In-situ exploration of deep-sea seabed resources is a valuable research direction.Neutron activation-based in-situ exploration methods for seabed polymetallic nodules or crust resources are theoretically feasible beca...In-situ exploration of deep-sea seabed resources is a valuable research direction.Neutron activation-based in-situ exploration methods for seabed polymetallic nodules or crust resources are theoretically feasible because of the high content and high neutron capture cross-section of manganese in these nodules or crusts.However,to date,only a few relevant studies have been conducted.In this study,a prototype deep-sea in-situ neutron activation spectrometer(DINAS)was designed for resource exploration.Through an analysis of the principles of the spectrometer combined with Monte Carlo simulations of the physical principles and finite element simulations of deep-sea pressure,the structure and fundamental components of the spectrometer were determined.The inner core of the spectrometer comprised three components:a compact neutron generator for neutron production,gamma-ray detectors,and an electronics system.The gamma-ray detector array of the spectrometer consisted of LaBr_(3)and Bi_(4)Ge_(3)O_(12)scintillation crystals coupled with silicon photomultiplier arrays.The electronics system was divided into two modules to implement the SiPM readout and digital signal analysis along the modular design lines.The experimental activation of neutron beamlines at the China Spallation Neutron Source demonstrated the capability of the spectrometer detectors to detect activated gamma-rays and showed that the spectrometer achieved an energy resolution of 2.8%at 847 keV for the LaBr_(3)detector and 6.7%at 2.113 MeV for the BGO detector.The laboratory model experiment tested the functionality of the spectrometer prototype,whereas the Geant4 simulation verified the reliability of the Monte Carlo method.The method and prototype proposed in this study proved feasible for the in-situ detection of polymetallic nodules or crusts in deep-sea environments.展开更多
The history,the major achievements in both methodology and applications,the current trends and future perspectives of neutron activation analysis (NAA) in China are briefly described.
The concentrations of 20 trace elements in several ceramics tiles and ceramic composites used in Egypt were elementally analyzed by neutron activation analysis(NAA) technique. The samples and standard were irradiate...The concentrations of 20 trace elements in several ceramics tiles and ceramic composites used in Egypt were elementally analyzed by neutron activation analysis(NAA) technique. The samples and standard were irradiated with reactor for 4 h(in the Second Research Egyptian Reactor(Et-RR-2)) with thermal neutron flux 5.9×10 13 n/(cm 2·s).The gamma-ray spectra obtained were measured for several times by means of the hyper pure germanium detection system(HPGe). Also a solid state nuclear track detector(SSNTD) CR-39, was used to measure the emanation rate of radon for these samples. The radium concentrations were found to vary from 0.39—3.59 ppm and the emanation rates were found to vary from (0.728—5.688) × 10 -4 kg/(m 2· s).The elemental analysis of the ceramic tiles and ceramic composites have a great importance in assigning the physical properties and in turn the quality of the material.展开更多
Thirty two surface (0—20 cm) soil samples were collected from different locations in Egypt representing non polluted, moderately and highly polluted soils. The aim of this study was to evaluate total Zn content in ...Thirty two surface (0—20 cm) soil samples were collected from different locations in Egypt representing non polluted, moderately and highly polluted soils. The aim of this study was to evaluate total Zn content in alluvial soils of Nile Delta in Egypt by using the delayed neutron activation analysis technique (DNAA), in the irradiation facilities of the first Egyptian research reactor (ET RR 1). The gamma ray spectra were recorded with a hyper pure germanium detection system. The well resolved gamma ray peak at 1116.0 keV was efficiently used for 65 Zn content determination. Zn content in non polluted soil samples ranged between 74.1 and 103.8 ppm with an average of 98.5±5.1 ppm. Zn content in moderately polluted soils ranged between 136.0 and 232.5 ppm with an average of 180.1±32.6 ppm. The highest Zn levels ranging from 240.0 and 733.0 ppm with an average of 410.3±54.4 ppm, were observed in soil samples collected from, either highly polluted agricultural soils exposed to prolonged irrigation with industrial wastewater or surface soil samples from industrial sites.展开更多
A simple computer program is designed for estimation of elemental concentration values in complex samples by neutron activation analysis technique. The program is applied for an Egyptian cement sample which irradiat...A simple computer program is designed for estimation of elemental concentration values in complex samples by neutron activation analysis technique. The program is applied for an Egyptian cement sample which irradiated at the Egyptian Research Reactor 1(ET RR 1). The data obtained is compared with the reported values. The time consumed for such calculations has a remarkable reduction in comparison with the routine work.展开更多
Elemental analysis of iron ore samples and first industrial iron production prepared by the Egyptian Iron and Steel Company of Helwan near Cairo were determined by instrumental neutron activation analysis technique. ...Elemental analysis of iron ore samples and first industrial iron production prepared by the Egyptian Iron and Steel Company of Helwan near Cairo were determined by instrumental neutron activation analysis technique. Five samples from each kind were irradiated for a 48 hours at a thermal neutron flux of 4×10 12 n/(cm 2.s) in the first Egyptian research reactor ET RR 1. Also the Pneumatic irradiation Rabbit system (PIRS) attached to the reactor in Inshass, was used to measure the elements of short life time. The gamma ray spectra were recorded by means of the hyper pure germanium detection system. The concentration percentage values of major, minor and trace elements are presented. The long and short lived isotopes were considered. A comparative study and a discussion on the elemental concentration values are given.展开更多
Instrumental neutron activation analysis （INAA） has turned out to be particularly useful in the analysis of suspended particles. This work describes the INAA characterization of air particulate matter collected in R...Instrumental neutron activation analysis （INAA） has turned out to be particularly useful in the analysis of suspended particles. This work describes the INAA characterization of air particulate matter collected in Rasht city, Iran. The particulate matter was collected in two sampling sites for elemental analysis in the period of winter-summer 2009. Samples have been transferred to the environmental laboratory of radiation applications research school. Neutron exposures were performed in Tehran Research Reactor, and measurements were carried out using HPGe detectors coupled to gamma ray spectrometer. In these filter samples, the elements, AI, As, Ba, Br, Ca, CI, Co, Cr, Cu, Fe, Hg, K, La, Mg, Mn, Na, Sb, Sc, Ti, V and Zn were determined using different irradiation and counting protocols. Results show that mean concentration of most air-pollutants in Rasht are lower than those measured in other cities in Iran （Tehran, Shiraz, Isfahan）. Collected data were also compared with reported results for other cities in the world.展开更多
Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as ...Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. </span><span style="font-family:Verdana;">However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end,</span><span style="font-family:Verdana;"> based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.展开更多
Tobacco addiction has been mentioned as a leading cause of preventable illnesses and premature disability. Smoking is the main cause of lung cancer and one of the factors that most contribute to the occurrence of hear...Tobacco addiction has been mentioned as a leading cause of preventable illnesses and premature disability. Smoking is the main cause of lung cancer and one of the factors that most contribute to the occurrence of heart diseases, among others. The herbaceous species Nicotiana tabacum is a plant of the solanaceae family used for tobacco production. Some authors have conducted research about heavy metals and the toxicity of tobacco. It is, frequently, found in low concentrations in the ground, and superficial and underground waters, even though they do not have environmental anthropogenic contributions. However, with the increase of industrial activities and mining together with the agrochemical use of contaminated organic and inorganic fertilizers, an alteration of the geochemical cycle occurs. As a consequence, the natural flow of these materials increases and is released into the biosphere, where they are often accumulated in the superior layer of the ground, accessible to the roots of the plants. During planting and plant development, fertilizers and insecticides, including organochlorines and organophosphates, are used;consequently, the smoke from cigarette smoking presents various toxic substances, such as bromine (Br), manganese (Mn) and antimony (Sb), elements studied in this work. The procedures for the preparation of the samples were carried out in our laboratories and submitted to irradiation with thermal neutrons at Nuclear and Energy Research Institute (IPEN/CNEN-SP), in the Atomic Energy Institute IEA-R1 research reactor. The irradiated material was, then, analyzed by gamma spectrometry, using a high purity germanium detector (HPGe).展开更多
Samples of two crop seeds (corn and sesame) grown on different contaminated soil sources were collected and prepared for neutron activation analysis. Soil contamination sources were organic waste compost applied to s...Samples of two crop seeds (corn and sesame) grown on different contaminated soil sources were collected and prepared for neutron activation analysis. Soil contamination sources were organic waste compost applied to soil amendments namely, sewage sludge(Bs) and municipal solid waste (MSW) at 4%, 6% and 8% respectively. The non destructive NAA technique was used to determine some trace elements accumulation in plant seeds. Results revealed that increasing rate of tested organic waste resulted in dramatic increase in tested heavy metals levels in seeds(i.e., Fe, Zn, Co, Cr, Sc and Hg). Sesame seeds showed higher affinity to accumulate trace elements than corn grains in most tested elements. Moreover, MSW addition enhanced the accumulation of tested metals in seeds more than Bs compost.展开更多
The ^232Th（n,γ）^233Th neutron capture reaction cross sections were measured at average neutron energies of 14.1 MeV and 14.8 MeV using the activation method.The neutron flux was determined using the monitor reactio...The ^232Th（n,γ）^233Th neutron capture reaction cross sections were measured at average neutron energies of 14.1 MeV and 14.8 MeV using the activation method.The neutron flux was determined using the monitor reaction^27Al（n,α）^24Na.The induced gamma-ray activities were measured using a low background gamma ray spectrometer equipped with a high resolution HPGe detector.The experimentally determined cross sections were compared with the data in the literature,and the evaluated data of ENDF/B-Ⅶ.1,JENDL-4.0u＋,and CENDL-3.1.The excitation functions of the ^232Th（n,γ）^233Th reaction were also calculated theoretically using the TALYS1.6 computer code.展开更多
Generalized the use of neutron activation analysis(NAA)in the investigations of unique processes occurring in early stages of formations and evolution of bodies in solar system Out of them the formation of chondrules,...Generalized the use of neutron activation analysis(NAA)in the investigations of unique processes occurring in early stages of formations and evolution of bodies in solar system Out of them the formation of chondrules,emergence of ultra refractory inclusions in carbonaceous chondrites,formation of metallic and silicate phases of iron and stone meteorites,and formation of iron meteorites of different chemical groups Changes in regolite and lunar rock contents,differentiation in the upper mantle matter, identification of earthly meteoritic craters,transportation of cosmic(meteoritic)materials on to the Earth, investigations of unique events like Tunguska fall of the year 1908 and also ore formation studies and processes taking place on geochemical barrier type river-sea,ocean-atmosphere and so on Prospectives of NAA are pointed out展开更多
Purpose Gamma spectrum of a cement sample is not straightforward to analyze as a result of peak overlapping produced by Compton effect of gamma rays radiated from activated elements in the neutron activation process a...Purpose Gamma spectrum of a cement sample is not straightforward to analyze as a result of peak overlapping produced by Compton effect of gamma rays radiated from activated elements in the neutron activation process and also because of the change into the neutron energy spectrum in the target sample during activation.Methods Artificial neural network(ANN)is an excellent solution for complex and nonlinear systems.Consequently,the use of ANN for quantitative analysis of major cement elements including Ca,Si,Al,and Fe would be very advantageous.Iranian inertial electrostatic confinement fusion device is a fast,monoenergetic and steady neutron generator.It was simulated as a high-energy neutron source for performing neutron activation analysis.In the present study,a library of 29 members of delayed gamma-ray spectra of knowing cement samples were generated via MCNPX version 2.7.Specific photo-peaks related to Ca,Si,Al and Fe obtained from these spectra were used as inputs for ANN(21 of them for training and 8 for testing).Then,using MLP architecture,an ANN model has been presented to model the system to predict the percentages of the elements in cement.The ANN model is optimized to have only a hidden layer with five neurons.Results The comparison between modeling data and results of proposed MLP network shows that there is a good consistency between them.The MAE of training set for Ca,Si and Fe outputs were 0.0351,0.0656 and 0.0660,respectively,and the MAE of testing set for mentioned outputs were 0.0997,0.3046 and 0.8699,respectively.Conclusion Overall,it can be concluded that the defined dispensable errors show that this modeling is a good one as a prediction tool for the mentioned purpose.展开更多
Burnup measurement is crucial for the management and disposal of spent fuel.The conventional approach indirectly estimates burnup by examining the fission product or actinide content.Compared to the first two methods,...Burnup measurement is crucial for the management and disposal of spent fuel.The conventional approach indirectly estimates burnup by examining the fission product or actinide content.Compared to the first two methods,the active neutron method exhibits a lower dependence on the irradiation history and initial enrichment degree of the spent fuel.In addition,it can be used to directly determine the content of fissile nuclides in spent fuel.This study proposed the design of a burnup measurement equipment specifically crafted for plate segments by utilizing a compact D-D neutron generator.The equipment initiates the fission of fissile nuclides within the spent fuel plate segment through thermal neutrons provided by the moderators.Subsequently,the burnup is determined by analyzing the transmitted thermal neutrons and counting the fission fast neutrons.The Monte Carlo program Geant4 was used to simulate the relationship between spent fuel plate segment assembly burnup and the detector count of 10 MW material test reactor designed by the International Atomic Energy Agency.Consequently,the feasibility of the method and rationality of the detector design were verified.展开更多
The identification of ore grades is a critical step in mineral resource exploration and mining.Prompt gamma neutron activation analysis(PGNAA)technology employs gamma rays generated by the nuclear reactions between ne...The identification of ore grades is a critical step in mineral resource exploration and mining.Prompt gamma neutron activation analysis(PGNAA)technology employs gamma rays generated by the nuclear reactions between neutrons and samples to achieve the qualitative and quantitative detection of sample components.In this study,we present a novel method for identifying copper grade by combining the vision transformer(ViT)model with the PGNAA technique.First,a Monte Carlo simulation is employed to determine the optimal sizes of the neutron moderator,thermal neutron absorption material,and dimensions of the device.Subsequently,based on the parameters obtained through optimization,a PGNAA copper ore measurement model is established.The gamma spectrum of the copper ore is analyzed using the ViT model.The ViT model is optimized for hyperparameters using a grid search.To ensure the reliability of the identification results,the test results are obtained through five repeated tenfold cross-validations.Long short-term memory and convolutional neural network models are compared with the ViT method.These results indicate that the ViT method is efficient in identifying copper ore grades with average accuracy,precision,recall,F_(1)score,and F_(1)(-)score values of 0.9795,0.9637,0.9614,0.9625,and 0.9942,respectively.When identifying associated minerals,the ViT model can identify Pb,Zn,Fe,and Co minerals with identification accuracies of 0.9215,0.9396,0.9966,and 0.8311,respectively.展开更多
The paper introduces the research progress in an emergency decision support system for marine pollution （EDSS） in China seas and elaborates on the possible role of the Neutron Activation Analysis （NAA） method ther...The paper introduces the research progress in an emergency decision support system for marine pollution （EDSS） in China seas and elaborates on the possible role of the Neutron Activation Analysis （NAA） method therein. To deal with the increasingly grave situation of offshore pollution, the EDSS for China seas has been researching and developing. Based on the prediction and analysis of the ocean three-dimensional current field, this system makes an inference on the possible path of diffusion and influencing area of marine pollutants and possible location of pollution source, and in combination with the environmentally sensitive information related to the technical integration of GIS, it puts forward the decision, making support for minimizing the hazard caused by pollutants. This system has been operationalized and running for many years on the Bohai and Huanghai seas＇ Marine Pollutants Prediction and Early-Warning, and it has achieved successful experience for many times in the emergencies of China＇s coastal pollution accidents. At present, the environmental guarantee system directed against heavy metals and radioactive pollutants is in the experimental stage. As the NAA method is especially applicable to the detection of part of heavy metals and radioactive substances, it is of very important practical value for the new system to realize the monitoring, prediction and early-warning of ocean heavy metals and radioactive pollutants.展开更多
Sinter is the main raw material in the blast furnace iron-making process,and basicity(CaO/SiO2)is an important quality index of sinter.Prompt gamma neutron activation analysis is a multi-elemental online detection tec...Sinter is the main raw material in the blast furnace iron-making process,and basicity(CaO/SiO2)is an important quality index of sinter.Prompt gamma neutron activation analysis is a multi-elemental online detection technology that has been successfully applied in cement,coal,etc.Compared with cement as a raw material,sinter exhibits poor moderation ability and a large neutron absorption cross section.Therefore,cement detection devices are not suitable for sinter mixture detection.In this study,a prompt gamma neutron activation analysis equipment used for testing cement was re-optimized to render it suitable for measuring a sinter mixture.Using Monte Carlo simulation,the comprehensive detection efficiency of the detection device improved by 71.52%.Because of the gamma-ray self-shielding effect of the sinter mixture,the detection errors of CaO and SiO2 are significant.By applying the gamma-ray self-shielding correction algorithm,the detection accuracies improved,and their linear correlation coefficients R2 exceeded 0.99.Furthermore,by applying an improved analyzer to a sintering plant,the first-grade product rate of the factory increased by 4.64%.展开更多
The growth of Arthrospira platensis and physiological changes in biomass under the effects of six rare earth elements Dy,Sm,Tb,La,Nd and Yb were evaluated.Elements were tested by three concentrations of 10,20 and 30 m...The growth of Arthrospira platensis and physiological changes in biomass under the effects of six rare earth elements Dy,Sm,Tb,La,Nd and Yb were evaluated.Elements were tested by three concentrations of 10,20 and 30 mg/L.According to neutron activation analysis data A.platensis’s accumulation capacity toward studied elements changes in the following order of La>Dy>Nd>Sm>Yb>Tb.The results show that Dy and La ions stimulate biomass growth and Yb ions inhibit it,while Sm,Tb and Nd ions do not affect biomass accumulation.The contents of proteins and chlorophyll a are not affected by the presence of rare earth elements in the cultivation medium.Studied elements affect to different extents carbohydrates,phycobilins,β-carotene,lipids and MDA contents in spirulina biomass.Changes in the antioxidant activity under applied metal loads reveal a moderate stress in exposed A.platensis.Cyanobacterium A.platensis can be successfully used for bioremediation of natural water contaminated with REEs as well as REEs recovery from low polluted industrial effluents.展开更多
A combination of NAA and micro-PIXE was used to study concentrations and distributions of platinum group elements (PGE) in ores from Xinjie Cu-Pt deposit.The NAA results of the bulk indicate that the ores belong to th...A combination of NAA and micro-PIXE was used to study concentrations and distributions of platinum group elements (PGE) in ores from Xinjie Cu-Pt deposit.The NAA results of the bulk indicate that the ores belong to the enriched Pt-Pd type.The element concentration maps of scanning micro-PIXE for the ores show that the occurence form of Pt is independent arsenide minerals. No PGE were detected in chalcopyrite of Xinjie Cu-Pt deposit. These information are economically beneficial to the mineral smelting process.展开更多
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA22020601)the National Natural Science Foundation of China(No.12075237)。
文摘In-situ exploration of deep-sea seabed resources is a valuable research direction.Neutron activation-based in-situ exploration methods for seabed polymetallic nodules or crust resources are theoretically feasible because of the high content and high neutron capture cross-section of manganese in these nodules or crusts.However,to date,only a few relevant studies have been conducted.In this study,a prototype deep-sea in-situ neutron activation spectrometer(DINAS)was designed for resource exploration.Through an analysis of the principles of the spectrometer combined with Monte Carlo simulations of the physical principles and finite element simulations of deep-sea pressure,the structure and fundamental components of the spectrometer were determined.The inner core of the spectrometer comprised three components:a compact neutron generator for neutron production,gamma-ray detectors,and an electronics system.The gamma-ray detector array of the spectrometer consisted of LaBr_(3)and Bi_(4)Ge_(3)O_(12)scintillation crystals coupled with silicon photomultiplier arrays.The electronics system was divided into two modules to implement the SiPM readout and digital signal analysis along the modular design lines.The experimental activation of neutron beamlines at the China Spallation Neutron Source demonstrated the capability of the spectrometer detectors to detect activated gamma-rays and showed that the spectrometer achieved an energy resolution of 2.8%at 847 keV for the LaBr_(3)detector and 6.7%at 2.113 MeV for the BGO detector.The laboratory model experiment tested the functionality of the spectrometer prototype,whereas the Geant4 simulation verified the reliability of the Monte Carlo method.The method and prototype proposed in this study proved feasible for the in-situ detection of polymetallic nodules or crusts in deep-sea environments.
文摘The history,the major achievements in both methodology and applications,the current trends and future perspectives of neutron activation analysis (NAA) in China are briefly described.
文摘The concentrations of 20 trace elements in several ceramics tiles and ceramic composites used in Egypt were elementally analyzed by neutron activation analysis(NAA) technique. The samples and standard were irradiated with reactor for 4 h(in the Second Research Egyptian Reactor(Et-RR-2)) with thermal neutron flux 5.9×10 13 n/(cm 2·s).The gamma-ray spectra obtained were measured for several times by means of the hyper pure germanium detection system(HPGe). Also a solid state nuclear track detector(SSNTD) CR-39, was used to measure the emanation rate of radon for these samples. The radium concentrations were found to vary from 0.39—3.59 ppm and the emanation rates were found to vary from (0.728—5.688) × 10 -4 kg/(m 2· s).The elemental analysis of the ceramic tiles and ceramic composites have a great importance in assigning the physical properties and in turn the quality of the material.
文摘Thirty two surface (0—20 cm) soil samples were collected from different locations in Egypt representing non polluted, moderately and highly polluted soils. The aim of this study was to evaluate total Zn content in alluvial soils of Nile Delta in Egypt by using the delayed neutron activation analysis technique (DNAA), in the irradiation facilities of the first Egyptian research reactor (ET RR 1). The gamma ray spectra were recorded with a hyper pure germanium detection system. The well resolved gamma ray peak at 1116.0 keV was efficiently used for 65 Zn content determination. Zn content in non polluted soil samples ranged between 74.1 and 103.8 ppm with an average of 98.5±5.1 ppm. Zn content in moderately polluted soils ranged between 136.0 and 232.5 ppm with an average of 180.1±32.6 ppm. The highest Zn levels ranging from 240.0 and 733.0 ppm with an average of 410.3±54.4 ppm, were observed in soil samples collected from, either highly polluted agricultural soils exposed to prolonged irrigation with industrial wastewater or surface soil samples from industrial sites.
文摘A simple computer program is designed for estimation of elemental concentration values in complex samples by neutron activation analysis technique. The program is applied for an Egyptian cement sample which irradiated at the Egyptian Research Reactor 1(ET RR 1). The data obtained is compared with the reported values. The time consumed for such calculations has a remarkable reduction in comparison with the routine work.
文摘Elemental analysis of iron ore samples and first industrial iron production prepared by the Egyptian Iron and Steel Company of Helwan near Cairo were determined by instrumental neutron activation analysis technique. Five samples from each kind were irradiated for a 48 hours at a thermal neutron flux of 4×10 12 n/(cm 2.s) in the first Egyptian research reactor ET RR 1. Also the Pneumatic irradiation Rabbit system (PIRS) attached to the reactor in Inshass, was used to measure the elements of short life time. The gamma ray spectra were recorded by means of the hyper pure germanium detection system. The concentration percentage values of major, minor and trace elements are presented. The long and short lived isotopes were considered. A comparative study and a discussion on the elemental concentration values are given.
文摘Instrumental neutron activation analysis （INAA） has turned out to be particularly useful in the analysis of suspended particles. This work describes the INAA characterization of air particulate matter collected in Rasht city, Iran. The particulate matter was collected in two sampling sites for elemental analysis in the period of winter-summer 2009. Samples have been transferred to the environmental laboratory of radiation applications research school. Neutron exposures were performed in Tehran Research Reactor, and measurements were carried out using HPGe detectors coupled to gamma ray spectrometer. In these filter samples, the elements, AI, As, Ba, Br, Ca, CI, Co, Cr, Cu, Fe, Hg, K, La, Mg, Mn, Na, Sb, Sc, Ti, V and Zn were determined using different irradiation and counting protocols. Results show that mean concentration of most air-pollutants in Rasht are lower than those measured in other cities in Iran （Tehran, Shiraz, Isfahan）. Collected data were also compared with reported results for other cities in the world.
文摘Prompt gamma neutron activation analysis (PGNAA) is a non-destructive online measurement nuclear analysis method. With its unique advantages, it has been widely used in online analysis of industrial materials such as coal, cement, and minerals in recent years. </span><span style="font-family:Verdana;">However, there are many kinds of literature on PGNAA in the field of industrial materials detection, and there are still a few concluding articles. To this end,</span><span style="font-family:Verdana;"> based on the principle of PGNAA online analysis, the status quo and development of the real-time online detection of industrial material components in the field are reviewed and discussed by consulting a large number of domestic and foreign PGNAA related literature and data, to facilitate the reference of relevant scientific researchers.
文摘Tobacco addiction has been mentioned as a leading cause of preventable illnesses and premature disability. Smoking is the main cause of lung cancer and one of the factors that most contribute to the occurrence of heart diseases, among others. The herbaceous species Nicotiana tabacum is a plant of the solanaceae family used for tobacco production. Some authors have conducted research about heavy metals and the toxicity of tobacco. It is, frequently, found in low concentrations in the ground, and superficial and underground waters, even though they do not have environmental anthropogenic contributions. However, with the increase of industrial activities and mining together with the agrochemical use of contaminated organic and inorganic fertilizers, an alteration of the geochemical cycle occurs. As a consequence, the natural flow of these materials increases and is released into the biosphere, where they are often accumulated in the superior layer of the ground, accessible to the roots of the plants. During planting and plant development, fertilizers and insecticides, including organochlorines and organophosphates, are used;consequently, the smoke from cigarette smoking presents various toxic substances, such as bromine (Br), manganese (Mn) and antimony (Sb), elements studied in this work. The procedures for the preparation of the samples were carried out in our laboratories and submitted to irradiation with thermal neutrons at Nuclear and Energy Research Institute (IPEN/CNEN-SP), in the Atomic Energy Institute IEA-R1 research reactor. The irradiated material was, then, analyzed by gamma spectrometry, using a high purity germanium detector (HPGe).
文摘Samples of two crop seeds (corn and sesame) grown on different contaminated soil sources were collected and prepared for neutron activation analysis. Soil contamination sources were organic waste compost applied to soil amendments namely, sewage sludge(Bs) and municipal solid waste (MSW) at 4%, 6% and 8% respectively. The non destructive NAA technique was used to determine some trace elements accumulation in plant seeds. Results revealed that increasing rate of tested organic waste resulted in dramatic increase in tested heavy metals levels in seeds(i.e., Fe, Zn, Co, Cr, Sc and Hg). Sesame seeds showed higher affinity to accumulate trace elements than corn grains in most tested elements. Moreover, MSW addition enhanced the accumulation of tested metals in seeds more than Bs compost.
基金Supported by Chinese TMSR Strategic Pioneer Science and Technology Project-The Th-U Fuel Physics Term(XDA02010100)National Natural Science Foundation of China(11205076,21327801)
文摘The ^232Th（n,γ）^233Th neutron capture reaction cross sections were measured at average neutron energies of 14.1 MeV and 14.8 MeV using the activation method.The neutron flux was determined using the monitor reaction^27Al（n,α）^24Na.The induced gamma-ray activities were measured using a low background gamma ray spectrometer equipped with a high resolution HPGe detector.The experimentally determined cross sections were compared with the data in the literature,and the evaluated data of ENDF/B-Ⅶ.1,JENDL-4.0u＋,and CENDL-3.1.The excitation functions of the ^232Th（n,γ）^233Th reaction were also calculated theoretically using the TALYS1.6 computer code.
文摘Generalized the use of neutron activation analysis(NAA)in the investigations of unique processes occurring in early stages of formations and evolution of bodies in solar system Out of them the formation of chondrules,emergence of ultra refractory inclusions in carbonaceous chondrites,formation of metallic and silicate phases of iron and stone meteorites,and formation of iron meteorites of different chemical groups Changes in regolite and lunar rock contents,differentiation in the upper mantle matter, identification of earthly meteoritic craters,transportation of cosmic(meteoritic)materials on to the Earth, investigations of unique events like Tunguska fall of the year 1908 and also ore formation studies and processes taking place on geochemical barrier type river-sea,ocean-atmosphere and so on Prospectives of NAA are pointed out
文摘Purpose Gamma spectrum of a cement sample is not straightforward to analyze as a result of peak overlapping produced by Compton effect of gamma rays radiated from activated elements in the neutron activation process and also because of the change into the neutron energy spectrum in the target sample during activation.Methods Artificial neural network(ANN)is an excellent solution for complex and nonlinear systems.Consequently,the use of ANN for quantitative analysis of major cement elements including Ca,Si,Al,and Fe would be very advantageous.Iranian inertial electrostatic confinement fusion device is a fast,monoenergetic and steady neutron generator.It was simulated as a high-energy neutron source for performing neutron activation analysis.In the present study,a library of 29 members of delayed gamma-ray spectra of knowing cement samples were generated via MCNPX version 2.7.Specific photo-peaks related to Ca,Si,Al and Fe obtained from these spectra were used as inputs for ANN(21 of them for training and 8 for testing).Then,using MLP architecture,an ANN model has been presented to model the system to predict the percentages of the elements in cement.The ANN model is optimized to have only a hidden layer with five neurons.Results The comparison between modeling data and results of proposed MLP network shows that there is a good consistency between them.The MAE of training set for Ca,Si and Fe outputs were 0.0351,0.0656 and 0.0660,respectively,and the MAE of testing set for mentioned outputs were 0.0997,0.3046 and 0.8699,respectively.Conclusion Overall,it can be concluded that the defined dispensable errors show that this modeling is a good one as a prediction tool for the mentioned purpose.
基金supported by the National Natural Science Foundation of China(No.12075105)the Major Science and Technology Projects of Gansu Province(No.22ZD6GB020)+1 种基金the NSFC-Nuclear Technology Innovation Joint Fund(No.U2167203)the Fundamental Research Funds for the Central Universities(lzujbky-2023-stlt01,lzujbky-2024-jdzx10)。
文摘Burnup measurement is crucial for the management and disposal of spent fuel.The conventional approach indirectly estimates burnup by examining the fission product or actinide content.Compared to the first two methods,the active neutron method exhibits a lower dependence on the irradiation history and initial enrichment degree of the spent fuel.In addition,it can be used to directly determine the content of fissile nuclides in spent fuel.This study proposed the design of a burnup measurement equipment specifically crafted for plate segments by utilizing a compact D-D neutron generator.The equipment initiates the fission of fissile nuclides within the spent fuel plate segment through thermal neutrons provided by the moderators.Subsequently,the burnup is determined by analyzing the transmitted thermal neutrons and counting the fission fast neutrons.The Monte Carlo program Geant4 was used to simulate the relationship between spent fuel plate segment assembly burnup and the detector count of 10 MW material test reactor designed by the International Atomic Energy Agency.Consequently,the feasibility of the method and rationality of the detector design were verified.
基金supported by the National Natural Science Foundation of China(Nos.U2BB2077 and 42374226)the Natural Science Foundation of Jiangxi Province(20232BAB201043 and 20232BCJ23006)the Nuclear energy development project of the National Defense Science and Industry Bureau(Nos.20201192-01,20201192-03).
文摘The identification of ore grades is a critical step in mineral resource exploration and mining.Prompt gamma neutron activation analysis(PGNAA)technology employs gamma rays generated by the nuclear reactions between neutrons and samples to achieve the qualitative and quantitative detection of sample components.In this study,we present a novel method for identifying copper grade by combining the vision transformer(ViT)model with the PGNAA technique.First,a Monte Carlo simulation is employed to determine the optimal sizes of the neutron moderator,thermal neutron absorption material,and dimensions of the device.Subsequently,based on the parameters obtained through optimization,a PGNAA copper ore measurement model is established.The gamma spectrum of the copper ore is analyzed using the ViT model.The ViT model is optimized for hyperparameters using a grid search.To ensure the reliability of the identification results,the test results are obtained through five repeated tenfold cross-validations.Long short-term memory and convolutional neural network models are compared with the ViT method.These results indicate that the ViT method is efficient in identifying copper ore grades with average accuracy,precision,recall,F_(1)score,and F_(1)(-)score values of 0.9795,0.9637,0.9614,0.9625,and 0.9942,respectively.When identifying associated minerals,the ViT model can identify Pb,Zn,Fe,and Co minerals with identification accuracies of 0.9215,0.9396,0.9966,and 0.8311,respectively.
基金supported by the National Natural Science Foundation of China(41206013,41376014,41430963)the Public Science and Technology Research Funds Projects of Ocean (201205018)+5 种基金Key Marine Science Foundation of the State Oceanic Administration of China for Young Scholar(2013203,2012202,2012223)National Sci-Tech Support Plan(2014BAB12B02)Tianjin Sci-Tech Support Plan(14ZCZDSF00012)POL Visiting Fellowship Program (Song Jun)China Scholarship Council ([2008]3019[2012]3013)
文摘The paper introduces the research progress in an emergency decision support system for marine pollution （EDSS） in China seas and elaborates on the possible role of the Neutron Activation Analysis （NAA） method therein. To deal with the increasingly grave situation of offshore pollution, the EDSS for China seas has been researching and developing. Based on the prediction and analysis of the ocean three-dimensional current field, this system makes an inference on the possible path of diffusion and influencing area of marine pollutants and possible location of pollution source, and in combination with the environmentally sensitive information related to the technical integration of GIS, it puts forward the decision, making support for minimizing the hazard caused by pollutants. This system has been operationalized and running for many years on the Bohai and Huanghai seas＇ Marine Pollutants Prediction and Early-Warning, and it has achieved successful experience for many times in the emergencies of China＇s coastal pollution accidents. At present, the environmental guarantee system directed against heavy metals and radioactive pollutants is in the experimental stage. As the NAA method is especially applicable to the detection of part of heavy metals and radioactive substances, it is of very important practical value for the new system to realize the monitoring, prediction and early-warning of ocean heavy metals and radioactive pollutants.
基金This work was supported by the National Key Scientific Instrument and Equipment Development Projects(No.2012YQ240121)Liaoning Science and Technology Project(No.2017220010)the Major Special Science and Technology Plan of Liaoning Province in 2020(No.2020JH1/10100009).
文摘Sinter is the main raw material in the blast furnace iron-making process,and basicity(CaO/SiO2)is an important quality index of sinter.Prompt gamma neutron activation analysis is a multi-elemental online detection technology that has been successfully applied in cement,coal,etc.Compared with cement as a raw material,sinter exhibits poor moderation ability and a large neutron absorption cross section.Therefore,cement detection devices are not suitable for sinter mixture detection.In this study,a prompt gamma neutron activation analysis equipment used for testing cement was re-optimized to render it suitable for measuring a sinter mixture.Using Monte Carlo simulation,the comprehensive detection efficiency of the detection device improved by 71.52%.Because of the gamma-ray self-shielding effect of the sinter mixture,the detection errors of CaO and SiO2 are significant.By applying the gamma-ray self-shielding correction algorithm,the detection accuracies improved,and their linear correlation coefficients R2 exceeded 0.99.Furthermore,by applying an improved analyzer to a sintering plant,the first-grade product rate of the factory increased by 4.64%.
文摘The growth of Arthrospira platensis and physiological changes in biomass under the effects of six rare earth elements Dy,Sm,Tb,La,Nd and Yb were evaluated.Elements were tested by three concentrations of 10,20 and 30 mg/L.According to neutron activation analysis data A.platensis’s accumulation capacity toward studied elements changes in the following order of La>Dy>Nd>Sm>Yb>Tb.The results show that Dy and La ions stimulate biomass growth and Yb ions inhibit it,while Sm,Tb and Nd ions do not affect biomass accumulation.The contents of proteins and chlorophyll a are not affected by the presence of rare earth elements in the cultivation medium.Studied elements affect to different extents carbohydrates,phycobilins,β-carotene,lipids and MDA contents in spirulina biomass.Changes in the antioxidant activity under applied metal loads reveal a moderate stress in exposed A.platensis.Cyanobacterium A.platensis can be successfully used for bioremediation of natural water contaminated with REEs as well as REEs recovery from low polluted industrial effluents.
文摘A combination of NAA and micro-PIXE was used to study concentrations and distributions of platinum group elements (PGE) in ores from Xinjie Cu-Pt deposit.The NAA results of the bulk indicate that the ores belong to the enriched Pt-Pd type.The element concentration maps of scanning micro-PIXE for the ores show that the occurence form of Pt is independent arsenide minerals. No PGE were detected in chalcopyrite of Xinjie Cu-Pt deposit. These information are economically beneficial to the mineral smelting process.
