High entropy alloys(HEAs)have attracted extensive attention due to their excellent properties in harsh environments.Here,we introduced the HEA NbMoTaW into the laminated structure to synthesize the Cu/HEA nanolaminate...High entropy alloys(HEAs)have attracted extensive attention due to their excellent properties in harsh environments.Here,we introduced the HEA NbMoTaW into the laminated structure to synthesize the Cu/HEA nanolaminates(NLs)with equal layer thickness h spanning from 5 to 100 nm,and comparatively investigated the size dependent mechanical properties and plastic deformation.The experimental results demonstrated that the hardness of Cu/HEA NLs increased with decreasing h,and reached a plateau at h≤50 nm,while the strain rate sensitivity m unexpectedly went through a maximum with reducing h.The emergence of maximum m results from a transition from the synergetic effect of crystalline constituents to the competitive effect between crystalline Cu and amorphous-like NbMoTaW.Microstructural examinations revealed that shear banding caused by the incoherent Cu/HEA interfaces occurred under severe deformation,and the soft Cu layers dominated plastic deformation of Cu/HEA NLs with large h.展开更多
Since most organic materials are very sensitive to moisture and oxygen, organic light emitting diodes (OLEDs) require an encapsulation layer to protect the active layer from these gases. Since light, flexible and port...Since most organic materials are very sensitive to moisture and oxygen, organic light emitting diodes (OLEDs) require an encapsulation layer to protect the active layer from these gases. Since light, flexible and portable OLEDs are being employed in more diverse climates and environmental conditions, the OLED encapsulation layer must retain robust mechanical properties and stability in high temperature/high humidity conditions. Al2O3 films have demonstrated excellent barrier performance, but they readily hydrolyze when exposed to prolonged harsh environments. In this study, we fabricated a thin film encapsulation (TFE) film that was resistant to hydrolysis, using Al2O3/MgO (AM) nanolaminates. MgO has superior resistance to harsh environments, and the aluminate phase generated by the chemical reaction of Al2O3 and MgO provided excellent barrier performance, even after storage in harsh conditions. A multi-barrier fabricated using the AM nanolaminate showed excellent barrier performance, close to the level required by OLEDs. It did not significantly deteriorate even after a bending test of 1,000 iterations at 0.63% strain. After 1,000 cycle of bending, the electrical properties of the passivated OLEDs were not significantly degraded at shelf-lifetime test where the fabricated device was stored for 50 days in a harsh environment of 60℃, 90% relative humidity. The multi-barrier shows the best performance compared to previous studies on flexible encapsulation that can be used in harsh environments.展开更多
基金supported by the National Natural Science Foundation of China (51621063, 51722104, 51625103, 51790482, 51761135031 and 51571157)the National Key Research and Development Program of China (2017YFA0700701 and 2017YFB0702301)+6 种基金the 111 Project 2.0 of China (BP2018008)the International Joint Laboratory for Micro/Nano Manufacturing and Measurement Technologiesthe Fundamental Research Funds for the Central Universities (xzy022019071)the Fok Ying-Tong Education Foundation (161096)China Postdoctoral Science Foundation (2017T100744)Shaanxi Province innovative talents promotion Projects (2018KJXX-004)the support from China Postdoctoral Science Foundation (2016M602811)
文摘High entropy alloys(HEAs)have attracted extensive attention due to their excellent properties in harsh environments.Here,we introduced the HEA NbMoTaW into the laminated structure to synthesize the Cu/HEA nanolaminates(NLs)with equal layer thickness h spanning from 5 to 100 nm,and comparatively investigated the size dependent mechanical properties and plastic deformation.The experimental results demonstrated that the hardness of Cu/HEA NLs increased with decreasing h,and reached a plateau at h≤50 nm,while the strain rate sensitivity m unexpectedly went through a maximum with reducing h.The emergence of maximum m results from a transition from the synergetic effect of crystalline constituents to the competitive effect between crystalline Cu and amorphous-like NbMoTaW.Microstructural examinations revealed that shear banding caused by the incoherent Cu/HEA interfaces occurred under severe deformation,and the soft Cu layers dominated plastic deformation of Cu/HEA NLs with large h.
基金This research was supported by the Engineering Research Center of Excellence(ERC)Program supported by the National Research Foundation(NRF)of the Korean Ministry of Science,ICT&Future Planning(MSIP)(Grant No.NRF-2017R1A5A1014708).The authors express sincere gratitude to National NanoFab(NNFC)for the measurements.We also thank Prof.Byeong:Soo Bae from KAIST for help in synthesis of the polymers.
文摘Since most organic materials are very sensitive to moisture and oxygen, organic light emitting diodes (OLEDs) require an encapsulation layer to protect the active layer from these gases. Since light, flexible and portable OLEDs are being employed in more diverse climates and environmental conditions, the OLED encapsulation layer must retain robust mechanical properties and stability in high temperature/high humidity conditions. Al2O3 films have demonstrated excellent barrier performance, but they readily hydrolyze when exposed to prolonged harsh environments. In this study, we fabricated a thin film encapsulation (TFE) film that was resistant to hydrolysis, using Al2O3/MgO (AM) nanolaminates. MgO has superior resistance to harsh environments, and the aluminate phase generated by the chemical reaction of Al2O3 and MgO provided excellent barrier performance, even after storage in harsh conditions. A multi-barrier fabricated using the AM nanolaminate showed excellent barrier performance, close to the level required by OLEDs. It did not significantly deteriorate even after a bending test of 1,000 iterations at 0.63% strain. After 1,000 cycle of bending, the electrical properties of the passivated OLEDs were not significantly degraded at shelf-lifetime test where the fabricated device was stored for 50 days in a harsh environment of 60℃, 90% relative humidity. The multi-barrier shows the best performance compared to previous studies on flexible encapsulation that can be used in harsh environments.
