Lithium-ion conductor Liz.3Alo.3Ti1.7（P04）3 with an ultrapure NASICON-type phase is syn- thesized by a 1,2-propylene glycol （1,2-PG）-assisted sol-gel method and characterized by differential thermal analysis-therm...Lithium-ion conductor Liz.3Alo.3Ti1.7（P04）3 with an ultrapure NASICON-type phase is syn- thesized by a 1,2-propylene glycol （1,2-PG）-assisted sol-gel method and characterized by differential thermal analysis-thermo gravimetric analysis, X-ray diffraction, scanning elec- tron microscopy, electrochemical impedance spectroscopy, and chronoamperornetry test. Due to the use of 1,2-PG, a homogeneous and light yellow transparent precursor solu- tion is obtained without the precipitation of Ti4＋ and A13＋ with PO43- Well crystallized Lil.3Alo.3Til.7（PO4）3 can be prepared at much lower temperatures from 850 ~C to 950 ~C within a shorter synthesis time compared with that prepared at a temperature above 1000 ~C by a conventional solid-state reaction method. The lithium ionic conductivity of the sintered pellets is up to 0.3 mS/cm at 50 ℃ with an activation energy as low as 36.6 k J/tool for the specimen pre-sintered at 700 ℃ and sintered at 850 ℃. The high conductivity, good chemi- cal stability and easy fabrication of the Li1.3Al0.3Ti1.7（PO4）a provide a promising candidate as solid electrolyte for all-solid-state Li-ion rechargeable batteries.展开更多
文摘Lithium-ion conductor Liz.3Alo.3Ti1.7（P04）3 with an ultrapure NASICON-type phase is syn- thesized by a 1,2-propylene glycol （1,2-PG）-assisted sol-gel method and characterized by differential thermal analysis-thermo gravimetric analysis, X-ray diffraction, scanning elec- tron microscopy, electrochemical impedance spectroscopy, and chronoamperornetry test. Due to the use of 1,2-PG, a homogeneous and light yellow transparent precursor solu- tion is obtained without the precipitation of Ti4＋ and A13＋ with PO43- Well crystallized Lil.3Alo.3Til.7（PO4）3 can be prepared at much lower temperatures from 850 ~C to 950 ~C within a shorter synthesis time compared with that prepared at a temperature above 1000 ~C by a conventional solid-state reaction method. The lithium ionic conductivity of the sintered pellets is up to 0.3 mS/cm at 50 ℃ with an activation energy as low as 36.6 k J/tool for the specimen pre-sintered at 700 ℃ and sintered at 850 ℃. The high conductivity, good chemi- cal stability and easy fabrication of the Li1.3Al0.3Ti1.7（PO4）a provide a promising candidate as solid electrolyte for all-solid-state Li-ion rechargeable batteries.
