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Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents 被引量:2
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作者 Hossein Ghasemzadeh Maryam Dargahi +1 位作者 Ghazaleh Eyvazi Bahman Vasheghani Farahani 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2019年第5期444-450,共7页
A novel nanomagnetic organogel was synthesized by in situ emulsion polymerization-crosslinking method using dodecyl methacrylate(DDMA) and styrene(St) as monomers, divinylbenzene(DVB) as a crosslinking agent, azobisis... A novel nanomagnetic organogel was synthesized by in situ emulsion polymerization-crosslinking method using dodecyl methacrylate(DDMA) and styrene(St) as monomers, divinylbenzene(DVB) as a crosslinking agent, azobisisobutyronitrile(AIBN) as an initiator, and Fe_3O_4 as a nanomagnetic particle. Modification of the network was carried out by inclusion of the multi-walled carbon nanotubes(MWCNT) into the organogel matrix. The structure of the nanocomposite was characterized using FTIR spectroscopy, SEM,TEM, TGA/DTG, VSM, and BET analysis. The effects of various parameters such as the amount of crosslinker, initiator, Fe_3O_4, and reaction time as well as monomer ratio on the oil absorption of the organogel were studied. The synthesized organogel can absorb about35.5, 22.1, 29.86, 14.58, 17.6, 15.3, and 13.7 g·g^(-1) of CHCl_3, toluene, CH_2Cl_2, hexane, crude oil, gasoline, and diesel oil, under the optimized polymerization conditions, respectively. The nanocomposite organogels can be easily separated by a magnetic field after absorption of organic solvents. 展开更多
关键词 nanomagnetic ORGANOGEL Dodecyl METHACRYLATE STYRENE CROSSLINKING MWCNT
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Nanomagnetism:Principles,nanostructures,and biomedical applications
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作者 杨策 侯仰龙 高松 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第5期1-8,共8页
Nanomagnetism is the origin of many unique properties in magnetic nanomaterials that can be used as building blocks in information technology, spintronics, and biomedicine. Progresses in nanomagnetic principles, disti... Nanomagnetism is the origin of many unique properties in magnetic nanomaterials that can be used as building blocks in information technology, spintronics, and biomedicine. Progresses in nanomagnetic principles, distinct magnetic nanostructures, and the biomedical applications of nanomagnetism are summarized. 展开更多
关键词 nanomagnetISM magnetic materials magnetic resonance imaging (MRI) magnetic hyperthermia
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Nanomagnet-facilitated pharmaco-compatibility for cancer diagnostics:Underlying risks and the emergence of ultrasmall nanomagnets
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作者 Divya S.Parimi Yamini Gupta +3 位作者 Sreekar Marpu Chandra S.Bhatt Tharun K.Bollu Anil K.Suresh 《Journal of Pharmaceutical Analysis》 SCIE CAS CSCD 2022年第3期365-379,共15页
Cancer therapy is a fast-emerging biomedical paradigm that elevates the diagnostic and therapeutic potential of a nanovector for identification,monitoring,targeting,and post-treatment response analysis.Nanovectors of ... Cancer therapy is a fast-emerging biomedical paradigm that elevates the diagnostic and therapeutic potential of a nanovector for identification,monitoring,targeting,and post-treatment response analysis.Nanovectors of superparamagnetic iron oxide nanoparticles(SPION)are of tremendous significance in cancer therapy because of their inherited high surface area,high reactivity,biocompatibility,superior contrast,and magnetic and photo-inducibility properties.In addition to a brief introduction,we summarize various progressive aspects of nanomagnets pertaining to their production with an emphasis on sustainable biomimetic approaches.Post-synthesis particulate and surface alterations in terms of pharmaco-affinity,liquid accessibility,and biocompatibility to facilitate cancer therapy are highlighted.SPION parameters including particle contrast,core-fusions,surface area,reactivity,photosensitivity,photodynamics,and photothermal properties,which facilitate diverse cancer diagnostics,are discussed.We also elaborate on the concept of magnetism to selectively focus chemotherapeutics on tumors,cell sorting,purification of bioentities,and elimination of toxins.Finally,while addressing the toxicity of nanomaterials,the advent of ultrasmall nanomagnets as a healthier alternative with superior properties and compatible cellular interactions is reviewed.In summary,these discussions spotlight the versatility and integration of multitasking nanomagnets and ultrasmall nanomagnets for diverse cancer theragnostics. 展开更多
关键词 nanomagnetS Biomimetics Utrasmall-SPIONs MAGNETIZATION Core-fusion Cancer theragnostics
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Calculation of Magnetic Configuration and Resistance for Nanomagnets
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作者 LIHai-Jin TAORul-Bao 《Communications in Theoretical Physics》 SCIE CAS CSCD 2002年第5期627-630,共4页
Based on a classical Heisenberg lattice model with dipole-dipole interaction and the method of spin dynamic simulation, the magnetic configurations (MC), hysteresis loops (HL) and magnetic resistance (MR) of the nanom... Based on a classical Heisenberg lattice model with dipole-dipole interaction and the method of spin dynamic simulation, the magnetic configurations (MC), hysteresis loops (HL) and magnetic resistance (MR) of the nanomagnets with different geometries, such as circle, square and rectangle, are studied for different directions of applied field. In the case of perpendicular field to the plane, the magnetization and MR are reversible and have not hysteresis. When the field is applied in the plane, the HL is irreversible and is qualitatively well agreeable with the current experimental results. The MR loop is also irreversible and appears two peaks distributed at two sides around zero field. The peaks of magnetic resistance are relative to the vortex state or similar configuration. Large easy-axis anisotropy will suppress the MC anisotropy, and the large magnetoresistance effect disappears. 展开更多
关键词 spin dynamics nanomagnet magnetic resistance
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Non-Abelian Geometric Manipulation of a Crystal of Molecular Nanomagnet Mn_(12)
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作者 俞立先 陈刚 梁九卿 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第8期382-384,共3页
Based on the strong magnetic anisotropy along the symmetry of the crystal, we construct a U(2) non-Abelian gauge potential for the molecular nanomagnet Mn12 by varying the external magnetic field adiabatically. More... Based on the strong magnetic anisotropy along the symmetry of the crystal, we construct a U(2) non-Abelian gauge potential for the molecular nanomagnet Mn12 by varying the external magnetic field adiabatically. Moreover, the non-Abelian geometric phase and the unitary matrix operation, which are tile key steps to realize the universal holonomic quantum computing in the degenerate subspace, are also obtained by means of choosing an evolution path properly. 展开更多
关键词 molecular nanomagnet non-Abelian gauge potential geometric manipulation
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Highly efficient and regioselective thiocyanation of aromatic amines,anisols and activated phenols with H_2O_2/NH_4SCN catalyzed by nanomagnetic Fe_3O_4
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作者 Dariush Khalili 《Chinese Chemical Letters》 SCIE CAS CSCD 2015年第5期547-552,共6页
A new method employing magnetic nanoparticles Fe3O4 as a catalyst and H2O2 as a green oxidant is developed for the oxidative thiocyanation of aromatic amines, anisols and activated phenols with high yields under mild ... A new method employing magnetic nanoparticles Fe3O4 as a catalyst and H2O2 as a green oxidant is developed for the oxidative thiocyanation of aromatic amines, anisols and activated phenols with high yields under mild reaction conditions. The catalyst could be easily recovered from the reaction mixture using an external magnet and reused in several reaction cycles without loss of activity. 展开更多
关键词 Arenes Green oxidant Hydrogen peroxide nanomagnetic Fe3O4 NH4SCN Thiocyaoation
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magnetic tunnel junctions spin-transfer torque magneto-resistance nanomagnet dynamics
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作者 Nader Ghobadi Reza Daqiq 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第2期254-258,共5页
We investigate bias and different barrier thicknesses effects on quantities related to spin and charge currents in MgO-based magnetic tunnel junctions. Using the non-Equilibrium Green's function formalism, we demonst... We investigate bias and different barrier thicknesses effects on quantities related to spin and charge currents in MgO-based magnetic tunnel junctions. Using the non-Equilibrium Green's function formalism, we demonstrate that the in-plane and out-of-plane components of the spin-transfer torque have asymmetric and symmetric behaviors respectively. Magneto-resistance also decreases with increasing barrier thickness. The Landau–Lifshits–Gilbert equation describes the dynamics of the magnetization made by spin transfer torque. Increasing in spin current above its critical value or smaller the magnet reduces the switching time which is major result for making of new memory devices. 展开更多
关键词 Magneto-Transport and nanomagnet Dynamics in MgO-Based Magnetic Tunnel Junctions(MTJs)
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Response Surface Methodology Optimization of Dibenzothiophene Biodesulfurization in Model Oil by Nanomagnet Immobilized Rhodococcus Erythropolis R1
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作者 Zahra Etemadifar Peyman Derikvand +1 位作者 Giti Emtiazi Mohammad H. Habibi 《材料科学与工程(中英文B版)》 2014年第10期322-330,共9页
关键词 细胞固定化 响应曲面法 二苯并噻吩 红串红球菌 纳米磁体 统计优化 生物脱硫 磁性纳米粒子
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Near-infrared emissive Er(Ⅲ)and Yb(Ⅲ)molecular nanomagnets in metal-organic chains functionalized by octacyanidometallates(Ⅳ)
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作者 Robert Jankowski Jakub JZakrzewski +3 位作者 Olga Surma Shin-ichi Ohkoshi Szymon Chorazy Barbara Sieklucka 《Inorganic Chemistry Frontiers》 2019年第9期2423-2434,共12页
The self-assembly of lanthanide(3+)ions with pyrazine N,N′-dioxide(pzdo)and bis(triphenylphosphine)iminium(PPN+)salts of diamagnetic octacyanidometallates of MoIV and WIV results in one-dimensional(PPN)[LnIII(pzdo)2(... The self-assembly of lanthanide(3+)ions with pyrazine N,N′-dioxide(pzdo)and bis(triphenylphosphine)iminium(PPN+)salts of diamagnetic octacyanidometallates of MoIV and WIV results in one-dimensional(PPN)[LnIII(pzdo)2(MeOH)0.3(H2O)3.7][MIV(CN)8]·7.7H2O·2MeOH(Ln=Er and Yb;M=Mo and W)coordination networks.They are constructed of zigzag metal–organic{LnIII(μ-pzdo)}n chains with terminal[MIV(CN)8]4−metalloligands attached to the LnIII centres.Both Er-and Yb-containing frameworks exhibit field-induced slow magnetic relaxation originating from the field-dependent equilibrium between quantum tunnelling of magnetization and the direct process along with the temperature-dependent Raman and Orbach relaxation processes.Transition metal substitution on[MIV(CN)8]4−sites modifies the intrinsic magnetic anisotropy of lanthanides,as depicted by the subtle change of thermal energy barriers of Orbach relaxation in Er-based systems,while it significantly affects Raman relaxation due to the modulated phonon mode scheme.All reported compounds exhibit strong visible light absorption due to a series of electronic transitions of pzdo ligands and[M(CN)8]4−ions and the appearance of low energy anion–π charge transfer band involving pzdo and octacyanidometallates.These charge transfer states were utilized in achieving the sensitized near-infrared photoluminescence of Er^(Ⅲ) and Yb^(Ⅲ) centers;thus,the energy transfer process is strongly dependent on the nature of the metal centre in the[M^(Ⅳ)(CN)8]4−ion.The W(Ⅳ)-pzdo system is a good sensitizer for Er^(Ⅲ),while the Mo(Ⅳ)-pzdo unit is better for Yb^(Ⅲ) emission which can be rationalized in terms of the positions of energy levels of their respective donor states.Therefore,we report NIR emissive Er^(Ⅲ) and Yb^(Ⅲ) single-molecule magnets with tunable magnetic and optical properties,uncovering the crucial role of octacyanidometallates and their anion–π interactions with pzdo ligands. 展开更多
关键词 octacyanidometallates self assembly zigzag metal organic lniii pzdo n er metal organic chains diamagnetic octacyanidometallates molecular nanomagnets near infrared emissive
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Eu(Ⅲ)dilution of Er(Ⅲ)and Yb(Ⅲ)molecular nanomagnets as a route to improving their magnetic features and creating a link with optical thermometry
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作者 Aleksander Hoffman Maja Romanowska +3 位作者 Mikolaj Zychowicz Sebastian Baś Jakub J.Zakrzewski Szymon Chorazy 《Inorganic Chemistry Frontiers》 2026年第8期3553-3573,共21页
Lanthanide(Ⅲ)single-molecule magnets(SMMs)are a tool for the combination of molecular nanomagnetism with luminescent thermometry,opening the pathway not only for broadened multifunctionality but also for the optical ... Lanthanide(Ⅲ)single-molecule magnets(SMMs)are a tool for the combination of molecular nanomagnetism with luminescent thermometry,opening the pathway not only for broadened multifunctionality but also for the optical self-monitoring of temperature in SMM-based systems.Usually,this goal is realized by exploring the intrinsic properties of a single lanthanide(Ln)ion.We present an innovative strategy based on embedding magnetically anisotropic Ln(Ⅲ)centers into a red-emissive coordination system based on Eu(Ⅲ)complexes of a nonmagnetic ground state.This concept is presented for novel cyanido-bridged chains,{[LnⅢ(dppmO_(2))_(3)][AgI(CN)_(2)]}[OTf]_(2)(Ln=Eu,EuAg;Ln=Er,ErAg;Ln=Yb,YbAg;Ln=Er_(0.05)Eu_(0.95),Er@EuAg;Ln=Yb_(0.04)Eu_(0.96),Yb@EuAg;dppmO_(2)=bis(diphenylphosphino)methane dioxide;OTf=trifluoromethanesulfonate).The Ln(Ⅲ)coordination sphere,consisting of O,O-bidentate dppmO_(2) ligands occupying the equatorial positions and two axially aligned cyanido bridges,generates the distinct SMM characteristics of Er(Ⅲ)/Yb(Ⅲ)centers.Alternatively,the strong photoluminescence of Eu(Ⅲ)in EuAg exhibits pronounced thermal variation of the excitation spectrum,which is employed for ratiometric optical thermometry,revealing a relative thermal sensitivity(Sr)of up to 2.1%K^(−1) at 55 K and a good thermometric response below 110 K.The incorporation of Er(Ⅲ)/Yb(Ⅲ)centers into the Eu(Ⅲ)-based framework leads to heterotrimetallic Er@EuAg and Yb@EuAg systems,which link the SMM features with luminescent thermometry.Both physical properties are enhanced upon mixing of the Ln(Ⅲ)centers,as depicted by the slowdown of magnetic relaxation,especially for Er(Ⅲ),due to the Eu(Ⅲ)-induced weakening of the quantum tunneling of magnetization,which is accompanied by the improved thermometric response,including an increase in the maximal Sr to 3.3%K^(−1) and broadening of its operating range to 150 K,due to the structural distortion induced by Er(Ⅲ)/Yb(Ⅲ)centers. 展开更多
关键词 luminescent thermometryopening optical thermometry er embedding magnetically anisotropic exploring intrinsic properties molecular nanomagnets broadened multifunctionality lanthanide single molecule magnets
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压控应变-自旋轨道矩协同调控的磁性随机存取存储器单元超低功耗翻转
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作者 郭宝军 杨晓阔 +3 位作者 豆树清 崔焕卿 夏永顺 危波 《物理学报》 北大核心 2026年第7期337-346,共10页
单一物理效应调控磁矩翻转,难以兼顾磁性随机存取存储器(MRAM)对“低能耗、高速度、高稳定性、全电学调控”的综合需求.为此,本文提出基于压控应变和自旋轨道矩(SOT)时钟协同调控的MRAM单元结构,其由磁性隧道结、重金属材料和压电衬底构... 单一物理效应调控磁矩翻转,难以兼顾磁性随机存取存储器(MRAM)对“低能耗、高速度、高稳定性、全电学调控”的综合需求.为此,本文提出基于压控应变和自旋轨道矩(SOT)时钟协同调控的MRAM单元结构,其由磁性隧道结、重金属材料和压电衬底构成.通过建立多铁异质结磁化动力学模型,采用MuMax3微磁学仿真研究压控应变和SOT时钟作用下多铁纳磁体的磁矩翻转特性.结果表明:协同调控克服了单一时钟调控的缺陷,可在零磁场下实现多铁纳磁体磁矩的确定性翻转,提高了器件工作的可靠性;相比单一时钟调控的高能耗,协同调控能耗更低,单个周期耗能约6.4 aJ/bit,较传统SOT调控能耗降低3个数量级,且写入速度更快.本研究为低功耗MRAM设计及磁性存储应用提供了重要的理论指导和技术支撑. 展开更多
关键词 多铁纳磁体 压控应变 自旋轨道矩 协同作用
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A Unifi ed Geometric Rule for Designing Nanomagnetism in Graphene 被引量:4
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作者 Decai Yu Elizabeth M.Lupton +2 位作者 H.J.Gao Chao Zhang Feng Liu 《Nano Research》 SCIE EI CSCD 2008年第6期497-501,共5页
Based on the underlying graphene lattice symmetry and an itinerant magnetism model on a bipartite lattice,we propose a unifi ed geometric rule for designing graphene-based magnetic nanostructures:spins are parallel(fe... Based on the underlying graphene lattice symmetry and an itinerant magnetism model on a bipartite lattice,we propose a unifi ed geometric rule for designing graphene-based magnetic nanostructures:spins are parallel(ferromagnetic(FM))on all zigzag edges which are at angles of 0°and 120°to each other,and antiparallel(antiferromagnetic(AF))at angles of 60°and 180°.The rule is found to be consistent with all the systems that have been studied so far.Applying the rule,we predict several novel graphene-based magnetic nanostructures:0-D FM nanodots with the highest possible magnetic moments,1-D FM nanoribbons,and 2-D magnetic superlattices. 展开更多
关键词 nanomagnetISM graphene-based nanostructures magnetic ordering
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Nonreciprocal coherent coupling of nanomagnets by exchange spin waves 被引量:2
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作者 Hanchen Wang Jilei Chen +16 位作者 Tao Yu Chuanpu Liu Chenyang Guo Song Liu Ka Shen Hao Jia Tao Liu Jianyu Zhang Marco A.Cabero Z Qiuming Song Sa Tu Mingzhong Wu Xiufeng Han Ke Xia Dapeng Yu Gerrit E.W.Bauer Haiming Yu 《Nano Research》 SCIE EI CSCD 2021年第7期2133-2138,共6页
Nanomagnets are widely used to store information in non-volatile spintronic devices.Spin waves can transfer information with low-power consumption as their propagations are independent of charge transport.However,to d... Nanomagnets are widely used to store information in non-volatile spintronic devices.Spin waves can transfer information with low-power consumption as their propagations are independent of charge transport.However,to dynamically couple two distant nanomagnets via spin waves remains a major challenge for magnonics.Here we experimentally demonstrate coherent coupling of two distant Co nanowires by fast propagating spin waves in an yttrium iron garnet thin film with sub-50 nm wavelengths.Magnons in two nanomagnets are unidirectionally phase-locked with phase shifts controlled by magnon spin torque and spin-wave propagation.The coupled system is finally formulated by an analytical theory in terms of an effective non-Hermitian Hamiltonian.Our results are attractive for analog neuromorphic computing that requires unidirectional information transmission. 展开更多
关键词 SPINTRONICS nanomagnetS spin waves coherent coupling NONRECIPROCITY
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纳米磁粒子/醇协同强化流态冰浆相变储冷性能
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作者 王子彦 邢美波 许超 《化工新型材料》 北大核心 2026年第4期173-179,共7页
冰浆作为一种高效相变储冷介质,在储能领域具有广泛应用。针对冰浆相变过程中含冰率较低、冰晶分布不均匀等问题,提出采用丙三醇(GLY)与聚乙二醇包覆的Fe_(3)O_(4)纳米磁粒子复合体系改善冰浆的相变储冷性能。结果表明:纳米磁粒子/醇复... 冰浆作为一种高效相变储冷介质,在储能领域具有广泛应用。针对冰浆相变过程中含冰率较低、冰晶分布不均匀等问题,提出采用丙三醇(GLY)与聚乙二醇包覆的Fe_(3)O_(4)纳米磁粒子复合体系改善冰浆的相变储冷性能。结果表明:纳米磁粒子/醇复合添加剂可显著降低系统成核功,从而降低过冷度且强化相变过程的传热特性。醇的添加使复合体系接触角降低至2°以下。此外,纳米磁粒子/醇复合添加体系的含冰率相较于同浓度醇溶液提升了近3倍,其冰晶的平均粒径随醇浓度的增加呈下降趋势。表明纳米磁粒子/醇复合添加剂可以有效降低冰晶粒径,提高含冰率,从而增强冰浆储冷能力。 展开更多
关键词 冰浆 蓄冷 丙三醇 纳米磁粒子 添加剂
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应变调控双组分纳磁体辐射状磁涡旋极性可逆翻转
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作者 夏永顺 崔焕卿 +5 位作者 杨晓阔 郭宝军 豆树清 康艳 危波 梁卜嘉 《物理学报》 北大核心 2025年第16期429-436,共8页
辐射状磁涡旋因具有拓扑稳定性及纳米级尺寸特性,被视为磁电子器件中极具潜力的信息载体.然而,传统基于磁场或自旋极化电流的辐射状磁涡旋极性翻转方法面临能耗过高的问题.针对这一挑战,本文提出了一种基于多铁异质结构的新型无场调控方... 辐射状磁涡旋因具有拓扑稳定性及纳米级尺寸特性,被视为磁电子器件中极具潜力的信息载体.然而,传统基于磁场或自旋极化电流的辐射状磁涡旋极性翻转方法面临能耗过高的问题.针对这一挑战,本文提出了一种基于多铁异质结构的新型无场调控方案,该结构由双组分纳磁体(Terfenol-D/Ni)、重金属层及压电层复合构成.其内在对称性破缺特性可有效打破辐射状磁涡旋的圆环对称性,通过磁电耦合效应实现极性翻转的电压驱动调控.基于MuMax_(3)的电-力-磁多场耦合仿真表明,当双组分材料比例d_(TD):d_(Ni)=1:2,界面Dzyaloshinskii-Moriya相互作用(DMI)系数(D)在1.2 mJ/m^(2)—1.9 mJ/m^(2)范围内时,系统稳定呈现辐射状磁涡旋态;当D=1.7mJ/m^(2)时,仅需90 mV电压脉冲即实现对双组分纳磁体辐射状磁涡旋极性翻转,能耗较传统方法降低6个数量级(达aJ级别).通过瞬态磁化动态模拟与能量演化分析,研究揭示了该双组分多铁异质结构中辐射状磁涡旋极性翻转的物理机制:应变作用下的双材料体系能量竞争驱动磁矩重构,实现高效、超低能耗的极性翻转.该方案为磁涡旋存储器的片上集成提供了新路径,开创了非电流驱动型“电写”磁存储器件设计的新范式,在低功耗自旋电子学领域具有重要应用价值. 展开更多
关键词 辐射状磁涡旋 应变调控 纳磁体 磁电耦合
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纳米免疫磁珠富集猪肉中的盐酸克伦特罗 被引量:15
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作者 李超辉 熊勇华 +2 位作者 郭亮 吴科盛 梁语嫣 《食品科学》 EI CAS CSCD 北大核心 2013年第14期182-186,共5页
以生物素-链霉亲和素系统为介导,将克伦特罗单克隆抗体与纳米磁珠偶联制备免疫磁珠,建立特异性快速富集猪肉中盐酸克伦特罗的方法。将1mg偶联有23.9μg链霉亲和素(SA)的磁珠与220μg生物素化抗体反应,得到抗体偶联量为77.2μg/mg的免疫... 以生物素-链霉亲和素系统为介导,将克伦特罗单克隆抗体与纳米磁珠偶联制备免疫磁珠,建立特异性快速富集猪肉中盐酸克伦特罗的方法。将1mg偶联有23.9μg链霉亲和素(SA)的磁珠与220μg生物素化抗体反应,得到抗体偶联量为77.2μg/mg的免疫磁珠。免疫磁珠最佳吸附、洗脱条件为4mL 0.15mol/L盐酸在剧烈振荡条件下提取1g猪肉匀浆样品中的克伦特罗,提取液中加入0.25mg免疫磁珠在37℃,200r/min振荡吸附5~10min,100μL甲醇洗脱磁珠5min,洗脱液用PB稀释10倍后ELISA方法检测。加标实验结果表明,加标量为0.25~2ng/g时回收率大于80%,相对标准偏差为11.9%~15.7%;加标量为5ng/g时回收率降至61.2%,相对标准偏差为7.8%。 展开更多
关键词 克伦特罗 富集 纳米磁珠 猪肉
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纳米磁性多层膜的微波电磁特性研究 被引量:7
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作者 冯则坤 邓联文 何华辉 《功能材料》 EI CAS CSCD 北大核心 2004年第1期86-88,共3页
 采用射频磁控溅射法制备了FeCoB/SiO2纳米磁性多层膜,并对其微波特性进行研究。用微波谐振腔法测量了该薄膜的复磁导率,2GHz频率处复磁导率实部及虚部分别可达251和22.7。重点研究了多层膜结构中介质层厚度及薄膜总厚度对磁导率的影响...  采用射频磁控溅射法制备了FeCoB/SiO2纳米磁性多层膜,并对其微波特性进行研究。用微波谐振腔法测量了该薄膜的复磁导率,2GHz频率处复磁导率实部及虚部分别可达251和22.7。重点研究了多层膜结构中介质层厚度及薄膜总厚度对磁导率的影响,同时结合直流电阻率ρ、静态磁参数Bs、Hc的测量结果分析,探讨了纳米磁性多层膜的微波高磁导率机理,并提出了微波频率下获得高磁导率及低磁损耗的途径。实验结果也表明这种纳米磁性多层膜材料有望在高频平面变压器、平面电感器、薄膜电磁干扰抑制器等领域获得应用。 展开更多
关键词 纳米磁性薄膜 多层膜 结构 微波磁导率 射频磁控溅射
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纳米晶双相交换耦合永磁体(NdDy)_2(FeNb)_(14)B/α-Fe的制备、微结构及磁性能研究 被引量:7
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作者 杨仕清 王豪才 +2 位作者 张万里 龚捷 何世光 《稀土》 EI CAS CSCD 北大核心 1997年第5期38-40,50,共4页
利用熔体快淬工艺制备了成份为Nd8.16Dy1Fe85.26Nb1B4.58合金的条带,对由(NdDy)2(FeNb)14B和α-Fe组成的两相快淬带进行了微结构分析与表征,探讨了晶化温度和退火时间及Dy、Nb元素的... 利用熔体快淬工艺制备了成份为Nd8.16Dy1Fe85.26Nb1B4.58合金的条带,对由(NdDy)2(FeNb)14B和α-Fe组成的两相快淬带进行了微结构分析与表征,探讨了晶化温度和退火时间及Dy、Nb元素的添加对稀土粘结永磁体磁性能的影响。 展开更多
关键词 纳米 磁性材料 交换耦合 永磁体 稀土
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磁性纳米四氧化三铁选择性富集-电感耦合等离子体原子发射光谱测定砷 被引量:10
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作者 吴少雄 邢志 +2 位作者 陈红兵 王娟 冯璐 《分析化学》 SCIE EI CAS CSCD 北大核心 2009年第5期711-714,共4页
基于磁性纳米Fe3O4对砷的选择性富集作用,建立了电感耦合等离子体原子发射光谱(ICP-OES)测定水溶液中砷的方法。考察了溶液酸度、吸附时间、吸附剂用量、试液体积和共存离子等因素对不同形态砷分离富集效率的影响。结果表明,在pH2~10... 基于磁性纳米Fe3O4对砷的选择性富集作用,建立了电感耦合等离子体原子发射光谱(ICP-OES)测定水溶液中砷的方法。考察了溶液酸度、吸附时间、吸附剂用量、试液体积和共存离子等因素对不同形态砷分离富集效率的影响。结果表明,在pH2~10范围内,选用6.0 mg纳米Fe3O4定量富集,振荡2 min后,三价砷、五价砷、一甲基砷以及二甲基砷等均可被磁性纳米Fe3O4定量富集。线性范围为0.063~20 mg/L;检出限(3σ)为0.0189 mg/L;对砷标准溶液测定的相对标准偏差为1.27%(n=6)。用本方法对自来水中加入的砷标准溶液进行了测定,回收率为100.3%~104.8%。本方法简便快速,可用于复杂基体中低含量砷的富集分离和测定。 展开更多
关键词 纳米四氧化三铁 磁性分离富集 电感耦合等离子体原子发射光谱
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磁流变智能液场致微结构变化的Monte Carlo模拟 被引量:9
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作者 杨仕清 龚捷 +2 位作者 张万里 王瑞芳 王豪才 《原子与分子物理学报》 CAS CSCD 北大核心 1998年第3期411-415,共5页
从磁流变液中存在的各种相互作用势出发,对N=100个球形羰基铁颗粒均匀分布于一正方形二维体系之中的物理模型,利用MonteCarlo方法和Metroplis算法着重计算了磁流变智能液的场致微结构变化。计算结果表明,磁... 从磁流变液中存在的各种相互作用势出发,对N=100个球形羰基铁颗粒均匀分布于一正方形二维体系之中的物理模型,利用MonteCarlo方法和Metroplis算法着重计算了磁流变智能液的场致微结构变化。计算结果表明,磁流变液(MRF)的流变效应在外磁场中的变化是由于其MRF中磁性颗粒的成链团簇有序化所致。这与磁流变液在外磁场中熵的下降和对MRF的光学显微镜观察结果是一致的。 展开更多
关键词 磁流变液 微观相互作用势 链状团簇 MC模拟
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