The crystal structure of the title complex, Mo(CO)4(NNP), (NNP=2-(N-cyclohexyl- N-diphenylphosphinomethyl)aminopyridine) has been determined, and its crystallographic data are as follows: triclinic, space group P , a ...The crystal structure of the title complex, Mo(CO)4(NNP), (NNP=2-(N-cyclohexyl- N-diphenylphosphinomethyl)aminopyridine) has been determined, and its crystallographic data are as follows: triclinic, space group P , a = 9.135(1), b = 9.772(1), c = 17.000(2) , a = 76.377(2), b = 78.333(2), g = 67.243(2)? Mr = 582.44, V = 1349.7(3) 3, Z = 2, Dc = 1.433 g/cm3, m(MoKa) = 0.581 mm-1 and F(000) = 596. A total of 5614 reflections were collected in the range of 2.30< q < 25.03? of which 4721 were independent (Rint = 0.0176) and 4159 observed reflections (I ≥ 2s(I)) were used in the refinement. R = 0.0326 and wR = 0.0867. The Mo centre is six-coordinated by four carbonyls (MoC 1.938(4), 2.003(4), 2.019(4), 2.035(4) ) and P, N atoms from the ligand (MoP 2.4812(8), MoN 2.349(3) ?. The coordination geometry of the complex can be described as an octahedron.展开更多
The diagnostic methods for the profile of the radiation source were estab-lished at first based on the pinhole imaging principle. In this paper, the relationships among various parameters of the gamma-rays crammer suc...The diagnostic methods for the profile of the radiation source were estab-lished at first based on the pinhole imaging principle. In this paper, the relationships among various parameters of the gamma-rays crammer such as the modulation transfer function (MTF), the noise power spectrum (NPS), the signal-noise ratio (SNR) and the detective quantum efficiency (DQE) are developed and studied experimentally on the cobalt radiation source. The image diagnostic system is consisting with rays-fluorescence convertor (YAG crystal), optical imaging system, MCP image intensifier, CCD camera and other devices. The spatial resolution of the modulation transfer function (MTF) at 10% intensity was measured as 1 lp/mm by knife-edge method. The quantum of the measurement system is about 150 under weak radiation condition due to the single particle detection efficiency of the system. The dynamic range was inferred preliminarily as about 437. The required radiation intensity was calculated using the experiment result for the (SNR) = 1, 5, 10, respectively. The theoretical investigation results show that the radiation image with (SNR) = 1 can be only obtained when the pinhole diameter is 0.7 mm, object distance and image distance are both 200 cm, and the radiation intensity is about 1.0 × 1012 Sr-1·cm-2.展开更多
CVD growth of uniform conformal polycrystalline diamond (PCD) coatings over complex three dimensional structures is very important material processing technique. It has been found that the nucleation and subsequent gr...CVD growth of uniform conformal polycrystalline diamond (PCD) coatings over complex three dimensional structures is very important material processing technique. It has been found that the nucleation and subsequent growth period is very critical for successful development of CVD diamond based technologies. There are many methods of enhancing diamond nucleation on foreign substrates-ultrasonic treatment with diamond seed suspension being the best among them. A combination of ultrasonic seeding (US) technique with prior treatment (PT) of the substrate under CVD diamond growth conditions for brief period of time, has found to be very effective in enhancing the diamond nucleation during CVD growth—together they are known as NNP. But successive usage of the same seeding suspension up to ten cycles deteriorates the seeding efficiency. 6th seeding cycle onwards the silicon substrates are barely get covered by diamond crystallites. Five different diamond micron grits were used for seeding the silicon substrates and it is observed that US with the sub-micron particles (0.25 μm) is very effective in efficient nucleation of PCD on Si substrates. PT of the substrate somewhat negates the effect of successive use of the same seeding slurry but it is best to avoid recycling of the same seeding suspension using micron size diamond grits.展开更多
基金This work was supported by the National Natural Science Foundation of China (No. 20102003)
文摘The crystal structure of the title complex, Mo(CO)4(NNP), (NNP=2-(N-cyclohexyl- N-diphenylphosphinomethyl)aminopyridine) has been determined, and its crystallographic data are as follows: triclinic, space group P , a = 9.135(1), b = 9.772(1), c = 17.000(2) , a = 76.377(2), b = 78.333(2), g = 67.243(2)? Mr = 582.44, V = 1349.7(3) 3, Z = 2, Dc = 1.433 g/cm3, m(MoKa) = 0.581 mm-1 and F(000) = 596. A total of 5614 reflections were collected in the range of 2.30< q < 25.03? of which 4721 were independent (Rint = 0.0176) and 4159 observed reflections (I ≥ 2s(I)) were used in the refinement. R = 0.0326 and wR = 0.0867. The Mo centre is six-coordinated by four carbonyls (MoC 1.938(4), 2.003(4), 2.019(4), 2.035(4) ) and P, N atoms from the ligand (MoP 2.4812(8), MoN 2.349(3) ?. The coordination geometry of the complex can be described as an octahedron.
文摘The diagnostic methods for the profile of the radiation source were estab-lished at first based on the pinhole imaging principle. In this paper, the relationships among various parameters of the gamma-rays crammer such as the modulation transfer function (MTF), the noise power spectrum (NPS), the signal-noise ratio (SNR) and the detective quantum efficiency (DQE) are developed and studied experimentally on the cobalt radiation source. The image diagnostic system is consisting with rays-fluorescence convertor (YAG crystal), optical imaging system, MCP image intensifier, CCD camera and other devices. The spatial resolution of the modulation transfer function (MTF) at 10% intensity was measured as 1 lp/mm by knife-edge method. The quantum of the measurement system is about 150 under weak radiation condition due to the single particle detection efficiency of the system. The dynamic range was inferred preliminarily as about 437. The required radiation intensity was calculated using the experiment result for the (SNR) = 1, 5, 10, respectively. The theoretical investigation results show that the radiation image with (SNR) = 1 can be only obtained when the pinhole diameter is 0.7 mm, object distance and image distance are both 200 cm, and the radiation intensity is about 1.0 × 1012 Sr-1·cm-2.
文摘CVD growth of uniform conformal polycrystalline diamond (PCD) coatings over complex three dimensional structures is very important material processing technique. It has been found that the nucleation and subsequent growth period is very critical for successful development of CVD diamond based technologies. There are many methods of enhancing diamond nucleation on foreign substrates-ultrasonic treatment with diamond seed suspension being the best among them. A combination of ultrasonic seeding (US) technique with prior treatment (PT) of the substrate under CVD diamond growth conditions for brief period of time, has found to be very effective in enhancing the diamond nucleation during CVD growth—together they are known as NNP. But successive usage of the same seeding suspension up to ten cycles deteriorates the seeding efficiency. 6th seeding cycle onwards the silicon substrates are barely get covered by diamond crystallites. Five different diamond micron grits were used for seeding the silicon substrates and it is observed that US with the sub-micron particles (0.25 μm) is very effective in efficient nucleation of PCD on Si substrates. PT of the substrate somewhat negates the effect of successive use of the same seeding slurry but it is best to avoid recycling of the same seeding suspension using micron size diamond grits.
