A new micro-spherical conjugated macrocycle polymer(P[5]-TFB-CMP)was prepared by the condensation reaction between dihydrazide functionalized pillar[5]arene and 1,3,5-triformylbenzene under ambient conditions.P[5]-TFB...A new micro-spherical conjugated macrocycle polymer(P[5]-TFB-CMP)was prepared by the condensation reaction between dihydrazide functionalized pillar[5]arene and 1,3,5-triformylbenzene under ambient conditions.P[5]-TFB-CMP exhibits large surface area with excellent thermal stability and has been used as additive to prepare composite PMMA film of photochromic naphthopyrans.The results showed that the addition of P[5]-TFB-CMP could dramatically accelerate the thermal fading rate of the photochromic composite film by up to 12 times.This is a new strategy to overcome the drawback of the matrix effect.展开更多
基金financially supported by Natural Science Foundation of Tianjin(No.18JCYBJC20700)the 111 Project(No.B12015)。
文摘A new micro-spherical conjugated macrocycle polymer(P[5]-TFB-CMP)was prepared by the condensation reaction between dihydrazide functionalized pillar[5]arene and 1,3,5-triformylbenzene under ambient conditions.P[5]-TFB-CMP exhibits large surface area with excellent thermal stability and has been used as additive to prepare composite PMMA film of photochromic naphthopyrans.The results showed that the addition of P[5]-TFB-CMP could dramatically accelerate the thermal fading rate of the photochromic composite film by up to 12 times.This is a new strategy to overcome the drawback of the matrix effect.
