Objectives:Novel drug delivery systems have been designed to enhance local drug concentrations while reducing side effects conducive to improved breast cancer treatment outcomes.This study aimed to identify the anti-c...Objectives:Novel drug delivery systems have been designed to enhance local drug concentrations while reducing side effects conducive to improved breast cancer treatment outcomes.This study aimed to identify the anti-cancer function of zeolite imidazole ester-based material loaded with camptothecin nanoparticles.Methods:We utilized a zeolitic imidazolate backbone material to fabricate 9-hydroxycamptothecin nanoparticles and investigated their impact on breast cancer cell proliferation.Scanning electron microscopy and Fourier-transform infrared spectroscopy revealed changes in the carrier skeleton of the loaded 9-hydroxyl camptothecin,characterized by a reduction in surface smoothness,accompanied by slight collapses and folds on the particle surface.Notably,we detected vibration of the benzene ring in the 9-hydroxycamptothecin structure within the nanoparticles.Cell proliferation was tested by CCK-8.Protein expression was measured byWestern blot.The efficacy of nanoparticles was evaluated by animal experiments.Results:In this study,we utilized a zeolitic imidazolate backbone material to fabricate 9-hydroxycamptothecin(9-HCPT)nanoparticles and investigated their impact on breast cancer cell proliferation.Scanning electron microscopy and Fourier-transform infrared spectroscopy revealed changes in the carrier skeleton of the loaded 9-hydroxyl camptothecin,characterized by a reduction in surface smoothness,accompanied by slight collapses and folds on the particle surface.Notably,we detected vibration of the benzene ring in the 9-HCPT structure within the nanoparticles.Using the CCK-8 method,we evaluated the inhibitory effect of these nanoparticles on breast cancer cells and observed a significant reduction in the cytotoxicity of camptothecin(CPT)when incorporated into the zeolite imidazole ester skeleton material.Immunoblot analysis showed upregulation of cyclic GMP-AMP synthase(cGAS),stimulator of interferon genes(STING),andNF-κB-p65 in response to the nanoparticles.These results showed that our nanoparticles might be a useful drug delivery strategy to overcome breast cancer drug resistance.Conclusion:Thefindings of this study suggest that nanoparticles loaded with CPT and formed fromzeolite imidazole ester backbone material possess immune-enhancing properties that could suppress breast cancer progression.Accordingly,these nanoparticles hold promise as potential lead compounds for combined immunotherapy in breast cancer treatment.展开更多
Correction to:Nano-Micro Letters(2025)17:123 https://doi.org/10.1007/s40820-025-01654-y Following publication of the original article[1],the authors reported that Dr.Mohamed Bououdina’s affiliation needed to be corre...Correction to:Nano-Micro Letters(2025)17:123 https://doi.org/10.1007/s40820-025-01654-y Following publication of the original article[1],the authors reported that Dr.Mohamed Bououdina’s affiliation needed to be corrected from 1 to 2.The correct author affiliation has been provided in this Correction and the original article[1]has been corrected.展开更多
Editors-in-Chief Zhong Lin Wang,Beijing Institute of Nanoenergy and Nanosys-tems,Chinese Academy of Sciences;Nanometer Institute of the University of Chinese Academy of Sciences,China Liqun Zhang,South China Universit...Editors-in-Chief Zhong Lin Wang,Beijing Institute of Nanoenergy and Nanosys-tems,Chinese Academy of Sciences;Nanometer Institute of the University of Chinese Academy of Sciences,China Liqun Zhang,South China University of Technology,China。展开更多
A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning elec...A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.展开更多
In 1823,Thomas Seebeck first discovered the thermoelectric effect.A temperature difference across any electric conductor junction will generate a corresponding voltage difference.Probably the most familiar use of this...In 1823,Thomas Seebeck first discovered the thermoelectric effect.A temperature difference across any electric conductor junction will generate a corresponding voltage difference.Probably the most familiar use of this so called Seebeck effect is thermocouple.When an electric current passing through junction which is composed of two dissimilar conductors results in the absorption or release of the heat,this is the Peltier effect.This effect makes thermoelectric refrigerator or heating devices possible.Moreover a power generator can be also invented from the application of thermoelectric materials.Thermoelectric materials are those which possess high thermoelectric figure of merit.The major problem for thermoelectric materials is poor efficiency.They are now used only in the fields in which cost is not a big problem such as space and some other instruments.Thermoelectric materials are not widely used nowadays.展开更多
A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanat...A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.展开更多
A cost-effective carbon-free nanocoating strategy was developed for the synthesis of ultra-fine SnO2 coatingα-Fe2O3 core-shell nanoparticles. This strategy only involves a two-step molten salt reaction at low tempera...A cost-effective carbon-free nanocoating strategy was developed for the synthesis of ultra-fine SnO2 coatingα-Fe2O3 core-shell nanoparticles. This strategy only involves a two-step molten salt reaction at low temperature of 300 °C. The as-preparedα-Fe2O3@SnO2 core-shell nanocomposites show enhanced electrochemical performances than the bareα-Fe2O3 nanoparticles. This involved metal oxide nanocoating method is easy to be carried out, and the heat treatment temperature is much lower than that of other traditional solid-state annealing method and many carbon or metal oxide nanocoating methods. The molten salt method may also be used to produce other metal oxides coating nanostructures as the electrode materials for lithium-ion batteries.展开更多
Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structu...Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.展开更多
In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect ...In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.展开更多
High-frequency seismic attenuation is conventionally attributed to anelastic absorption. In this paper, I present three studies on high-frequency seismic attenuation and propose that the physical mechanism results fro...High-frequency seismic attenuation is conventionally attributed to anelastic absorption. In this paper, I present three studies on high-frequency seismic attenuation and propose that the physical mechanism results from the interference of elastic microscopic multiple scattering waves. First, I propose a new theory on wave propagation in a two-phase medium which is based on the concept that the basic unit for wave propagation is a nano- mass point. As a result of the elasticity variations of pore fluid and rock framework, micro multiple scattering waves would emerge at the wavelength of the seismic waves passing through the two-phase medium and their interference and overlap would generate high- frequency seismic attenuation. Second, I present a study of the frequency response of seismic transmitted waves by modeling thin-layers with thicknesses no larger than pore diameters. Results indicate that high-frequency seismic waves attenuate slightly in a near-surface water zone but decay significantly in a near-surface gas zone. Third, I analyze the seismic attenuation characteristics in near-surface water and gas zones using dual-well shots in the Songliao Basin, and demonstrate that the high-frequency seismic waves attenuate slightly in water zones but in gas zones the 160-1600 Hz propagating waves decay significantly. The seismic attenuation characteristics from field observations coincide with the modeling results. Conclusions drawn from these studies theoretically support seismic attenuation recovery.展开更多
The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom...The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom and the micro vibration test bed. The result of stimulational experiment indicates that the isolation of vibration of this system is satisfactory. The design method of vibration can be used as the reference to ultra precision machine tool, super micro orientation machanism and so on.展开更多
Based on the 65nm CMOS process,a novel parallel RLC coupling interconnect analytical model is presented synthetically considering parasitical capacitive and parasitical inductive effects. Applying function approximati...Based on the 65nm CMOS process,a novel parallel RLC coupling interconnect analytical model is presented synthetically considering parasitical capacitive and parasitical inductive effects. Applying function approximation and model order-reduction to the model, we derive a closed-form and time-domain waveform for the far-end crosstalk of a victim line under ramp input transition. For various interconnect coupling sizes, the proposed RLC coupling analytical model enables the estimation of the crosstalk voltage within 2.50% error compared with Hspice simulation in a 65nm CMOS process. This model can be used in computer-aided-design of nanometer SOCs.展开更多
The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid dro...The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.展开更多
Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structu...Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.展开更多
The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct ...The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct magnetic phases has been calculated by using Born approximation.The results show that the average scattering cross section of the magnetic cluster decreases with the increasing number n of the atom.The origin of the giant magnetoresistance comes from the spin dependent scattering between conduction electrons and magnetic granules and the field dependence of magnetoresistance and the quadratic relation of magnetoresistance on the rate of magnetic moment are in good agreement with the experiments reported.展开更多
The low-carbon magnesia-carbon （MgO-C） composites containing 3% （mass fraction, the same below） carbon were prepared by adding various types of carbon black （CB）. The mechanical properties, oxidation resistance ...The low-carbon magnesia-carbon （MgO-C） composites containing 3% （mass fraction, the same below） carbon were prepared by adding various types of carbon black （CB）. The mechanical properties, oxidation resistance at 1 100 ℃ in oxidizing atmosphere, and thermal shock resistance after 5 times dipping in 1 600 ℃molten steel of the low-carbon composite samples were investigated, compared with a commercial high-carbon MgO-C composite contai- ning carbon of 16 %. The results show that the mechanical properties, oxidation resistance and thermal shock resist- ance of the low-carbon samples are improved with the decrease of CB particle size. Thermal shock resistance of the low-carbon sample containing nanometer CB N220 is obviously better than that of other low-carbon samples, and rea- ches the level of the high-carbon samples.展开更多
Methyl methacrylate (MMA) emulsion polymerization in the presence of nanometer calcium carbonate(nano-CaCO3) surface modified with γ-methacryloxypropyltrimethoxysilane (MPTMS) was carried out to prepare poly (methyl ...Methyl methacrylate (MMA) emulsion polymerization in the presence of nanometer calcium carbonate(nano-CaCO3) surface modified with γ-methacryloxypropyltrimethoxysilane (MPTMS) was carried out to prepare poly (methyl methacrylate) (PMMA)/nano-CaCO3 composite. The reaction between nano-CaCO3 and MPTMS, and the grafting of PMMA onto nano-CaCO3 were confirmed by infrared spectrum. The grafting ratio and grafting efficiency of PMMA on nano-CaCO3 modified with MPTMS were much higher than that on nano-CaCO3 modified with stearic acid. The grafting ratio of PMMA increased as the weight ratio between MMA and nano-CaCO3 increased, while the grafting efficiency of PMMA decreased. Transmission electron micrograph showed that nano-CaCO3 covered with PMMA was formed by in-situ emulsion polymerization.展开更多
The effect of nanometer anatase TiO2 was investigated on the photocatalytic degradation of phenanthrene on soil surfaces under a variety of conditions. After being spiked with phenanthrene, soil samples loaded with di...The effect of nanometer anatase TiO2 was investigated on the photocatalytic degradation of phenanthrene on soil surfaces under a variety of conditions. After being spiked with phenanthrene, soil samples loaded with different amounts of TiO2 （0 wt.%, 1 wt.%, 2 wt.%, 3 wt.%, and 4 wt.%） were exposed to UV-light irradiation for 25 hr. The results indicated that the photocatalytic degradation of phenanthrene followed the pseudo first-order kinetics. TiO2 significantly accelerated the degradation of phenanthrene with the half-life reduced from 45.90 to 31.36 hr for TiO2 loading of 0 wt.% and 4 wt.%, respectively. In addition, the effects of H202, light intensity and humic acid on the degradation of phenanthrene were investigated. The degradation of phenanthrene increased with the concentration of H202, light intensity and the concentration of humic acids. It has been demonstrated that the photocatalytic method in the presence of nanometer anatase TiO2 was a very promising technology for the treatments of soil polluted with organic substances in the future.展开更多
基金supported by grants from the Guangdong Basic and Applied Basic Research Foundation(No.2023B1515130009)the Science and Technology Bureau of Foshan(No.FS0AA-KJ819-4901-0082).
文摘Objectives:Novel drug delivery systems have been designed to enhance local drug concentrations while reducing side effects conducive to improved breast cancer treatment outcomes.This study aimed to identify the anti-cancer function of zeolite imidazole ester-based material loaded with camptothecin nanoparticles.Methods:We utilized a zeolitic imidazolate backbone material to fabricate 9-hydroxycamptothecin nanoparticles and investigated their impact on breast cancer cell proliferation.Scanning electron microscopy and Fourier-transform infrared spectroscopy revealed changes in the carrier skeleton of the loaded 9-hydroxyl camptothecin,characterized by a reduction in surface smoothness,accompanied by slight collapses and folds on the particle surface.Notably,we detected vibration of the benzene ring in the 9-hydroxycamptothecin structure within the nanoparticles.Cell proliferation was tested by CCK-8.Protein expression was measured byWestern blot.The efficacy of nanoparticles was evaluated by animal experiments.Results:In this study,we utilized a zeolitic imidazolate backbone material to fabricate 9-hydroxycamptothecin(9-HCPT)nanoparticles and investigated their impact on breast cancer cell proliferation.Scanning electron microscopy and Fourier-transform infrared spectroscopy revealed changes in the carrier skeleton of the loaded 9-hydroxyl camptothecin,characterized by a reduction in surface smoothness,accompanied by slight collapses and folds on the particle surface.Notably,we detected vibration of the benzene ring in the 9-HCPT structure within the nanoparticles.Using the CCK-8 method,we evaluated the inhibitory effect of these nanoparticles on breast cancer cells and observed a significant reduction in the cytotoxicity of camptothecin(CPT)when incorporated into the zeolite imidazole ester skeleton material.Immunoblot analysis showed upregulation of cyclic GMP-AMP synthase(cGAS),stimulator of interferon genes(STING),andNF-κB-p65 in response to the nanoparticles.These results showed that our nanoparticles might be a useful drug delivery strategy to overcome breast cancer drug resistance.Conclusion:Thefindings of this study suggest that nanoparticles loaded with CPT and formed fromzeolite imidazole ester backbone material possess immune-enhancing properties that could suppress breast cancer progression.Accordingly,these nanoparticles hold promise as potential lead compounds for combined immunotherapy in breast cancer treatment.
文摘Correction to:Nano-Micro Letters(2025)17:123 https://doi.org/10.1007/s40820-025-01654-y Following publication of the original article[1],the authors reported that Dr.Mohamed Bououdina’s affiliation needed to be corrected from 1 to 2.The correct author affiliation has been provided in this Correction and the original article[1]has been corrected.
文摘Editors-in-Chief Zhong Lin Wang,Beijing Institute of Nanoenergy and Nanosys-tems,Chinese Academy of Sciences;Nanometer Institute of the University of Chinese Academy of Sciences,China Liqun Zhang,South China University of Technology,China。
文摘A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.
文摘In 1823,Thomas Seebeck first discovered the thermoelectric effect.A temperature difference across any electric conductor junction will generate a corresponding voltage difference.Probably the most familiar use of this so called Seebeck effect is thermocouple.When an electric current passing through junction which is composed of two dissimilar conductors results in the absorption or release of the heat,this is the Peltier effect.This effect makes thermoelectric refrigerator or heating devices possible.Moreover a power generator can be also invented from the application of thermoelectric materials.Thermoelectric materials are those which possess high thermoelectric figure of merit.The major problem for thermoelectric materials is poor efficiency.They are now used only in the fields in which cost is not a big problem such as space and some other instruments.Thermoelectric materials are not widely used nowadays.
文摘A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.
基金Projects(51202297,81372464,51472271)supported by the National Natural Science Foundation of ChinaProject(NCET-12-0554)supported by the New Century Excellent Talents in UniversityProject(2013CB932901)supported by the National Basic Research Program of China
文摘A cost-effective carbon-free nanocoating strategy was developed for the synthesis of ultra-fine SnO2 coatingα-Fe2O3 core-shell nanoparticles. This strategy only involves a two-step molten salt reaction at low temperature of 300 °C. The as-preparedα-Fe2O3@SnO2 core-shell nanocomposites show enhanced electrochemical performances than the bareα-Fe2O3 nanoparticles. This involved metal oxide nanocoating method is easy to be carried out, and the heat treatment temperature is much lower than that of other traditional solid-state annealing method and many carbon or metal oxide nanocoating methods. The molten salt method may also be used to produce other metal oxides coating nanostructures as the electrode materials for lithium-ion batteries.
文摘Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.
文摘In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.
文摘High-frequency seismic attenuation is conventionally attributed to anelastic absorption. In this paper, I present three studies on high-frequency seismic attenuation and propose that the physical mechanism results from the interference of elastic microscopic multiple scattering waves. First, I propose a new theory on wave propagation in a two-phase medium which is based on the concept that the basic unit for wave propagation is a nano- mass point. As a result of the elasticity variations of pore fluid and rock framework, micro multiple scattering waves would emerge at the wavelength of the seismic waves passing through the two-phase medium and their interference and overlap would generate high- frequency seismic attenuation. Second, I present a study of the frequency response of seismic transmitted waves by modeling thin-layers with thicknesses no larger than pore diameters. Results indicate that high-frequency seismic waves attenuate slightly in a near-surface water zone but decay significantly in a near-surface gas zone. Third, I analyze the seismic attenuation characteristics in near-surface water and gas zones using dual-well shots in the Songliao Basin, and demonstrate that the high-frequency seismic waves attenuate slightly in water zones but in gas zones the 160-1600 Hz propagating waves decay significantly. The seismic attenuation characteristics from field observations coincide with the modeling results. Conclusions drawn from these studies theoretically support seismic attenuation recovery.
文摘The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom and the micro vibration test bed. The result of stimulational experiment indicates that the isolation of vibration of this system is satisfactory. The design method of vibration can be used as the reference to ultra precision machine tool, super micro orientation machanism and so on.
文摘Based on the 65nm CMOS process,a novel parallel RLC coupling interconnect analytical model is presented synthetically considering parasitical capacitive and parasitical inductive effects. Applying function approximation and model order-reduction to the model, we derive a closed-form and time-domain waveform for the far-end crosstalk of a victim line under ramp input transition. For various interconnect coupling sizes, the proposed RLC coupling analytical model enables the estimation of the crosstalk voltage within 2.50% error compared with Hspice simulation in a 65nm CMOS process. This model can be used in computer-aided-design of nanometer SOCs.
文摘The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.
文摘Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.
基金Supported by National Natural Science Foundation of China!(No.194 7710 5)
文摘The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct magnetic phases has been calculated by using Born approximation.The results show that the average scattering cross section of the magnetic cluster decreases with the increasing number n of the atom.The origin of the giant magnetoresistance comes from the spin dependent scattering between conduction electrons and magnetic granules and the field dependence of magnetoresistance and the quadratic relation of magnetoresistance on the rate of magnetic moment are in good agreement with the experiments reported.
基金Item Sponsored by National Natural Science Foundation of China(50572032)
文摘The low-carbon magnesia-carbon （MgO-C） composites containing 3% （mass fraction, the same below） carbon were prepared by adding various types of carbon black （CB）. The mechanical properties, oxidation resistance at 1 100 ℃ in oxidizing atmosphere, and thermal shock resistance after 5 times dipping in 1 600 ℃molten steel of the low-carbon composite samples were investigated, compared with a commercial high-carbon MgO-C composite contai- ning carbon of 16 %. The results show that the mechanical properties, oxidation resistance and thermal shock resist- ance of the low-carbon samples are improved with the decrease of CB particle size. Thermal shock resistance of the low-carbon sample containing nanometer CB N220 is obviously better than that of other low-carbon samples, and rea- ches the level of the high-carbon samples.
文摘Methyl methacrylate (MMA) emulsion polymerization in the presence of nanometer calcium carbonate(nano-CaCO3) surface modified with γ-methacryloxypropyltrimethoxysilane (MPTMS) was carried out to prepare poly (methyl methacrylate) (PMMA)/nano-CaCO3 composite. The reaction between nano-CaCO3 and MPTMS, and the grafting of PMMA onto nano-CaCO3 were confirmed by infrared spectrum. The grafting ratio and grafting efficiency of PMMA on nano-CaCO3 modified with MPTMS were much higher than that on nano-CaCO3 modified with stearic acid. The grafting ratio of PMMA increased as the weight ratio between MMA and nano-CaCO3 increased, while the grafting efficiency of PMMA decreased. Transmission electron micrograph showed that nano-CaCO3 covered with PMMA was formed by in-situ emulsion polymerization.
基金supported by the Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering (No. KLIEEE-09-04)the Liaoning Doctoral Funds (No. 20111076)
文摘The effect of nanometer anatase TiO2 was investigated on the photocatalytic degradation of phenanthrene on soil surfaces under a variety of conditions. After being spiked with phenanthrene, soil samples loaded with different amounts of TiO2 （0 wt.%, 1 wt.%, 2 wt.%, 3 wt.%, and 4 wt.%） were exposed to UV-light irradiation for 25 hr. The results indicated that the photocatalytic degradation of phenanthrene followed the pseudo first-order kinetics. TiO2 significantly accelerated the degradation of phenanthrene with the half-life reduced from 45.90 to 31.36 hr for TiO2 loading of 0 wt.% and 4 wt.%, respectively. In addition, the effects of H202, light intensity and humic acid on the degradation of phenanthrene were investigated. The degradation of phenanthrene increased with the concentration of H202, light intensity and the concentration of humic acids. It has been demonstrated that the photocatalytic method in the presence of nanometer anatase TiO2 was a very promising technology for the treatments of soil polluted with organic substances in the future.
