provides a theoretical and experimental reference for improving the functional properties of ferromagnetic alloys.展开更多
The carbides of NdDy0.2Fe12-yMoyC0.6 （y = 1.5, 2） crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongl...The carbides of NdDy0.2Fe12-yMoyC0.6 （y = 1.5, 2） crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongly enhanced with the addition of carbon. Upon the carbonation the saturation magnetization Ms is increased by about 20emu/g and the Curie temperature Tc is enhanced by 40-70K. The spin reorientation （SR） temperature decreases from 125 K for NdDy0.2Fe10Mo2 to 55 K for NdDy0.2Fe10MO2C0.6 indicating the change of magnetocrystalline anisotropy in the Nd sublattice. It is found that the intrinsic magnetic properties of the carbides can be improved by further nitrogenation, The composite carbon-nitrogen compounds show a Tc - 560K, M8 - 105 emu/g and Ha （anisotropy field） - 86kOe for NdDy0.2Fe10Mo2Co.6Nz and a Tc- 628K, M8 - 119 emu/g and Ha - 115kOe for NdDy0.2Fe10.5Mo1.5C0.6Nz. These magnetic properties are even better than those of simple nitrides, suggesting that these compounds can be considered as a good candidate for permanent magnet applications.展开更多
Molecular dynamics simulation is employed to study structural evolution during compressing low density amorphous ice from one atmosphere to 2.5 GPa. The calculated results show that high density amorphous ice is forme...Molecular dynamics simulation is employed to study structural evolution during compressing low density amorphous ice from one atmosphere to 2.5 GPa. The calculated results show that high density amorphous ice is formed under intermediate pressure of about 1.0GPa and O-O-O angle ranges from about 83°to 113° and O-H…O is bent from 112° to 160°The very high density amorphous ice is also formed under the pressure larger than 1.4 GPa and interstitial molecules are found in 0.3-0.4 A just beyond the nearest O-O distance. Low angle O-H… O disappears and it is believed that these hydrogen bonds are broken or re-bonded under high pressures.展开更多
基金supported financially by the National Natural Science Foundation of China(No.51971212)the Russian Science Foundation(No.19-72-20080)。
文摘Ferromagnetic high damping(FHA)alloys with a wide temperature range from-150℃to 300℃have unique application value in extreme environments.In the present work,the damping behaviors of Fe-21 Ga-xLa(x=0.12 wt.%,0.24 wt.%,0.47 wt.%,1.18 wt.%,and 2.33 wt.%La)alloys have been studied in detail,and a new phenomenological model has been proposed.With the increase of La content,the Laves phase(LaGa_(2))in the matrix increases gradually,and the resistance opposing the domain movement increases as well.Combined with the results of synchrotron radiation X-ray diffraction,neutron diffraction,and magnetic domain observation,the resistance mainly comes from three parts:the average stress related to the lattice distortion of the matrix,the average stress related to the increasing area energy of domain walls(DWs),and the ave rage stress related to the increasing demagnetization energy induced by the Laves phase.Different from the traditional method of reducing internal stress through annealing to improve the damping capacity,the proper internal stress barriers are necessary to Barkhausen jumps to dissipate energy.Therefore,proper doping to balance resistance and mobility of DWs is a reliable way to improve damping capacity.Meanwhile,for Fe-Al and Fe-Cr based Alloys,the new model also has a good fitting effect.This study provides a theoretical and experimental reference for improving the functional properties of ferromagnetic alloys.
文摘The carbides of NdDy0.2Fe12-yMoyC0.6 （y = 1.5, 2） crystallized in the ThMn12-type structure have been successfully synthesized by arc melting method, followed by a heat treatment. The magnetic properties are strongly enhanced with the addition of carbon. Upon the carbonation the saturation magnetization Ms is increased by about 20emu/g and the Curie temperature Tc is enhanced by 40-70K. The spin reorientation （SR） temperature decreases from 125 K for NdDy0.2Fe10Mo2 to 55 K for NdDy0.2Fe10MO2C0.6 indicating the change of magnetocrystalline anisotropy in the Nd sublattice. It is found that the intrinsic magnetic properties of the carbides can be improved by further nitrogenation, The composite carbon-nitrogen compounds show a Tc - 560K, M8 - 105 emu/g and Ha （anisotropy field） - 86kOe for NdDy0.2Fe10Mo2Co.6Nz and a Tc- 628K, M8 - 119 emu/g and Ha - 115kOe for NdDy0.2Fe10.5Mo1.5C0.6Nz. These magnetic properties are even better than those of simple nitrides, suggesting that these compounds can be considered as a good candidate for permanent magnet applications.
基金Supported by the National Natural Science Foundation of China under Grand No 10474085.
文摘Molecular dynamics simulation is employed to study structural evolution during compressing low density amorphous ice from one atmosphere to 2.5 GPa. The calculated results show that high density amorphous ice is formed under intermediate pressure of about 1.0GPa and O-O-O angle ranges from about 83°to 113° and O-H…O is bent from 112° to 160°The very high density amorphous ice is also formed under the pressure larger than 1.4 GPa and interstitial molecules are found in 0.3-0.4 A just beyond the nearest O-O distance. Low angle O-H… O disappears and it is believed that these hydrogen bonds are broken or re-bonded under high pressures.
