Two near single-phase NiTiNb alloys--NisoTi4sNb2 and Ni49.5Ti46.5Nb4-are prepared and studied by means of scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, differential scanning calorimetry...Two near single-phase NiTiNb alloys--NisoTi4sNb2 and Ni49.5Ti46.5Nb4-are prepared and studied by means of scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, differential scanning calorimetry （DSC） and tensile tests in order to unearth the effects of Nb-atom solid solution in NiTi phase on the yield strength induced by self-accommodation of martensite variants. The results show that the yield strength of near single-phase NiTiNb alloys varies inversely with the amount of Nb-atoms solid-dissolved in NiTi phase. From the results out of the prior and current studies, it can be surmised that the effects of Nb content on the yield strength of NiTiNb alloys in martensite state depend on the coaction. Nb solid solution weakening mechanism and β-Nb phase composite strengthening mechanism. This inference might be a satisfactory explanation to the fact that the yield strength of （NiTi）50-0.5xNbx alloys in martensite state begins with decline and then rises when the Nb content increases.展开更多
Vacuum brazing was successfully used to join Ti-22Al-25Nb alloy using Ti-Ni-Nb brazing alloys prepared by arc-melting. The influence of Nb content in the Ti-Ni-Nb brazing alloys on the interfacial microstructure and m...Vacuum brazing was successfully used to join Ti-22Al-25Nb alloy using Ti-Ni-Nb brazing alloys prepared by arc-melting. The influence of Nb content in the Ti-Ni-Nb brazing alloys on the interfacial microstructure and mechanical properties of the brazed joints was investigated. The results showed that the interfacial microstructure of brazed joint consisted of B2, O, ？3, and Ti2 Ni phase, while the width of brazing seams varied at different Nb contents. The room temperature shear strength reached359 MPa when the joints were brazed with eutectic Ti40Ni40Nb20 alloy at 1180？C for 20 min, and it was321, 308 and 256 MPa at 500, 650 and 800？C, respectively. Cracks primarily initiated and propagated in ？3compounds, and partially traversed B2＋O region. Moreover, the fracture surface displayed typical ductile dimples when cracks propagated through B2＋O region, which was favorable for the mechanical properties of the brazed joint.展开更多
The influence of Nb content on the microstructure and cryogenic mechanical properties of a 7%Ni steel was investigated within the Nb content range from 0 to 0.05%. The microstructure was characterized by optical micro...The influence of Nb content on the microstructure and cryogenic mechanical properties of a 7%Ni steel was investigated within the Nb content range from 0 to 0.05%. The microstructure was characterized by optical microscope, scanning electron microscope, transmission electron microscopy and X-ray diffraction, and the low-temperature mechanical property tests were conducted. The Nb addition can effectively refine the prior austenite grains and microstructure of the steel. Fine niobium precipitates with a diameter of about 10-50 nm were observed. They tend to be spherical and locate mainly in the vicinity of grain boundaries. Although there are considerable amounts of reversed austenite forming at grain boundaries in the specimen containing the highest Nb content, no Nb element was detected in such reversed austenite, which implies that Nb element did not affect the formation of the reversed austenite directly. Mechanical test results suggest that the strength of the 7%Ni steel is not simply in relation to the prior austenite grain size, but also depends on the amount of reversed austenite. On the other hand, the grain refinement, enhanced with increasing Nb content, has a good effect on cryogenic toughness.展开更多
The recrystallization and texture evolution of cold-rolled FeCrAl-0.65 Nb and FeCrAl-1.2 Nb alloys thin-wall tubes annealed at 600−900℃ for 1−600 min were investigated.The microstructures were characterized by electr...The recrystallization and texture evolution of cold-rolled FeCrAl-0.65 Nb and FeCrAl-1.2 Nb alloys thin-wall tubes annealed at 600−900℃ for 1−600 min were investigated.The microstructures were characterized by electron back scattering diffraction,electron probe micro-analyzer and transmission electron microscopy.The Vickers hardness and room temperature tensile properties were tested.The results showed that the hardness of fully recrystallized FeCrAl-1.2 Nb alloy was higher and more likely to recrystallize than FeCrAl-0.65 Nb alloy.The weak texture strength of annealing sample was obtained and the proportion of<111>//ND texture increased.The fine Laves phase distributed uniformly in FeCrAl-0.65 Nb alloy had good pinning effect and inhibited recrystallization.Higher Nb content had little effects on tensile properties of thin-wall tube,and induced the formation of larger Laves phase.There was less fine Laves phase pinning in the large area adjacent to the blocky Laves phase,which resulted in easy recrystallization in FeCrAl-1.2 Nb alloy.展开更多
The hot deformation behavior of S460 ML steel with different Nb contents was investigated by single-pass compression experiment on the Gleeble-1500 thermo-machine simulator at deformation temperatures ranging from 900...The hot deformation behavior of S460 ML steel with different Nb contents was investigated by single-pass compression experiment on the Gleeble-1500 thermo-machine simulator at deformation temperatures ranging from 900 to 1200 ℃ and strain rates from 0.1 to 5.0 s^(-1). The critical strain of dynamic recrystallization(DRC) under different conditions was determined by using working hardening rate-strain curves. The relationship between critical strain and peak strain of DRC was discussed. By means of regression analysis method, the hot deformation activation energy of steels and the mathematical model for predicting DRC critical strain were calculated and established, respectively. The results showed that DRC occurred during hot deformation. As the deformation temperature increased and strain rate decreased, the critical strain of DRC decreased. The critical strain(εc) showed linear relationship with peak strain(εp). As Nb content increased,the needed deformation temperature for occurring DRC increased, while the needed strain rate for it decreased. The activation energy for hot deformation of S460 ML steel increased with increasing Nb content.展开更多
The influence mechanism of trace Nb on the corrosion resistance of surface corrosion products of high-strength anti-seismic rebar in the simulated marine environment was studied by combining first-principles calculati...The influence mechanism of trace Nb on the corrosion resistance of surface corrosion products of high-strength anti-seismic rebar in the simulated marine environment was studied by combining first-principles calculations with corrosion mass loss method,surface analysis,cross-sectional analysis,quantitative analysis,and electrochemical test.The results demonstrated that the addition of trace Nb effectively improved the compactness and stability of surface corrosion layer of rebar,and the corrosion resistance of corrosion layer increased with the increase in Nb content.The beneficial effect of Nb content on the corrosion layer summarized two important key points.Firstly,the addition of Nb was beneficial to promoting the improvement in the structural stability of α-FeOOH,and α-FeOOH structure of solid solution Nb atoms was beneficial to strengthening the fixation of Cl atoms,thus increasing α/(β+γ)ratio,total impedance value,and corrosion potential.Secondly,the formation of Nb oxides can not only repair the corrosion layer,but also play a role in the fixation Cl atoms,resulting in the improvement in corrosion resistance of corrosion layer.展开更多
Effect of Nb contents on microstructure and magnetic properties of FeCoNbB films has been studied. X-ray diffraction （XRD） analysis reveals that Nb plays a role in refining grain and in facilitating formation of amo...Effect of Nb contents on microstructure and magnetic properties of FeCoNbB films has been studied. X-ray diffraction （XRD） analysis reveals that Nb plays a role in refining grain and in facilitating formation of amorphous structure. When Nb content is more than 8 at%, the films transform from crystalline to amorphous structure, accompanied by variations in magnetic properties. An unusual out-of-plane anisotropy component is consequently observed. It can be suggested that the anisotropy induced by increasing Nb contents be attributed to stress-related magnetoelastic anisotropy. The undesirable anisotropy is greatly reduced by thermal annealing, reducing film thicknesses or applying an external magnetic field together with Si addition.展开更多
基金National Natural Science Foundation of China （50971009） Science Fund for Creative Research Groups （50921003） Aviation Science Foundation of China （2009ZF51059）
文摘Two near single-phase NiTiNb alloys--NisoTi4sNb2 and Ni49.5Ti46.5Nb4-are prepared and studied by means of scanning electron microscopy （SEM）, energy dispersive spectroscopy （EDS）, differential scanning calorimetry （DSC） and tensile tests in order to unearth the effects of Nb-atom solid solution in NiTi phase on the yield strength induced by self-accommodation of martensite variants. The results show that the yield strength of near single-phase NiTiNb alloys varies inversely with the amount of Nb-atoms solid-dissolved in NiTi phase. From the results out of the prior and current studies, it can be surmised that the effects of Nb content on the yield strength of NiTiNb alloys in martensite state depend on the coaction. Nb solid solution weakening mechanism and β-Nb phase composite strengthening mechanism. This inference might be a satisfactory explanation to the fact that the yield strength of （NiTi）50-0.5xNbx alloys in martensite state begins with decline and then rises when the Nb content increases.
基金supported by the National Natural Science Foundation of China (Grant No. 51574177)the China Natural Founds for Distinguished Young Scientists (Grant No. 51325401)the National High Technology Research and Development Program of China (“863” Program, Granted No. 2015AA042504)
文摘Vacuum brazing was successfully used to join Ti-22Al-25Nb alloy using Ti-Ni-Nb brazing alloys prepared by arc-melting. The influence of Nb content in the Ti-Ni-Nb brazing alloys on the interfacial microstructure and mechanical properties of the brazed joints was investigated. The results showed that the interfacial microstructure of brazed joint consisted of B2, O, ？3, and Ti2 Ni phase, while the width of brazing seams varied at different Nb contents. The room temperature shear strength reached359 MPa when the joints were brazed with eutectic Ti40Ni40Nb20 alloy at 1180？C for 20 min, and it was321, 308 and 256 MPa at 500, 650 and 800？C, respectively. Cracks primarily initiated and propagated in ？3compounds, and partially traversed B2＋O region. Moreover, the fracture surface displayed typical ductile dimples when cracks propagated through B2＋O region, which was favorable for the mechanical properties of the brazed joint.
基金financially supported by Wuhan Iron&Steel Co.,Ltd.
文摘The influence of Nb content on the microstructure and cryogenic mechanical properties of a 7%Ni steel was investigated within the Nb content range from 0 to 0.05%. The microstructure was characterized by optical microscope, scanning electron microscope, transmission electron microscopy and X-ray diffraction, and the low-temperature mechanical property tests were conducted. The Nb addition can effectively refine the prior austenite grains and microstructure of the steel. Fine niobium precipitates with a diameter of about 10-50 nm were observed. They tend to be spherical and locate mainly in the vicinity of grain boundaries. Although there are considerable amounts of reversed austenite forming at grain boundaries in the specimen containing the highest Nb content, no Nb element was detected in such reversed austenite, which implies that Nb element did not affect the formation of the reversed austenite directly. Mechanical test results suggest that the strength of the 7%Ni steel is not simply in relation to the prior austenite grain size, but also depends on the amount of reversed austenite. On the other hand, the grain refinement, enhanced with increasing Nb content, has a good effect on cryogenic toughness.
基金Project(2019YFB1901002)supported by the Key Project of Nuclear Safety and Advanced Nuclear Technology,ChinaProject supported by State Key Laboratory of Powder Metallurgy,China。
文摘The recrystallization and texture evolution of cold-rolled FeCrAl-0.65 Nb and FeCrAl-1.2 Nb alloys thin-wall tubes annealed at 600−900℃ for 1−600 min were investigated.The microstructures were characterized by electron back scattering diffraction,electron probe micro-analyzer and transmission electron microscopy.The Vickers hardness and room temperature tensile properties were tested.The results showed that the hardness of fully recrystallized FeCrAl-1.2 Nb alloy was higher and more likely to recrystallize than FeCrAl-0.65 Nb alloy.The weak texture strength of annealing sample was obtained and the proportion of<111>//ND texture increased.The fine Laves phase distributed uniformly in FeCrAl-0.65 Nb alloy had good pinning effect and inhibited recrystallization.Higher Nb content had little effects on tensile properties of thin-wall tube,and induced the formation of larger Laves phase.There was less fine Laves phase pinning in the large area adjacent to the blocky Laves phase,which resulted in easy recrystallization in FeCrAl-1.2 Nb alloy.
文摘The hot deformation behavior of S460 ML steel with different Nb contents was investigated by single-pass compression experiment on the Gleeble-1500 thermo-machine simulator at deformation temperatures ranging from 900 to 1200 ℃ and strain rates from 0.1 to 5.0 s^(-1). The critical strain of dynamic recrystallization(DRC) under different conditions was determined by using working hardening rate-strain curves. The relationship between critical strain and peak strain of DRC was discussed. By means of regression analysis method, the hot deformation activation energy of steels and the mathematical model for predicting DRC critical strain were calculated and established, respectively. The results showed that DRC occurred during hot deformation. As the deformation temperature increased and strain rate decreased, the critical strain of DRC decreased. The critical strain(εc) showed linear relationship with peak strain(εp). As Nb content increased,the needed deformation temperature for occurring DRC increased, while the needed strain rate for it decreased. The activation energy for hot deformation of S460 ML steel increased with increasing Nb content.
基金supported by National Natural Science Foundation of China(Grant No.52074095)Guizhou Provincial Basic Research Program(Natural Science)(Grant No.QKHJC-ZK[2023]YB072)+2 种基金Guizhou Provincial Key Technology R&D Program(Grant No.QKHZC[2023]YB404)Guizhou Provincial Key Technology R&D Program(Grant No.QKHZC[2022]YB053)The numerical calculation of the first-principles was supported and assisted by the High-Performance Computing Center of Guizhou University.
文摘The influence mechanism of trace Nb on the corrosion resistance of surface corrosion products of high-strength anti-seismic rebar in the simulated marine environment was studied by combining first-principles calculations with corrosion mass loss method,surface analysis,cross-sectional analysis,quantitative analysis,and electrochemical test.The results demonstrated that the addition of trace Nb effectively improved the compactness and stability of surface corrosion layer of rebar,and the corrosion resistance of corrosion layer increased with the increase in Nb content.The beneficial effect of Nb content on the corrosion layer summarized two important key points.Firstly,the addition of Nb was beneficial to promoting the improvement in the structural stability of α-FeOOH,and α-FeOOH structure of solid solution Nb atoms was beneficial to strengthening the fixation of Cl atoms,thus increasing α/(β+γ)ratio,total impedance value,and corrosion potential.Secondly,the formation of Nb oxides can not only repair the corrosion layer,but also play a role in the fixation Cl atoms,resulting in the improvement in corrosion resistance of corrosion layer.
基金National Natural Science Foundation of China (50941046)
文摘Effect of Nb contents on microstructure and magnetic properties of FeCoNbB films has been studied. X-ray diffraction （XRD） analysis reveals that Nb plays a role in refining grain and in facilitating formation of amorphous structure. When Nb content is more than 8 at%, the films transform from crystalline to amorphous structure, accompanied by variations in magnetic properties. An unusual out-of-plane anisotropy component is consequently observed. It can be suggested that the anisotropy induced by increasing Nb contents be attributed to stress-related magnetoelastic anisotropy. The undesirable anisotropy is greatly reduced by thermal annealing, reducing film thicknesses or applying an external magnetic field together with Si addition.
