SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。...SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。通过调节电极间隙(1~6 mm)和气压(150~350 k Pa),测量了气体在不同条件下的击穿电压及击穿电流波形,得到了气体的绝缘特性并与SF_6气体进行了对比分析。实验结果表明:纯净的c-C_4F_8气体的绝缘强度约为SF_6的1.3倍,体积比为1:1的c-C_4F_8/N_2混合气体的绝缘强度约为与SF_6的0.9倍。通过计算,c-C_4F_8/N_2混合气体的液化温度可以达到电力系统使用要求。考虑到c-C_4F_8气体对于环境的影响较小,使用c-C_4F_8/N_2混合气体作为替代SF_6的绝缘气体,有着良好的应用前景。展开更多
Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tire...Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tireference single and double excitation configuration interaction(MRSDCI)calculations with a double zeta plus polarization(DZ+P)basis set.Vertical excitation energy for these two electronic states is determined using MRSDCI/DZ+P calculations at the ground state equilibrium geometry.The oscillator strength for the X^1Σ+→ A ~1Π transition and the radiative lifetime for the A^1Π state are calculated based on the MRSDCI wavefunc- tions.展开更多
文摘SF_6因具有良好的绝缘效果而被广泛地应用于电力系统中。但同时,SF_6也是一种温室气体,随着环境问题日益恶化,人们迫切需要找到替代SF_6的绝缘气体。为此,通过实验研究了环境友好气体c-C_4F_8及c-C_4F_8/N_2混合气体替代SF_6的可行性。通过调节电极间隙(1~6 mm)和气压(150~350 k Pa),测量了气体在不同条件下的击穿电压及击穿电流波形,得到了气体的绝缘特性并与SF_6气体进行了对比分析。实验结果表明:纯净的c-C_4F_8气体的绝缘强度约为SF_6的1.3倍,体积比为1:1的c-C_4F_8/N_2混合气体的绝缘强度约为与SF_6的0.9倍。通过计算,c-C_4F_8/N_2混合气体的液化温度可以达到电力系统使用要求。考虑到c-C_4F_8气体对于环境的影响较小,使用c-C_4F_8/N_2混合气体作为替代SF_6的绝缘气体,有着良好的应用前景。
文摘Ab initio electronic structure calculations are reported for low-lying electronic states,X ~1Σ^+and A ~1Π of the N_2F^+ molecule.Geometric parameters for the ground state X ~1Σ^+ are predicted by means of mul- tireference single and double excitation configuration interaction(MRSDCI)calculations with a double zeta plus polarization(DZ+P)basis set.Vertical excitation energy for these two electronic states is determined using MRSDCI/DZ+P calculations at the ground state equilibrium geometry.The oscillator strength for the X^1Σ+→ A ~1Π transition and the radiative lifetime for the A^1Π state are calculated based on the MRSDCI wavefunc- tions.
