Metal-Organic Frameworks(MOFs)have emerged as promising materials for gas adsorption and separation due to their exceptional surface area,tunable porosity,and versatility in functionalization.This paper explores the m...Metal-Organic Frameworks(MOFs)have emerged as promising materials for gas adsorption and separation due to their exceptional surface area,tunable porosity,and versatility in functionalization.This paper explores the mechanisms of gas adsorption in MOFs,including physical adsorption,chemisorption,and synergistic effects,which contribute to their efficiency in capturing and separating gases.The applications of MOFs in key areas such as carbon dioxide capture,hydrogen storage,natural gas separation,and air purification are discussed,highlighting their potential to address pressing environmental and energy challenges.Additionally,the use of MOFs in selective gas separation,membranes,and adsorption-based technologies like Pressure Swing Adsorption(PSA)and Vacuum Swing Adsorption(VSA)is explored,emphasizing their advantages over traditional materials.Despite challenges related to scalability,stability,and cost,MOFs hold great promise for advancing gas separation technologies in the near future,offering more efficient,sustainable,and environmentally friendly solutions.展开更多
The supersonic nozzle is a new apparatus which can be used to condense and separate water and heavy hydrocarbons from natural gas.The swirling separation of natural gas in the convergent-divergent nozzle was numerical...The supersonic nozzle is a new apparatus which can be used to condense and separate water and heavy hydrocarbons from natural gas.The swirling separation of natural gas in the convergent-divergent nozzle was numerically simulated based on a new design which incorporates a central body. Axial distribution of the main parameters of gas flow was investigated,while the basic parameters of gas flow were obtained as functions of radius at the nozzle exit.The effect of the nozzle geometry on the swirling separation was analyzed.The numerical results show that water and heavy hydrocarbons can be condensed and separated from natural gas under the combined effect of the low temperature（-80℃） and the centrifugal field（482,400g,g is the acceleration of gravity）.The gas dynamic parameters are uniformly distributed correspondingly in the radial central region of the channel,for example the distribution range of the static temperature and the centrifugal acceleration are from -80 to -55℃and 220,000g to 500,000g,respectively,which would create good conditions for the cyclone separation of the liquids.However,high gradients of gas dynamic parameters near the channel walls may impair the process of separation.The geometry of the nozzle has a great influence on the separation performance. Increasing the nozzle convergent angle can improve the separation efficiency.The swirling natural gas can be well separated when the divergent angle takes values from 4°to 12°in the convergent-divergent nozzle.展开更多
The application of swirl tube cyclone for gas-liquid separation is attractive due to its small size and weight. However, very scarce information on the performance of the swirl tube cyclone especially at high operatin...The application of swirl tube cyclone for gas-liquid separation is attractive due to its small size and weight. However, very scarce information on the performance of the swirl tube cyclone especially at high operating pressure emulating actual field condition was published in journals. Performance assessment was usually done at a low operating pressure using either air-water, air-fine particle mixtures or dense gas such as SF6 . This paper fills the existing gaps and reports the initial findings on the performance assessment of a horizontal swirl tube cyclone for gas-liquid separation operating at a flow rate of 5 MMSCFD at 40-60 bar operating pressure.展开更多
文摘Metal-Organic Frameworks(MOFs)have emerged as promising materials for gas adsorption and separation due to their exceptional surface area,tunable porosity,and versatility in functionalization.This paper explores the mechanisms of gas adsorption in MOFs,including physical adsorption,chemisorption,and synergistic effects,which contribute to their efficiency in capturing and separating gases.The applications of MOFs in key areas such as carbon dioxide capture,hydrogen storage,natural gas separation,and air purification are discussed,highlighting their potential to address pressing environmental and energy challenges.Additionally,the use of MOFs in selective gas separation,membranes,and adsorption-based technologies like Pressure Swing Adsorption(PSA)and Vacuum Swing Adsorption(VSA)is explored,emphasizing their advantages over traditional materials.Despite challenges related to scalability,stability,and cost,MOFs hold great promise for advancing gas separation technologies in the near future,offering more efficient,sustainable,and environmentally friendly solutions.
基金supported by the National High Technology Research and Development Program of China("863 program",No.2007AA09Z301) the National Major Science&Technology Specific Projects(No.2008ZX05017-004)
文摘The supersonic nozzle is a new apparatus which can be used to condense and separate water and heavy hydrocarbons from natural gas.The swirling separation of natural gas in the convergent-divergent nozzle was numerically simulated based on a new design which incorporates a central body. Axial distribution of the main parameters of gas flow was investigated,while the basic parameters of gas flow were obtained as functions of radius at the nozzle exit.The effect of the nozzle geometry on the swirling separation was analyzed.The numerical results show that water and heavy hydrocarbons can be condensed and separated from natural gas under the combined effect of the low temperature（-80℃） and the centrifugal field（482,400g,g is the acceleration of gravity）.The gas dynamic parameters are uniformly distributed correspondingly in the radial central region of the channel,for example the distribution range of the static temperature and the centrifugal acceleration are from -80 to -55℃and 220,000g to 500,000g,respectively,which would create good conditions for the cyclone separation of the liquids.However,high gradients of gas dynamic parameters near the channel walls may impair the process of separation.The geometry of the nozzle has a great influence on the separation performance. Increasing the nozzle convergent angle can improve the separation efficiency.The swirling natural gas can be well separated when the divergent angle takes values from 4°to 12°in the convergent-divergent nozzle.
文摘The application of swirl tube cyclone for gas-liquid separation is attractive due to its small size and weight. However, very scarce information on the performance of the swirl tube cyclone especially at high operating pressure emulating actual field condition was published in journals. Performance assessment was usually done at a low operating pressure using either air-water, air-fine particle mixtures or dense gas such as SF6 . This paper fills the existing gaps and reports the initial findings on the performance assessment of a horizontal swirl tube cyclone for gas-liquid separation operating at a flow rate of 5 MMSCFD at 40-60 bar operating pressure.
