The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HA...The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HAZ)toughness of Mo16 steel is obviously higher than that of Mo8 steel at all the heat inputs of 50,100,150 and 200 kJ/cm,with HAZ toughness of both steels decreased with increasing the welding heat input.When the Mo content is increased from 0.08 to 0.16%,the size of nano-scaled particles in HAZ is decreased from 18 to 15 nm,and their number density is increased from 0.7 to 0.9μm^(−2).Thus,the Zener pinning force is increased,and the prior austenite grain size(PAGS)is decreased,leading to the improved HAZ toughness.Microstructural characterizations show that the nano-scaled particles in both steels are Ti(C,N)with the solute elements of Nb and Mo.The calculated critical particle size of TiN is 10.2 and 8.4 nm in Mo8 and Mo16 steels at 1350℃,and the particles larger than the critical size are stable during the welding process.From the Zener pinning force calculation,Ti(C,N)particles play the more important role in the pinning effect on the prior austenite grain growth.Based on the regression analysis by the MATLAB results,the predicted values of PAGS at different heat inputs are well fitted with the experimental data.展开更多
Nano-scaled Ti-B-N coatings could be produced by inductively coupled plasma (ICP) assisted magnetron spurtering. The properties and microstructure of the coating can be changed drastically by applying ICP to conventio...Nano-scaled Ti-B-N coatings could be produced by inductively coupled plasma (ICP) assisted magnetron spurtering. The properties and microstructure of the coating can be changed drastically by applying ICP to conventional magnetron sputtering. In this work, an internal type rf ICP process is used. The core of this technology is the efficient production and control of self-depositing ions and reactive gas ions by an induced electric field. Ti-B-N coatings were prepared by using a TiB2 target and a gas mixture of N2 and Ar at 200 ℃ and a pressure of 60 mTorr. In addition to ICP, the effect of the substrate bias voltage on the structure and properties of the coating was investigated. By applying ICP and a bias voltage to the substrate the hardness of the Ti-B-N coating is increased by more than 75 GPa, as a result of enhanced ionization in the plasma. The Ti-B-N coating, which has the highest hardness, shows the best surface uniformity and a very dense structure with a grain size of 3 nm. This sample also shows a high crystallinity compared to the coating prepared using other deposition parameters.展开更多
Cu nanoparticles were fabricated by ball milling with the anhydrous alcohol as dispersant. The size and figure of Cu nanoparticles were characterized by X-ray diffractometry and transmission electron microscopy. The t...Cu nanoparticles were fabricated by ball milling with the anhydrous alcohol as dispersant. The size and figure of Cu nanoparticles were characterized by X-ray diffractometry and transmission electron microscopy. The tribological properties of adding Cu and MoS2 nanoparticles to the pure grease were measured on MM-200 tester, compared with the single additive and pure grease. The results show the size of Cu nanoparticles is about 50 nm. The surface with lubricant added nanopowder as additive possesses a remarkable decrease in wear volume. The friction coefficient and wear volume of lubricant mixed with 5% copper and 30% disulfide molybdenum nanoparticles are 0.09 and 1.80mm3, respectively. This mixed additive can not only increase the ability of supporting heavy load but repair the microscopic channels and cracks on the wear surface. Under higher load and long period of time, this lubricant has the characteristics of self-repairing, occluding resistance and ability of enduring higher temperature.展开更多
Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that...Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that copper segregation and enrichment at interfacial layer between oxidized surface and steel matrix is the key factor, which results in microcracks and edge flaws on the strips. The primary considerations to prevent detrimental effects from Cu include controlling copper content in proper level, higher soaking temperature and non-oxidizable atmosphere during soaking. Copper sulfide precipitates with nanometers in size were observed, they may be beneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips is discussed.展开更多
Nanoengineered carbon bonded refractories as well as fine grained carbon free refractories with improved thermal shock performance are presented in terms of this contribution.
The porous solids 2—50 nm in pore diameter and larger than 40% of porosity are de-fined as the mesoporous solid.Their pore number is up to 10<sup>19</sup>/g and the specific surfacearea up to 900m<sup&...The porous solids 2—50 nm in pore diameter and larger than 40% of porosity are de-fined as the mesoporous solid.Their pore number is up to 10<sup>19</sup>/g and the specific surfacearea up to 900m<sup>2</sup>/g.Therefore,the mesoporous solids have important application in thecatalysis,sorption and separation,etc.According to the arrangement of the pores。展开更多
基金supported by the National Natural Science Foundation of China(U1960202).
文摘The effect of Mo on nano-scaled particles,prior austenite grains and impact toughness of coarse-grained heat-affected zone(CGHAZ)in offshore engineering steels with Ca deoxidation was studied.The heat-affected zone(HAZ)toughness of Mo16 steel is obviously higher than that of Mo8 steel at all the heat inputs of 50,100,150 and 200 kJ/cm,with HAZ toughness of both steels decreased with increasing the welding heat input.When the Mo content is increased from 0.08 to 0.16%,the size of nano-scaled particles in HAZ is decreased from 18 to 15 nm,and their number density is increased from 0.7 to 0.9μm^(−2).Thus,the Zener pinning force is increased,and the prior austenite grain size(PAGS)is decreased,leading to the improved HAZ toughness.Microstructural characterizations show that the nano-scaled particles in both steels are Ti(C,N)with the solute elements of Nb and Mo.The calculated critical particle size of TiN is 10.2 and 8.4 nm in Mo8 and Mo16 steels at 1350℃,and the particles larger than the critical size are stable during the welding process.From the Zener pinning force calculation,Ti(C,N)particles play the more important role in the pinning effect on the prior austenite grain growth.Based on the regression analysis by the MATLAB results,the predicted values of PAGS at different heat inputs are well fitted with the experimental data.
文摘Nano-scaled Ti-B-N coatings could be produced by inductively coupled plasma (ICP) assisted magnetron spurtering. The properties and microstructure of the coating can be changed drastically by applying ICP to conventional magnetron sputtering. In this work, an internal type rf ICP process is used. The core of this technology is the efficient production and control of self-depositing ions and reactive gas ions by an induced electric field. Ti-B-N coatings were prepared by using a TiB2 target and a gas mixture of N2 and Ar at 200 ℃ and a pressure of 60 mTorr. In addition to ICP, the effect of the substrate bias voltage on the structure and properties of the coating was investigated. By applying ICP and a bias voltage to the substrate the hardness of the Ti-B-N coating is increased by more than 75 GPa, as a result of enhanced ionization in the plasma. The Ti-B-N coating, which has the highest hardness, shows the best surface uniformity and a very dense structure with a grain size of 3 nm. This sample also shows a high crystallinity compared to the coating prepared using other deposition parameters.
文摘Cu nanoparticles were fabricated by ball milling with the anhydrous alcohol as dispersant. The size and figure of Cu nanoparticles were characterized by X-ray diffractometry and transmission electron microscopy. The tribological properties of adding Cu and MoS2 nanoparticles to the pure grease were measured on MM-200 tester, compared with the single additive and pure grease. The results show the size of Cu nanoparticles is about 50 nm. The surface with lubricant added nanopowder as additive possesses a remarkable decrease in wear volume. The friction coefficient and wear volume of lubricant mixed with 5% copper and 30% disulfide molybdenum nanoparticles are 0.09 and 1.80mm3, respectively. This mixed additive can not only increase the ability of supporting heavy load but repair the microscopic channels and cracks on the wear surface. Under higher load and long period of time, this lubricant has the characteristics of self-repairing, occluding resistance and ability of enduring higher temperature.
文摘Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that copper segregation and enrichment at interfacial layer between oxidized surface and steel matrix is the key factor, which results in microcracks and edge flaws on the strips. The primary considerations to prevent detrimental effects from Cu include controlling copper content in proper level, higher soaking temperature and non-oxidizable atmosphere during soaking. Copper sulfide precipitates with nanometers in size were observed, they may be beneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips is discussed.
文摘Nanoengineered carbon bonded refractories as well as fine grained carbon free refractories with improved thermal shock performance are presented in terms of this contribution.
文摘The porous solids 2—50 nm in pore diameter and larger than 40% of porosity are de-fined as the mesoporous solid.Their pore number is up to 10<sup>19</sup>/g and the specific surfacearea up to 900m<sup>2</sup>/g.Therefore,the mesoporous solids have important application in thecatalysis,sorption and separation,etc.According to the arrangement of the pores。
